KR980002192A - 감압성 접착제 - Google Patents

감압성 접착제 Download PDF

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Publication number
KR980002192A
KR980002192A KR1019970025304A KR19970025304A KR980002192A KR 980002192 A KR980002192 A KR 980002192A KR 1019970025304 A KR1019970025304 A KR 1019970025304A KR 19970025304 A KR19970025304 A KR 19970025304A KR 980002192 A KR980002192 A KR 980002192A
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South Korea
Prior art keywords
sensitive adhesive
pressure sensitive
adhesive composition
group
allyl
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KR1019970025304A
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English (en)
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KR100466731B1 (ko
Inventor
야코부스 게 드훌루
디르크 크뤼토프
빌렌미엔 게 살로몬스
아드리아나 벨드호르스트
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마르코비츠 스티븐 에이치
헤르큘레스 인코포레이티드
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08—Cellulose derivatives
    • C08L1/26—Cellulose ethers
    • C08L1/28—Alkyl ethers
    • C08L1/284—Alkyl ethers with hydroxylated hydrocarbon radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08—Cellulose derivatives
    • C08L1/26—Cellulose ethers
    • C08L1/28—Alkyl ethers
    • C08L1/286—Alkyl ethers substituted with acid radicals, e.g. carboxymethyl cellulose [CMC]
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Adhesive Tapes (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

감압성 접착제(pressure sensitive adhesive, PSA) 조성물은 수용성 보호 콜로이드의 존재하에 에틸렌계 불포화 단량체로부터 유도된 수성 중합체 분산액의 라텍스 시스템을 포함한다. PSA조성물은 압력만의 인가하여 다른 기재에 용이하게 부착될 수 있는 각종의 제품의 제조에 사용될 수 있다.

