KR101706395B1 - 실세스퀴옥산 광개시제 - Google Patents

Info

Publication number

KR101706395B1

KR101706395B1 KR1020117015080A KR20117015080A KR101706395B1 KR 101706395 B1 KR101706395 B1 KR 101706395B1 KR 1020117015080 A KR1020117015080 A KR 1020117015080A KR 20117015080 A KR20117015080 A KR 20117015080A KR 101706395 B1 KR101706395 B1 KR 101706395B1

Authority

KR

South Korea

Prior art keywords

alkylene

alkyl

branched

linear

substituted

Prior art date

2008-12-01

Links

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• 150000001875 compounds Chemical class 0.000 claims abstract description 130
• 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 111
• 239000001257 hydrogen Substances 0.000 claims abstract description 107
• 125000000217 alkyl group Chemical group 0.000 claims abstract description 86
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 57
• 125000003161 (C1-C6) alkylene group Chemical group 0.000 claims abstract description 26
• 239000000203 mixture Substances 0.000 claims description 247
• 229910052760 oxygen Inorganic materials 0.000 claims description 73
• YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 63
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 62
• 150000002431 hydrogen Chemical group 0.000 claims description 50
• 238000000576 coating method Methods 0.000 claims description 43
• 238000004519 manufacturing process Methods 0.000 claims description 37
• 238000000034 method Methods 0.000 claims description 34
• 239000011248 coating agent Substances 0.000 claims description 31
• HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 29
• 229910052736 halogen Inorganic materials 0.000 claims description 29
• 125000002947 alkylene group Chemical group 0.000 claims description 28
• 150000002367 halogens Chemical class 0.000 claims description 28
• 238000007639 printing Methods 0.000 claims description 22
• 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 21
• 239000000463 material Substances 0.000 claims description 21
• 229920000642 polymer Polymers 0.000 claims description 21
• 239000000843 powder Substances 0.000 claims description 21
• 125000003118 aryl group Chemical group 0.000 claims description 20
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 20
• 239000000178 monomer Substances 0.000 claims description 19
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 18
• 229910052799 carbon Inorganic materials 0.000 claims description 17
• 229910052757 nitrogen Inorganic materials 0.000 claims description 16
• 125000003277 amino group Chemical group 0.000 claims description 15
• XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 14
• 125000004433 nitrogen atom Chemical group N* 0.000 claims description 14
• 239000000654 additive Substances 0.000 claims description 13
• 125000004432 carbon atom Chemical group C* 0.000 claims description 13
• 229910052710 silicon Inorganic materials 0.000 claims description 13
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 11
• 239000000853 adhesive Substances 0.000 claims description 10
• 230000001070 adhesive effect Effects 0.000 claims description 10
• 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims description 10
• 229920002120 photoresistant polymer Polymers 0.000 claims description 10
• 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 9
• 238000007650 screen-printing Methods 0.000 claims description 9
• 229920002554 vinyl polymer Polymers 0.000 claims description 9
• 239000003795 chemical substances by application Substances 0.000 claims description 8
• 239000010703 silicon Substances 0.000 claims description 8
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
• 238000002360 preparation method Methods 0.000 claims description 7
• 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims description 6
• 239000003973 paint Substances 0.000 claims description 6
• 239000002966 varnish Substances 0.000 claims description 6
• 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims description 5
• 125000004414 alkyl thio group Chemical group 0.000 claims description 5
• 230000000996 additive effect Effects 0.000 claims description 4
• 239000003094 microcapsule Substances 0.000 claims description 4
• 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 4
• 125000004429 atom Chemical group 0.000 claims description 3
• 238000004040 coloring Methods 0.000 claims description 3
• 239000006260 foam Substances 0.000 claims description 3
• 229910052717 sulfur Inorganic materials 0.000 claims description 3
• 230000005670 electromagnetic radiation Effects 0.000 claims description 2
• 230000001678 irradiating effect Effects 0.000 claims description 2
• 238000004382 potting Methods 0.000 claims description 2
• 238000007789 sealing Methods 0.000 claims 1
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract description 34
