KR960041274A - 섬유 강화 복합 재료용 에폭시 수지 조성물, 프리프레그 및 섬유 강화 복합 재료 - Google Patents

섬유 강화 복합 재료용 에폭시 수지 조성물, 프리프레그 및 섬유 강화 복합 재료 Download PDF

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KR960041274A
KR960041274A KR1019960015191A KR19960015191A KR960041274A KR 960041274 A KR960041274 A KR 960041274A KR 1019960015191 A KR1019960015191 A KR 1019960015191A KR 19960015191 A KR19960015191 A KR 19960015191A KR 960041274 A KR960041274 A KR 960041274A
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epoxy resin
resin composition
fiber
reinforced composite
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슌사꾸 노다
히로끼 오세도
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마에다 가쯔노스께
도레이 가부시끼가이샤
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    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
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    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
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    • C08L2666/66—Substances characterised by their function in the composition
    • C08L2666/72—Fillers; Inorganic pigments; Reinforcing additives
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Abstract

본 명세서에는 적어도 에폭시 수지 100중량부 중에, 2관능 에폭시 수지를 70중량부 이상 함유하는 에폭시 수지, 고무상을 함유하며 에폭시 수지에 실질적으로 불용성인 미립자 및 경화제를 함유하는 섬유 강화 복합재료용 에폭시 수지 조성물에 관한 발명을 개시한다.상기 에폭시 수지 조성물 및 강화 섬유로 이루어지는 프로프레그 및 상기 에폭시 수지 조성물의 경화물 및 강화 섬유로 이루어지는 섬유 강화 복합 재료에 관한 발명 또한 개시되어 있다.

Description

섬유 강화 복합 재료용 에폭시 수지 조성물, 프리프레그 및 섬유 강화 복합 재료
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (23)

  1. 적어도 하기 구성 요소 〔A〕,〔B〕 및 〔C〕를 함유하는 섬유 강화 복합 재료용 에폭시 수지 조성물. 〔A〕에폭시 수지 100중량부 중 2관능 에폭시 수지를 70중량부 이상 함유하는 에폭시 수지; 〔B〕고무상을 함유하며 에폭시 수지에 실질적으로 불용성인 미립자 및〔C〕경화제.
  2. 제1항에 있어서, 상기 구성 요소〔A〕가 추가로 3관능 이상의 에폭시 수지를 에폭시 수지 100중량부에 대해 1 내지 30중량부 함유하는 에폭시 수지인 섬유 강화 복합 재료용 에폭시 수지 조성물.
  3. 제1 또는 2항에 있어서, 상기 구성 요소〔A〕가 2관능 에폭시 수지를 에폭시 수지 100중량부 당 80중량부 이상 함유하는 에폭시 수지인 섬유 강화 복합 재료용 에폭시 수지 조성물.
  4. 제1 내지 3항 중 어느 한 항에 있어서, 상기 구성 요소〔A〕가 3관능 이상의 에폭시 수지를 에폭시 수지 100 중량부에 대해 1 내지 20중량부 함유하는 에폭시 수지인 섬유 강화 복합 재료용 애폭시 수지 조성물.
  5. 제1 내지 4항 중 어느 한 항에 있어서, 상기 구성 요소〔A〕의 에폭시 수지의 에폭시 당량이 에폭시 수지 전체로서 250 이상인 섬유 강화 복합 재료용 에폭시 수지 조성물.
  6. 제1 내지 5항 중 어느 한 항에 있어서, 상기 구성 요소〔A〕의 에폭시 수지의 에폭시 달양이 에폭시 수지 전체로서 250 내지 400인 섬유 강화 복합 재료용 에폭시 수지 조성물.
  7. 제1 내지 6항 중 어느 한 항에 있어서, 상기 구성 요소〔B〕의 미립자가 가교 고무인 섬유 강화 복합 재료용 에폭시 수지 조성물.
  8. 제1 내지 6항 중 어느 한 항에 있어서, 상기 구성 요소〔B〕의 미립자가 코어/쉘 입자인 섬유 강화 복합 재료용 에폭시 수지 조성물.
  9. 제8항에 있어서, 상기 코어/쉘 입자가 소프트 코어/하드 쉘인 섬유 강화 복합 재료용 에폭시 수지 조성물.
