KR950018026A - 메탈로센 및 촉매로서의 이의 용도 - Google Patents
메탈로센 및 촉매로서의 이의 용도 Download PDFInfo
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- KR950018026A KR950018026A KR1019940036506A KR19940036506A KR950018026A KR 950018026 A KR950018026 A KR 950018026A KR 1019940036506 A KR1019940036506 A KR 1019940036506A KR 19940036506 A KR19940036506 A KR 19940036506A KR 950018026 A KR950018026 A KR 950018026A
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- 239000003054 catalyst Substances 0.000 title claims 3
- 150000001875 compounds Chemical class 0.000 claims abstract 12
- 125000002950 monocyclic group Chemical group 0.000 claims abstract 10
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims abstract 8
- 229920001577 copolymer Polymers 0.000 claims abstract 7
- 239000003446 ligand Substances 0.000 claims abstract 5
- 238000000034 method Methods 0.000 claims abstract 5
- 125000005843 halogen group Chemical group 0.000 claims 20
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 16
- 125000000041 C6-C10 aryl group Chemical group 0.000 claims 14
- 239000004215 Carbon black (E152) Substances 0.000 claims 12
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 claims 11
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 claims 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 10
- 125000004429 atom Chemical group 0.000 claims 9
- 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims 6
- 125000006736 (C6-C20) aryl group Chemical group 0.000 claims 6
- 125000006374 C2-C10 alkenyl group Chemical group 0.000 claims 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 5
- 229910052739 hydrogen Inorganic materials 0.000 claims 5
- 239000001257 hydrogen Substances 0.000 claims 5
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 4
- 229910052799 carbon Inorganic materials 0.000 claims 4
- 125000004122 cyclic group Chemical group 0.000 claims 4
- 229910052732 germanium Inorganic materials 0.000 claims 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 4
- 229930195733 hydrocarbon Natural products 0.000 claims 4
- 229910052710 silicon Inorganic materials 0.000 claims 4
- 239000010703 silicon Substances 0.000 claims 4
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 150000002430 hydrocarbons Chemical class 0.000 claims 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 2
- 125000005915 C6-C14 aryl group Chemical group 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 2
- 125000003342 alkenyl group Chemical group 0.000 claims 2
- 239000000956 alloy Substances 0.000 claims 2
- 229910045601 alloy Inorganic materials 0.000 claims 2
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims 2
- 150000001721 carbon Chemical group 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 150000002367 halogens Chemical class 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- 230000000737 periodic effect Effects 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- -1 polycyclic olefin Chemical class 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- 229910052718 tin Inorganic materials 0.000 claims 2
- 229910052726 zirconium Inorganic materials 0.000 claims 2
- 125000002015 acyclic group Chemical group 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 125000002877 alkyl aryl group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- 239000003638 chemical reducing agent Substances 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 125000006413 ring segment Chemical group 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 238000002347 injection Methods 0.000 abstract 1
- 239000007924 injection Substances 0.000 abstract 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
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- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
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- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
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- C08F2420/00—Metallocene catalysts
- C08F2420/09—Cyclic bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is part of a cyclic group
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- C08F4/00—Polymerisation catalysts
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- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
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- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
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- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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Abstract
본 발명은 모노사이클릭 또는 폴리사이클릭 환 시스템을 통해 서로 결합된 2개 이상의 치환되거나 치환되지 않은 사이클로펜타디에닐 그룹[여기서, 하나 이상의 사이클로 펜타디에닐 그룹은 모노사이클릭 또는 폴리사이클릭 환 시스템에 융합된다]을 리간드로서 포함하는 입체강성 메탈로센 화합물 및 사이클로올레핀 공중합체를 제조하는 방법에 관한 것이다. 이 방법으로 제조한 사이클로올레핀 공중합체는 인열 강도가 크고 압출 부품 및 사출 성형품의 제조시에 적합하다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (15)
- 모노사이클릭 또는 폴리사이클릭 환 시스템을 통해 서로 결합된 2개 이상의 치환되거나 치환되지 않은 사이클로펜타디에닐 그룹[여기서, 하나 이상의 사이클로 펜타디에닐 그룹은 모노사이클릭 또는 폴리사이클릭 환 시스템에 융합된다]을 리간드로서 함유하고, 리간드 시스템이 배제되는 경우에는, 4-(n5-3'-알킬사이클로 펜타디에닐)-4, 6, 6-트리메틸-(n5-2-알킬-4, 5, -테트라하이드로 펜탈렌을 포함하는 입체강성(stereorgid) 메탈로센 화합물.
