KR960025875A - 전기 이중층 커패시터 - Google Patents

전기 이중층 커패시터 Download PDF

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KR960025875A
KR960025875A KR1019950059779A KR19950059779A KR960025875A KR 960025875 A KR960025875 A KR 960025875A KR 1019950059779 A KR1019950059779 A KR 1019950059779A KR 19950059779 A KR19950059779 A KR 19950059779A KR 960025875 A KR960025875 A KR 960025875A
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South Korea
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double layer
electric double
current collector
layer capacitor
positive electrode
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KR1019950059779A
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마나부 수하라
가즈야 히라쓰까
다께시 모리모또
가쓰지 이께다
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세야 히로미찌
아사히가라스 가부시끼가이샤
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Publication of KR960025875A publication Critical patent/KR960025875A/ko

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/04—Hybrid capacitors
    • H01G11/06—Hybrid capacitors with one of the electrodes allowing ions to be reversibly doped thereinto, e.g. lithium ion capacitors [LIC]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/32—Carbon-based
    • H01G11/34—Carbon-based characterised by carbonisation or activation of carbon
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/32—Carbon-based
    • H01G11/38—Carbon pastes or blends; Binders or additives therein
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/50—Electrodes characterised by their material specially adapted for lithium-ion capacitors, e.g. for lithium-doping or for intercalation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/54—Electrolytes
    • H01G11/58—Liquid electrolytes
    • H01G11/60—Liquid electrolytes characterised by the solvent
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/54—Electrolytes
    • H01G11/58—Liquid electrolytes
    • H01G11/62—Liquid electrolytes characterised by the solute, e.g. salts, anions or cations therein
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/66—Current collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/74—Terminals, e.g. extensions of current collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/78—Cases; Housings; Encapsulations; Mountings
    • H01G11/82—Fixing or assembling a capacitive element in a housing, e.g. mounting electrodes, current collectors or terminals in containers or encapsulations
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/66—Current collectors
    • H01G11/70—Current collectors characterised by their structure
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13—Energy storage using capacitors

Abstract

전기 이중층 커패시터는 주로 활성탄으로 이루어진 분극 전극 물질과 결합된 전류 콜렉터를 갖는 포지티브 전극과, 화학적 방법 또는 전기화학적 방법에 의해 리튬 이온을 흡장하고 방출할 수 있는 탄소 물질에 흡장된 리튬 이온을 갖는 탄소질의 물질과 결합되고 리튬과 함께 합금을 형성할 수 없는 다공성 금속의 전류 콜렉터를 갖는 네가티브 전극과, 리튬염을 함유하는 비수용성 전해질을 구비한다.

Description

전기 이중층 커패시터
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제 1도는 본 발명에 의한 코인형상의 EDLC의 일실시예를 나타내는 단면도.

Claims (12)