  10. 제9항에 있어서, 상기 코어/쉘 입자가, 코어의 주성분이 폴리부타디엔 또는 폴리부틸아크릴레이트, 쉘의 주성분이 아크릴레이트 또는 메타크릴레이트계 중합체인 섬유 강화 복합 재료용 에폭시 수지 조성물.
  11. 제8항 내지 10항 중 어느 한 항에 있어서, 상기 코어/쉘 입자의 쉘상에 상기 구성 요소〔A〕의 에폭시 수지 및 상기 구성 요소〔C〕의 경화제와 반응하는 관능기를 함유하지 않는 섬유 강화 복합 재료용 에폭시 수지 조성물.
  12. 제1 내지 11항 중 어느 한 항에 있어서, 상기 구성 요소〔B〕의 미립자의 평균 입경이 10㎛ 이하인 섬유 강화 복합 재료용 에폭시 수지 조성물.
  13. 제12항에 있어서, 상기 구성 요소〔B〕의 미립자의 평균 입경이 5㎛ 이하인 섬유 강화 복합 재료용 에폭시 수지 조성물.
  14. 제1 내지 13항 중 어느 한 항에 있어서, 상기 구성 요소〔B〕의 미립자를 에폭시 수지 100중량부에 대해 1 내지 20중량부 함유하는 섬유 강화 복합 재료용 에폭시 수지 조성물..
  15. 제1 내지 14항 중 어느 한 항에 있어서, 상기 구성 요소〔C〕의 경화제가 디시안디아미드이며, 또한 경화촉진제를 함유하는 섬유 강화 복합 재료용 에폭시 수지 조성물.
  16. 제1 내지 15항 중 어느 한 항에 있어서, 열가소성 수지를 함유하는 것을 특징으로 하는 섬유 강화 복합 재료용 에폭시 수지 조성물.
  17. 제16항에 있어서, 상기 열가소성 수지가 알코올성 수산기, 아미도기, 이미도기, 술포닐기 및 시아노기로 이루어지는 군으로부터 선택된 적어도 1개의 구조를 갖는 섬유 강화 복합 재료용 에폭시 수지 조성물.
  18. 제16항에 있어서, 상기 열가소성 수지가 폴리비닐아세탈, 페녹시 수지, 폴리아미드, 폴리이미드 및 폴리술폰으로 이루어지는 군으로부터 선택되는 적어도 1개의 수지인 섬유 강화 복합 재료용 에폭시 수지 조성물.
  19. 제18항에 있어서, 상기 열가소성 수지가 비닐포르말 부분을 60중량% 이상 함유하는 폴리비닐 포르말인 섬유 강화 복합 재료용 에폭시 수지 조성물.
  20. 제1 내지 19항 중 어느 한 항에 기재된 에폭시 수지 조성물을 강화 섬유에 함침시킴으로써 얻어지는 프리프레그.
  21. 제20항에 있어서, 상기 강화 섬유가 탄소 섬유, 방향족 폴리아미드 섬유, 유리 섬유, 실리콘 카바이드 섬유, 붕소 섬유, 알루미나 섬유 및 스테인레스 스틸 섬유로 이루어지는 군으로부터 선택되는 것을 특징을 하는 프리프레그.
  22. 제21항에 있어서, 상기 강화 섬유가 탄성률 200GPa 이상의 탄소 섬유인 프리프레그.