- 제1항에 있어서, 모노사이클릭 또는 폴리사이클릭 환 시스템이 6개 이상의 환 원자를 갖는 입체강성 메탈로센 화합물.
- 제1항에 있어서, 일반식 (I)로 나타내어지는 입체강성 메탈로센 화합물.상기식에서, M1은 주기율표의 Ⅲb족, Ⅳb족, Ⅴb족 또는 Ⅵb족으로 부터의 금속이고, ,M2는 탄소, 규소 또는 게르마늄이고, R1및 R2는 동일하거나 상이하며 수소 원자, C1-C40-탄화수소 함유 그룹(예:C1-C10-알킬 그룹, C1-C10-알콕시그룹, C6-C10-아릴그룹, C6-C25-아릴옥시 그룹, C2-C10-알케닐 그룹, C7-C40-아릴알킬 그룹 또는 C7-C40-아릴 알케닐 그룹), OH그룹, 할로겐 원자 또는 NRR14 2(여기서, R14는 할로겐 원자, C1-C10-알킬 그룹 또는 C6-C10-아릴그룹이다)이거나, R1및 R2는 이들을 연결시키는 원자와 함께 환 시스템을 형성하고, R3, R4, R5, R6, R7, R8및 R9는 동일하거나 상이하며, 수소 원자, 할로겐 원자, C1-C20-탄화수소 함유 그룹(예:할로겐화 될 수 있는 C1-C10-알킬 그룹, C6-C20-아릴 그룹, C6-C20-아릴 옥시 그룹, C2-C12-알케닐 그룹, C2-C12-알케닐 그룹, C7-C40-아릴알킬 그룹, C7-C40-알킬아릴 그룹 또는 C8-C40-아릴알케닐 그룹), -SiR14 3, -NR14 2, -SiOR14 3, -SISR14 3또는 -PR14 2라디칼(여기서, R14는 할로겐 원자, C1-C10-알킬 그룹 또는 C6-C10-아릴그룹이다)이거나, 2개 이상의 인접 라디칼 R3, R4, R5, R6, R7, R8및 R9는 이들을 연결시키는 원자와 함께 바람직하게는 탄소수가 4 내지 40, 특히 바람직하게는 6 내지 15인 환 시스템을 형성하고, R10은 수소 원자이거나, C1-C20-알킬 그룹, C1-C10-알콕시 그룹, C6-C20-아릴 그룹, C6-C20-아릴 옥시 그룹, C2-C12-알케닐 그룹, C7-C40-아릴알킬 그룹, C7-C40-알킬아릴 그룹 또는 C8-C40-아릴 알케닐 그룹(여기서, 이들 각각은 -NR14 3, -SiR14 3, -SR14 2또는 -OSiR14 3라디칼을 가질 수 있고, R14는 할로겐 원자, C1-C10-알킬 그룹 또는 C6-C10-아릴그룹이다)와 같은 C1-C40-탄화수소 함유 그룹이거나 또는 R10은 라디칼 R3, R4, R5및 R6하나 이상에 연결되어 있고, R11은(여기서, n은 1 내지 20의 정수이고, 0 내지 20의 정수이며, X는 O,=NR14, =CO14, =PR, =P(O)R14, =SO, =SO2또는 -S-이고, R14는 할로겐 원자, C1-C10-알킬 그룹또는 C6-C10-아릴 그룹으며, R15및 R16은 동일하거나 상이하며 수소원자 또는 할로겐 원자 이거나, C1-C10-알킬 그룹, C1-C10-플루오로알킬 그룹, C1-C10-알콕시 그룹, C6-C10-아릴 그룹, C6-C10-플루오로아릴 그룹, C6-C10-아릴옥시 그룹, C2-C10-알케닐그룹, C7-C40-아릴알킬 그룹, C7-C40-알칼아릴 