KR960705909A - 알파-술폰화 지방산 메틸에스테르 및 음이온성 계연활성제를 포함하는 액체 세제 조성물(liquid detergent compositions comprising salts of alpha sulfonated fatty acid methyl esters, and anionic surfactants) - Google Patents

알파-술폰화 지방산 메틸에스테르 및 음이온성 계연활성제를 포함하는 액체 세제 조성물(liquid detergent compositions comprising salts of alpha sulfonated fatty acid methyl esters, and anionic surfactants)

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KR960705909A
KR960705909A KR1019960701971A KR19960701971A KR960705909A KR 960705909 A KR960705909 A KR 960705909A KR 1019960701971 A KR1019960701971 A KR 1019960701971A KR 19960701971 A KR19960701971 A KR 19960701971A KR 960705909 A KR960705909 A KR 960705909A
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detergent composition
surfactant
alpha
mixture
salt
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KR100209789B1 (ko
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사지크 브랭코
라이클린 이어마
엘. 프랭크 브라이언
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제프리 더블유. 버틀렛
스테판 컴파니
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/37—Mixtures of compounds all of which are anionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/92—Sulfobetaines ; Sulfitobetaines

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

본 발명은 1개 이상의 음이온성 황산염 또는 술폰산염 계면활성제 및 마그네슘을 포함하는 세제 조성물에 관한 것이다.

Description

알파-술폰화 지방산 메틸에스테르 및 음이온성 계연활성제를 포함하는 액체 세제 조성물(LIQUIDDETERGENT COMPOSITIONS COMPRISING SALTS OF ALPHA SYLFONATED FATTY ACID METHYL ACID METHYL ESTERS, AND ANIONIC SYRFACTANTS)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (29)

