KR950011481A - 올레핀 중합법 - Google Patents

올레핀 중합법 Download PDF

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KR950011481A
KR950011481A KR1019940025212A KR19940025212A KR950011481A KR 950011481 A KR950011481 A KR 950011481A KR 1019940025212 A KR1019940025212 A KR 1019940025212A KR 19940025212 A KR19940025212 A KR 19940025212A KR 950011481 A KR950011481 A KR 950011481A
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South Korea
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group
bis
zircon
dichloride
methyl
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KR1019940025212A
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KR100321016B1 (ko
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헤르만 한스-프리드리히
슈팔렉 발터
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게르하르트 아울미히, 위르겐 루츠
훽스트 아크티엔게젤샤프트
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

하나 이상의 올레핀을 하나 이상의 일반식(I)의 메탈로센과 하나 이상의 보조 촉매를 포함하는 촉매의 존재하에 100 내지 200℃의 온도 및 0.5내지 100bar의 압력에서 단독 중합시키거나 공중합시켜 폴리올레핀을 제조하는 방법.
상기식에서, M¹, R¹,R2, R3, R4, R5,R6, R7, R8, R9및 R10은 명세서내에서 정의한 바와 같다.

Description

올레핀 중합법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 하나 이상의 올레핀을 하나 이상의 일반식(I)의 메탈로센과 하나 이상의 보조 촉매를 포함하는 촉매의 존재하에 100 내지 200℃의 온도 및 0.5내지 100bar의 압력에서 단독 중합시키거나 공중합시켜 폴리올레핀을 제조하는 방법.
    상기식에서, M1은 티탄또는 지르콘이고, R1및 R2는 동일하거나 상이하며, 수소원자, C1-C10알킬 그룹, Cl-C10알콕시 그룹, C6-C10아릴 그룹, C6-C10아릴옥시 그룹, C2-C10알케닐 그룹, C7-C40아릴알킬 그룹, C7-C40알킬아릴 그룹, C8-C40아릴알케닐 그룹 또는 할로겐 원자이며, R3및 R4는 동일하거나 상이하며, 수소원자,하로겐 원자, Cl-C30알킬 그룹, Cl-C10플루오로알킬 그룹, C6-Cl0플루오로 아릴 그룹, C6-C10아릴 그룹, Cl-C10알콕시 그룹, C2-C1O알키닐 그룹, C7-C40아릴알킬 그룹, C8-C40아릴알케닐 그룹 또는 C7-C40알킬아릴 그룹이거나, R3과 R4는 이들이 결합되어 있는 원자들과 함께 환을 형성하고, R5,R6, R7, R8, R9및 R10은 동일하거나 상이하며, 수소원자, 할로겐 원자, Cl-C30알킬 그룹, Cl-C1O플루오로알킬 그룹, C6-Cl0플루오로 아릴 그룹, C6-Cl0아릴 그룹, C1-Cl0알콕시 그룹, C2-Cl0알키닐 그룹, C7-C40아릴알킬 그룹, C8-C40아릴 알케닐 그룹 또는 C7-C40알킬아릴 그룹이거나, 이들 래디칼 중의 2개 이상은 이들이 결합되어 있는 원자와 함께 환 시스템을 형성한다.
  2. 제1항에 있어서, M1이 지르콘이고, R¹과R2가 염소 또는 메틸이며, R3과 R4가 동일하거나 상이하고, Cl-C4알킬 그룹 또는 페닐 그룹이며, R5가 Cl-C4알킬 그룹이고, R6이 수소이며, R7, R8, R9및 R10이 수소, C1-C4알킬 그룹 또는 C6-C10아릴 그룹이거나, 이들 중의 2개 이상은 이들이 결합되어 있는 원자들과 함께 환 시스템을 형성하는 방법.
  3. 제1항에 있어서, 일반식(I)의 메탈로센이 디메틸실란디일-비스-1-(2-메틸-4-페닐인데닐)지르콘디클로라이드, 디메틸실란디일-비스-1-(2-메틸-4-(1-나프틸)인데닐)지르콘 디클로라이드, 디메틸실란디일-비스-1-(2-에틸-4-페닐인데닐)지르콘 디플로라이드, 디메틸실란디일-비스-1-(2-에틸-4-(1-나프틸)인데닐)지르콘 디클로라이드, 디메틸실란디일-비스-1 (2-메틸아세나프틸인데닐)지르콘 디클로라이드, 디 메틸실란디일-비스-1-(2-메틸-4,5-벤조틸인데닐)지르콘 디클로라이드, 페닐메틸 실 란디일-비스-1-(2-메틸-4-퍼닐인데닐)지르콘 디클로라이드, 페닐메틸실란디일-비 스-1-(2-메틸-4-(1-나프틸)인데닐)지르콘 디클로라이드, 퍼닐메틸실란디 일-비스-1-(2-에틸-4-페닐인데닐)지르콘 디클로라이드, 페닐메틸메틸실란디일-비스-1-(2-에틸-4-(1-나프틸)인데닐)지르콘 디클로라이드, 페닐메틸신란디일-비스-1- (2-메틸아세나프틸인데닐)지르콘 디클로라이드, 페닐메틸실란디일-비스-1-(2-메틸-4,5-벤조틸인메닐)지르콘 디클로라이드, 디메틸실란디일-비스-1-(2-4,6-디이소프로필인데닐)지르콘 디클로라이드, 페닐메틸실란디일-비스-1-(2-4,6-디이소프로필 인데닐)지르콘 디클로라이드, 디메틸실란디일-비스-1-(2-4-에틸인데닐)지르콘 디클로라이드, 디메틸실란더일-비스-1-(2-4-이소프로필인데닐)지르콘 디클로라이드인 방법.
  4. 제1항 내지 제3항 중의 어느 한 항에 있어서, 알루미녹산을 보조 촉매로서 사용하는 방법.
  5. 제1항 내지 제4항 중의 어느 한 항에 있어서, 탄소수 2 내지 18의 올레핀 또는 디올레핀이 중합되거나 공중합 되는 방법.
  6. 제1항 내지 제5항 중의 어느 한 항에 있어서, 촉매가 지지된 형태 및/또는 예비중합된 형태로 사용되는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940025212A 1993-10-01 1994-10-01 올레핀중합법 KR100321016B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4333569A DE4333569A1 (de) 1993-10-01 1993-10-01 Verfahren zur Olefinpolymerisation
DEP4333569.1 1993-10-01