그룹 또는 C8-C40-아릴알케닐 그룹과 같은 C1-C40-탄화수소 함유 그룹이거나, 2개의 라디칼 R15, 2개의 라디칼 R16또는 R15와 R16은 각 경우에 있어서, 이들을 연결시키는 원자와 함께, 하나 이상의 환을 형성하고, M3은 규소, 게르마늄 또는 주석이다)이고, R12및 R13은 동일하거나 상이하며 수소 원자이거나, C1-C20-알킬 그룹, C1-C10-알콕시 그룹, C6-C20-아릴 그룹, C6-C20-아릴옥시 그룹, C2-C12-알케닐 그룹, C7-C40-아릴알킬 그룹, C7-C40-알킬아릴 그룹 또는 C8-C40-아릴알케닐 그룹[여기서, 이들 각각은 -NR14 3, -SR14 2, -SiR14 3또는 - OSiR14 3라디칼(여기서, R14는 할로겐 원자, C1-C10-알킬 그룹 또는 C6-C10-아릴 그룹이다)을 가지거나 할로겐을 가질 수 있다]와 같은 C1-C40-탄화수소 함유 그룹이고, R23은 동일하거나 상이하며 수소 원자, 할로겐 원자 또는 C1-C40-탄화수소 함유 그룹(예: C1-C10-알킬 그룹, C1-C10-알콕시 그룹, C6-C10-아릴 그룹, C6-C25-아릴옥시 그룹, C2-C10-알케닐 그룹, C7-C40-아릴알킬 그룹 또는 C7-C40-아릴알케닐 그룹)이거나, 하나 이상의 라디칼 R23은 R15및 R16라디칼 중의 하나 또는 둘 모두에 결합되고/되거나 하나 이상의 라디칼 R10, R11, R12및 R13에 결합되고, m은 0 내지 24의 정수이고, 단 M2가 C이고, m이 0이고, R11이 CH2일 경우, 라디칼 R4, R8, R10, R12및 R13중의 하나 이상은 알킬이 아니고/아니거나 라디칼 R3, R5, R6, R7및 R9중의 하나 이상은 수소가 아니다.
- 제3항에 있어서, M1이 지르코늄이고, R1및 R2가 동일하며 할로겐 원자이고, R3, R4, R5, R6, R7, R8및 R9가 동일하거나 상이하고 수소, C1-C4-알킬 그룹 또는 C6-C14-아릴 그룹이거나, R8와 R9및 R3과 R4및/또는 R5와 R6이 이들을 연결시키는 원자와 함께 방향족 탄화수소 환을 형성하고, M2가 탄소원자이고, R10이 C1-C6-알킬그룹이고, R11이 -CH2-CH2-이고, R12및 R13이 동일하거나 상이하며 메틸 또는 페닐그룹이고 m이 0인 입체강성 메탈로센 화합물.
- 지지되고/되거나 예비중합된 제1항 내지 제4항 중의 어느 한 항에 따르는 입체강성 메탈로센 화합물을 하나 이상 함유하는 촉매 성분.
- 모노사이클릭 또는 폴리사이클릭 환 시스템을 통해 서로 결합된 2개 이상의 치환되거나 치환되지 않은 사이클로펜타디에닐 그룹[여기서, 하나 이상의 사이클로펜타디에닐 그룹은 모노사이클릭 또는 폴리사이클릭 환 시스템에 융합된다]을 리간드로서 포함하는 하나 이상의 입체강성 메탈로센 화합물 및 하나 이상의 조촉매를 함유하는 촉매의 존재하에서, a) 하나 이상의 폴리사이클릭 올레핀, b) 하나 이상의 아시이클릭 1-올레핀 및 c) 필요한 경우, 하나 이상의 모노사이클릭 올레핀을 중합시킴으로써 사이클로올레핀 공중합체를 제조하는 방법.
