KR960031509A - 열경화성 실리콘 수지 - Google Patents

열경화성 실리콘 수지 Download PDF

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KR960031509A
KR960031509A KR1019960002499A KR19960002499A KR960031509A KR 960031509 A KR960031509 A KR 960031509A KR 1019960002499 A KR1019960002499 A KR 1019960002499A KR 19960002499 A KR19960002499 A KR 19960002499A KR 960031509 A KR960031509 A KR 960031509A
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South Korea
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group
silicone resin
rti
sio
compounds
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KR1019960002499A
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KR100359392B1 (ko
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로버트 하크니스 브라이언
마노루 다치카와
가스미 다케우치
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마쓰무라 다다시
다우 코닝 아시아, 리미티드
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Publication of KR960031509A publication Critical patent/KR960031509A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/24—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/06—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/12—Polysiloxanes containing silicon bound to hydrogen

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Silicon Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

경화 도중에 다량의 휘발 성분을 생성시키지 않고 경도가 우수한 고내열성의 광학적으로 투명한 경화 제품에 대한 전구체인 고도로 스핀 피복 가능한 실리콘 수지가 기재되어 있다.
이러한 실리콘 수지는 다음 일반식(1)의 실리콘 중합체를 포함한다.
(Ph2SiO)a(HSiO3/2)b(R1SiO3/2)c(1)
상기 식에서, R1은 수소원자 또는 헤테로원자를 함유할 수 있는 C1내지 C18탄화수소 그룹이며, Ph는 페닐 그룹이고, a+b+c는 6 내지 1,000이며, a(a+b+c)는 0.4 내지 0.6 미만이고, b/(b+c)는 0.2 내지 1.0이다.

Description

열경화성 실리콘 수지
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. 평균 중합도가 6 내지 1,000인 일반식(1)의 실리콘 중합체를 포함하는 실리콘 수지.
    (Ph2SiO)a(HSiO3/2)b(R1SiO3/2)c(1)
    상기 식에서, R1은 각각 서로 독립적으로 산소, 질소, 염소, 불소 및 규소로 이루어진 그룹으로부터 선택된 하나 이상의 원자를 함유할 수 있는 C1내지 C18탄화수소 그룹이고 ; Ph는 페닐 그룹이며 ; O의 또 다른 결합은 규소에 결합하여 실록산 결합을 형성하거나, 수소원자에 결합하여 실란올을 형성할 수 있고 ; 단량체 단위의 평균 비율은 a/(a+b+c)가 0.4 내지 0.6 미만이고 b/(b+c)가 0.2 내지 1.0의 범위로 되도록 하는 비율이다.
  2. HSiX3또는 HSiX와 R1SiX3와의 혼합물(여기서, X는 각각 독립적으로 염소원자 및 브롬 원자로부터 선택된 가수분해 가능한 그룹이고, R1은 독립적으로 산소, 질소, 염소, 불소 및 규소로 이루어진 그룹으로부터 선택된 하나 이상의 원자를 함유할 수 있는 C1내지 C18탄화수소 그룹이다)에 디페닐 실란디올을 첨가하여 가수분해 혼합물을 수득하는 단계 및 가수분해 혼합물을 100℃를 초과하지 않는 온도에서 가수분해시키는 단계를 포함하는, 제1항에 따르는 실리콘 수지를 제조하는 방법.
  3. 제2항에 있어서, 반응 전에, 반응물이 유기 용매에 용해되는 방법.
  4. 제1항에 따르는 실리콘 수지(a)와 염기성 화합물, 2가 및 4가 주석 화합물, 팔라듐 금속, 백금 금속, 팔라듐 화합물 및 백금 화합물로 이루어진 그룹으로부터 선택된 하나 이상의 촉매 성분(b)를 포함하는 열경화성 폴리오가노실록산 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960002499A 1995-02-02 1996-02-02 열경화성실리콘수지 KR100359392B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP01618695A JP3542185B2 (ja) 1995-02-02 1995-02-02 シリコーンレジン、これを含む組成物およびその硬化方法
JP95-016186 1995-02-02

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KR960031509A true KR960031509A (ko) 1996-09-17
KR100359392B1 KR100359392B1 (ko) 2003-01-24

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US (1) US5614603A (ko)
EP (1) EP0725103B1 (ko)
JP (1) JP3542185B2 (ko)
KR (1) KR100359392B1 (ko)
DE (1) DE69629405T2 (ko)
TW (1) TW413693B (ko)

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Publication number Publication date
DE69629405D1 (de) 2003-09-18
KR100359392B1 (ko) 2003-01-24
US5614603A (en) 1997-03-25
EP0725103B1 (en) 2003-08-13
JP3542185B2 (ja) 2004-07-14
EP0725103A3 (en) 1997-07-16
DE69629405T2 (de) 2004-06-09
TW413693B (en) 2000-12-01
JPH08208840A (ja) 1996-08-13
EP0725103A2 (en) 1996-08-07

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