KR910007973A - 헤미이소택틱 폴리프로필렌 제조용 촉매 - Google Patents

헤미이소택틱 폴리프로필렌 제조용 촉매 Download PDF

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KR910007973A
KR910007973A KR1019900016066A KR900016066A KR910007973A KR 910007973 A KR910007973 A KR 910007973A KR 1019900016066 A KR1019900016066 A KR 1019900016066A KR 900016066 A KR900016066 A KR 900016066A KR 910007973 A KR910007973 A KR 910007973A
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plasticizer
compound
metallocene
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catalyst
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에웬 존
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원본미기재
피나 테크놀로지. 인코포레이티드
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

내용 없음

Description

헤미이소태틱 폴리프로필렌 제조용 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. 하기 일반식의 메탈로센 화합물.
    R"(CpRn)(CpR'm)MHal2
    상기식에서, Cp는 사이클로펜타디에닐 또는 치환된 사이클로펜타디에닐이고, R 및 R'는 각각 탄소수 1내지 20의 하이드로카빌 라디칼이며 동일하거나 상이하고, CpR'm이 CpRn과 입체적으로 상이한 환임으로써 화합물에 대해 이중-측면 대칭이 되지 않도록 선택되며, R"는 화합물에 입체 경질을 주는 구조적 가교이고, M는 4족 금속이며, n은 0내지 4이고, m은 0내지 4이며, Hal은 할로겐이다.
  2. 제1항에 있어서, M이 티탄, 지르코늄 및 하프늄인 메탈로센 화합물.
  3. 제1항에 있어서, Hal이 염소인 메탈로센 화합물.
  4. 제1항에 있어서, 화합물이 이소프로필리텐 (3-메틸사이클로펜타디에닐-1-플루오레닐) 지르코늄 디클로 라이드인 메탈로센 화합물.
  5. a) 하기 일반식의 메탈로센 화합물, 및 b) 이온화제를 함유하는 메탈로센 촉매.
    R"(CpRn)(CpR'm)MHal2
    상기식에서, Cp는 사이클로펜타디에닐이고, R 및 R'는 각각 탄소수 1내지 20의 하이드로카빌 라디칼이며 동일하거나 상이하고, CpR'm이 CpRn과 입체적으로 상이한 환입으로써 화합물에 대해 이중-측면 대칭이 되지 않도록 선택되며, R"는 화합물에 입체 경질 경질을 주는 구조적 가교이고, M는 3족, 4족, 5족 또는 6족 금속이며, n은 0 내지 4이고, m은 0 내지 4이며, Hal은 할로겐이다.
  6. 제5항에 있어서, M이 티탄, 지르코늄 및 하프늄 중에서 선택된 메탈로센 촉매.
  7. 제5항에 있어서, Hal이 염소인 메탈로센 촉매.
  8. 제5항에 있어서, 화합물이 이소프로필리덴 (3-메틸사이클로펜타디에닐-1-플루오레닐) 지르코늄 디클로 라이드인 메탈로센 촉매.
  9. 하기 일반식의 치환된 비닐 화합물로부터의 단량체 단위를 갖는 중합체를 포함하는 가소제.
    CH2=CHRS
    상기식에서, Rs는 하이드로카빌 그룹 또는 비하이드로카빌 치환체이고, 상기 중합체는 하기 주고를 중합체 주쇄와 동일면에 있는 비대칭 탄소에 하나 걸려 결합된 Rs 그룹 및 이러한 Rs 그룹과 동일면 또는 반대면에 있는 나머지 비대칭 탄소에 결합된 Rs 그룹을 특징으로 한다.
  10. 제9항에 있어서, 단량체가 프로필렌이고 가소제가 이소택틱 폴리프로필렌 및 신디오택틱 폴리프로필렌중에서 선택된 플라스틱으로 사용되는 가소제.
  11. 제10항에 있어서, 플라스틱이 신디오택틱 폴리프로필렌인 가소제.
  12. 제11항에 있어서, 가소제의 양이 1내지 90중량%인 가소제.
  13. 제12항에 있어서, 가소제의 양이 5내지 50중량%인 가소제.
  14. 제13항에 있어서, 가소제의 양이 약10중량%인 가소제.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900016066A 1989-10-10 1990-10-10 헤미이소택틱 폴리프로필렌 제조용 촉매 KR0181495B1 (ko)

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US419,221 1989-10-10
US07/419,221 US5036034A (en) 1989-10-10 1989-10-10 Catalyst for producing hemiisotactic polypropylene
US419221 1989-10-10

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KR0181495B1 KR0181495B1 (ko) 1999-05-15

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US (2) US5036034A (ko)
EP (2) EP0423101B2 (ko)
JP (1) JPH03193796A (ko)
KR (1) KR0181495B1 (ko)
CN (2) CN1028532C (ko)
AT (2) ATE189226T1 (ko)
CA (1) CA2027124C (ko)
DE (2) DE69033435T3 (ko)
DK (2) DK0423101T4 (ko)
ES (2) ES2142303T5 (ko)
GR (2) GR3033307T3 (ko)

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ATE189226T1 (de) 2000-02-15
DK0423101T3 (da) 2000-07-17
EP0423101A2 (en) 1991-04-17
GR3036018T3 (en) 2001-09-28
DK0423101T4 (da) 2006-08-21
DE69033715D1 (de) 2001-04-19
EP0742227B1 (en) 2001-03-14
EP0742227A2 (en) 1996-11-13
CN1028532C (zh) 1995-05-24
DK0742227T3 (da) 2001-06-05
DE69033715T2 (de) 2001-07-12
DE69033435T3 (de) 2006-10-19
EP0423101B1 (en) 2000-01-26
DE69033435T2 (de) 2000-07-20
EP0423101B2 (en) 2006-05-03
DE69033435D1 (de) 2000-03-02
CA2027124C (en) 2001-09-04
JPH03193796A (ja) 1991-08-23
CN1100733A (zh) 1995-03-29
ATE199722T1 (de) 2001-03-15
KR0181495B1 (ko) 1999-05-15
US5036034A (en) 1991-07-30
ES2142303T5 (es) 2006-12-01
ES2155909T3 (es) 2001-06-01
US6369175B1 (en) 2002-04-09
CN1058022C (zh) 2000-11-01
GR3033307T3 (en) 2000-09-29
EP0742227A3 (en) 1997-01-22
ES2142303T3 (es) 2000-04-16
CN1051735A (zh) 1991-05-29
EP0423101A3 (en) 1991-08-07
CA2027124A1 (en) 1991-04-11

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