  1. 주로 활성탄으로 이루어진 분극 전극 물질과 결합된 전류 콜렉터를 갖는 포지티브 전극과, 화학적 방법 또는 전기화학적 방법에 의해 리튬 이온을 흡장하고 방출할 수 있는 탄소 물질에 흡장된 리튬 이온을 갖는 탄소질의 물질과 결합되고 리튬과 함께 합금을 형성할 수 없는 다공성 금속의 전류 콜렉터를 갖는 네가티브 전극과, 리튬염을 함유하는 비수용성 전해질을 구비하는 것을 특징으로 하는 전기 이중층 커패시터.
  2. 제1항에 있어서, 상기 네가티브 전극은 결합체와 리튬 이온을 흡장하고 방출할 수 있는 탄소 물질의 혼합물을 80% 이상의 다공율을 갖는 다공성 금속의 전류 콜렉터상에 지지하고 압축함으로써 두께가 0.1~1㎜로 되고 다공율이 5~80%로 되도록 형성되는 것을 특징으로 하는 전기 이중층 커패시터.
  3. 제1항에 있어서, 상기 네가티브 전극용 상기 전류 콜렉터는 90~99%의 다공율을 갖는 다공성 니켈이고, 상기 전류 콜렉터의 단면상에서 1㎝ 길이의 선을 가로지르는 동공의 평균 갯수가 적어도 5개인 것을 특징으로 하는 전기 이중층 커패시터.
  4. 제1항에 있어서, 리튬 이온을 흡장하고 방출할 수 있는 상기 탄소 물질이 흑연 물질, 높은 커패시티용 탄소 물질 또는 쉽게 흑연화할 수 있는 탄소 물질인 것을 특징으로하는 전기 이중층 커패시터.
  5. 제1항에 있어서, 리튬 이온을 흡장하고 방출할 수 있는 상기 탄소 물질의 X-선 회절에 의해 측정된[002] 면의 격자 공간(d002)이 0.365~0.390㎚인 것을 특징으로 하는 전기 이중층 커패시터.
  6. 제1항에 있어서, 상기 포지티브 전극용 상기 전류 콜렉터가 다공성 금속으로 이루어진 것을 특징으로 하는 전기 이중층 커패시터.
  7. 제6항에 있어서, 상기 포지티브 전극은 1000~3000㎡/g의 비표면적을 갖는 활성탄과 전기전도성 카본 블랙과 결합제로 구성된 분극 전극 물질을 80% 이상의 다공율을 갖는 다공성 금속의 전류 콜렉터상에 지지하고 압축함으로써 두께가 0.2~2.0㎜로 되고 다공율이 10~80%로 되도록 형성되는 것을 특징으로 하는 전기 이중층 커패시터.
  8. 제6항에 있어서, 상기 포지티브 전극용 상기 전류콜렉터는 다공성 알루미늄 또는 80~99%의 다공율을 갖는 다공성 니켈로 이루어지며, 다공성 금속의 단면상에서 1㎝ 길이의 선을 가로지르는 동공의 평균 갯수가 적어도 5개인 것을 특징으로 하는 전기 이중층 커패시터.
  9. 제1항에 있어서, 상기 리튬염은 LiCℓO4, LiBF4, LiN(CF3SO2)2, LiPF6으로 구성된 군으로부터 선택된 적어도 하나의 요소인 것을 특징으로 하는 전기 이중층 커패시터.
  10. 제1항에 있어서, 상기 비수용성전해질용 용매는 프로필렌카르보네이트, 에틸렌카르보네이트, 디에틸렌카르보네이트, 디메톡시에탄, 부틸렌카르보네이트, 디메틸카르보네이트, 술포란, 에틸메틸카르보네이트로 구성된 군으로부터 적어도 하나의 요소인 것을 특징으로 하는 전기 이중층 커패시터.
  11. 제1항에 있어서, 상기 포지티브 전극, 상기 네가티브 전극, 상기 비수용성 전해질이 케이싱과 커버를 구비하는 금속의 코인 형상 컨테이너내에 수용되고, 상기 포지티브 전극은 스테인레스 강 시트와 알루미늄과 스테인레스 강의 적층 시트로 이루어진 케이싱과 커버의 한쪽끝에 배치되고, 상기 네가티브 전극은 스테인레스강 시트, 니켈 시트, 구리 시트, 또는 스테인레스 강, 니켈, 구리로 구성된 군으로부터 선택된 적어도 2개의 요소의 적층 시트로 이루어진 커버 또는 케이싱의 다른 한쪽끝에 배치되는 것을 특징으로하는 전기 이중층 커패시터.
  12. 제1항에 있어서, b가 분극 포지티브 전극의 단일 전극 커패시티(단위:F)이고, d는 네가티브 전극의 리튬 이온 방출 커패시티(단위:㎃h)이고, V가 동작 전압 범위내의 포텐셜 차(단위: V)일때, bv/3.6d의 비가 0.05~0.90의 범위내에 있는 것을 특징으로 하는 전기 이중층 커패시터.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950059779A 1994-12-27 1995-12-27 전기 이중층 커패시터 KR960025875A (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP94-326109 1994-12-27
JP32610994 1994-12-27
JP95-141815 1995-06-08
JP14181595 1995-06-08

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KR960025875A true KR960025875A (ko) 1996-07-20

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DE (1) DE19548005B4 (ko)

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