KR101615875B1 - 아미노알콕시실란 그룹에 의해 커플링된 디엔 탄성중합체를 주로 포함하는 탄성중합체 혼합물, 이를 포함하는 고무 조성물 및 이의 수득 방법 - Google Patents
아미노알콕시실란 그룹에 의해 커플링된 디엔 탄성중합체를 주로 포함하는 탄성중합체 혼합물, 이를 포함하는 고무 조성물 및 이의 수득 방법 Download PDFInfo
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- KR101615875B1 KR101615875B1 KR1020107026646A KR20107026646A KR101615875B1 KR 101615875 B1 KR101615875 B1 KR 101615875B1 KR 1020107026646 A KR1020107026646 A KR 1020107026646A KR 20107026646 A KR20107026646 A KR 20107026646A KR 101615875 B1 KR101615875 B1 KR 101615875B1
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- elastomer
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- diene elastomer
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- 238000011208 chromatographic data Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 150000001934 cyclohexanes Chemical class 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000002897 diene group Chemical group 0.000 description 1
- 229940043279 diisopropylamine Drugs 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012156 elution solvent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- BLHLJVCOVBYQQS-UHFFFAOYSA-N ethyllithium Chemical compound [Li]CC BLHLJVCOVBYQQS-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 125000000879 imine group Chemical group 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- AFRJJFRNGGLMDW-UHFFFAOYSA-N lithium amide Chemical class [Li+].[NH2-] AFRJJFRNGGLMDW-UHFFFAOYSA-N 0.000 description 1
- CCZVEWRRAVASGL-UHFFFAOYSA-N lithium;2-methanidylpropane Chemical compound [Li+].CC(C)[CH2-] CCZVEWRRAVASGL-UHFFFAOYSA-N 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 230000005226 mechanical processes and functions Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical group [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 125000001979 organolithium group Chemical group 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003192 poly(bis maleimide) Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000009870 specific binding Effects 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- FBBATURSCRIBHN-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSCCC[Si](OCC)(OCC)OCC FBBATURSCRIBHN-UHFFFAOYSA-N 0.000 description 1
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/22—Incorporating nitrogen atoms into the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/25—Incorporating silicon atoms into the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
Landscapes
- Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Tires In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0852868 | 2008-04-29 | ||
| FR0852868A FR2930554B1 (fr) | 2008-04-29 | 2008-04-29 | Melange elastomerique comprenant majoritairement un elastomere dienique couple par un groupe amino-alcoxysilane, composition de caoutchouc le comprenant et leurs procedes d'obtention. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20110021821A KR20110021821A (ko) | 2011-03-04 |
| KR101615875B1 true KR101615875B1 (ko) | 2016-04-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020107026646A Active KR101615875B1 (ko) | 2008-04-29 | 2009-04-27 | 아미노알콕시실란 그룹에 의해 커플링된 디엔 탄성중합체를 주로 포함하는 탄성중합체 혼합물, 이를 포함하는 고무 조성물 및 이의 수득 방법 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9175124B2 (enExample) |
| EP (1) | EP2285852B1 (enExample) |
| JP (2) | JP5705721B2 (enExample) |
| KR (1) | KR101615875B1 (enExample) |
| CN (1) | CN102015799B (enExample) |
| BR (1) | BRPI0911836B1 (enExample) |
| EA (1) | EA020173B1 (enExample) |
