KR960705084A - 비스무트염을 포함하는 제제의 제조방법 및 음극 도장에 의해 도포되는 전기영동 도료에서 촉매 성분으로서의 이의 용도(Method for producing preparations containing bismuth salts and their use as catalytic components in electrophoretic paints applied by cathodic deposition) - Google Patents

비스무트염을 포함하는 제제의 제조방법 및 음극 도장에 의해 도포되는 전기영동 도료에서 촉매 성분으로서의 이의 용도(Method for producing preparations containing bismuth salts and their use as catalytic components in electrophoretic paints applied by cathodic deposition) Download PDF

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Publication number
KR960705084A
KR960705084A KR1019960701147A KR19960701147A KR960705084A KR 960705084 A KR960705084 A KR 960705084A KR 1019960701147 A KR1019960701147 A KR 1019960701147A KR 19960701147 A KR19960701147 A KR 19960701147A KR 960705084 A KR960705084 A KR 960705084A
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South Korea
Prior art keywords
paint binder
weight
bismuth
mol
formulation
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KR1019960701147A
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KR100340367B1 (ko
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페올라 롤란트
부르그만 브리기테
쿠르츠만 프란츠
Original Assignee
메르텐 슐링만·한스-디터 하누스
비아노바 레진스 아크티엔게젤샤프트
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Publication of KR960705084A publication Critical patent/KR960705084A/ko
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D13/00—Electrophoretic coating characterised by the process
    • C25D13/12—Electrophoretic coating characterised by the process characterised by the article coated
    • C25D13/14—Tubes; Rings; Hollow bodies
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4488—Cathodic paints
    • C09D5/4492—Cathodic paints containing special additives, e.g. grinding agents

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Paints Or Removers (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

본 발명은 비스무트 염을 함유하는 제제의 제조방법에 관한 것이며, 여기서 산화비스무트는 특정한 방법으로 유산과 반응하고 생성된 비스무틸 락테이트와 비스무트 락테이트와의 혼합물은 도료 결합제에 분산된다. 이러한 제제는 음극 도장에 의해 도포되는 전기영동 도료에서 촉매 성분으로서 사용된다. 이러한 종류의 침지 도료는 도포성과 막 특성이 우수하다. 이로써 납 화합물과 주석 화합물을 촉매로서 사용할 필요가 없다.

