KR950010227B1 - 올레핀 중합지지 촉매 - Google Patents

올레핀 중합지지 촉매 Download PDF

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Publication number
KR950010227B1
KR950010227B1 KR1019880700511A KR880700511A KR950010227B1 KR 950010227 B1 KR950010227 B1 KR 950010227B1 KR 1019880700511 A KR1019880700511 A KR 1019880700511A KR 880700511 A KR880700511 A KR 880700511A KR 950010227 B1 KR950010227 B1 KR 950010227B1
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KR
South Korea
Prior art keywords
bis
cyclopentadienyl
metallocene
titanium
zirconium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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KR1019880700511A
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English (en)
Korean (ko)
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KR880701741A (ko
Inventor
쥬니어 하워드 커티스 웰보른
Original Assignee
엑손 케미칼 패턴츠, 인코포레이티드
벤씨. 카덴헤드
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Publication of KR880701741A publication Critical patent/KR880701741A/ko
Application granted granted Critical
Publication of KR950010227B1 publication Critical patent/KR950010227B1/ko
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
KR1019880700511A 1986-09-09 1987-09-09 올레핀 중합지지 촉매 Expired - Fee Related KR950010227B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US906103 1986-09-09
US06/906,103 US5077255A (en) 1986-09-09 1986-09-09 New supported polymerization catalyst
US906.103 1986-09-09
PCT/US1987/002308 WO1988002008A1 (en) 1986-09-09 1987-09-09 New supported polymerization catalyst

Publications (2)

Publication Number Publication Date
KR880701741A KR880701741A (ko) 1988-11-04
KR950010227B1 true KR950010227B1 (ko) 1995-09-12

Family

ID=25421940

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880700511A Expired - Fee Related KR950010227B1 (ko) 1986-09-09 1987-09-09 올레핀 중합지지 촉매

Country Status (21)

Country Link
US (2) US5077255A (enExample)
EP (1) EP0260130B1 (enExample)
JP (1) JP2725010B2 (enExample)
KR (1) KR950010227B1 (enExample)
AT (1) ATE97139T1 (enExample)
AU (1) AU620316B2 (enExample)
BR (1) BR8707851A (enExample)
CA (1) CA1300119C (enExample)
DE (1) DE3788096T2 (enExample)
DK (1) DK254988D0 (enExample)
ES (1) ES2059389T3 (enExample)
FI (1) FI891109A7 (enExample)
HU (1) HUT51651A (enExample)
IL (1) IL83708A (enExample)
IN (1) IN171879B (enExample)
MX (1) MX169193B (enExample)
NO (1) NO881826D0 (enExample)
PL (1) PL267645A1 (enExample)
WO (1) WO1988002008A1 (enExample)
YU (2) YU46069B (enExample)
ZA (1) ZA876545B (enExample)

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PL267645A1 (en) 1988-07-21
FI891109A0 (fi) 1989-03-08
JPH01503715A (ja) 1989-12-14
NO881826L (no) 1988-04-26
IL83708A (en) 1991-11-21
YU10289A (en) 1990-04-30
CA1300119C (en) 1992-05-05
YU166987A (en) 1989-04-30
AU7916587A (en) 1988-04-07
US5077255A (en) 1991-12-31
US5183867A (en) 1993-02-02
KR880701741A (ko) 1988-11-04
NO881826D0 (no) 1988-04-26
ES2059389T3 (es) 1994-11-16
FI891109L (fi) 1989-03-08
IL83708A0 (en) 1988-01-31
DK254988A (da) 1988-05-09
EP0260130B1 (en) 1993-11-10
HUT51651A (en) 1990-05-28
WO1988002008A1 (en) 1988-03-24
MX169193B (es) 1993-06-24
DE3788096T2 (de) 1994-03-17
IN171879B (enExample) 1993-01-30
DE3788096D1 (de) 1993-12-16
ATE97139T1 (de) 1993-11-15
JP2725010B2 (ja) 1998-03-09
ZA876545B (enExample) 1988-03-02
BR8707851A (pt) 1989-10-03
YU46069B (sh) 1992-12-21
DK254988D0 (da) 1988-05-09
FI891109A7 (fi) 1989-03-08
EP0260130A1 (en) 1988-03-16
AU620316B2 (en) 1992-02-20

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