| FR (1) | FR2930554B1 (enExample) |
| HU (1) | HUE028614T2 (enExample) |
| WO (1) | WO2009133068A1 (enExample) |
Families Citing this family (118)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2940294B1 (fr) | 2008-12-23 | 2011-02-18 | Michelin Soc Tech | Nouveau systeme d'amorcage pour polymerisation anionique de dienes conjugues, procede de preparation d'elastomeres dieniques. |
| FR2947828B1 (fr) | 2009-07-10 | 2012-01-06 | Michelin Soc Tech | Composition a base de caoutchouc naturel et d'un compose poly-imine |
| FR2947827B1 (fr) | 2009-07-10 | 2012-01-06 | Michelin Soc Tech | Composition a base de caoutchouc naturel et d'un compose poly-imine |
| US8816014B2 (en) | 2009-10-02 | 2014-08-26 | Asahi Kasei Chemicals Corporation | Method for producing modified conjugated diene-based polymer, modified conjugated diene-based polymer, and modified conjugated diene-based polymer composition |
| FR2955116B1 (fr) * | 2010-01-14 | 2013-05-24 | Soc Tech Michelin | Composition de caoutchouc comprenant un elastomere thermoplastique polaire comprenant un bloc alkylacrylate |
| EP2357211B1 (de) | 2010-02-17 | 2018-11-21 | Continental Reifen Deutschland GmbH | Schwefelvernetzbare kautschukmischung |
| FR2957601B1 (fr) | 2010-03-18 | 2012-03-16 | Michelin Soc Tech | Pneumatique et composition de caoutchouc contenant un polymere greffe |
| SG191566A1 (en) | 2010-04-16 | 2013-07-31 | Asahi Kasei Chemicals Corp | Method for producing modified conjugated diene-based polymer, modified conjugated diene-based polymer, and modified conjugated diene-based polymer composition |
| FR2967681B1 (fr) * | 2010-11-23 | 2012-11-30 | Michelin Soc Tech | Elastomere dienique a blocs a ip faible fonctionnel a fluage a froid ameliore et composition de caoutchouc le contenant |
| FR2967680B1 (fr) * | 2010-11-23 | 2012-11-30 | Soc Tech Michelin | Elastomere dienique a bloc pour des compositions de caoutchouc utilisables pour des pneumatiques |
| FR2968006B1 (fr) | 2010-11-26 | 2012-12-21 | Michelin Soc Tech | Bande de roulement de pneumatique |
| FR2968005B1 (fr) | 2010-11-26 | 2012-12-21 | Michelin Soc Tech | Bande de roulement de pneumatique neige |
| FR2968307B1 (fr) | 2010-11-26 | 2018-04-06 | Societe De Technologie Michelin | Bande de roulement de pneumatique |
| JP5630344B2 (ja) * | 2011-03-16 | 2014-11-26 | Jsr株式会社 | 変性共役ジエン系ゴムの製造方法 |
| FR2975406B1 (fr) | 2011-05-18 | 2014-10-17 | Michelin Soc Tech | Cordon composite caoutchouteux pour bande de roulement de bandage pneumatique |
| US20140141262A1 (en) * | 2011-06-29 | 2014-05-22 | Sun Chemical Corporation | Vinyl alcohol polymers with silane side chains and compositions comprising the same |
| FR2980481B1 (fr) | 2011-09-26 | 2013-10-11 | Michelin Soc Tech | Pneumatique a adherence amelioree sur sol mouille |
| FR2980480B1 (fr) | 2011-09-26 | 2013-10-11 | Michelin Soc Tech | Pneumatique a adherence amelioree sur sol mouille |
| FR2984229B1 (fr) | 2011-12-16 | 2013-12-27 | Michelin Soc Tech | Bandage pneumatique comportant un cordon composite de recreusage |
| JP5838088B2 (ja) * | 2011-12-21 | 2015-12-24 | 株式会社ブリヂストン | ゴム組成物の製造方法 |
| FR2984904B1 (fr) * | 2011-12-22 | 2014-01-03 | Michelin Soc Tech | Composition de caoutchouc |
| TWI503331B (zh) * | 2012-12-03 | 2015-10-11 | Chi Mei Corp | 末端改質的共軛二烯-乙烯基芳香烴共聚物及其合成方法 |
| CN105189565B (zh) * | 2013-03-07 | 2017-03-15 | 东洋橡胶工业株式会社 | 改性聚合物的制造方法及橡胶组合物 |
| JP2014208805A (ja) * | 2013-03-27 | 2014-11-06 | 日本ゼオン株式会社 | 変性共役ジエン系ゴムの製造方法 |