  23. 제20 내지 22항 중 어느 한 항에 기재된 에폭시 수지 조성물의 경화물 및 강화 섬유로 이루어지는 섬유 강화 복합 재료.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019960015191A 1995-05-09 1996-05-09 섬유 강화 복합 재료용 에폭시 수지 조성물, 프리프레그 및 섬유 강화 복합 재료 KR960041274A (ko)

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KR100367039B1 (ko) * 1995-11-01 2003-03-10 미쯔비시 레이온 가부시끼가이샤 기존구조물의보수보강방법및여기에사용되는이방성직물
JPH10212364A (ja) * 1996-11-26 1998-08-11 Ajinomoto Co Inc 積層板用プリプレグ及びこれを用いたプリント配線板の製造方法
US6776735B1 (en) 1998-12-14 2004-08-17 Reichhold, Inc. Baseball bat
AU2174500A (en) * 1998-12-14 2000-07-03 Reichhold, Inc. Baseball bat
US6620510B1 (en) * 1998-12-25 2003-09-16 Mitsubishi Rayon Co., Ltd. Epoxy resin composition, prepreg, and roll made of resin reinforced with reinforcing fibers
TW367873U (en) * 1999-02-09 1999-08-21 Paderson Sporting Goods Co Ltd Improved structure for shaft of golf clubs
WO2000053654A1 (fr) * 1999-03-11 2000-09-14 Toray Industries, Inc. Composition de resine epoxy, composition de resine epoxy pour materiau composite a fibres, et materiau composite a fibres contenant ladite composition
KR100785572B1 (ko) * 1999-04-13 2007-12-13 히다치 가세고교 가부시끼가이샤 에폭시수지조성물 및 전자장치
JP4568940B2 (ja) * 1999-04-13 2010-10-27 日立化成工業株式会社 封止用エポキシ樹脂組成物及び電子部品装置
WO2000066338A1 (ko) * 1999-04-28 2000-11-09 Kunhyung Co., Ltd. Fiber reinforced epoxy resin product and method for the manufacture thereof
DE60013181T2 (de) 1999-12-20 2005-08-11 3M Innovative Properties Co., Saint Paul Bei umgebungstemperatur stabiler und einkomponentiger härtbarer epoxidharzklebstoff
CA2330083C (en) * 2000-01-07 2010-04-13 Jas. D. Easton, Inc. Hockey stick
JP2001302887A (ja) * 2000-04-25 2001-10-31 Matsushita Electric Works Ltd エポキシ樹脂組成物、樹脂付き金属箔及び絶縁性フィルム
US7963868B2 (en) 2000-09-15 2011-06-21 Easton Sports, Inc. Hockey stick
CA2357331C (en) * 2000-09-15 2010-07-20 Jas D. Easton, Inc. Hockey stick
MY142518A (en) * 2001-01-10 2010-12-15 Hitachi Chemical Co Ltd Dihydrobenzoxazine ring-containing resin, phenolic-triazine-aldehyde condensate and epoxy resin
JP2002338790A (ja) * 2001-05-22 2002-11-27 Nippon Kayaku Co Ltd 固着含浸用エポキシ樹脂組成物
JP4859082B2 (ja) * 2001-06-27 2012-01-18 三菱レイヨン株式会社 エポキシ樹脂組成物及びそれを用いたテニスラケット
WO2003005118A1 (en) * 2001-07-02 2003-01-16 Loctite Corporation Epoxy-based composition
JP3894035B2 (ja) * 2001-07-04 2007-03-14 東レ株式会社 炭素繊維強化基材、それからなるプリフォームおよび複合材料
US7255927B2 (en) * 2001-12-05 2007-08-14 Isola Usa Corp. Laminate composition
EP1461387B1 (en) * 2001-12-05 2012-02-08 Isola Laminate Systems, Corp. Prepreg and composition of epoxy resin(s), sma copolymers(s) and bis-maleimide triazine resin(s)
AU2002365606A1 (en) * 2001-12-05 2003-06-17 Isola Laminate Systems Corp. Thermosetting resin composition for high performance laminates
US20040039120A1 (en) * 2002-05-23 2004-02-26 Hidekazu Takeyama Process for producing a prepreg resin composition
US7208228B2 (en) * 2003-04-23 2007-04-24 Toray Composites (America), Inc. Epoxy resin for fiber reinforced composite materials
US7232386B2 (en) 2003-05-15 2007-06-19 Easton Sports, Inc. Hockey stick
US6874573B2 (en) * 2003-07-31 2005-04-05 National Starch And Chemical Investment Holding Corporation Thermal interface material
JP4506189B2 (ja) * 2004-02-13 2010-07-21 東レ株式会社 エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料
CA2557572A1 (en) * 2004-03-02 2005-09-09 Toray Industries, Inc. Epoxy resin composition for fiber-reinforced composite material, prepreg and fiber-reinforced composite material