Description

비스무트염을 포함하는 제제의 제조방법 및 음극 도장에 의해 도포되는 전기영동 도료에서 촉매 성분으로서의 이의 용도(Method for producing preparations containing bismuth salts and their use as catalytic components in electrophoretic paints applied by cathodic deposition)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. A) 1.0mol의 산화비스무트가 총 4.0mol의 유산과 여러 단계로 반응함(이 단계들은 Aa) 산화비스무트 1.0mol과 유산 2.0mol을 물의 존재하에 20 내지 40℃에서 30 내지 60분 동안 먼저 균질화하는 단계, Ab) 유산 1.0mol을 단계 Aa)에서 수득한 혼합물에 가하고 다시 30 내지 40℃에서 30분 내지 60분 동안 균질화하는 단계 및 Ac) 단계 Ab)에 따르는 방법을 반복하고, 반응 혼합물의 색상이 처음의 황색에서 백색으로 변할 때까지 균질화하는 단계를 포함한다)을 특징으로 하며, B) 단계 Aa) 내지 Ac)에 따라서 수득한 비스무틸 락테이트와의 혼합물을 계속해서 양이온 도료 결합제와 배합하며, 단 비스무트의 함량은, 제제의 전체 고형분을 기준으로 하여, 25 내지 45중량%, 바람직하게는 30 내지 40중량%임을 특징으로 하는 비스무트염을 포함하고 양이온도료 결합제위 가교결합 반응을 촉매화하기 위한 제제의 제조방법.
  2. 제1항에 있어서, B)에서 에스테르 교환반응 및/또는 아미드 교환반응 및/또는 우레탄 교환반응 및/또는 말단 이중결합의 반응에 의해 가교결합될 수 있는 양이온 도료 결합제, 바람직하게는 안료 페이스트 수지, 바람직하게는 점도 범위가 4,000 내지 10,000mPa.s/23℃인 제제를 사용함을 특징으로 하는 방법.
  3. 에스테르 교환반응 및/또는 아미드 교환반응 및/또는 우레탄 교환반응 및/또는 말단 이중결합의 반응에 의해 가교결합될 수 있으며 제제에 존재하는 도료 결합제와 동일하거나 상이하고, 필요한 경우, 비스무트 함량이, 전체 도료 결합제의 고형분을 기준으로 하여, 0.5 내지 3.0중량%, 바람직하게는 0.8 내지 2.5중량%인 음극 전착 도료의 제제용으로 분산액 형태인 양이온 도료 결합제와 배합된, 필요한 경우, 안료 페이스트 형태인 제1항 또는 제2항에 따라 제조된 제제의 용도.
  4. 제1항 또는 제2항에 따라서 제조되고, 필요한 경우, 안료 페이스트 형태인 제제와, 에스테르 교환반응및/또는 아미드 교환반응 및/또는 우레탄 교환반응 및/또는 말단 이중결합의 반응에 의해 가교결합될 수 있으며 제제에 존재하는 도료 결합제와 동일하거나 상이하고, 필요한 경우, 분산액 형태인 또 다른 양이온 도료결합제를 포함하는 비스무트 함량이 전체 도료 결합제의 고형분을 기준으로 하여, 0.5 내지 3.0중량%, 바람직하게는 0.8 내지 2.5중량%인 음극 전착 도료.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960701147A 1993-09-07 1994-09-02 비스무트염을포함하는제제의제조방법및이의음극전착도료에서촉매성분으로서의용도 KR100340367B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
AT0179493A AT398987B (de) 1993-09-07 1993-09-07 Verfahren zur herstellung von wismutsalze enthaltenden zubereitungen und deren verwendung als katalysatorkomponente in kathodisch abscheidbaren elektrotauchlacken
ATA1794/93 1993-09-07
PCT/AT1994/000123 WO1995007377A1 (de) 1993-09-07 1994-09-02 Verfahren zur herstellung von wismutsalze enthaltenden zubereitungen und deren verwendung als katalysatorkomponente in kathodisch abscheidbaren elektrotauchlacken

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KR960705084A true KR960705084A (ko) 1996-10-09
KR100340367B1 KR100340367B1 (ko) 2002-11-13