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract description 32
• 150000001412 amines Chemical group 0.000 abstract description 11
• 238000012546 transfer Methods 0.000 abstract description 2
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 170
• 239000000243 solution Substances 0.000 description 145
• BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 111
• -1 polysiloxane Polymers 0.000 description 98
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 88
• 238000006243 chemical reaction Methods 0.000 description 60
• 239000002904 solvent Substances 0.000 description 52
• 238000005227 gel permeation chromatography Methods 0.000 description 48
• SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 43
• 239000004793 Polystyrene Substances 0.000 description 39
• 238000003756 stirring Methods 0.000 description 38
• SWFHGTMLYIBPPA-UHFFFAOYSA-N (4-methoxyphenyl)-phenylmethanone Chemical compound C1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 SWFHGTMLYIBPPA-UHFFFAOYSA-N 0.000 description 37
• 229920002223 polystyrene Polymers 0.000 description 37
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 35
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 35
• LJRIZGQRKVWXSI-UHFFFAOYSA-N [4-(oxiran-2-ylmethoxy)phenyl]-phenylmethanone Chemical compound C=1C=C(OCC2OC2)C=CC=1C(=O)C1=CC=CC=C1 LJRIZGQRKVWXSI-UHFFFAOYSA-N 0.000 description 32
• 150000003377 silicon compounds Chemical class 0.000 description 32
• 239000006185 dispersion Substances 0.000 description 31
• YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 description 29
• 238000001879 gelation Methods 0.000 description 28
• 239000003039 volatile agent Substances 0.000 description 28
• RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 27
• 238000007142 ring opening reaction Methods 0.000 description 26
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 25
• 229920005989 resin Polymers 0.000 description 25
• 239000011347 resin Substances 0.000 description 25
• RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 24
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
• 150000002118 epoxides Chemical group 0.000 description 23
• 239000007787 solid Substances 0.000 description 23
• 0 CC(CCC1[*+])CC1*#**C(CCC1*)CC1[N+] Chemical compound CC(CCC1[*+])CC1*#**C(CCC1*)CC1[N+] 0.000 description 20
• 239000000758 substrate Substances 0.000 description 20
• 229920001577 copolymer Polymers 0.000 description 19
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
• 239000010408 film Substances 0.000 description 17
• 239000000976 ink Substances 0.000 description 17
• 239000000047 product Substances 0.000 description 17
• ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 15
• 239000006184 cosolvent Substances 0.000 description 15
• 238000009472 formulation Methods 0.000 description 15
• KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 14
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 14
• 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 14
• 239000000126 substance Substances 0.000 description 14
• 238000001723 curing Methods 0.000 description 13
• 239000000049 pigment Substances 0.000 description 13
• RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 12
• LSWYGACWGAICNM-UHFFFAOYSA-N 2-(prop-2-enoxymethyl)oxirane Chemical group C=CCOCC1CO1 LSWYGACWGAICNM-UHFFFAOYSA-N 0.000 description 12
• 238000001704 evaporation Methods 0.000 description 12
• 230000008020 evaporation Effects 0.000 description 12
• 229920000728 polyester Polymers 0.000 description 12
• 238000010992 reflux Methods 0.000 description 12
• ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 11
• RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 11
• 239000012965 benzophenone Substances 0.000 description 11
• 238000009826 distribution Methods 0.000 description 11
• 239000010410 layer Substances 0.000 description 11
• 229920005862 polyol Polymers 0.000 description 11
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
• 239000011230 binding agent Substances 0.000 description 10
• WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 9
• WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 9
• 229910052751 metal Inorganic materials 0.000 description 9
• 239000002184 metal Substances 0.000 description 9
• 238000006116 polymerization reaction Methods 0.000 description 9
• 150000003077 polyols Chemical class 0.000 description 9
• YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 9
• TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 8
• BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 8
• 239000012267 brine Substances 0.000 description 8
• 238000000816 matrix-assisted laser desorption--ionisation Methods 0.000 description 8
• 125000004430 oxygen atom Chemical group O* 0.000 description 8
• HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 8
