KR930002361A - 플루오레닐 함유 메탈로센 제조 방법 - Google Patents

플루오레닐 함유 메탈로센 제조 방법 Download PDF

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KR930002361A
KR930002361A KR1019920010768A KR920010768A KR930002361A KR 930002361 A KR930002361 A KR 930002361A KR 1019920010768 A KR1019920010768 A KR 1019920010768A KR 920010768 A KR920010768 A KR 920010768A KR 930002361 A KR930002361 A KR 930002361A
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fluorenyl
ppm
radical
metallocene
peak
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KR100192683B1 (ko
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지이 알트 헬무트
조오지프 파락칼 시리아크
파치디스 콘스탄티노스
브루스 웰치 멜빈
레오나아드 기어츠 롤프
츠-윈 후시이 에릭
폴 맥다니엘 막스
아아르 호우리 길
데이빗 스미스 폴
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제이 이이 휘립프스
휘립프스 피트로오리암 캄파니
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Abstract

내용 없음.

Description

플루오레닐 함유 메탈로센 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 촉매로서(1-플루오레닐-1-시클로펜타디에닐메탄) 지르코늄 디클로라이드를 사용해서 4-메틸-펜텐을 중합함으로써 생성되는 중합체의13C NMR 스펙트럼이다.

Claims (23)