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Country Link
US (1) US5936013A (ko)
EP (1) EP0717794B1 (ko)
KR (1) KR100340367B1 (ko)
CN (1) CN1044140C (ko)
AT (2) AT398987B (ko)
AU (1) AU7484894A (ko)
BR (1) BR9407408A (ko)
CZ (1) CZ285838B6 (ko)
DE (1) DE59403675D1 (ko)
ES (1) ES2107244T3 (ko)
RU (1) RU2137866C1 (ko)
TW (1) TW474977B (ko)
WO (1) WO1995007377A1 (ko)
ZA (1) ZA946894B (ko)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5908912A (en) * 1996-09-06 1999-06-01 Ppg Industries Ohio, Inc. Electrodepositable coating composition containing bismuth and amino acid materials and electrodeposition method
DE69837091D1 (de) * 1997-07-29 2007-03-29 Kansai Paint Co Ltd Kationische elektrotauchlackierung-zusammensetzung
EP1719806B1 (en) 1997-12-12 2009-06-03 Kansai Paint Co., Ltd. Cationic electro-coating composition
US5972189A (en) * 1998-05-29 1999-10-26 Ppg Industries Ohio, Inc. Electrodepositable coating composition containing bismuth diorganodithiocarbamates and method of electrodeposition
US6353057B1 (en) 1999-02-10 2002-03-05 King Industries, Inc. Catalyzing cationic resin and blocked polyisocyanate with bismuth carboxylate
CA2305973C (en) * 1999-04-21 2008-10-07 Kansai Paint Co., Ltd. Cationically electrodepositable coating material
DE10001222A1 (de) 2000-01-14 2001-08-09 Basf Coatings Ag Beschichtung, enthaltend kolloidal verteiltes metallisches Bismut
AT410442B (de) * 2001-06-15 2003-04-25 Solutia Austria Gmbh Wässrige bindemittel
US6811667B2 (en) * 2002-03-04 2004-11-02 E. I. Du Pont De Nemours And Company Cathodic electrodeposition coating agents containing bismuth complexes, preparation and use thereof
US7374650B2 (en) * 2002-08-22 2008-05-20 E.I. Du Pont De Nemours & Company Cathodic electrodeposition coating agents containing bismuth salts together with yttrium and/or neodymium compounds, production and use thereof
US7118726B2 (en) * 2002-12-13 2006-10-10 Clark Manufacturing, Llc Method for making oxide compounds
US7351319B2 (en) * 2003-01-24 2008-04-01 E. I. Du Pont De Nemours & Co. Cathodic electrodeposition coating compositions containing bismuth compounds and dicarboxylic acids, production and use thereof
US7632386B2 (en) * 2003-08-28 2009-12-15 E.I. Du Pont De Nemours And Company Process for producing coatings on electrically conductive substrates by cathodic electrodeposition coating
US7211182B2 (en) * 2003-09-23 2007-05-01 E. I. Du Pont De Nemours And Company Process for producing coatings on electrically conductive substrates by cathodic electrodeposition coating
US7485729B2 (en) 2004-08-12 2009-02-03 King Industries, Inc. Organometallic compositions and coating compositions
US7842762B2 (en) * 2007-08-08 2010-11-30 Ppg Industries Ohio, Inc. Electrodepositable coating composition containing a cyclic guanidine
DE102008016220A1 (de) * 2008-03-27 2009-10-01 Basf Coatings Ag Elektrotauchlacke enthaltend Polymethylenharnstoff
CN104790014B (zh) 2008-05-29 2017-08-25 日本帕卡濑精株式会社 带有铋被膜的金属材料及其制造方法、在其中所使用的表面处理液以及阳离子电沉积涂覆金属材料及其制造方法
US8912113B2 (en) 2011-03-06 2014-12-16 King Industries, Inc. Compositions of a metal amidine complex and second compound, coating compositions comprising same
CN103183608B (zh) * 2011-12-30 2015-02-04 广东先导稀材股份有限公司 次水杨酸铋的制备方法
RU2538869C1 (ru) * 2013-04-30 2015-01-10 Федеральное казенное предприятие "Государственный научно-исследовательский институт химических продуктов" (ФКП "ГосНИИХП") Сферический порох для дробовых патронов к гладкоствольному спортивно-охотничьему оружию 12, 16 и 20 калибров
EP2806001A1 (en) 2013-05-21 2014-11-26 PPG Industries Ohio Inc. Coating composition
EP2862905A1 (en) * 2013-10-17 2015-04-22 ALLNEX AUSTRIA GmbH Cationic water-dilutable binders
JP6406842B2 (ja) * 2014-03-25 2018-10-17 日本ペイント・オートモーティブコーティングス株式会社 電着塗料組成物および電着塗装方法
JP6441126B2 (ja) 2015-03-06 2018-12-19 日本ペイント・オートモーティブコーティングス株式会社 カチオン電着塗料組成物の調製方法
JP2018184489A (ja) 2015-09-25 2018-11-22 日本ペイント・オートモーティブコーティングス株式会社 カチオン電着塗料組成物の調製方法
CN105837775A (zh) * 2016-03-23 2016-08-10 赵洪枝 一种环保型催化剂及其制备方法
RU2692370C1 (ru) * 2018-10-29 2019-06-24 Федеральное государственное бюджетное учреждение науки Институт химии твердого тела и механохимии Сибирского отделения Российской академии наук Способ получения висмут лактата

