KR850003377A - 고강도 산화지르코늄형 소결체 및 그의 제조방법 - Google Patents
고강도 산화지르코늄형 소결체 및 그의 제조방법 Download PDFInfo
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- KR850003377A KR850003377A KR1019840006430A KR840006430A KR850003377A KR 850003377 A KR850003377 A KR 850003377A KR 1019840006430 A KR1019840006430 A KR 1019840006430A KR 840006430 A KR840006430 A KR 840006430A KR 850003377 A KR850003377 A KR 850003377A
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- zirconium oxide
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- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 title claims description 37
- 229910001928 zirconium oxide Inorganic materials 0.000 title claims description 37
- 238000004519 manufacturing process Methods 0.000 title claims 16
- 239000000843 powder Substances 0.000 claims 31
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 14
- 239000000203 mixture Substances 0.000 claims 11
- 239000002245 particle Substances 0.000 claims 10
- 238000007906 compression Methods 0.000 claims 9
- 230000006835 compression Effects 0.000 claims 7
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 6
- 239000013078 crystal Substances 0.000 claims 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 4
- 229910052782 aluminium Inorganic materials 0.000 claims 4
- 239000000047 product Substances 0.000 claims 4
- 239000000377 silicon dioxide Substances 0.000 claims 4
- 229910052727 yttrium Inorganic materials 0.000 claims 4
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims 4
- 239000000395 magnesium oxide Substances 0.000 claims 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims 2
- 239000001099 ammonium carbonate Substances 0.000 claims 2
- 235000012501 ammonium carbonate Nutrition 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- 239000002775 capsule Substances 0.000 claims 2
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 claims 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 229910020068 MgAl Inorganic materials 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- UAMZXLIURMNTHD-UHFFFAOYSA-N dialuminum;magnesium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Mg+2].[Al+3].[Al+3] UAMZXLIURMNTHD-UHFFFAOYSA-N 0.000 claims 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 229910052863 mullite Inorganic materials 0.000 claims 1
- 150000002902 organometallic compounds Chemical class 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 238000013001 point bending Methods 0.000 claims 1
- 239000011148 porous material Substances 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 238000000197 pyrolysis Methods 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 238000005245 sintering Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 229910052596 spinel Inorganic materials 0.000 claims 1
- 239000011029 spinel Substances 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
- C04B35/645—Pressure sintering
- C04B35/6455—Hot isostatic pressing
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/44—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminates
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/486—Fine ceramics
- C04B35/488—Composites
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/486—Fine ceramics
- C04B35/488—Composites
- C04B35/4885—Composites with aluminium oxide
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- Compositions Of Oxide Ceramics (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 따른 산화지르코늄형 소결체 표면의 주사현미경 사진(2000배 확대)이다.
Claims (22)
- 산화이트륨(Y2O3) 1.5 내지 5몰%를 포함하는 산화지르코늄(ZrO2) 50 내지 90중량%와 알루미나(Al2O3), 스피넬(MgAl2O4) 또는 멀라이트(3A2O3·2SiO2) 50 내지 2중량%로 필수적으로 구성되며, 적어도 1700MPa의 삼점굽힘강도를 갖는 것을 특징으로 하는 산화지르코늄형 소결체.
- 제1항에 있어서, 산화이트륨 함유 산화지르코늄과 알루미나로 필수적으로 구성되는 것을 특징으로 하는 상기 산화지르코늄형 소결체.
- 제1항에 있어서, 소결체를 구성하는 산화지르코늄의 결정상이 정방결정, 또는 정방결정과 등방결정으로 주로 구성되는 것을 특징으로 하는 산화지르코늄형 소결체.
- 제1항에 있어서, 소결체결정의 입도가 2μm보다 더 크지 않은 것을 특징으로 하는 산화지르코늄형 소결체.
- 제1항에 있어서, 소결체의 부피밀도가 이론밀도의 적어도 99.5%인 것을 특징으로 하는 산화지르코늄형 소결체.
- 제1항에 있어서, 소결체가 그안에 30μm이상 크기의 기공을 포함하지 않는 것을 특징으로 하는 산화지르코늄형 소결체.