US20050227560A1 (en) * 2004-03-29 2005-10-13 Allred Jimmie B Iii Flexible carbon-fiber laminates
JP4529534B2 (ja) * 2004-04-28 2010-08-25 東レ株式会社 繊維強化複合材料用熱硬化性樹脂組成物
JP4639766B2 (ja) * 2004-11-16 2011-02-23 横浜ゴム株式会社 二液型常温硬化性エポキシ樹脂組成物および金属接着剤組成物
US8211502B2 (en) * 2004-12-30 2012-07-03 Veyance Technologies, Inc. Aramid cord treatment
JP5099998B2 (ja) * 2005-02-18 2012-12-19 三菱レイヨン株式会社 繊維強化複合材料用エポキシ樹脂組成物
ATE534703T1 (de) * 2005-08-24 2011-12-15 Henkel Kgaa Epoxidzusammensetzungen mit verbesserter schlagzähigkeit
WO2007038674A1 (en) * 2005-09-28 2007-04-05 Entrotech Composites, Llc Braid-reinforced composites and processes for their preparation
CN101517029B (zh) 2006-07-31 2013-10-16 汉高股份及两合公司 可固化的环氧树脂-基粘合剂组合物
JP2008081681A (ja) * 2006-09-28 2008-04-10 Fujikura Ltd エポキシ系接着剤、カバーレイ、プリプレグ、金属張積層板、プリント配線基板
KR20090080956A (ko) * 2006-10-06 2009-07-27 헨켈 아게 운트 코. 카게아아 발수성의 펌핑가능한 에폭시 페이스트 접착제
US20100108259A1 (en) * 2007-01-17 2010-05-06 Hexcel Composites Limited Low Temperature Curing Of Toughened Adhesives
WO2008104822A1 (en) 2007-02-26 2008-09-04 Hexcel Composites, Ltd. Improved surface finish for composite materials
WO2008133054A1 (ja) * 2007-04-13 2008-11-06 Toho Tenax Co., Ltd. 樹脂組成物、及びプリプレグ
US8345345B2 (en) 2007-06-27 2013-01-01 Gentex Corporation Electrochromic device having an improved fill port plug
US7884995B2 (en) * 2007-06-27 2011-02-08 Gentex Corporation Electrochromic device having an improved fill port plug
WO2009058295A2 (en) 2007-10-30 2009-05-07 Henkel Ag & Co. Kgaa Epoxy paste adhesives resistant to wash-off
KR100971873B1 (ko) * 2008-01-31 2010-07-22 주식회사 한국화이바 운송차량용 일체형 복합소재 차체 및 그 제조방법
GB2460050A (en) * 2008-05-14 2009-11-18 Hexcel Composites Ltd Epoxy composite
JP2009280669A (ja) * 2008-05-21 2009-12-03 Toray Ind Inc Ｒｔｍ成形繊維強化複合材料、およびその製造方法
US7914403B2 (en) 2008-08-06 2011-03-29 Easton Sports, Inc. Hockey stick
JP5332471B2 (ja) * 2008-10-02 2013-11-06 横浜ゴム株式会社 接着剤用エポキシ樹脂組成物
CA2742948C (en) * 2008-11-14 2014-06-03 Jfe Steel Corporation Colored and laminated metal plate for container
JP5152026B2 (ja) * 2009-02-06 2013-02-27 横浜ゴム株式会社 エポキシ樹脂組成物
JP2010222452A (ja) * 2009-03-23 2010-10-07 Hitachi Chem Co Ltd 樹脂ペースト組成物及びそれを用いた半導体装置
US20100280151A1 (en) * 2009-05-04 2010-11-04 Toray Industries, Inc. Toughened fiber reinforced polymer composite with core-shell particles
US8080313B2 (en) * 2009-05-28 2011-12-20 Cytec Technology Corp. Particle-toughened fiber-reinforced polymer composites
US8846818B2 (en) * 2009-05-29 2014-09-30 Cytec Technology Corp. Engineered cross-linked thermoplastic particles for interlaminar toughening
WO2011039879A1 (ja) * 2009-10-01 2011-04-07 株式会社Ｉｈｉエアロスペース 繊維強化プラスチック用のマトリックス樹脂組成物及び繊維強化プラスチック構造体
US9061499B2 (en) 2010-02-05 2015-06-23 Canon Kabushiki Kaisha Negative photosensitive resin composition, pattern formation method, and liquid discharge head
EP3064996B1 (en) * 2010-02-05 2020-07-22 Canon Kabushiki Kaisha Liquid discharge head
US8470923B2 (en) * 2010-04-21 2013-06-25 Hexcel Corporation Composite material for structural applications
JP5929046B2 (ja) * 2010-09-17 2016-06-01 東レ株式会社 炭素繊維織物プリプレグおよび炭素繊維強化複合材料
MY164047A (en) * 2010-11-09 2017-11-15 Cytec Tech Corp Compatible carrier for secondary toughening
BR112013012882A2 (pt) 2010-12-22 2020-05-12 Cytec Technology Corp Composição, prepreg, e, artigo compósito
