ES2142303T3 - Un catalizador para producir polipropileno hemiisotactico. - Google Patents

Un catalizador para producir polipropileno hemiisotactico.

Info

Publication number
ES2142303T3
ES2142303T3 ES90870177T ES90870177T ES2142303T3 ES 2142303 T3 ES2142303 T3 ES 2142303T3 ES 90870177 T ES90870177 T ES 90870177T ES 90870177 T ES90870177 T ES 90870177T ES 2142303 T3 ES2142303 T3 ES 2142303T3
Authority
ES
Spain
Prior art keywords
catalyst
compound
produce
polymer
same side
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90870177T
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English (en)
Other versions
ES2142303T5 (es
Inventor
John A Ewen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fina Technology Inc
Original Assignee
Fina Technology Inc
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Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23661315&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2142303(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Fina Technology Inc filed Critical Fina Technology Inc
Publication of ES2142303T3 publication Critical patent/ES2142303T3/es
Application granted granted Critical
Publication of ES2142303T5 publication Critical patent/ES2142303T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

ESTE INVENTO ES PARA UN COMPONENTE METALOCENO QUE PUEDE SER USADO EN UN SISTEMA CATALIZADOR PARA PRODUCIR POLIMERO HEMIISOTACTICO. EL COMPONENTE ES UN METALOCENO PUENTEADO QUE TIENE GRUPOS CICLOPENTADIENIL DISTINTOS Y SIMETRIA NO BILATERAL. UN EJEMPLO DEL COMPONENTE ES DICLORURO DE ZIRCONIO (FLUORENIL-1-METILCICLOPENTADIENIL-3)ISOPROPILIDENO. EL CATALIZADOR DE ESTE INVENTO PUEDE SER CONVERTIDO A UN CATALIZADOR DE METALOCENO IONICO POR UN AGENTE IONIZADOR, TAL COMO METILALUMINOXANO. EL POLIMERO PRODUCIDO CON ESTE CATALIZADOR ESTA CARACTERIZADO POR TENER UNA ESTRUCTURA EFECTIVA SOLO CON OTRO CARBONO ASIMETRICO. EN EL CASO DEL POLIPROPILENO, CADA OTRO GRUPO METIL ESTA EN EL MISMO LADO DE LA CADENA POLIMERA PRINCIPAL COMO SE REPRESENTA POR UNA PROYECCION FISHER. LOS GRUPOS METIL RESTANTES PUEDEN ESTAR O EN EL MISMO LADO O EN EL OPUESTO DE LA CADENA POLIMERA PRINCIPAL. EL POLIMERO PRODUCIDO CON EL CATALIZADOR DEL INVENTO PUEDE SER USADO COMO UN PLASTIFICADOR.
ES90870177T 1989-10-10 1990-10-09 Un catalizador para producir polipropileno hemiisotactico. Expired - Lifetime ES2142303T5 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US419221 1989-10-10
US07/419,221 US5036034A (en) 1989-10-10 1989-10-10 Catalyst for producing hemiisotactic polypropylene

Publications (2)

Publication Number Publication Date
ES2142303T3 true ES2142303T3 (es) 2000-04-16
ES2142303T5 ES2142303T5 (es) 2006-12-01

Family

ID=23661315

Family Applications (2)

Application Number Title Priority Date Filing Date
ES96112193T Expired - Lifetime ES2155909T3 (es) 1989-10-10 1990-10-09 Polipropileno hemiisotactico como plastificante para polipropileno sindiotactico o isotactico.
ES90870177T Expired - Lifetime ES2142303T5 (es) 1989-10-10 1990-10-09 Un catalizador para producir polipropileno hemiisotactico.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES96112193T Expired - Lifetime ES2155909T3 (es) 1989-10-10 1990-10-09 Polipropileno hemiisotactico como plastificante para polipropileno sindiotactico o isotactico.

Country Status (11)

Country Link
US (2) US5036034A (es)
EP (2) EP0742227B1 (es)
JP (1) JPH03193796A (es)
KR (1) KR0181495B1 (es)
CN (2) CN1028532C (es)
AT (2) ATE199722T1 (es)
CA (1) CA2027124C (es)
DE (2) DE69033715T2 (es)
DK (2) DK0742227T3 (es)
ES (2) ES2155909T3 (es)
GR (2) GR3033307T3 (es)

Families Citing this family (246)

* Cited by examiner, † Cited by third party
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US5036034A (en) 1991-07-30
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ES2142303T5 (es) 2006-12-01
US6369175B1 (en) 2002-04-09
CN1028532C (zh) 1995-05-24
DE69033715D1 (de) 2001-04-19
DE69033715T2 (de) 2001-07-12
EP0423101B1 (en) 2000-01-26
CA2027124A1 (en) 1991-04-11
KR910007973A (ko) 1991-05-30
ATE189226T1 (de) 2000-02-15
CN1100733A (zh) 1995-03-29
EP0742227A2 (en) 1996-11-13
DK0423101T4 (da) 2006-08-21
DE69033435D1 (de) 2000-03-02
EP0423101B2 (en) 2006-05-03

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