| DE102013105193B4 (de) * | 2013-05-22 | 2024-10-17 | Continental Reifen Deutschland Gmbh | Kautschukmischung und Verwendung derselben in Fahrzeugreifen |
| WO2015015679A1 (ja) * | 2013-07-31 | 2015-02-05 | 東洋ゴム工業株式会社 | ゴム-シリカ複合体及びその製造方法、並びにゴム組成物及び空気入りタイヤ |
| FR3009559A1 (fr) | 2013-08-08 | 2015-02-13 | Michelin & Cie | Elastomere dienique modifie, son procede de synthese et composition de caoutchouc le comprenant |
| FR3009560B1 (fr) | 2013-08-08 | 2018-01-05 | Compagnie Generale Des Etablissements Michelin | Elastomere dienique modifie par couplage porteur de fonctions silanol, son procede de synthese et composition de caoutchouc le comprenant. |
| FR3009558B1 (fr) * | 2013-08-09 | 2015-09-04 | Michelin & Cie | Elastomere dienique couple possedant une fonction silanol en milieu de chaine et fonctionnalise amine en extremite de chaine et composition de caoutchouc le comprenant |
| FR3009557B1 (fr) * | 2013-08-09 | 2015-09-11 | Michelin & Cie | Elastomere dienique modifie comprenant un elastomere dienique couple par un compose aminoalcoxysilane et fonctionnalise amine en extremite de chaine et composition de caoutchouc le comprenant |
| FR3012454B1 (fr) * | 2013-10-30 | 2015-12-18 | Michelin & Cie | Elastomere dienique modifie comprenant majoritairement un elastomere dienique couple par un compose alcoxysilane portant un groupe epoxyde et fonctionnalise amine en extremite de chaine |
| CN105745086B (zh) * | 2013-10-31 | 2018-11-09 | 米其林集团总公司 | 用于改良磨损的官能化聚合物掺合物 |
| FR3014443B1 (fr) * | 2013-12-10 | 2016-01-15 | Michelin & Cie | Bande de roulement de pneumatique |
| PL3080167T3 (pl) * | 2013-12-12 | 2025-03-03 | Firestone Polymers, Llc | Sposób wytwarzania kompozycji polimerowych zawierających funkcjonalizowane polimery |
| FR3014872B1 (fr) * | 2013-12-18 | 2017-03-10 | Michelin & Cie | Elastomere dienique modifie et composition de caoutchouc le contenant |
| FR3015499B1 (fr) | 2013-12-20 | 2017-04-28 | Michelin & Cie | Pneumatique pour vehicules destines a porter de lourdes charges |
| FR3015494B1 (fr) | 2013-12-20 | 2016-01-15 | Michelin & Cie | Bande de roulement pour pneumatique comportant un elastomere thermoplastique |
| JP6468283B2 (ja) * | 2014-03-31 | 2019-02-13 | 日本ゼオン株式会社 | 変性共役ジエン系ゴムの製造方法 |
| FR3021971B1 (fr) | 2014-06-05 | 2016-06-03 | Michelin & Cie | Pneumatique a faible resistance au roulement |
| US20160160071A1 (en) | 2014-12-04 | 2016-06-09 | Exxonmobil Chemical Patents Inc. | Water-Based Polyolefin Corrosion Inhibitors Based on Vinyl/Vinylidene Terminated Polyolefins |
| WO2016109476A1 (en) | 2014-12-30 | 2016-07-07 | Compagnie Generale Des Etablissements Michelin | Rubber composition with resins |
| FR3036115B1 (fr) | 2015-05-11 | 2017-05-19 | Michelin & Cie | Composition de caoutchouc |
| FR3037593A1 (fr) | 2015-06-18 | 2016-12-23 | Michelin & Cie | Pneumatique pour vehicules destines a porter de lourdes charges |
| US10828937B2 (en) | 2015-07-01 | 2020-11-10 | Bridgestone Corporation | Copolymer end-functionalized with functional silane, compositions thereof and related processes |
| FR3038315B1 (fr) * | 2015-07-02 | 2017-07-21 | Michelin & Cie | Elastomere dienique modifie a ip reduit et composition le contenant |
| WO2017015592A1 (en) * | 2015-07-22 | 2017-01-26 | Bridgestone Corporation | Silane-functionalized polymer and process for making and using same |
| FR3042194A1 (fr) * | 2015-10-08 | 2017-04-14 | Michelin & Cie | Composition de caoutchouc contenant un elastomere dienique possedant une fonction en milieu de chaine |
