AU2016218996A1 - Continuous carbonylation processes - Google Patents
Continuous carbonylation processes Download PDFInfo
- Publication number
- AU2016218996A1 AU2016218996A1 AU2016218996A AU2016218996A AU2016218996A1 AU 2016218996 A1 AU2016218996 A1 AU 2016218996A1 AU 2016218996 A AU2016218996 A AU 2016218996A AU 2016218996 A AU2016218996 A AU 2016218996A AU 2016218996 A1 AU2016218996 A1 AU 2016218996A1
- Authority
- AU
- Australia
- Prior art keywords
- carbonylation
- lewis acid
- reaction vessel
- metal carbonyl
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000005810 carbonylation reaction Methods 0.000 title claims abstract description 320
- 238000000034 method Methods 0.000 title claims abstract description 168
- 230000008569 process Effects 0.000 title claims abstract description 125
- 230000006315 carbonylation Effects 0.000 title claims abstract description 107
- 239000003054 catalyst Substances 0.000 claims abstract description 269
- 150000002596 lactones Chemical class 0.000 claims abstract description 45
- 229910052751 metal Inorganic materials 0.000 claims description 333
- 239000002184 metal Substances 0.000 claims description 332
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 218
- 239000002841 Lewis acid Substances 0.000 claims description 189
- 150000007517 lewis acids Chemical class 0.000 claims description 186
- 239000000047 product Substances 0.000 claims description 117
- 239000002243 precursor Substances 0.000 claims description 92
- 239000003446 ligand Substances 0.000 claims description 75
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 52
- 238000000354 decomposition reaction Methods 0.000 claims description 52
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 51
- 230000007935 neutral effect Effects 0.000 claims description 48
- 125000001931 aliphatic group Chemical group 0.000 claims description 44
- 125000000129 anionic group Chemical group 0.000 claims description 29
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/60—Two oxygen atoms, e.g. succinic anhydride
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D305/00—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
- C07D305/02—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings
- C07D305/10—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having one or more double bonds between ring members or between ring members and non-ring members
- C07D305/12—Beta-lactones
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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| JP2019116486A (ja) | 2019-07-18 |
| US20190345125A1 (en) | 2019-11-14 |
| EP3256441A4 (en) | 2018-07-25 |
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