KR101711788B1 - 혼성 촉매 조성물, 이의 제조방법, 및 이를 이용하여 제조된 폴리올레핀 - Google Patents

혼성 촉매 조성물, 이의 제조방법, 및 이를 이용하여 제조된 폴리올레핀 Download PDF

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KR101711788B1
KR101711788B1 KR1020160028278A KR20160028278A KR101711788B1 KR 101711788 B1 KR101711788 B1 KR 101711788B1 KR 1020160028278 A KR1020160028278 A KR 1020160028278A KR 20160028278 A KR20160028278 A KR 20160028278A KR 101711788 B1 KR101711788 B1 KR 101711788B1
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tetrakis
transition metal
phenyl
carbon atoms
group
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Korean (ko)
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정의갑
정동욱
김아름
최승일
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한화케미칼 주식회사
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Priority to KR1020160028278A priority Critical patent/KR101711788B1/ko
Priority to JP2018546823A priority patent/JP6811783B2/ja
Priority to US16/083,125 priority patent/US11267917B2/en
Priority to EP16893664.9A priority patent/EP3428201A4/en
Priority to PCT/KR2016/002842 priority patent/WO2017155149A1/ko
Priority to CN201680085502.6A priority patent/CN109476776B/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/01—Cp or analog bridged to a non-Cp X neutral donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/03—Cp or analog not bridged to a non-Cp X ancillary neutral donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

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  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1020160028278A 2016-03-09 2016-03-09 혼성 촉매 조성물, 이의 제조방법, 및 이를 이용하여 제조된 폴리올레핀 Active KR101711788B1 (ko)

Priority Applications (6)

Application Number Priority Date Filing Date Title
KR1020160028278A KR101711788B1 (ko) 2016-03-09 2016-03-09 혼성 촉매 조성물, 이의 제조방법, 및 이를 이용하여 제조된 폴리올레핀
JP2018546823A JP6811783B2 (ja) 2016-03-09 2016-03-22 混成触媒組成物、その製造方法、及びそれを用いて製造されたポリオレフィン
US16/083,125 US11267917B2 (en) 2016-03-09 2016-03-22 Hybrid catalyst composition, preparation method therefor, and polyolefin prepared using same
EP16893664.9A EP3428201A4 (en) 2016-03-09 2016-03-22 HYBRID CATALYST COMPOSITION, MANUFACTURING METHOD AND POLYOLEFINE MANUFACTURED THEREFOR
PCT/KR2016/002842 WO2017155149A1 (ko) 2016-03-09 2016-03-22 혼성 촉매 조성물, 이의 제조방법, 및 이를 이용하여 제조된 폴리올레핀
CN201680085502.6A CN109476776B (zh) 2016-03-09 2016-03-22 复合催化剂组合物、其制备方法以及利用其制备的聚烯烃

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KR1020160028278A KR101711788B1 (ko) 2016-03-09 2016-03-09 혼성 촉매 조성물, 이의 제조방법, 및 이를 이용하여 제조된 폴리올레핀