Publications (2)

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KR950011481A true KR950011481A (ko) 1995-05-15
KR100321016B1 KR100321016B1 (ko) 2002-06-20

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EP (1) EP0646604B1 (ko)
JP (1) JP3453580B2 (ko)
KR (1) KR100321016B1 (ko)
CN (1) CN1107859A (ko)
AT (1) ATE165844T1 (ko)
CA (1) CA2133389A1 (ko)
DE (2) DE4333569A1 (ko)
ES (1) ES2115125T3 (ko)
FI (1) FI112368B (ko)
NO (1) NO311259B1 (ko)
RU (1) RU2145613C1 (ko)

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KR100330180B1 (ko) * 1999-10-25 2002-03-28 서평원 교환 시스템에서의 아이피씨 장애 검출 방법

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DE19623707A1 (de) * 1996-06-14 1997-12-18 Hoechst Ag Übergangsmetallverbindung
DE19806918A1 (de) 1998-02-19 1999-08-26 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
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GB0918736D0 (en) * 2009-10-26 2009-12-09 Isis Innovation Catalysts
GB201407000D0 (en) * 2014-04-17 2014-06-04 Isis Innovation Catalysts
CN106459278B (zh) * 2014-04-17 2020-11-06 博里利斯股份公司 用于以高温溶液聚合法制备聚乙烯共聚物的经改善的催化剂体系
CN107108799B (zh) 2015-01-06 2020-07-21 Scg化学有限公司 SiO2层状双氢氧化物微球及其作为乙烯聚合中的催化剂载体的用途
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ES2086397T5 (es) * 1989-10-30 2005-07-16 Fina Technology, Inc. Adicion de alkiloaluminio para un catalizador metaloceno mejorado.
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Publication number Priority date Publication date Assignee Title
KR100330180B1 (ko) * 1999-10-25 2002-03-28 서평원 교환 시스템에서의 아이피씨 장애 검출 방법

Also Published As

Publication number Publication date
EP0646604B1 (de) 1998-05-06
DE4333569A1 (de) 1995-04-06
CN1107859A (zh) 1995-09-06
NO311259B1 (no) 2001-11-05
ES2115125T3 (es) 1998-06-16
ATE165844T1 (de) 1998-05-15
EP0646604A1 (de) 1995-04-05
CA2133389A1 (en) 1995-04-02
NO943642L (no) 1995-04-03
JPH07149815A (ja) 1995-06-13
FI112368B (fi) 2003-11-28
RU94035670A (ru) 1997-02-27
FI944528A (fi) 1995-04-02
NO943642D0 (no) 1994-09-30
RU2145613C1 (ru) 2000-02-20
DE59405886D1 (de) 1998-06-10
KR100321016B1 (ko) 2002-06-20
FI944528A0 (fi) 1994-09-29
JP3453580B2 (ja) 2003-10-06

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