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5218746A (en) * 1975-08-01 1977-02-12 Ppg Industries Inc Resin vehicle for cathode electrodeposition
US4009133A (en) * 1975-08-01 1977-02-22 Ppg Industries, Inc. Electrodepositable epoxy resins having quaternary groups carrying blocked NCO, and aqueous dispersions
US4040924A (en) * 1975-08-01 1977-08-09 Ppg Industries, Inc. Aqueous cationic electrodeposition of epoxy resins having quaternary groups carrying blocked NCO
CA1097449A (en) * 1975-08-01 1981-03-10 Karl F. Schimmel Pigment grinding vehicle
US4007154A (en) * 1975-08-01 1977-02-08 Ppg Industries, Inc. Novel pigment paste for cationic electrodeposition
EP0001879B2 (en) * 1977-09-07 1989-11-23 Imperial Chemical Industries Plc Thermoplastic aromatic polyetherketones, a method for their preparation and their application as electrical insulants
US4162205A (en) * 1978-10-19 1979-07-24 Vulcan Materials Company Method of electroplating tin and alkaline electroplating bath therefor
US4195972A (en) * 1978-10-20 1980-04-01 Combe Incorporated Aqueous-based hair dyeing composition containing a soluble bismuth salt and a reducing compound
JPS586243A (ja) * 1981-07-02 1983-01-13 Ube Ind Ltd メタクリル酸製造用触媒の製法
US4436931A (en) * 1982-07-28 1984-03-13 Texaco Inc. Alkane acetates produced by oxidative esterification of olefins over certain oxide catalysts
DE3371348D1 (en) * 1982-09-30 1987-06-11 Ppg Industries Inc Novel pigment grinding vehicle
US4485259A (en) * 1982-09-30 1984-11-27 Ppg Industries, Inc. Pigment grinding vehicle
AU547702B2 (en) * 1982-09-30 1985-10-31 Ppg Industries, Inc. Amine modified epoxy
US4715898A (en) * 1986-06-30 1987-12-29 Ppg Industries, Inc. Sulfonium resins useful as pigment grinding vehicles in cationic electrodeposition
DE3640855A1 (de) * 1986-11-29 1988-06-09 Bayer Ag Verfahren zur herstellung von uretdionringen enthaltenden polyurethanen
ZA891937B (en) * 1988-04-04 1990-11-28 Ppg Industries Inc Pigment grinding vehicles containing quaternary ammonium and ternary sulfonium groups
US5059671A (en) * 1988-12-28 1991-10-22 Mitsui Toatsu Chemicals, Inc. Manufacturing process of spray urethane elastomer
BE1002762A7 (nl) * 1989-01-20 1991-05-28 Recticel Werkwijze voor het bereiden en toepassen van verspuitbaar lichtstabiel polyurethaan.
AT394372B (de) * 1990-08-02 1992-03-25 Vianova Kunstharz Ag Verfahren zur herstellung von pigmentpastenharzen fuer kathodisch abscheidbare ueberzugsmittelzusammensetzungen
BR9306440A (pt) * 1992-05-29 1998-06-30 Vianova Kunstharz Ag Aglutinantes catiônicos catalisados para verniz processo para o seu preparo e sua utilização
AT397820B (de) * 1992-05-29 1994-07-25 Vianova Kunstharz Ag Katalysatorhältige kationische lackbindemittel, verfahren zu ihrer herstellung und ihre verwendung

Also Published As

Publication number Publication date
AT398987B (de) 1995-02-27
KR100340367B1 (ko) 2002-11-13
JPH09505837A (ja) 1997-06-10
ES2107244T3 (es) 1997-11-16
BR9407408A (pt) 1996-11-12
US5936013A (en) 1999-08-10
CZ285838B6 (cs) 1999-11-17
ATE156525T1 (de) 1997-08-15
JP3617010B2 (ja) 2005-02-02
CN1044140C (zh) 1999-07-14
WO1995007377A1 (de) 1995-03-16
TW474977B (en) 2002-02-01
ATA179493A (de) 1994-07-15
CN1133072A (zh) 1996-10-09
DE59403675D1 (de) 1997-09-11
ZA946894B (en) 1995-04-13
CZ69096A3 (en) 1996-08-14
RU2137866C1 (ru) 1999-09-20
AU7484894A (en) 1995-03-27
EP0717794B1 (de) 1997-08-06
EP0717794A1 (de) 1996-06-26

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