- 제6항에 있어서, 입체강성 메탈로센 화합물의 모노사이클릭 또는 폴리사이클릭 환 시스템이 6개 이상의 환원자를 갖는 방법.
- 제6항에 있어서, 입체강성 메탈로센 화합물이 일반식 (I)의 화합물인 방법.상기식에서, M1은 주기율표의 Ⅲb족, Ⅳb족, Ⅴb족 또는 Ⅵb족으로 부터의 금속이고, M2는 탄소, 규소 또는 게르마늄이고, R1및 R2는 동일하거나 상이하며 수소 원자, C1-C40-탄화수소 함유 그룹(예: C1-C10-알킬 그룹, C1-C10-알콕시 그룹, C6-C10-아릴 그룹, C6-C25-아릴옥시 그룹, C2-C10-알케닐 그룹, C7-C40-아릴알킬 그룹 또는 C7-C40-아릴알케닐 그룹), OH그룹, 할로겐 원자 또는 NR14 2(여기서, R14는 할로겐 원자, C1-C10-알킬 그룹 또는 C6-C10-아릴 그룹이다)이거나, R1및 R2는 이들을 연결시키는원자와 함께 환시스템을 형성하고, R3, R4, R5, R6, R7, R8및 R9가 동일하거나 상이하며, 수소 원자, 할로겐 원자, C2-C20-탄화수소 함유 그룹(예: 할로겐화할 수 있는 C1-C10-알킬 그룹, C6-C20-아릴 그룹, C6-C20-아릴옥시 그룹, C2-C12알케닐 그룹, C7-C40아릴알킬 그룹, C7-C40알킬아릴 그룹 또는 C8-C40-아릴알케닐 그룹), -SiR14 3, -NR14 2, -SiOR14 3, -SiSR14 3또는 -PR14 2라디칼(여기서, R14는 할로겐 원자, C1-C10-알킬 그룹 또는 C6-C10-아릴 그룹이다)이거나, 2개 이상의 인접 라디칼 R3, R4, R5, R6, R7, R8및 R9는 이들을 연결시키는 원자와 함께, 바람직하게는 탄소수가 4 내지 40, 특히 바람직하게는 6 내지 15인 환시스템을 형성하고, R10은 수소 원자이거나, C1-C20-알킬 그룹, C1-C10-알콕시 그룹, C6-C20-아릴 그룹, C6-C20-아릴옥시 그룹, C2-C12-알케닐 그룹, C7-C40-아릴알킬 그룹, C7-C40-알킬아릴 그룹 또는 C8-C40-아릴알케닐 그룹(여기서, 이들 각각은 -NR14 3, SiR14 3, -SR14 2또는 -OSiR14 3라디칼을 가질 수 있고, R14는 할로겐 원자, C1-C10-알킬 그룹 또는 C6-C10-아릴 그룹이다)와 같은 C1-C40-탄화수소 함유 그룹이거나 R10은 라디칼 R3, R4, R5및 R6중의 하나 이상에 연결되어 있고, R11은(여기서, n은 1 내지 20의 정수이고, 1은 0 내지 20의 정수이며, X는 O, =NR14, =CO, =PR14, =P(O)R14, =SO, =SO2또는 -S-이고, R14는 할로겐 원자, C1-C10-알킬 그룹 또는 C6-C10-아릴 그룹이며, R15및 R16은 동일하거나 상이하며 수소 원자 또는 할로겐 