KR960000935A - 사이클로올레핀 공중합체를 제조하는 방법 - Google Patents
사이클로올레핀 공중합체를 제조하는 방법 Download PDFInfo
- Publication number
- KR960000935A KR960000935A KR1019950017248A KR19950017248A KR960000935A KR 960000935 A KR960000935 A KR 960000935A KR 1019950017248 A KR1019950017248 A KR 1019950017248A KR 19950017248 A KR19950017248 A KR 19950017248A KR 960000935 A KR960000935 A KR 960000935A
- Authority
- KR
- South Korea
- Prior art keywords
- group
- same
- aryl
- cycloolefin
- different
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F232/00—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
- C08F32/02—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having no condensed rings
- C08F32/04—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having no condensed rings having one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Abstract
본 발명은 하나 이상의 공촉매 및 하나 이상의 일반식(I)의 메탈로센을 함유하는 촉매의 존재하에 하나 이상의 사이클로올레핀 및 하나 이상의 비환식 올레핀의 중합에 의해 사이클로올레핀 공중합체를 제조하는 방법에 관한 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (6)
- 하나 이상의 공촉매 및 하나 이상의 일반식(I)의 메탈로센을 함유하는 촉매의 존재하에 하나 이상의 사이클로올레핀 및 하나 이상의 비환식 올레핀의 중합에 의해 사이클로올레핀 공중합체를 제조하는 방법.상기 식에서,M은 원소 주기율표의 IVb족, Vb족 또는 VIb족 금속이고, R1및 R2는 동일하거나 상이하며, 각각 C1-C10-알킬그룹, C6-C10-아릴그룹,C1-C10알콕시 그룹, C6-C10-아릴옥시 그룹, C2-C10-알케닐 그룹, C7-C40-아릴알킬 그룹, C7-C40-알킬아릴 그룹, C8-C40-아릴알케닐 그룹,할로겐 원자 또는 트리플루오로설폰산 라디칼이고, R3및 R4는 동일하거나 상이하며, 각각 전이 금속과 샌드위치 구조를 형성할수 있는 일반식 또는 다환식 탄화수소 라디칼이고, R5및 R6은 동일하거나, 상이하며, 각각 수소원자, 할로겐원자, C1-C10-알킬그룹, C1-C10-알콕시 그룹, C6-C10-아릴그룹, C6-C10-아릴옥시그룹, C2-C10-알케닐 그룹, C7-C40-아릴알킬 그룹, C7-C40-알킬아릴 그룹, C8-C40-아릴알케닐 그룹,C1-C10-할로알킬 그룹, -SiR7 3-, NR7 2-, -PR7 2-, -P(O)R7 2-, Si(OR7)7R2-, Si(OR7)2R7-, Si(OR7)3-, -AsR7 2- 또는 SR7-라디칼이고, 라디칼 R7은 동일하거나 상이하며, 각각 C1-C10알킬그룹,C1-C10알콕시 그룹,C6-C10-아릴 그룹, C6-C10-아릴옥시그룹, C2-C10-알케닐 그룹, C7-C40-아릴알킬 그룹, C7-C40-알킬아릴 그룹, C8-C40-아릴알케닐 그룹, 할로겐 원자 또는 트리플루오로메틸 설폰산 그룹이다.
- 제1항에 있어서, 일반식(I)의 메탈로센에서 M이 티탄, 지르코늄 또는 하프늄이고, R1및 R2가 동일하고 각각 C1-C10-알킬그룹 또는 할로겐 원자이고, R3및 R2가 동일하고 각각 치환된 사이클로펜타디에닐, 인데닐 또는 치환된 인데닐이고 R5및 R6이 동일하거나 상이하며, 각각 C1-C10-알킬그룹 또는 C6-C10-아릴그룹인 방법.
- 제1항 또는 제2항에 있어서, 공촉매가 알루민옥산의 방법.
- 제1항 내지 제3항 중 어느 한 항에 있어서, 하나 이상의 다환식 올렌핀 및 하나 이상의 비환식 올레핀이 중합되는 방법.
- 결정성 에틸렌 연쇄를 함유하지 않고, 인장강도가 50 내지 100MPa이며, 점도수가 100 내지 250㎤/g인, 하나 이상의 사이클로올레핀, 에틸렌및, 필요에 따라, 하나 이상의 탄소수 3이상인 비환식 올레핀의 반복단위를 함유하는 사이클로올레핀 공중합체.