- (a1) 산화이트륨 1.5 내지 5몰%를 포함하는 산화지르코늄분말 또는 (a2) 산화이트륨분말 1.5 내지 5몰%와 산화지르코늄 분말 95 내지 98.5%로 이루어지는 혼합물 50 내지 98중량%와 (b) 알루미늄, 알루미늄-마그네시아형 산화물, 알루미나-실리카형 산화물, 알루미나와 마그네시아의 혼합물 및 알루미나와 실리카의 혼합물로부터 선택된 알루미나형 산화물 분말 2 내지 50중량%로 필수적으로 구성되는 분말조성물을 1300℃ 내지 1700℃의 온도에서 적어도 50MPa의 압력하에 균형적으로 (isostatically)고열압착하는 것으로 이루어지는 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- 제7항에 있어서, 산화지르코늄분말 또는 산화이트륨함유 산화지르코늄분말의 평균주요입도는 0.1μm보다 크지 않으며 산화이트륨분말의 평균주요입도는 0.5μm보다 크지않고 알루미나형 산화물분말의 평균 주요입도는 0.5μm보다 크지 않은 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- 제7항에 있어서, 알루미나형 산화물분말은 20㎡g보다 더 작은 비표면적과, 0.2 내지 0.4μm의 평균 주요입도를 갖는 α-알루미나 분말인 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- 제7항에 있어서, 분말혼합물은 캡슐내에 충전된 다음 고온균형 압착처리를 받는 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- 제7항에 있어서, 분말혼합물을 성형시키고 성형된 분말혼합물을 예비적으로 소결시켜 1.5μm보다 크지 않은 평균입도를 갖는 입자(grains)로 구성되는 예비소결제품을 얻고 다음에 예비소결제품을 고열균형 압착처리를 받게 하는 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- 제7항에 있어서, 50MPa 내지 500MPa의 압력하에 고열균형 압착처리를 수행하는 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- (a1) 산화이트륨 1.5 내지 5몰%를 포함하는 산화지르코늄분말 또는 (a2) 산화이트륨분말 1.5 내지 5몰%와 산화지르코늄 분말 95 내지 98.5몰%로 이루어지는 혼합물 50 내지 98중량%와 (b) 알루미나, 알루미나-마그네시아형 산화물, 알루미나-실리카형 산화물, 알루미나와 마그네시아의 혼합물 및 알루미나와 실리카의 혼합물로부터 선택된 알루미나형 산화물 분말 2 내지 50중량%로 필수적으로 구성되는 분말조성물을 1400℃ 내지 1700℃의 온도에서 적어도 20MPa의 압력하에 단일축상으로 압축소결시키는 것으로 이루어지는 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- 제13항에 있어서, 산화지르코늄분말 또는 산화이트륨함유 산화지르코늄 분말의 평균 주요입도는 0.1μm보다 크지 않으며 산화이트륨분말의 평균주요입도는 0.5μm보다 크지 않고 알루미늄형 산화물분말의 평균 주요입도는 0.5μm보다 크지 않은 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- 제13항에 있어서, 알루미나형 산화물분말은 20㎡/g보다 더 작은 비표면적과, 0.2 내지 0.4μm의 평균 주요입도를 갖는 α-알루미나 분말인 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- (a) 지르코늄, (b) 안정제로서 이트륨 및 (c) 알루미늄, 알루미늄과 마그네슘, 또는 알루미늄과 실리콘을 이들 원소의 염, 유기금속화합물 또는 산화물의 형태로 포함하는 수용액에 탄산암모늄을 가하는 단계와 형성된 침전을 산화지르코늄형 분말을 얻기 위하여 열분해시키는 단계, 그리고 얻어진 분말을 1300℃ 내지 1700℃의 온도에서 적어도 50MPa의 압력하에 고열균형 압착처리를 받게하는 단계로 이루어지는 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- 제16항에 있어서, 탄산암모늄을 격렬한 교반을 하면서 출발수용액에 한번 가하여 용액의 pH갖이 약 9가 되도록 하는 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- 제16항에 있어서, 침전을 900℃ 내지 1150℃에서 공기대기중에서 열분해시키는 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- 제16항에 있어서, 산화지르코늄분말의 평균주요입도는 0.1μm보다 더 크지 않은 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- 제16항에 있어서, 산화지르코늄형분말을 성형시키고 성형된 분말을 1500℃보다 더 높지 않은 온도에서 예비소결시킨 다음, 예비소결제품을 고열균형 압착처리를 받게 하는 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- 제16항에 있어서, 50MPa 내지 500MPa의 압력하에 고열균형 압착처리를 수행하는 것을 특징으로 하는 산화지르코늄형 소결체의 제조방법.
- 제16항에 있어서, 산화지르코늄형 분말을 캡슐에 충전시킨 다음 고열균형 압착처리를 받게하는 것을 특징으로 하는 산화카르코늄형 소결체의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
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JP58-192470 | 1983-10-17 | ||
JP58192470A JPS6086073A (ja) | 1983-10-17 | 1983-10-17 | 高強度ジルコニア系焼結体およびその製造方法 |
JP59-71829 | 1984-04-12 | ||
JP59071829A JPS60215571A (ja) | 1984-04-12 | 1984-04-12 | 高強度ジルコニア系焼結体の製法 |
JP59-82019 | 1984-04-25 | ||
JP59082019A JPS60226457A (ja) | 1984-04-25 | 1984-04-25 | 高強度ジルコニア系焼結体の製造法 |
JP59089272A JPS60235762A (ja) | 1984-05-07 | 1984-05-07 | 高強度ジルコニア系焼結体 |
JP59-89272 | 1984-05-07 |
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KR850003377A true KR850003377A (ko) | 1985-06-17 |
KR920007020B1 KR920007020B1 (ko) | 1992-08-24 |
Family
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KR1019840006430A KR920007020B1 (ko) | 1983-10-17 | 1984-10-17 | 고강도 산화지르코늄형 소결체 및 그의 제조방법 |
Country Status (5)
Country | Link |
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US (2) | US4587225A (ko) |
EP (1) | EP0140638B1 (ko) |
KR (1) | KR920007020B1 (ko) |
AU (1) | AU573631B2 (ko) |
DE (1) | DE3472398D1 (ko) |
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KR100400263B1 (ko) * | 2001-07-04 | 2003-10-01 | 주식회사 코스마 | 와이어 본딩용 알루미나-지르코니아 복합체 캐필러리소결체 및 그의 제조 방법 |
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EP0140638A1 (en) | 1985-05-08 |
AU573631B2 (en) | 1988-06-16 |
US4587225A (en) | 1986-05-06 |
DE3472398D1 (en) | 1988-08-04 |
AU3425484A (en) | 1985-04-26 |
US4774041A (en) | 1988-09-27 |
KR920007020B1 (ko) | 1992-08-24 |
EP0140638B1 (en) | 1988-06-29 |
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