JP6036706B2 (ja) * 2011-02-24 2016-11-30 東レ株式会社 繊維強化ポリマー組成物、プリプレグ、複合物を製造する方法
CN103547610B (zh) * 2011-05-19 2017-08-11 陶氏环球技术有限责任公司 新的结构粘合剂及其应用
GB2503503B (en) * 2012-06-29 2015-04-29 Gurit Uk Ltd Prepregs for manufacturing composite materials
GB201217226D0 (en) 2012-09-26 2012-11-07 Hexcel Composites Ltd Resin composition and composite structure containing resin
KR20150086270A (ko) 2012-11-15 2015-07-27 사이텍 인더스트리스 인코포레이티드 층간 강인화 입자를 포함하는 열경화성 수지 복합재료
WO2014151083A1 (en) 2013-03-15 2014-09-25 Gentex Corporation Fill port plugs for electrochromic devices
TWI478982B (zh) * 2013-03-25 2015-04-01 Elite Materials Co Ltd 樹脂組合物、使用其之半固化膠片、積層板及印刷電路板
US20150064397A1 (en) * 2013-08-27 2015-03-05 Agency For Science, Technology And Research Composite foam laminate and its usage
US9454054B2 (en) 2013-11-18 2016-09-27 Magna Mirrors Of America, Inc. Electro-optic mirror element and process of making same
US20150174872A1 (en) 2013-12-23 2015-06-25 Cytec Engineered Materials Inc. Toughened composite materials and methods of manufacturing thereof
JP6362067B2 (ja) 2014-01-31 2018-07-25 キヤノン株式会社 ポリマーナノファイバシート及びその製造方法
DE102014207785A1 (de) * 2014-04-25 2015-10-29 Evonik Degussa Gmbh Verfahren zur Herstellung von lagerstabilen Epoxy-Prepregs und daraus hergestellte Composites auf Basis von radikalisch polymerisierbaren Säuren und Epoxiden
CN106471047B (zh) * 2014-06-30 2019-02-22 三菱化学株式会社 丝束预浸料、以及复合材料压力容器及其制造方法
US10363724B2 (en) 2014-10-16 2019-07-30 Mitsubishi Chemical Corporation Resin composition and compression-molded article of same
CN109153902A (zh) 2016-05-26 2019-01-04 泽菲罗斯有限公司 具有高使用温度的固体聚合物粘合剂组合物及其制品和方法
JP7199354B2 (ja) * 2017-07-28 2023-01-05 株式会社カネカ エポキシ樹脂組成物
WO2020080474A1 (ja) * 2018-10-17 2020-04-23 三菱ケミカル株式会社 プリプレグ、繊維強化複合樹脂成形体、管状成形体の製造方法、エポキシ樹脂組成物、および管状成形体
CN111116814B (zh) * 2018-10-31 2022-08-30 台光电子材料(昆山)有限公司 预聚物、制备方法、树脂组合物及其制品
JP7255411B2 (ja) * 2019-07-30 2023-04-11 味の素株式会社 樹脂組成物
RU2718831C1 (ru) * 2019-10-10 2020-04-14 Акционерное общество "Препрег-Современные Композиционные Материалы" Эпоксидное связующее, препрег на его основе и изделие, выполненное из него
JPWO2021132464A1 (ko) * 2019-12-27 2021-07-01
KR20240023502A (ko) 2021-06-29 2024-02-22 오츠카 가가쿠 가부시키가이샤 에폭시 수지 개질제, 이것을 함유하는 에폭시 수지 조성물, 에폭시 수지 조성물로 이루어지는 접착제, 및 에폭시 수지 조성물을 경화하여 이루어지는 수지 경화물

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1299177A (en) * 1969-01-17 1972-12-06 Ciba Geigy Uk Ltd Reinforced composites
JPS5749646A (en) * 1980-09-11 1982-03-23 Toho Rayon Co Ltd Epoxy resin composition
US5089560A (en) * 1980-09-23 1992-02-18 Amoco Corporation Exopy resin with aromatic oligomer and rubber particles
US4419496A (en) * 1982-02-22 1983-12-06 The Dow Chemical Company Particle agglomeration in rubber latices
JPS58183723A (ja) * 1982-04-21 1983-10-27 Toho Rayon Co Ltd エポキシ樹脂組成物
US4524181A (en) * 1983-08-11 1985-06-18 Minnesota Mining And Manufacturing Company Curable epoxy compositions and cured resins obtained therefrom
US4604319B1 (en) * 1984-06-01 1995-07-04 American Cyanamid Co Thermoplastic interleafed resin matrix composites with improved impact strength and toughness
US4863787A (en) * 1986-07-09 1989-09-05 Hercules Incorporated Damage tolerant composites containing infusible particles
US4999238A (en) * 1986-07-09 1991-03-12 Hercules Incorporated Damage tolerant composites containing infusible particles
DE3789054T2 (de) * 1986-12-25 1994-07-07 Toray Industries Zähe Verbundmaterialien.