- 제5항에 따른 사이클로올레핀 공중합체를 함유하는 성형제품.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4422157.6 | 1994-06-24 | ||
DE4422157A DE4422157A1 (de) | 1994-06-24 | 1994-06-24 | Verfahren zur Herstellung von Cycloolefincopolymeren |
Publications (2)
Publication Number | Publication Date |
---|---|
KR960000935A true KR960000935A (ko) | 1996-01-25 |
KR100386759B1 KR100386759B1 (ko) | 2003-08-09 |
Family
ID=6521429
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019950017248A KR100386759B1 (ko) | 1994-06-24 | 1995-06-24 | 사이클로올레핀공중합체의제조방법 |
Country Status (7)
Country | Link |
---|---|
US (1) | US5698645A (ko) |
EP (1) | EP0688801B1 (ko) |
JP (1) | JP3703525B2 (ko) |
KR (1) | KR100386759B1 (ko) |
CN (1) | CN1116324C (ko) |
CA (1) | CA2152552C (ko) |
DE (2) | DE4422157A1 (ko) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19546500A1 (de) * | 1995-12-13 | 1997-06-19 | Hoechst Ag | Verfahren zur Herstellung eines Cycloolefincopolymeren |
DE19633641A1 (de) * | 1996-08-21 | 1998-02-26 | Hoechst Ag | Elastomere Cycloolefincopolymere |
DE19652774A1 (de) * | 1996-12-19 | 1998-06-25 | Hoechst Ag | Folien |
EP0914323B1 (en) * | 1997-03-29 | 2003-08-06 | Basell Polyolefine GmbH | Metallocenes and catalysts for polymerization of olefins |
US5889128A (en) * | 1997-04-11 | 1999-03-30 | Massachusetts Institute Of Technology | Living olefin polymerization processes |
US6632318B1 (en) | 1999-09-09 | 2003-10-14 | Baxter International Inc. | Method for solvent bonding polyolefins |
US6590033B2 (en) | 1999-09-09 | 2003-07-08 | Baxter International Inc. | Cycloolefin blends and method for solvent bonding polyolefins |
US6613187B1 (en) | 1999-09-09 | 2003-09-02 | Baxter International Inc | Solvent bonding method for polyolefin materials |
US6297322B1 (en) | 1999-09-09 | 2001-10-02 | Baxter International Inc. | Cycloolefin blends and method for solvent bonding polyolefins |
US6497676B1 (en) | 2000-02-10 | 2002-12-24 | Baxter International | Method and apparatus for monitoring and controlling peritoneal dialysis therapy |
US6677175B2 (en) | 2000-07-28 | 2004-01-13 | Promerus, Llc | Optical waveguides and methods for making the same |
US6372848B1 (en) | 2000-10-10 | 2002-04-16 | Baxter International Inc. | Blend of ethylene and α-olefin copolymers obtained using a metallocene catalyst for fabricating medical films and tubings |
US20030125662A1 (en) | 2002-01-03 | 2003-07-03 | Tuan Bui | Method and apparatus for providing medical treatment therapy based on calculated demand |
US7238164B2 (en) | 2002-07-19 | 2007-07-03 | Baxter International Inc. | Systems, methods and apparatuses for pumping cassette-based therapies |
US20060255049A1 (en) * | 2002-08-09 | 2006-11-16 | Fort James Corporation | Stretch blow-molded stackable tumbler |
US7101654B2 (en) * | 2004-01-14 | 2006-09-05 | Promerus Llc | Norbornene-type monomers and polymers containing pendent lactone or sultone groups |
WO2006100974A1 (ja) * | 2005-03-18 | 2006-09-28 | Mitsui Chemicals, Inc. | 太陽電池容器用樹脂組成物 |
JP5295566B2 (ja) * | 2005-11-24 | 2013-09-18 | トパース・アドヴァンスト・ポリマーズ・ゲーエムベーハー | シクロオレフィン系共重合体 |
DE102007006825A1 (de) | 2007-02-07 | 2008-08-14 | Evonik Röhm Gmbh | Kunststoffformkörper mir anisotroper Lichtstreuung |
US8558964B2 (en) | 2007-02-15 | 2013-10-15 | Baxter International Inc. | Dialysis system having display with electromagnetic compliance (“EMC”) seal |
US7998115B2 (en) | 2007-02-15 | 2011-08-16 | Baxter International Inc. | Dialysis system having optical flowrate detection |