| FR3042193A1 (fr) | 2015-10-08 | 2017-04-14 | Michelin & Cie | Elastomere dienique possedant une fonction en milieu de chaine et composition de caoutchouc le contenant |
| CN108473599B (zh) * | 2016-06-24 | 2020-09-15 | Jsr株式会社 | 改性共轭二烯系聚合物的制造方法、改性共轭二烯系聚合物、聚合物组合物、交联体、轮胎以及化合物 |
| CN107641219B (zh) * | 2016-07-20 | 2020-12-18 | 中国石油化工股份有限公司 | 有机硅烷的应用和橡胶组合物以及硫化橡胶及其制备方法 |
| CN109937147B (zh) | 2016-10-31 | 2021-04-20 | 米其林集团总公司 | 包括胎面的轮胎 |
| WO2018079804A1 (en) | 2016-10-31 | 2018-05-03 | Compagnie Generale Des Etablissements Michelin | A tire comprising a tread |
| CN109982862B (zh) | 2016-10-31 | 2021-01-29 | 米其林集团总公司 | 包括胎面的轮胎 |
| CN109922974A (zh) | 2016-10-31 | 2019-06-21 | 米其林集团总公司 | 包括胎面的轮胎 |
| FR3060585A1 (fr) * | 2016-12-19 | 2018-06-22 | Compagnie Generale Des Etablissements Michelin | Bande de roulement pour pneumatique comprenant un elastomere modifie |
| FR3060453A1 (fr) | 2016-12-20 | 2018-06-22 | Compagnie Generale Des Etablissements Michelin | Pneumatique pour vehicule portant des lourdes charges comprenant une nouvelle bande de roulement |
| JP2020502358A (ja) * | 2016-12-20 | 2020-01-23 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | 変性ジエンエラストマーを含むゴム組成物 |
| US11390117B2 (en) | 2017-01-31 | 2022-07-19 | Compagnie Generale Des Etablissements Michelin | Tire comprising a rubber composition |
| US11241912B2 (en) | 2017-03-21 | 2022-02-08 | Compagnie Generale Des Etablissements Michelin | Tire comprising a tread |
| FR3064532A1 (fr) | 2017-03-30 | 2018-10-05 | Compagnie Generale Des Etablissements Michelin | Pneumatique pour vehicule de tourisme |
| FR3065001A1 (fr) * | 2017-04-11 | 2018-10-12 | Compagnie Generale Des Etablissements Michelin | Elastomere dienique modifie par un groupement comprenant un atome de silicium, procede pour sa synthese et composition de caoutchouc le contenant |
| WO2018221630A1 (en) | 2017-05-31 | 2018-12-06 | Compagnie Generale Des Etablissements Michelin | A tire comprising a tread |
| FR3069550A1 (fr) | 2017-07-28 | 2019-02-01 | Compagnie Generale Des Etablissements Michelin | Elastomere etendu a la resine |
| CN109384975B (zh) * | 2017-08-03 | 2021-05-11 | 中国石油化工股份有限公司 | 用于鞋底的橡胶组合物和硫化橡胶及其制备方法和应用 |
| CN107474313B (zh) * | 2017-09-19 | 2019-12-27 | 荆州市江汉精细化工有限公司 | 一种改性的橡胶助剂及其制备方法 |
| WO2019073145A1 (fr) | 2017-10-09 | 2019-04-18 | Compagnie Generale Des Etablissements Michelin | Pneumatique pourvu d'une bande de roulement comportant au moins un caoutchouc butyl et un copolymere a base de butadiene et de styrene |
| WO2019102150A1 (fr) | 2017-11-24 | 2019-05-31 | Compagnie Generale Des Etablissements Michelin | Pneumatique pour vehicule de tourisme |
| WO2019122605A1 (fr) | 2017-12-19 | 2019-06-27 | Compagnie Generale Des Etablissements Michelin | Bande de roulement de pneumatique dont le systeme de reticulation est a base de peroxyde organique |
| US20210079200A1 (en) | 2017-12-19 | 2021-03-18 | Compagnie Generale Des Etablissements Michelin | Tire tread, the crosslinking system of which is based on organic peroxide |
| WO2019122602A1 (fr) | 2017-12-19 | 2019-06-27 | Compagnie Generale Des Etablissements Michelin | Bande de roulement de pneumatique dont le systeme de reticulation est a base de peroxyde organique |
| WO2019122604A1 (fr) | 2017-12-19 | 2019-06-27 | Compagnie Generale Des Etablissements Michelin | Bande de roulement de pneumatique dont le systeme de reticulation est a base de peroxyde organique |
| CN108508701A (zh) * | 2018-03-21 | 2018-09-07 | 深圳市华星光电技术有限公司 | 一种光刻胶的制备方法,光刻胶及滤光片 |
| JP6624231B2 (ja) | 2018-04-17 | 2019-12-25 | 横浜ゴム株式会社 | 空気入りタイヤ |