원자이거나, C1-C10-알킬 그룹, C1-C10-플루오로알킬 그룹, C1-C10-알콕시 그룹, C6-C10-아릴 그룹, C6-C10-플루오로아릴 그룹, C6-C10-아릴옥시 그룹, C2-C10-알케닐 그룹, C7-C40-아릴알킬 그룹, C7-C40-알킬아릴 그룹 또는 C8-C40-아릴 알케닐 그룹과 같은 C1-C40-탄화수소 함유그룹이거나, 2개의 라디칼 R15, 2개의 라디칼 R16또는 R15와 R16은 각 경우에 있어서, 이들을 연결시키는 원자와 함께, 하나 이상의 환을 형성하고, M3은 규소, 게르마늄 또는 주석이다)이고, R12및 R13은 동일하거나 상이하며 수소 원자이거나, C1-C20-알킬 그룹, C1-C10-알콕시 그룹, C6-C20-아릴 그룹, C6-C20-아릴옥시 그룹, C2-C12-알케닐 그룹, C7-C40-아릴알킬 그룹, C7-C40-알킬아릴 그룹 또는 C8-C40-아릴알케닐 그룹[여기서, 이들 각각은 -NR14 3, -SR14 2, -SiR14 3또는 - OSiR14 3라디칼(여기서, R14는 할로겐 원자, C1-C10-알킬 그룹 또는 C6-C10-아릴 그룹이다)을 가지거나 할로겐을 가질 수 있다]와 같은 C1-C40-탄화수소 함유 그룹이고, R23은 동일하거나 상이하며 수소 원자, 할로겐 원자 또는 C1-C40-탄화수소 함유 그룹(예: C1-C10-알킬 그룹, C1-C10-알콕시 그룹, C6-C10-아릴 그룹, C6-C25-아릴옥시 그룹, C2-C10-알케닐 그룹, C7-C40-아릴알킬 그룹 또는 C7-C40-아릴알케닐 그룹)이거나, 하나 이상의 라디칼 R23은 R15및 R16라디칼 중의 하나 또는 둘 모두에 결합되고/되거나 하나 이상의 라디칼 R10, R11, R12및 R13에 결합되고, m은 0 내지 24의 정수이고.
- 제8항에 있어서, M1이 지르코늄이고, R1및 R2가 동일하며 할로겐 원자이고, R3, R4, R5, R6, R7, R8및 R9가 동일하거나 상이하고 수소, C1-C4-알킬 그룹 또는 C6-C14-아릴 그룹이거나, R8와 R9및 R3과 R4및/또는 R5와 R6이 이들을 연결시키는 원자와 함께 방향족 탄화수소 환을 형성하고, M2가 탄소원자이고, R10이 C1-C6-알킬그룹이고, R11이 -CH2-CH2-이고, R12및 R13이 동일하거나 상이하며 메틸 또는 페닐그룹이고 m이 0인 방법.
- 제6항 내지 제9항 중의 어느 한 항에 있어서, 조촉매가 알루민옥산인 방법.
- 제6항 내지 제10항 중의 어느 한 항에 따르는 방법으로 제조할 수 있는 사이클로올레핀 공중합체.
- 제11항에 따르는 하나 이상의 사이클로올레핀 공중합체를 함유하는 중합체합금.
- 제11항에 따르는 하나 이상의 사이클로올레핀 공중합체를 함유하는 성형품.
- 제12항에 따르는 중합체 합금을 함유하는 성형품.
