KR20170134374A - 연속 카보닐화 방법 - Google Patents
연속 카보닐화 방법 Download PDFInfo
- Publication number
- KR20170134374A KR20170134374A KR1020177025875A KR20177025875A KR20170134374A KR 20170134374 A KR20170134374 A KR 20170134374A KR 1020177025875 A KR1020177025875 A KR 1020177025875A KR 20177025875 A KR20177025875 A KR 20177025875A KR 20170134374 A KR20170134374 A KR 20170134374A
- Authority
- KR
- South Korea
- Prior art keywords
- lewis acid
- carbonylation
- reaction vessel
- catalyst
- metal carbonyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000005810 carbonylation reaction Methods 0.000 title claims abstract description 316
- 238000000034 method Methods 0.000 title claims abstract description 166
- 230000006315 carbonylation Effects 0.000 title claims abstract description 106
- 230000008569 process Effects 0.000 title claims description 83
- 239000003054 catalyst Substances 0.000 claims abstract description 260
- 150000002596 lactones Chemical class 0.000 claims abstract description 44
- 229910052751 metal Inorganic materials 0.000 claims description 328
- 239000002184 metal Substances 0.000 claims description 327
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 217
- 239000002841 Lewis acid Substances 0.000 claims description 189
- 150000007517 lewis acids Chemical class 0.000 claims description 185
- 239000002243 precursor Substances 0.000 claims description 93
- 239000003446 ligand Substances 0.000 claims description 74
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 48
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 48
- 230000007935 neutral effect Effects 0.000 claims description 48
- 125000001931 aliphatic group Chemical group 0.000 claims description 44
- 238000000354 decomposition reaction Methods 0.000 claims description 37
- 239000012528 membrane Substances 0.000 claims description 13
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- 230000003197 catalytic effect Effects 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
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- 125000002950 monocyclic group Chemical group 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- 210000002706 plastid Anatomy 0.000 description 5
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- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 4
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/60—Two oxygen atoms, e.g. succinic anhydride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D305/00—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
- C07D305/02—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings
- C07D305/10—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having one or more double bonds between ring members or between ring members and non-ring members
- C07D305/12—Beta-lactones
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Furan Compounds (AREA)
- Epoxy Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
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| US201562116089P | 2015-02-13 | 2015-02-13 | |
| US62/116,089 | 2015-02-13 | ||
| PCT/US2016/017875 WO2016130998A1 (en) | 2015-02-13 | 2016-02-12 | Continuous carbonylation processes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20170134374A true KR20170134374A (ko) | 2017-12-06 |
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| KR1020177025875A Withdrawn KR20170134374A (ko) | 2015-02-13 | 2016-02-12 | 연속 카보닐화 방법 |
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| Country | Link |
|---|---|
| US (3) | US10221150B2 (enExample) |
| EP (2) | EP3256441B1 (enExample) |
| JP (3) | JP7053264B2 (enExample) |
| KR (1) | KR20170134374A (enExample) |
| CN (1) | CN107428656B (enExample) |
| AU (1) | AU2016218996A1 (enExample) |
| CA (1) | CA2976253A1 (enExample) |
| HK (1) | HK1245761A1 (enExample) |
| MX (1) | MX2017010408A (enExample) |
| SA (1) | SA517382089B1 (enExample) |
| WO (1) | WO2016130998A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019143220A1 (ko) * | 2018-01-22 | 2019-07-25 | 국민대학교 산학협력단 | 전이금속 기반 비균질계 카보닐화 반응촉매 및 이를 이용한 락톤 또는 숙신산 무수물의 제조방법 |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103649038A (zh) | 2011-05-13 | 2014-03-19 | 诺沃梅尔公司 | 催化羰基化催化剂和方法 |
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2016
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- 2016-02-12 WO PCT/US2016/017875 patent/WO2016130998A1/en not_active Ceased
- 2016-02-12 KR KR1020177025875A patent/KR20170134374A/ko not_active Withdrawn
- 2016-02-12 CA CA2976253A patent/CA2976253A1/en not_active Abandoned
- 2016-02-12 HK HK18105401.2A patent/HK1245761A1/zh unknown
- 2016-02-12 JP JP2017542467A patent/JP7053264B2/ja active Active
- 2016-02-12 CN CN201680018399.3A patent/CN107428656B/zh active Active
- 2016-02-12 AU AU2016218996A patent/AU2016218996A1/en not_active Abandoned
- 2016-02-12 MX MX2017010408A patent/MX2017010408A/es unknown
- 2016-02-12 EP EP20168015.4A patent/EP3696161A1/en not_active Withdrawn
- 2016-02-12 US US15/550,217 patent/US10221150B2/en active Active
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019143220A1 (ko) * | 2018-01-22 | 2019-07-25 | 국민대학교 산학협력단 | 전이금속 기반 비균질계 카보닐화 반응촉매 및 이를 이용한 락톤 또는 숙신산 무수물의 제조방법 |
| KR20190089312A (ko) * | 2018-01-22 | 2019-07-31 | 국민대학교산학협력단 | 전이금속 기반 비균질계 카보닐화 반응촉매 및 이를 이용한 락톤 또는 숙신산 무수물의 제조방법 |
| US11071973B2 (en) | 2018-01-22 | 2021-07-27 | Kookmin University Industry Academy Cooperation Foundation | Transition metal-based heterogeneous carbonylation reaction catalyst and method for preparing lactone or succinic anhydride using catalyst |
| US11648545B2 (en) | 2018-01-22 | 2023-05-16 | Kookmin University Industry Academy Cooperation Foundation | Transition metal-based heterogeneous carbonylation reaction catalyst and method for preparing lactone or succinic anhydride using catalyst |
Also Published As
| Publication number | Publication date |
|---|---|
| US10927091B2 (en) | 2021-02-23 |
| JP2021185147A (ja) | 2021-12-09 |
| JP7170351B2 (ja) | 2022-11-14 |
| SA517382089B1 (ar) | 2022-06-19 |
| US10221150B2 (en) | 2019-03-05 |
| JP2018507855A (ja) | 2018-03-22 |
| JP7053264B2 (ja) | 2022-04-12 |
| US10738022B2 (en) | 2020-08-11 |
| CN107428656B (zh) | 2021-06-08 |
| EP3256441A1 (en) | 2017-12-20 |
| HK1245761A1 (zh) | 2018-08-31 |
| WO2016130998A1 (en) | 2016-08-18 |
| CA2976253A1 (en) | 2016-08-18 |
| EP3256441B1 (en) | 2020-04-08 |
| AU2016218996A1 (en) | 2017-08-24 |
| EP3696161A1 (en) | 2020-08-19 |
| US20180030015A1 (en) | 2018-02-01 |
| US20200331878A1 (en) | 2020-10-22 |
| MX2017010408A (es) | 2018-02-23 |
| CN107428656A (zh) | 2017-12-01 |
| JP2019116486A (ja) | 2019-07-18 |
| US20190345125A1 (en) | 2019-11-14 |
| EP3256441A4 (en) | 2018-07-25 |
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