| EP3781374A4 (en) * | 2018-04-27 | 2022-01-26 | Algix, LLC | Elastomer composite including algae biomass filler |
| JP2021523261A (ja) | 2018-05-04 | 2021-09-02 | ブリヂストン アメリカズ タイヤ オペレーションズ、 エルエルシー | タイヤトレッドゴム組成物 |
| WO2019213229A1 (en) | 2018-05-04 | 2019-11-07 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition |
| US12371553B2 (en) | 2018-05-04 | 2025-07-29 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition |
| WO2019213185A1 (en) | 2018-05-04 | 2019-11-07 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition |
| US11702485B2 (en) | 2018-05-08 | 2023-07-18 | Lg Chem, Ltd. | Modified conjugated diene-based polymer and rubber composition including the same |
| FR3081161B1 (fr) | 2018-05-17 | 2020-07-10 | Compagnie Generale Des Etablissements Michelin | Bande de roulement de pneumatique dont le systeme de reticulation est a base de peroxyde organique |
| FR3081162B1 (fr) | 2018-05-17 | 2020-04-24 | Compagnie Generale Des Etablissements Michelin | Bande de roulement de pneumatique dont le systeme de reticulation est a base de peroxyde organique |
| WO2019220627A1 (en) | 2018-05-18 | 2019-11-21 | Compagnie Generale Des Etablissements Michelin | A composition for a tire tread |
| WO2019240071A1 (ja) * | 2018-06-12 | 2019-12-19 | 横浜ゴム株式会社 | ゴム組成物 |
| FR3082847B1 (fr) * | 2018-06-21 | 2020-06-05 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc comprenant un elastomere fonctionnel |
| FR3085954B1 (fr) | 2018-09-17 | 2020-09-11 | Michelin & Cie | Pneumatique avec bourrelets comprenant une composition de caoutchouc specifique |
| WO2020068128A1 (en) | 2018-09-28 | 2020-04-02 | Compagnie Generale Des Etablissements Michelin | Tire tread with low tg functionalized sbr |
| FR3087443B3 (fr) * | 2018-10-23 | 2020-10-23 | Michelin & Cie | Composition de caoutchouc |
| FR3088333A3 (fr) | 2018-11-08 | 2020-05-15 | Michelin & Cie | Composition de caoutchouc a base d'un elastomere dienique modifie |
| FR3088336A3 (fr) | 2018-11-08 | 2020-05-15 | Michelin & Cie | Composition de caoutchouc a base d'un elastomere dienique modifie |
| FR3088335A3 (fr) | 2018-11-08 | 2020-05-15 | Michelin & Cie | Composition de caoutchouc a base d’un elastomere dienique modifie |
| WO2020128207A1 (fr) | 2018-12-19 | 2020-06-25 | Compagnie Generale Des Etablissements Michelin | Pneumatique pour camionnette optimise |
| WO2020128209A1 (fr) | 2018-12-19 | 2020-06-25 | Compagnie Generale Des Etablissements Michelin | Pneumatique pour camionnette optimise |
| FR3090476A3 (fr) | 2018-12-19 | 2020-06-26 | Michelin & Cie | Pneumatique pour camionnette optimisé |
| FR3090475A3 (fr) | 2018-12-19 | 2020-06-26 | Michelin & Cie | Pneumatique pour camionnette optimisé |
| WO2020128208A1 (fr) | 2018-12-19 | 2020-06-25 | Compagnie Generale Des Etablissements Michelin | Pneumatique pour camionnette optimise |
| FR3090473A3 (fr) | 2018-12-19 | 2020-06-26 | Michelin & Cie | Pneumatique pour camionnette optimisé |
| JP7555960B2 (ja) | 2019-04-25 | 2024-09-25 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | ゴム組成物 |
| US20220220288A1 (en) | 2019-04-25 | 2022-07-14 | Compagnie Generale Des Etablissements Michelin | A rubber composition |
| US12325797B2 (en) | 2019-05-29 | 2025-06-10 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition and related methods |
| US12371552B2 (en) | 2019-05-29 | 2025-07-29 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition and related methods |
| EP3976709A1 (en) | 2019-05-29 | 2022-04-06 | Bridgestone Americas Tire Operations, LLC | Tire tread rubber composition and related methods |