- 사이클로올레핀 공중합체를 제조하기 위한, 리간드로서, 모노사이클릭 또는폴리사이클릭 환 시스템을 통해 서로 결합된 2개 이상의 치환되거나 치환되지 않은 사이클로 펜타디에닐 그룹[여기서, 하나 이상의 사이클로펜타디에닐 그룹은 모노사이클릭 또는 폴리사이클릭 환 시스템에 융합된다]을 포함하는 입체강성 메탈로센 화합물의 용도.참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19934343566 DE4343566A1 (de) | 1993-12-21 | 1993-12-21 | Metallocene und ihre Verwendung als Katalysatoren |
DEP4343566.1 | 1993-12-21 | ||
DE19934344631 DE4344631A1 (de) | 1993-12-24 | 1993-12-24 | Verfahren zur Herstellung von Cycloolefincopolymeren |
DEP4344631.0 | 1993-12-24 | ||
DE4432617A DE4432617A1 (de) | 1994-09-14 | 1994-09-14 | Metallocene und ihre Verwendung als Katalysatoren |
DEP4432617.3 | 1994-09-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR950018026A true KR950018026A (ko) | 1995-07-22 |
Family
ID=27205883
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR1019940036506A KR950018026A (ko) | 1993-12-21 | 1994-12-21 | 메탈로센 및 촉매로서의 이의 용도 |
Country Status (15)
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---|---|
US (2) | US5710297A (ko) |
EP (1) | EP0659758B1 (ko) |
JP (1) | JP3493387B2 (ko) |
KR (1) | KR950018026A (ko) |
CN (2) | CN1056148C (ko) |
AT (1) | ATE173480T1 (ko) |
AU (1) | AU687927B2 (ko) |
BR (1) | BR9405204A (ko) |
CA (1) | CA2138723C (ko) |
CZ (1) | CZ324994A3 (ko) |
DE (1) | DE59407303D1 (ko) |
ES (1) | ES2123701T3 (ko) |
FI (1) | FI945959A (ko) |
HU (1) | HU220638B1 (ko) |
NO (1) | NO307520B1 (ko) |
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-
1994
- 1994-12-19 FI FI945959A patent/FI945959A/fi unknown
- 1994-12-20 NO NO944949A patent/NO307520B1/no not_active IP Right Cessation
- 1994-12-20 ES ES94120162T patent/ES2123701T3/es not_active Expired - Lifetime
- 1994-12-20 EP EP94120162A patent/EP0659758B1/de not_active Expired - Lifetime
- 1994-12-20 DE DE59407303T patent/DE59407303D1/de not_active Expired - Fee Related
- 1994-12-20 AT AT94120162T patent/ATE173480T1/de not_active IP Right Cessation
- 1994-12-20 CZ CZ943249A patent/CZ324994A3/cs unknown
- 1994-12-21 CN CN94120496A patent/CN1056148C/zh not_active Expired - Fee Related
- 1994-12-21 KR KR1019940036506A patent/KR950018026A/ko not_active Application Discontinuation
- 1994-12-21 HU HU9403703A patent/HU220638B1/hu not_active IP Right Cessation
- 1994-12-21 BR BR9405204A patent/BR9405204A/pt active Search and Examination
- 1994-12-21 JP JP34078694A patent/JP3493387B2/ja not_active Expired - Fee Related
- 1994-12-21 AU AU81654/94A patent/AU687927B2/en not_active Ceased
- 1994-12-21 CA CA002138723A patent/CA2138723C/en not_active Expired - Fee Related
-
1996
- 1996-09-13 US US08/712,681 patent/US5710297A/en not_active Expired - Fee Related
- 1996-12-26 US US08/780,179 patent/US5990254A/en not_active Expired - Fee Related
-
1999
- 1999-04-21 CN CN99105162A patent/CN1235172A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
HU220638B1 (hu) | 2002-03-28 |
AU687927B2 (en) | 1998-03-05 |
NO944949D0 (no) | 1994-12-20 |
CN1056148C (zh) | 2000-09-06 |
CZ324994A3 (en) | 1996-04-17 |
EP0659758B1 (de) | 1998-11-18 |
ATE173480T1 (de) | 1998-12-15 |
JPH07292020A (ja) | 1995-11-07 |
DE59407303D1 (de) | 1998-12-24 |
CA2138723A1 (en) | 1995-06-22 |
EP0659758A1 (de) | 1995-06-28 |
CN1235172A (zh) | 1999-11-17 |
CN1112564A (zh) | 1995-11-29 |
NO944949L (no) | 1995-06-22 |
US5710297A (en) | 1998-01-20 |
FI945959A (fi) | 1995-06-22 |
AU8165494A (en) | 1995-06-29 |
ES2123701T3 (es) | 1999-01-16 |
CA2138723C (en) | 2005-07-26 |
FI945959A0 (fi) | 1994-12-19 |
BR9405204A (pt) | 1995-08-01 |
NO307520B1 (no) | 2000-04-17 |
JP3493387B2 (ja) | 2004-02-03 |
US5990254A (en) | 1999-11-23 |
HUT70864A (en) | 1995-11-28 |
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