US4868050A (en) * 1987-02-27 1989-09-19 Ube Industries, Ltd. Interleaf-containing, fiber-reinforced epoxy resin prepreg
US4798761A (en) * 1987-11-03 1989-01-17 The Dow Chemical Company Epoxy resin compositions for use in low temperature curing applications
US4992325A (en) * 1987-12-15 1991-02-12 The Dexter Corporation Inorganic whisker containing impact enhanced prepregs and formulations formulations
US4874661A (en) * 1987-12-15 1989-10-17 Browne James M Impact enhanced prepregs and formulations
US5025045A (en) * 1987-12-24 1991-06-18 Hercules Incorporated Damage tolerant composites containing infusible particles
US4908088A (en) * 1988-02-29 1990-03-13 Basf Aktiengesellschaft Extreme damage tolerant graphite composites and method of making same
US4846905A (en) * 1988-04-06 1989-07-11 Minnesota Mining And Manufacturing Company Acid catalyzed, toughened epoxy adhesives
ES2046299T3 (es) * 1988-05-18 1994-02-01 Rohm And Haas Company Composiciones polimericas termoestables y termoplasticas.
US5242748A (en) * 1989-01-04 1993-09-07 Basf Aktiengesellschaft Toughened thermosetting structural materials
US4954195A (en) * 1989-02-13 1990-09-04 Lockheed Corporation Production of thermoset composites containing thermoplastic fillers
US5248711A (en) * 1989-02-16 1993-09-28 Hexcel Corporation Toughened resin systems for composite applications
US5037689A (en) * 1989-02-17 1991-08-06 Basf Aktiengesellschaft Toughened thermosetting structural materials
US5087657A (en) * 1989-02-23 1992-02-11 Amoco Corporation Fiber-reinforced composites toughened with resin particles
US4957801A (en) * 1989-05-17 1990-09-18 American Cyanamid Company Advance composites with thermoplastic particles at the interface between layers
JP3066907B2 (ja) * 1990-08-15 2000-07-17 日石三菱株式会社 複合材料用樹脂組成物、中間材および複合材料
US5290857A (en) * 1991-09-04 1994-03-01 Nippon Zeon Co., Ltd. Epoxy resin adhesive composition
US5350826A (en) * 1991-11-29 1994-09-27 Tonen Corporation Epoxy resin composition containing a polyaminoamide and a latent curing agent for fiber impregnation
USH1405H (en) * 1992-04-09 1995-01-03 Shell Oil Company Epoxy resin composition
JPH05339472A (ja) * 1992-06-04 1993-12-21 Japan Synthetic Rubber Co Ltd 繊維強化複合材料
JPH05339471A (ja) * 1992-06-05 1993-12-21 Japan Synthetic Rubber Co Ltd 注型材料用組成物
ATE168712T1 (de) * 1992-06-25 1998-08-15 Ciba Geigy Ag Lagerstabile suspension von härtern und zähigkeitsvermittlern für epoxidharze
EP0578613B1 (de) * 1992-07-09 2000-07-12 Ciba SC Holding AG Härtbare Suspensionen auf Basis von Epoxidharzen
CA2112146A1 (en) * 1992-12-23 1994-06-24 Nitya P. Khasat Polydicyclopentadiene having improved stability and toughened with polymeric particles
JPH07138550A (ja) * 1993-11-16 1995-05-30 Three Bond Co Ltd エポキシ樹脂系粘接着剤組成物
JPH0881617A (ja) * 1994-09-14 1996-03-26 Dainippon Ink & Chem Inc 熱硬化性樹脂組成物

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