Description

감압성 접착제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. a) 아크릴산, 메타크릴산, 부틸 아크릴레이트, 메틸 메타크릴레이트, 2-에틸헥실아크릴레이트, 아크릴산 에스테르, 스티렌, 비닐 에테르, 비닐, 비닐리덴 할라이드, N-비닐 피롤리돈, 에틸렌, C 3이상의 알파-올레핀, 알릴 아민, 포화 모노카복실산 및 이의 아미드의 알릴 에스테르, 프로필렌, 1-부텐, 1-펜탄, 1-헥센, 1-데센, 알릴 아민, 알릴 아세테이트, 알릴 프로피오네이트, 알릴 락테이트, 이들의 아미드, 이들의 혼합물, 1,3-부타디엔, 1,3-펜타디엔, 1,4-펜타디엔, 사이클로펜타디엔, 헥사디엔 이성체로 구성되는 군으로부터 선택된 하나 이상의 에틸렌계 불포화 단량체의 중합체, 및 b) 약 0.7의 카복실 치환도 하한을 갖는 카복시메틸셀룰로즈 및 그의 유도체, 하이드록시에틸셀룰로즈, 에틸 하이드록시에틸셀룰로즈, 메틸셀룰로즈, 메틸 하이드록시프로필셀룰로즈, 하이드록시프로필셀룰로즈, 폴리(아크릴산) 및 그의 알카리 금속염, 에톡실화 전분유도체, 나트륨 및 기타 알카리 금속 폴리아크릴레이트, 수용성 전분 글루(glue), 젤라틴, 수용성 알기네이트, 카제인, 아가, 천연 및 합성 검, 부분 및 완전 가수분해된 폴리(비닐 알콜), 폴리아크릴아미드, 폴리(비닐피롤리돈), 폴리(메틸 비닐에테르-말레산 무수물), 구아 및 그의 유도체, 젤라틴 및 카제인으로 구성되는 군으로부터 선택되고 약 75000미만의 분자량을 갖는, 라텍스 시스템 안정화에 효과적인 양의 수용성 보호 콜로이드를 포함하는 수성 유화 라텍스 시스템을 포함하는 감압성 접착제 조성물.
  2. 제1항에 있어서, 하나 이상의 기타 접착제 성분이 존재하는 감압성 접착제 조성물.
  3. 제2항에 있어서, 하나 이상의 기타 접착제 성분이 존재하는 감압성 접착제 조성물.
  4. 제3항에 있어서, 상기 접착제가 로진 에스테르, 로진산, 탄화수소 수지, 로진 에스테르계 수지 분산액, 로진산계 수진 분산액, 탄화수소 수지계 수지 분산액, 및 종래의 계면활성제 대신에 로진 비누로 유화된 상기 수지의 수지 분산액으로 구성되는 군으로부터 선택되는 감압성 접착제 조성물.
  5. 제2항에 있어서, 습윤제, 소포제, 농후제, 용매, 및 방부제로 구성되는 군으로부터 선택되는 하나 이상의 물질이 또한 존재하는 감압성 접착제 조성물.
  6. 제1항에 있어서, 중합체가 수용성 보호 콜로이드의 존재하에서 수성 유화 중합반응에 의해 중합된 감압성 접착제 조성물.
  7. 제1항에 있어서, 에틸렌계 불포화 단량체의 총함량을 기준으로 약 0.01 내지 약 4.0 중량%의 계면활성제를 추가로 포함하는 감압성 접착제 조성물.
  8. 제1항에 있어서, 보호 콜로이드의 분자량 상한이 약 75000인 감압성 접착제 조성물.
  9. 제1항에 있어서, 보호 콜로이드의 분자량 상한이 약 20000인 감압성 접착제 조성물.
  10. 제1항에 있어서, 상기 보호 콜로이드가 하이드록시에틸셀룰로즈, 에틸하이드록시에틸셀룰로즈, 약 0.7의 카복실 치환도 하한을 갖는 카복시메틸셀룰로즈, 메틸셀룰로즈, 메틸하이드록시프로필셀룰로즈, 하이드록시프로필셀룰로즈 및 이들의 혼합물로 구성되는 군으로부터 선택되는 셀룰로즈 에테르를 포함하는 감압성 접착제 조성물.
  11. 제10항에 있어서, 셀룰로즈 에테르가 약 0.7 내지 2.9의 카복실 치환도를 갖는 카복시메틸셀룰로즈를 포함하는 감압성 접착제 조성물.
  12. 제10항에 있어서, 셀룰로즈 에테르가 0.2 내지 2.0의 하이드록시에틸 몰치환도 및 0.1 내지 1.0의 카복시메틸 몰치환도를 갖는 카복시메틸하이드록시에틸셀룰로즈를 포함하는 감압성 접착제 조성물.
  13. 제1항에 있어서, 하나 이상의 에틸렌계 불포화 단량체가 아크릴산, 메타크릴산, 부틸 아크릴레이트, 메틸 메타크릴레이트, 2-에틸헥실 아크릴레이트, 아크릴산 에스테르, 스티렌, 1,3-부타디엔, 1,3-펜타디엔, 1,4-펜타디엔, 사이클로펜타디엔, 헥사디엔 이성체 및 이들의 혼합물로 구성되는 군으로부터 선택된 1종을 포함하는 감압성 접착제 조성물.
  14. 제1항에 있어서, 하나 이상의 에틸렌계 불포화 단량체가 비닐 에스테르, 비닐 에테르, 비닐, 비닐리덴할라이드, N-비닐 피롤리돈, 에틸렌, C3이상의 알파-올레핀, 알릴 아민, 포화모노카복실산 및 그의 아미드의 알릴 에스테르, 및 이들의 혼합물로 구성되는 군으로부터 선택된 1종을 포함하는 감압성 접착제 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970025304A 1996-06-18 1997-06-18 감압성접착제 KR100466731B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/664,606 US5834538A (en) 1996-06-18 1996-06-18 Pressure sensitive adhesives
US08/664,,606 1996-06-18
US08/664,606 1996-06-18

Publications (2)

Publication Number Publication Date
KR980002192A true KR980002192A (ko) 1998-03-30
KR100466731B1 KR100466731B1 (ko) 2005-12-21

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US (1) US5834538A (ko)
EP (1) EP0814140B1 (ko)
JP (1) JPH1060402A (ko)
KR (1) KR100466731B1 (ko)
AR (1) AR007418A1 (ko)
AT (1) ATE252145T1 (ko)
AU (1) AU727984B2 (ko)
BR (1) BR9703621A (ko)
CA (1) CA2207879A1 (ko)
CZ (1) CZ187997A3 (ko)
DE (1) DE69725511T2 (ko)
HU (1) HUP9701065A3 (ko)
ID (1) ID17829A (ko)
IL (1) IL121095A (ko)
MX (1) MX9704522A (ko)
NO (1) NO972791L (ko)
NZ (1) NZ328105A (ko)
PA (1) PA8432801A1 (ko)
PL (1) PL187497B1 (ko)
RU (1) RU2208030C2 (ko)
SG (1) SG64426A1 (ko)
TW (1) TW523539B (ko)

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AU2495897A (en) 1998-01-08
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