  1. 혼합물로서, (a) 12~16개의 탄소원자를 갖는 알파-술폰화된 메틸 또는 에틸 에스테르 지방산의 1-염과 알파-술폰화된 지방산의 2-염이,1-염; 2-염의 비율이 최소한 2:1이 되도록 블렌딩된 굴수성 계면 활성제; (b) 음이온성 계면 활성제; (c) 보조제 포움 안정화 계면 활성제; 및 (d) Ca++및 Mg++로 이루어진 그룹으로부터 선택된 2가 양이온으로 이루어진 계면 활성제의 혼합물을 함유하고, 2가 양이온의 염으로서 조성물중에 존재되는 게면 활성제의 양이 계면 활성제 혼합물의 30중량% 이상이고, 굴수성 계면 활성제 대 음이온성 계면 활성제의 중량비가 1:1.5 내지 1:8이고, 조성물중의 계면 활성제의 혼합물의 양이 32 내지 90중량%임을 특징으로 하는 세제 조성물.
  2. 제1항에 있어서, 음이온성 계면 활성제가 C8내지 C15의 알킬기를 갖는 선형의 알킬 벤젠 술폰산염; C8내지 C18의 알킬기를 갖는 알킬 황산염, C8내지 C18의 알칼기를 가지며 각각의 알콕시기가 C1내지 C7의 알콕 시기를 갖는 평균 알콕시화도가 1 내지 7인 알킬 알콕시 황산염; 올레핀 부분이 C8내지 C24의 직선형 또는 가지형 사슬의 비포화된 탄화수소를 갖는 알파-올레핀 술폰산염; C8내지 C18의 파라핀 술폰산염; C8내지 C20의 알킬 글리세릴에테르 술폰산염; C8내지 C18의 2차 알칸 술폰산염; C9내지 C17의 아실-N-(C1-C4알킬) 또는 -N-(C2-C4히드록시알킬) 글루카민 황산염; C8내지 C18의 2차 알코올 황산염, C8내지 C18의 알킬 술포아세트산염 및 이것들의 혼합물로 이루어진 그룹으로부터 선택됨을 특징으로 하는 세제 조성물.
  3. 제2항에 있어서, 계면 활성제와 2가 양이온의 혼합물이 상호작용하게 세제 조성물의 투명한 상태를 영구적으로 유지시킴을 특징으로 하는 세제 조성물.
  4. 제3항에 있어서, 보조제 계면 활성제가 지방산 아미드, 긴-사슬의 알킬아민 산화물, 베타인, 술타인, 및 C8-C18지방 알코올 및 이것들의 혼합물로 이루어진 그룹으로부터 선택됨을 특징으로 하는 세제 조성물.
  5. 제4항에 있어서, 굴수성 계면 활성제 대 음이온성 계면 활성제의 중량비가 1:1.75 내지 1:4임을 특징으로 하는 세제 조성물.
  6. 제5항에 있어서, 굴수성 계면 활성제가 9:1의 1-염 대 2-염의 비율을 갖는 알파-술폰화된 메틸 에스테르의 염임을 특징으로 하는 세제 조성물.
  7. 제6항에 있어서, 알파-술폰화된 메틸 에스테르의 염이 2 내지 30중량%의 농도로 혼합물중에 존재됨을 특징으로 하는 세제 조성물.
  8. 제6항에 있어서, 알파-술폰화된 메틸 에스테르의 염이 5 내지 12중량%의 농도로 혼합물중에 존재됨을 특징으로 하는 세제 조성물.
  9. 제6항에 있어서, 음이온성 계면 활성제가 선형의 알킬 벤젠 술폰산 마그네슘염이고 조성물의 5 내지 40중량%의 범위내에 존재됨을 특징으로 하는 세제 조성물.
  10. 제6항에 있어서, 음이온성 계면 활성제가 선형의 알킬 벤젠 술폰산 마그네슘염이고 조성물의 10 내지 30중량%의 범위내에 존재됨을 특징으로 하는 세제 조성물.
  11. 제6항에 있어서, 음이온성 계면 활성제가 조성물의 2 내지 70중량%의 범위내에 존재됨을 특징으로 하는 세제 조성물.
  12. 제11항에 있어서, 알파-술폰화된 메틸 에스테르의 양이 조성물의 3 내지 25중량%임을 특징으로 하는 세제 조성물.
  13. 제11항에 있어서, 알파-술폰화된 메틸 에스테르의 양이 조성물의 7 내지 12중량%임을 특징으로 하는 세제 조성물.
  14. 제12항에 있어서, 알파-술폰화된 메틸 에스테르의 염의 지방산 부분이 평균 8 내지 20개의 탄소원자를 가짐을 특징으로 하는 세제 조성물.
  15. 제13항에 있어서, 알파-술폰화된 메틸 에스테르의 염의 지방산 부분이 평균 10 내지 15개의 탄소원자를 가짐을 특징으로 하는 세제 조성물.
  16. 제13항에 있어서, 알파-술폰화된 메틸 에스테르의 염의 지방산 부분이 평균 12 내지 14개의 탄소원자를 가짐을 특징으로 하는 세제 조성물.
  17. 제16항에 있어서, 음이온성 계면 활성제가 라우릴 황산염, 선형의 알킬 벤젠 술폰산염 또는 평균 에톡시화도가 1~7인 라우릴 에톡시 황산염임을 특징으로 하는 세제 조성물.
  18. 제16항에 있어서, 음이온성 계면 활성제가 평균 에톡시화도가 3인 라우릴 에톡시 황산염임을 특징으로 하는 세제 조성물.
  19. 제6항에 있어서, 조성물중의 유일한 굴수성 유발물질이 술폰화된 메틸 에스테르임을 특징으로 하는 세제 조성물.
  20. 2가 양이온이 음이온성 계면 활성제의 염으로서 조성물에 부가되는 방법에 의해 제조되는 제1항에 따른 세제 조성물.
  21. 2가 양이온이 2가 양이온의 할로겐화물, 2가 양이온의 황산염 및 2가 양이온의 산화물로부터 선택된 2가 염으로서 조성물에 부가되는 방법에 의해 제조되는 제1항에 따른 세제 조성물.
  22. 제21항에 있어서, 2가 염이 마그네슘, 황산마그네슘 또는 수산화 마그네슘임을 특징으로 하는 세제 조성물.