| FR3099084B1 (fr) | 2019-07-26 | 2021-06-25 | Michelin & Cie | Pneumatique comportant une bande de roulement |
| FR3099085B1 (fr) | 2019-07-26 | 2021-06-25 | Michelin & Cie | Pneumatique comportant une bande de roulement |
| SG11202110158PA (en) | 2019-09-11 | 2021-10-28 | Lg Chemical Ltd | Modified conjugated diene-based polymer, method for preparing the same and rubber composition including the same |
| KR102604539B1 (ko) | 2019-09-11 | 2023-11-22 | 주식회사 엘지화학 | 변성 공액디엔계 중합체, 이의 제조방법 및 이를 포함하는 고무 조성물 |
| JP7665524B2 (ja) | 2019-09-11 | 2025-04-21 | エルジー・ケム・リミテッド | 変性共役ジエン系重合体およびそれを含むゴム組成物 |
| WO2021049911A1 (ko) | 2019-09-11 | 2021-03-18 | 주식회사 엘지화학 | 변성 공액디엔계 중합체, 이의 제조방법 및 이를 포함하는 고무 조성물 |
| SG11202108200TA (en) | 2019-09-11 | 2021-08-30 | Lg Chemical Ltd | Modified conjugated diene-based polymer and rubber composition including the same |
| US20220410629A1 (en) | 2019-11-06 | 2022-12-29 | Compagnie Generale Des Etablissements Michelin | Tire comprising a tread |
| EP4054858B1 (fr) | 2019-11-06 | 2025-06-25 | Compagnie Generale Des Etablissements Michelin | Pneumatique comportant une bande de roulement |
| WO2021089964A1 (fr) | 2019-11-06 | 2021-05-14 | Compagnie Generale Des Etablissements Michelin | Pneumatique comportant une bande de roulement |
| EP4054864B1 (fr) | 2019-11-06 | 2023-09-13 | Compagnie Generale Des Etablissements Michelin | Pneumatique comportant une bande de roulement |
| US20220388346A1 (en) | 2019-11-06 | 2022-12-08 | Compagnie Generale Des Etablissements Michelin | Tire comprising a tread |
| EP4054862B1 (fr) | 2019-11-06 | 2025-01-01 | Compagnie Generale Des Etablissements Michelin | Pneumatique comportant une bande de roulement |
| FR3144142A1 (fr) | 2022-12-21 | 2024-06-28 | Compagnie Generale Des Etablissements Michelin | Compositions elastomeriques comprenant un noir de carbone de pyrolyse |
| FR3144143A1 (fr) | 2022-12-21 | 2024-06-28 | Compagnie Generale Des Etablissements Michelin | Compositions elastomeriques comprenant un noir de carbone traité au silicium |
| CN120957875A (zh) | 2023-03-28 | 2025-11-14 | 米其林集团总公司 | 包含特定增塑体系的橡胶组合物 |
| CN118812781A (zh) * | 2024-09-20 | 2024-10-22 | 新疆独山子石油化工有限公司 | 间歇改性溶聚丁苯橡胶及其制备方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001131340A (ja) | 1999-11-08 | 2001-05-15 | Bridgestone Corp | ゴム組成物及びそれを用いた空気入りタイヤ |
| JP2001158834A (ja) * | 1999-12-02 | 2001-06-12 | Bridgestone Corp | ゴム組成物及びそれを用いた空気入りタイヤ |
| JP2005232367A (ja) | 2004-02-20 | 2005-09-02 | Bridgestone Corp | 変性共役ジエン系重合体、並びにそれを用いたゴム組成物及びタイヤ |
| JP2008038119A (ja) * | 2006-08-10 | 2008-02-21 | Bridgestone Corp | 重荷重用空気入りタイヤ |
Family Cites Families (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1310787C (en) | 1986-12-01 | 1992-11-24 | Hiroyoshi Takao | Process for preparing modified diene polymer rubbers |
| EP0299074B1 (en) | 1987-01-14 | 1992-01-29 | Bridgestone Corporation | Tire |
| DE68909999T2 (de) | 1988-05-02 | 1994-04-14 | Sumitomo Chemical Co | Modifizierte Kautschuk-Dienpolymere. |
| US5329005A (en) | 1992-10-02 | 1994-07-12 | Bridgestone Corporation | Soluble anionic polymerization initiators and preparation thereof |
| US5393721A (en) | 1992-10-16 | 1995-02-28 | Bridgestone Corporation | Anionic polymerization initiators and reduced hysteresis products therefom |
| ES2179965T3 (es) * | 1993-12-29 | 2003-02-01 | Bridgestone Corp | Polimeros y copolimeros de dieno que tienen un grupo de alcoxisilano. |