US7731689B2 (en) | 2007-02-15 | 2010-06-08 | Baxter International Inc. | Dialysis system having inductive heating |
US8361023B2 (en) | 2007-02-15 | 2013-01-29 | Baxter International Inc. | Dialysis system with efficient battery back-up |
US8870812B2 (en) | 2007-02-15 | 2014-10-28 | Baxter International Inc. | Dialysis system having video display with ambient light adjustment |
US8092628B2 (en) | 2008-10-31 | 2012-01-10 | Brewer Science Inc. | Cyclic olefin compositions for temporary wafer bonding |
US8771927B2 (en) * | 2009-04-15 | 2014-07-08 | Brewer Science Inc. | Acid-etch resistant, protective coatings |
DE102010030074A1 (de) | 2010-06-15 | 2011-12-15 | Evonik Degussa Gmbh | Kunststoff-Photovoltaik-Modul und Verfahren zu seiner Herstellung |
JP6176015B2 (ja) | 2012-11-01 | 2017-08-09 | 日本ポリプロ株式会社 | メタロセン錯体およびオレフィンの重合方法 |
JP5710035B2 (ja) * | 2013-02-27 | 2015-04-30 | 日本ポリエチレン株式会社 | メタロセン化合物およびオレフィン重合体の製造方法 |
US11179516B2 (en) | 2017-06-22 | 2021-11-23 | Baxter International Inc. | Systems and methods for incorporating patient pressure into medical fluid delivery |
CN109593160A (zh) * | 2017-09-30 | 2019-04-09 | 中国石化扬子石油化工有限公司 | 一种环烯烃共聚物的制备方法 |
CN109627366A (zh) * | 2017-10-09 | 2019-04-16 | 中国石化扬子石油化工有限公司 | 一种茂金属催化剂及在环烯烃共聚物制备中的应用 |
CN112745431B (zh) * | 2020-12-23 | 2023-04-21 | 广东华锦达新材科技有限公司 | 一种环烯烃共聚物及其制备方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5003019A (en) * | 1987-03-02 | 1991-03-26 | Mitsui Petrochemical Industries, Ltd. | Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers |
DE3922546A1 (de) * | 1989-07-08 | 1991-01-17 | Hoechst Ag | Verfahren zur herstellung von cycloolefinpolymeren |
ATE212042T1 (de) * | 1990-03-06 | 2002-02-15 | Mitsui Chemicals Inc | Statistische cycloolefincopolymere und verfahren zu ihrer herstellung |
US5371158A (en) * | 1990-07-05 | 1994-12-06 | Hoechst Aktiengesellschaft | Bulk polymerization using specific metallocene catalysts for the preparation of cycloolefin polymers |
TW227005B (ko) * | 1990-11-14 | 1994-07-21 | Hoechst Ag | |
DE59209568D1 (de) * | 1991-02-27 | 1999-01-07 | Ticona Gmbh | Verfahren zur Herstellung von Cycloolefin(co)polymeren mit enger Molekulargewichtsverteilung |
DE59209354D1 (de) * | 1991-03-09 | 1998-07-09 | Targor Gmbh | Verfahren zur Herstellung chemisch einheitlicher Cycloolefincopolymere |
-
1994
- 1994-06-24 DE DE4422157A patent/DE4422157A1/de not_active Withdrawn
-
1995
- 1995-06-12 DE DE59501145T patent/DE59501145D1/de not_active Expired - Lifetime
- 1995-06-12 EP EP95109013A patent/EP0688801B1/de not_active Expired - Lifetime
- 1995-06-23 CA CA002152552A patent/CA2152552C/en not_active Expired - Fee Related
- 1995-06-23 CN CN95107662A patent/CN1116324C/zh not_active Expired - Fee Related
- 1995-06-24 KR KR1019950017248A patent/KR100386759B1/ko not_active IP Right Cessation
- 1995-06-26 JP JP15908495A patent/JP3703525B2/ja not_active Expired - Fee Related
-
1997
- 1997-02-07 US US08/796,312 patent/US5698645A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE59501145D1 (de) | 1998-02-05 |
JPH0812712A (ja) | 1996-01-16 |
CA2152552A1 (en) | 1995-12-25 |
DE4422157A1 (de) | 1996-01-04 |
CA2152552C (en) | 2008-03-18 |
US5698645A (en) | 1997-12-16 |
EP0688801A1 (de) | 1995-12-27 |
CN1116324C (zh) | 2003-07-30 |
KR100386759B1 (ko) | 2003-08-09 |
EP0688801B1 (de) | 1997-12-29 |
JP3703525B2 (ja) | 2005-10-05 |
CN1120551A (zh) | 1996-04-17 |
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