  23. 계면 활성제의 혼합물로서, (a) 12~16개의 탄소원자를 갖는 알파-술폰화된 메틸 또는 에틸 에스테르 지방산의 1-염과 알파-술폰화된 지방산의 2-염이,1-염; 2-염의 비율이 최소한 2:1이 되도록 블렌딩된 굴수성 계면 활성제; (b) 음이온성 계면 활성제; (c) 보조제 포움 안정화 계면 활성제; 및 (d) 2가 양이온의 몰 대 계면 활성제의 몰비가 1:2 내지 1:1인 2가 양이온으로 이루어진 계면 활성제의 혼합물을 함유하고, 굴수성 계면 활성제 대 음이온성 계면 활성제의 중량비가 1:1.5 내지 1:8이고, 조성물중의 계면 활성제의 혼합물의 양이 32 내지 90중량%임을 특징으로 하는 세제 조성물.
  24. 제23항에 있어서, 음이온성 계면 활성제가 C8내지 C15의 알킬기를 갖는 선형의 알킬 벤젠 술폰산염; C8내지 C18의 알킬기를 갖는 알킬 황산염, C8내지 C18의 알칼기를 가지며 각각의 알콕시기가 C1내지 C7의 알콕 시기를 갖는 평균 알콕시화도가 1 내지 7인 알킬 알콕시 황산염; 올레핀 부분이 C8내지 C24의 직선형 또는 가지형 사슬의 비포화된 탄화수소를 갖는 알파-올레핀 술폰산염; C8내지 C18의 파라핀 술폰산염; C8내지 C20의 알킬 글리세릴에테르 술폰산염; C8내지 C18의 2차 알칸 술폰산염; C9내지 C17의 아실-N-(C1-C4알킬) 또는 -N-(C2-C4히드록시알킬)글루카민황산염; C8내지 C18의 2차 알코올 황산염, C8내지 C18의 알킬 술포아세트산염 및 이것들의 혼합물로 이루어진 그룹으로부터 선택됨을 특징으로 하는 세제 조성물.
  25. 제24항에 있어서, 계면 활성제와 2가 양이온의 혼합물이 상호 작용하게 세제 조성물의 투명한 상태를 영구적으로 유지시킴을 특징으로 하는 세제 조성물.
  26. (a) 1-염대 2-염의 비율이 최소한 2:1인, 평균 13.6개의 탄소원자를 갖는 알파-술폰화된 메틸 에스테르 지방산의 1-마그네슘염과 알파-술폰화된 지방산의 2-마그네슘염과의 7 내지 8중량%의 블렌드; (b) 에톡시화도가 3인 3 내지 5중량%의 암모늄 라우릴 에톡시 황산염; (c) 10 내지 13개의 탄소원자를 갖는 22 내지 25중량%의 선형의 알킬 벤젠 술폰산 마그네슘; 및 (d)4 내지 6중량%의지방산 알칸올아미드로 이루어진 세제 조성물.
  27. 제26항에 있어서, 지방산 알칸올아미드가 라우르산 모노에탄올 아미드와 미리스트산 모노에탄올아미드의 혼합물임을 특징으로 하는 세제 조성물.
  28. 경질 표면을 제1항의 세제 조성물 수용액과 접촉시켜 경질 표면을 세척하는 방법.
  29. (a) 수성 음이온 계면 활성제를 제조하는 단계; (b) 수성 음이온 계면 활성제에 1-염 대 2-염의 비율이 최소한 2:1인, 12~16개의 탄소원자를 갖는 알파-술폰화된 메틸 또는 에틸 에스테르 지방산의 1-염과 알파-술폰화된 지방산의 2-염과의 렌드인 굴수성 계면 활성제를 부가하는 단계; (c) 혼합물을 13-~150。F의 온도로 가열하는 단계; 및 (d) 혼합물에 보조제 포움 안정화 계면 활성제를 부가하는 단계로 이루어진 계면 활성제의 혼하물을 함유하는 세제 조성물의 제조방법으로서, 굴수성 계면 활성제 대 음이온성 계면 활성제의 중량비가 1:1.5 내지1:8이고, 계면 활성제의 혼합물이 Ca++및 Mg++로 이루어진 그룹으로부터 선택된 2가 양이온을 함유하고, 2가 양이온의 염으로서 조성물중에 존재되는 계면 활성제의 양이 계면 활성제의 혼합물의 30중량% 이상임을 특징으로 하는 세제 조성물의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960701971A 1993-10-12 1994-10-11 알파-술폰화 지방산 메틸에스테르 및 음이온성 계면활성제를 포함하는 액체세제 조성물 KR100209789B1 (ko)

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IN184497B (ko) * 1990-10-12 2000-08-26 Procter & Gamble
JP2945495B2 (ja) * 1990-10-18 1999-09-06 ライオン株式会社 高嵩密度粒状洗剤組成物
JPH04202300A (ja) * 1990-11-29 1992-07-23 Shin Etsu Chem Co Ltd 洗浄剤組成物
CA2170732A1 (en) * 1993-09-09 1995-03-16 Jeffrey John Scheibel Detergent compositions with mixture of n-alkoxy or n-aryloxy polyhydroxy fatty acid amide plus alkoxylated carboxylate surfactant
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DE69423225D1 (de) 2000-04-06
WO1995010585A1 (en) 1995-04-20
US5616781A (en) 1997-04-01
US5637758A (en) 1997-06-10
EP0723576B1 (en) 2000-03-01
JP2710468B2 (ja) 1998-02-10
DE69423225T2 (de) 2000-06-21
EP0723576A1 (en) 1996-07-31
JPH09505088A (ja) 1997-05-20
CN1137286A (zh) 1996-12-04
ES2142958T3 (es) 2000-05-01
AU7974994A (en) 1995-05-04
KR100209789B1 (ko) 1999-07-15

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