| FR2744127A1 (fr) * | 1996-01-26 | 1997-08-01 | Michelin & Cie | Composition de caoutchouc a base d'un polymere dienique ayant une fonction silanol et comprenant un derive organosilane |
| DE69739057D1 (de) | 1996-04-01 | 2008-12-04 | Cabot Corp | Neue elastomere verbundwerkstoffe, verfahren und vorrichtung zur herstellung derselben |
| ATE283753T1 (de) | 1997-09-30 | 2004-12-15 | Cabot Corp | Mischungen aus elastomeren verbundwerkstoffen und verfahren zu ihrer herstellung |
| DE69922900T2 (de) | 1998-10-07 | 2006-01-12 | Jsr Corp. | Ölgestreckter Gummi und Gummizusammensetzung |
| JP2001131230A (ja) | 1999-10-29 | 2001-05-15 | Bridgestone Corp | 重合体、その製造方法、及びそれを用いたゴム組成物 |
| JP4478262B2 (ja) | 1999-11-08 | 2010-06-09 | 株式会社ブリヂストン | ゴム組成物及びそれを用いた空気入りタイヤ |
| JP2001131345A (ja) | 1999-11-08 | 2001-05-15 | Bridgestone Corp | ゴム組成物,油展ゴム及び空気入りタイヤ |
| JP4621320B2 (ja) | 1999-11-08 | 2011-01-26 | 株式会社ブリヂストン | タイヤ用ゴム組成物及びそれを用いた空気入りタイヤ |
| JP2001158835A (ja) | 1999-12-02 | 2001-06-12 | Bridgestone Corp | ゴム組成物及びそれを用いた空気入りタイヤ |
| ES2195496T3 (es) | 1999-12-02 | 2003-12-01 | Bridgestone Corp | Polimero, procedimiento para la preparacion del polimero, y composicion de caucho que utiliza dicho polimero. |
| JP2001158836A (ja) | 1999-12-02 | 2001-06-12 | Bridgestone Corp | ゴム組成物,油展ゴム及び空気入りタイヤ |
| JP4928017B2 (ja) | 1999-12-02 | 2012-05-09 | 株式会社ブリヂストン | ゴム組成物及びそれを用いた空気入りタイヤ |
| CA2417681A1 (fr) | 2000-07-31 | 2002-02-07 | Michelin Recherche Et Technique S.A. | Bande de roulement pour pneumatique |
| EP1326914B1 (fr) | 2000-10-13 | 2006-06-21 | Société de Technologie Michelin | Composition de caoutchouc comportant a titre d'agent de couplage un organosilane polyfonctionnel |
| ES2256317T3 (es) | 2000-10-13 | 2006-07-16 | Societe De Technologie Michelin | Organosilano polifuncional utilizable como agente de acoplamiento y su procedimiento de obtencion. |
| FR2823215B1 (fr) | 2001-04-10 | 2005-04-08 | Michelin Soc Tech | Pneumatique et bande de roulement de pneumatique comportant a titre d'agent de couplage un tetrasulfure de bis-alkoxysilane |
| WO2003002648A1 (fr) | 2001-06-28 | 2003-01-09 | Societe De Technologie Michelin | Bande de roulement pour pneumatique renforcee d'une silice a basse surface specifique |
| CN1325549C (zh) | 2001-06-28 | 2007-07-11 | 米其林技术公司 | 采用具有非常低比表面积的二氧化硅增强的轮胎胎面 |
| SE519792C2 (sv) | 2001-08-17 | 2003-04-08 | Volvo Lastvagnar Ab | Metod för estimering av massan hos ett fordon vilket framförs på en väg med en varierande lutning samt metod för estimering av lutningen av den väg där ett fordon framförs |
| CN1274719C (zh) | 2001-09-27 | 2006-09-13 | Jsr株式会社 | 共轭二烯(共)聚合橡胶、(共)聚合橡胶的制造方法、橡胶组合物、复合体以及轮胎 |
| JP4129619B2 (ja) * | 2001-09-27 | 2008-08-06 | Jsr株式会社 | 共役ジオレフィン(共)重合ゴム、該(共)重合ゴムの製造方法、ゴム組成物およびタイヤ |
| WO2003037946A2 (fr) * | 2001-10-31 | 2003-05-08 | Societe De Technologie Michelin | Procede de preparation de copolymeres a blocs pour compositions de bande de roulement de pneumatique |
| JP4298489B2 (ja) | 2003-12-10 | 2009-07-22 | 株式会社ブリヂストン | トレッド用ゴム組成物及びそれを用いた乗用車用タイヤ |
| FR2866028B1 (fr) | 2004-02-11 | 2006-03-24 | Michelin Soc Tech | Systeme plastifiant pour composition de caoutchouc |
| US20050203251A1 (en) | 2004-03-11 | 2005-09-15 | Sumitomo Chemical Company, Limited | Process for producing modified diene polymer rubber |
| FR2877348B1 (fr) | 2004-10-28 | 2007-01-12 | Michelin Soc Tech | Systeme plastifiant pour composition de caoutchouc |
| FR2880349B1 (fr) | 2004-12-31 | 2009-03-06 | Michelin Soc Tech | Nanoparticules de polyvinylaromatique fonctionnalise |