• 241000566146 Asio Species 0.000 description 7
• UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 7
• ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 7
• 238000003848 UV Light-Curing Methods 0.000 description 7
• QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 7
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 7
• 239000000460 chlorine Substances 0.000 description 7
• 239000000975 dye Substances 0.000 description 7
• 238000000921 elemental analysis Methods 0.000 description 7
• 239000003999 initiator Substances 0.000 description 7
• 238000000465 moulding Methods 0.000 description 7
• 125000001624 naphthyl group Chemical group 0.000 description 7
• 229920000647 polyepoxide Polymers 0.000 description 7
• 239000011541 reaction mixture Substances 0.000 description 7
• 125000001424 substituent group Chemical group 0.000 description 7
• 239000000725 suspension Substances 0.000 description 7
• AQFXIWDRLHRFIC-UHFFFAOYSA-N 1-[5-phenyl-3-(trifluoromethyl)pyrazol-1-yl]ethanone Chemical compound CC(=O)N1N=C(C(F)(F)F)C=C1C1=CC=CC=C1 AQFXIWDRLHRFIC-UHFFFAOYSA-N 0.000 description 6
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
• DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 6
• 239000002131 composite material Substances 0.000 description 6
• ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 6
• QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 6
• 229910052753 mercury Inorganic materials 0.000 description 6
• 230000003287 optical effect Effects 0.000 description 6
• VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 6
• FAQJJMHZNSSFSM-UHFFFAOYSA-N phenylglyoxylic acid Chemical compound OC(=O)C(=O)C1=CC=CC=C1 FAQJJMHZNSSFSM-UHFFFAOYSA-N 0.000 description 6
• 229920000570 polyether Polymers 0.000 description 6
• 230000008569 process Effects 0.000 description 6
• 230000005855 radiation Effects 0.000 description 6
• CDSULTPOCMWJCM-UHFFFAOYSA-N 4h-chromene-2,3-dione Chemical compound C1=CC=C2OC(=O)C(=O)CC2=C1 CDSULTPOCMWJCM-UHFFFAOYSA-N 0.000 description 5
• HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 5
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
• 239000005977 Ethylene Substances 0.000 description 5
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
• 239000004820 Pressure-sensitive adhesive Substances 0.000 description 5
• XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 5
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 5
• 229910052782 aluminium Inorganic materials 0.000 description 5
• 239000007864 aqueous solution Substances 0.000 description 5
• KXHPPCXNWTUNSB-UHFFFAOYSA-M benzyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1=CC=CC=C1 KXHPPCXNWTUNSB-UHFFFAOYSA-M 0.000 description 5
• IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
• 229910052801 chlorine Inorganic materials 0.000 description 5
• 238000009833 condensation Methods 0.000 description 5
• 230000005494 condensation Effects 0.000 description 5
• 239000003995 emulsifying agent Substances 0.000 description 5
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
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• 238000004128 high performance liquid chromatography Methods 0.000 description 5
• 238000007645 offset printing Methods 0.000 description 5
• 239000012074 organic phase Substances 0.000 description 5
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• 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 5
• 238000000016 photochemical curing Methods 0.000 description 5
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• OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 4
• GJKGAPPUXSSCFI-UHFFFAOYSA-N 2-Hydroxy-4'-(2-hydroxyethoxy)-2-methylpropiophenone Chemical compound CC(C)(O)C(=O)C1=CC=C(OCCO)C=C1 GJKGAPPUXSSCFI-UHFFFAOYSA-N 0.000 description 4
• VJJZFUUHKVZKLP-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-[4-[2-(oxiran-2-ylmethoxy)ethoxy]phenyl]propan-1-one Chemical compound C1=CC(C(=O)C(C)(O)C)=CC=C1OCCOCC1OC1 VJJZFUUHKVZKLP-UHFFFAOYSA-N 0.000 description 4
• VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 4
• YDIYEOMDOWUDTJ-UHFFFAOYSA-M 4-(dimethylamino)benzoate Chemical compound CN(C)C1=CC=C(C([O-])=O)C=C1 YDIYEOMDOWUDTJ-UHFFFAOYSA-M 0.000 description 4
• NPFYZDNDJHZQKY-UHFFFAOYSA-N 4-Hydroxybenzophenone Chemical compound C1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 NPFYZDNDJHZQKY-UHFFFAOYSA-N 0.000 description 4
• FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
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• KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 4
• 150000003254 radicals Chemical class 0.000 description 4
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• YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
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