  1. a) 플루오레닐 염을 생성하기 위해 메탈로센의 전이금속과 q-배위된 비 할로겐화된 액체로 본질적으로 구성된 액체 희석제의 존재하에, 알칼리 금속 알킬을 플루오레닐-함유 화합물과 반응시키고; b) 그리고 나서, 일반식 MeOK(여기서 Me는 주기율표의 IVB, VB 또는 VIB 족금속이고, 각 Q는 같거나 다르고, 1-20 탄소원자를 가지는 히드로카르빌 또는 히드로카르빌옥시 라디칼 또는 할로겐이고, K는 Me의 남아 있는 원자가를 채우는데 충분한 수이다.)의 전이 금속 화합물과 플루오레닐 염을 반응시키되 전이 금속 화합물과 플루오레닐 염의 반응은 메탈로센의 전이 금속과 비-배위된 비할로겐화된 액체로 본질적으로 구성된 액체 희석제의 존재하에 수행되는 것으로 구성되는 플루오레닐-함유 메탈로센 제조 방법.
  2. 제1항에 있어서, Me가 Zr 또는 Hf인 방법.
  3. 제1항에 있어서, 각 Q가 할로겐인 방법.
  4. 1-3항 중 어느 하나에 있어서, 단계 a) 및 b)를 위한 액체 희석제가 같거나 다를 수 있는 것으로, 액체 탄화수소 또는 디에틸 에테르인 방법.
  5. 제4항에 있어서, 액체 탄화수소가 액체 알칸 또는 톨루엔인 방법.
  6. 제5항에 있어서, a) 및 b)에 사용된 액체 알칸이 같은 것으로, 펜탄 또는 헥산인 방법.
  7. 1-6항 중 어느 하나에 있어서, 상기플루오레닐-함유 화합물이, 플루오레닐 라디칼이 브리징기에 의해 다른 시클로펜타디에닐 라디칼에 결합되고 생성된 메탈로센이 샌드위치 결합 메탈로센인 브리징 화합물인 방법.
  8. 제7항에 있어서, F1이 플루오레닐 라디칼이고, Cp가 시클로펜타디에닐, 인데닐, 테트라히드로인데닐 또는 플루오레닐 라디칼이고, 각 R이 같거나 다르고 1-20 탄소 원자를 가진 유기 라디칼이고, R″가 구조적 브리지 연결(F1Rn) 및 (CpRm)이고, n이 0-7의 범위내 수이고, m은 0-7의 범위내 수인 일반식 R″(F1Rn)(CpRm) MeQk의 메탈로센을 생성하는 방법.
  9. 제8항에 있어서, 생성된 메탈로센이 (,2-디플루오레닐에탄) 지르코늄 디클로라이드, (1-플루오레닐)-2-(시클로펜타디에닐)에탄지르코늄 디클로라이드, (1-플루오레닐)-2-(인데닐)에탄 지르코늄 디클로라이드, 1,2-디(2-터트-부틸플루오레닐)에탄 지르코늄 디클로라이드, (1-플루오레닐-2-메틸-2-인데닐)에탄 지르코늄 디클로라이드, 또는 (1,2-디플루오레닐에탄) 하프늄 디클로라이드인 방법.
  10. 제8항에 있어서, R″가 2가 메틸렌 라디칼 -CH2-인 방법.
  11. 제10항에 있어서, F1Rn이 비치환 플루오레닐 라디칼이고 CpRm이 비치환 시클로 펜타디에닐 라디칼인 방법.
  12. 제10항에 있어서, 생성된 메탈로센의 리간드가 1-플루오레닐-1-시클로펜타디에닐 메탄인 방법.
  13. 적당한 중합 조건하에, 제1-6항중 어느 하나에 따른 방법에 의해 생성된 메탈로센 및 적합한 보조 촉매로 구성되는 촉매 시스템과 상기 올레핀을 접촉시키는 것으로 구성되는 올레핀 중합방법.
  14. 제13항에 있어서, 상기 보조 촉매가 알킬 알루미녹산을 포함하는 방법.
  15. 제14항에 있어서, 프로필렌 단독중합체가 생성되는 방법.
  16. 제14항에 있어서, 4-메틸-1-펜텐의 단독중합체가 생성되는 방법.
  17. 제14항에 있어서, 에틸렌이 0.91 이하의 밀도를 가지는 공중합체를 생성하기 위해 C4-C8알파-올레핀 공단량체와 중합되는 방법.
  18. 제17항에 있어서, 0.90 이하의 밀도 및 적어도 약 106%의 상대적 공단량체 분산도를 가지는 에틸렌 및 1-헥센으로 본질적으로 구성되는 공중합체를 생성하는 방법.
  19. 제18항에 있어서, 공중합체가 약 0.88의 밀도를 가지는 방법.
  20. 42.0 및 43.5ppm의 범위내 존재하는 0.5 이상의 전체 피이크 세기인 피이크롤 43.1ppm에서 가지는13C NMR 스펙트럼을 가지는 4-메틸-1-펜덴의 단독중합체.
  21. 제20항에 있어서,13C NMR 스펙트럼에서, 약 46.1ppm에서의 피이크위 다음의 가장 강한 피이크가 46.1ppm 및 43.1ppm에서 주요 피이크 사이의 임의 피이크보다 더 강하고, 43.1ppm 및 35ppM 사이의 다음의 가장 강한 피이크가 46.1ppm 및 43.1ppm에서 주요 피이크 사이의 임의 피이크보다 더 강한 단독중합체.
  22. 1-플루오레닐-1-시클로펜타디에닐 메탄 지르코늄 디클로라이드로 본질적으로 구성되는 샌드위치-결합 메탈로센.
  23. 실시예 중 어느 하나를 참고로 앞서 기술된 바와같이 실질적으로 플루오레닐-함유 메탈로센을 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920010768A 1991-07-23 1992-06-20 플루오레닐 함유 메탈로센 화합물, 이의 제조방법 및 이의 용도 KR100192683B1 (ko)

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NO922910L (no) 1993-01-25
DE69232608T2 (de) 2002-11-28
HUT63972A (en) 1993-11-29
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SG44707A1 (en) 1997-12-19
US5436305A (en) 1995-07-25
EP0524624A3 (en) 1993-05-05
CZ230392A3 (en) 1993-02-17
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SK230392A3 (en) 1995-05-10
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IE922381A1 (en) 1993-01-27
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AU649821B2 (en) 1994-06-02
RO111683B1 (ro) 1996-12-30
CN1068829A (zh) 1993-02-10
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