| FR2880354B1 (fr) | 2004-12-31 | 2007-03-02 | Michelin Soc Tech | Composition elastomerique renforcee d'une charge de polyvinylaromatique fonctionnalise |
| WO2006076629A1 (en) | 2005-01-14 | 2006-07-20 | Bridgestone Corporation | Functionalized polymers and improved tires therefrom |
| FR2886304B1 (fr) | 2005-05-26 | 2007-08-10 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un systeme de couplage organosilicique |
| FR2886305B1 (fr) | 2005-05-26 | 2007-08-10 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de couplage organosilicique et un agent de recouvrement de charge inorganique |
| FR2886306B1 (fr) | 2005-05-26 | 2007-07-06 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de couplage organosiloxane |
| FR2889538B1 (fr) | 2005-08-08 | 2007-09-14 | Michelin Soc Tech | Systeme plastifiant pour compsition de caoutchouc. |
| US7789117B2 (en) * | 2006-01-27 | 2010-09-07 | The Goodyear Tire & Rubber Company | Tire with circumferential rubber tread having a lateral outboard control element |
| FR2903416B1 (fr) | 2006-07-06 | 2008-09-05 | Michelin Soc Tech | Composition elastomerique renforcee d'une charge de polymere vinylique non aromatique fonctionnalise |
| FR2903411B1 (fr) | 2006-07-06 | 2012-11-02 | Soc Tech Michelin | Nanoparticules de polymere vinylique fonctionnalise |
| JP5446859B2 (ja) * | 2007-03-15 | 2014-03-19 | Jsr株式会社 | 共役ジオレフィン共重合ゴム、その製造方法、ゴム組成物およびタイヤ |
| US8058357B2 (en) * | 2007-12-31 | 2011-11-15 | Bridgestone Corporation | Vulcanizable compositions and tire treads prepared therewith |
-
2008
- 2008-04-29 FR FR0852868A patent/FR2930554B1/fr not_active Expired - Fee Related
-
2009
- 2009-04-27 BR BRPI0911836A patent/BRPI0911836B1/pt active IP Right Grant
- 2009-04-27 EA EA201071242A patent/EA020173B1/ru not_active IP Right Cessation
- 2009-04-27 HU HUE09738112A patent/HUE028614T2/en unknown
- 2009-04-27 EP EP09738112.3A patent/EP2285852B1/fr active Active
- 2009-04-27 CN CN200980115392.3A patent/CN102015799B/zh active Active
- 2009-04-27 US US12/990,212 patent/US9175124B2/en active Active
- 2009-04-27 WO PCT/EP2009/055061 patent/WO2009133068A1/fr not_active Ceased
- 2009-04-27 KR KR1020107026646A patent/KR101615875B1/ko active Active
- 2009-04-27 JP JP2011506675A patent/JP5705721B2/ja active Active
-
2014
- 2014-12-10 JP JP2014249898A patent/JP5921657B2/ja not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001131340A (ja) | 1999-11-08 | 2001-05-15 | Bridgestone Corp | ゴム組成物及びそれを用いた空気入りタイヤ |
| JP2001158834A (ja) * | 1999-12-02 | 2001-06-12 | Bridgestone Corp | ゴム組成物及びそれを用いた空気入りタイヤ |
| JP2005232367A (ja) | 2004-02-20 | 2005-09-02 | Bridgestone Corp | 変性共役ジエン系重合体、並びにそれを用いたゴム組成物及びタイヤ |
| JP2008038119A (ja) * | 2006-08-10 | 2008-02-21 | Bridgestone Corp | 重荷重用空気入りタイヤ |
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| US20110178233A1 (en) | 2011-07-21 |
| JP5705721B2 (ja) | 2015-04-22 |
| FR2930554A1 (fr) | 2009-10-30 |
| US9175124B2 (en) | 2015-11-03 |
| EA020173B1 (ru) | 2014-09-30 |
| JP5921657B2 (ja) | 2016-05-24 |
| JP2011518934A (ja) | 2011-06-30 |
| CN102015799B (zh) | 2014-11-19 |
| KR20110021821A (ko) | 2011-03-04 |
| FR2930554B1 (fr) | 2012-08-17 |
| EP2285852A1 (fr) | 2011-02-23 |
| HUE028614T2 (en) | 2016-12-28 |
| WO2009133068A1 (fr) | 2009-11-05 |
| BRPI0911836A2 (pt) | 2015-10-06 |
| JP2015057499A (ja) | 2015-03-26 |
| EP2285852B1 (fr) | 2015-11-04 |
| EA201071242A1 (ru) | 2011-06-30 |
| BRPI0911836B1 (pt) | 2019-12-24 |
| CN102015799A (zh) | 2011-04-13 |
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