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US (1) US11267917B2 (https=)
EP (1) EP3428201A4 (https=)
JP (1) JP6811783B2 (https=)
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CN (1) CN109476776B (https=)
WO (1) WO2017155149A1 (https=)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018067289A1 (en) * 2016-10-05 2018-04-12 Exxonmobil Chemical Patents Inc. Sterically hindered metallocenes, synthesis and use
KR20180103349A (ko) * 2017-03-09 2018-09-19 주식회사 엘지화학 올레핀 공중합체
CN111164112A (zh) * 2017-07-13 2020-05-15 韩华化学株式会社 利用负载型混杂茂金属催化剂的高密度乙烯类聚合物以及管道
WO2020101373A1 (ko) * 2018-11-15 2020-05-22 롯데케미칼 주식회사 프로필렌 중합용 담지촉매 및 이를 이용하는 폴리프로필렌 수지의 제조방법
KR20200058047A (ko) * 2018-11-19 2020-05-27 한화솔루션 주식회사 올레핀 중합용 촉매의 제조방법
KR20200066803A (ko) * 2018-12-03 2020-06-11 한화솔루션 주식회사 올레핀 중합용 촉매의 제조방법
US10882932B2 (en) 2016-10-05 2021-01-05 Exxonmobil Chemical Patents Inc. Sterically hindered metallocenes, synthesis and use
WO2021080249A1 (ko) * 2019-10-24 2021-04-29 한화솔루션 주식회사 올레핀 중합용 촉매의 제조방법
WO2021086027A1 (ko) * 2019-11-01 2021-05-06 주식회사 엘지화학 메탈로센 담지 촉매의 제조방법 및 메탈로센 담지 촉매
WO2021112489A1 (ko) * 2019-12-05 2021-06-10 한화솔루션 주식회사 올레핀계 중합체의 제조방법
CN113166293A (zh) * 2018-12-11 2021-07-23 韩华思路信株式会社 用于聚合烯烃的催化剂的制备方法
KR20210118204A (ko) * 2019-02-12 2021-09-29 엑손모빌 케미칼 패턴츠 인코포레이티드 전이 금속 비스(페놀레이트) 착물 및 올레핀 중합을 위한 촉매로서의 이의 용도
WO2022139317A1 (ko) * 2020-12-23 2022-06-30 한화솔루션 주식회사 혼성 촉매 조성물, 이를 포함하는 촉매 및 이를 이용한 올레핀계 중합체의 제조방법
US11384183B2 (en) 2019-01-17 2022-07-12 Lg Chem, Ltd. Hybrid supported metallocene catalyst and method for preparing olefin polymer using the same
KR20230148043A (ko) * 2022-04-15 2023-10-24 지에스칼텍스 주식회사 올레핀 중합용 메탈로센 담지 촉매 및 이의 제조방법
US12528891B2 (en) 2020-08-04 2026-01-20 Lg Chem, Ltd. Hybrid supported metallocene catalyst and method for preparing polypropylene using the same

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KR101711788B1 (ko) 2016-03-09 2017-03-14 한화케미칼 주식회사 혼성 촉매 조성물, 이의 제조방법, 및 이를 이용하여 제조된 폴리올레핀
KR101692346B1 (ko) * 2016-04-27 2017-01-03 한화케미칼 주식회사 혼성 담지 메탈로센 촉매를 이용한 고밀도 에틸렌계 중합체 및 제조방법
KR101706073B1 (ko) 2016-04-27 2017-02-13 한화케미칼 주식회사 혼성 담지 메탈로센 촉매를 이용한 고밀도 에틸렌계 중합체 및 제조방법
KR101723774B1 (ko) * 2016-07-28 2017-04-18 한화케미칼 주식회사 혼성 담지 메탈로센 촉매를 이용한 고가공성 고밀도 에틸렌계 중합체 및 제조방법
US10968290B2 (en) 2017-03-28 2021-04-06 Exxonmobil Chemical Patents Inc. Metallocene-catalyzed polyalpha-olefins
WO2019099577A1 (en) * 2017-11-15 2019-05-23 Exxonmobil Chemical Patents Inc. Polymerization processes
KR20190071187A (ko) * 2017-12-14 2019-06-24 한화케미칼 주식회사 장기 내압 특성이 우수한 에틸렌계 중합체 및 이를 이용한 파이프
US11021553B2 (en) 2018-02-12 2021-06-01 Exxonmobil Chemical Patents Inc. Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers
WO2019157169A1 (en) 2018-02-12 2019-08-15 Exxonmobil Chemical Patents Inc. Catalyst systems and processes for poly alpha-olefin having high vinylidene content
US11078308B2 (en) 2018-02-12 2021-08-03 Exxonmobil Chemical Patents Inc. Processes to produce poly alpha-olefin trimers
WO2020060692A2 (en) 2018-09-17 2020-03-26 Exxonmobil Chemical Patents Inc. Processes to produce poly alpha-olefin trimer and apparatus therefor
KR102382131B1 (ko) * 2018-12-11 2022-04-01 한화솔루션 주식회사 폴리올레핀 및 이의 제조 방법
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KR102524952B1 (ko) * 2019-06-13 2023-04-24 주식회사 엘지화학 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법
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