KR101248262B1 - 글리세롤을 아크롤레인으로 탈수시키는 방법 - Google Patents

글리세롤을 아크롤레인으로 탈수시키는 방법 Download PDF

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Publication number
KR101248262B1
KR101248262B1 KR1020077018650A KR20077018650A KR101248262B1 KR 101248262 B1 KR101248262 B1 KR 101248262B1 KR 1020077018650 A KR1020077018650 A KR 1020077018650A KR 20077018650 A KR20077018650 A KR 20077018650A KR 101248262 B1 KR101248262 B1 KR 101248262B1
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Prior art keywords
glycerol
catalyst
acrolein
reaction
zirconia
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Korean (ko)
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KR20070104412A (ko
Inventor
쟝-뤽 뒤부아
크리스토프 뒤켄
볼프강 횔데리흐
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아르끄마 프랑스
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C47/22—Acryaldehyde; Methacryaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C07C45/66—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups by dehydration

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020077018650A 2005-02-15 2006-01-06 글리세롤을 아크롤레인으로 탈수시키는 방법 Expired - Fee Related KR101248262B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
FR0501499 2005-02-15
FR0501499A FR2882052B1 (fr) 2005-02-15 2005-02-15 Procede de deshydratation du glycerol en acroleine
US68939505P 2005-06-10 2005-06-10
US60/689,395 2005-06-10
PCT/EP2006/000735 WO2006087083A2 (en) 2005-02-15 2006-01-06 Process for dehydrating glycerol to acrolein

Publications (2)

Publication Number Publication Date
KR20070104412A KR20070104412A (ko) 2007-10-25
KR101248262B1 true KR101248262B1 (ko) 2013-03-27

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KR1020077018650A Expired - Fee Related KR101248262B1 (ko) 2005-02-15 2006-01-06 글리세롤을 아크롤레인으로 탈수시키는 방법

Country Status (11)

Country Link
US (1) US7396962B1 (enExample)
EP (2) EP1853541B1 (enExample)
JP (2) JP2008530150A (enExample)
KR (1) KR101248262B1 (enExample)
CN (1) CN101119955B (enExample)
BR (1) BRPI0607727B1 (enExample)
ES (1) ES2393273T3 (enExample)
FR (1) FR2882052B1 (enExample)
PL (1) PL1853541T3 (enExample)
PT (1) PT1853541E (enExample)
WO (1) WO2006087083A2 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10435347B2 (en) 2015-12-23 2019-10-08 Lg Chem, Ltd. Method for preparing acrylic acid from glycerin
US10569259B2 (en) 2015-12-22 2020-02-25 Lg Chem, Ltd. Catalyst for dehydration of glycerin, preparation method thereof, and production method of acrolein using the catalyst

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JP5162123B2 (ja) * 2006-12-01 2013-03-13 株式会社日本触媒 グリセリン脱水によるアクロレインの製造方法
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WO2007132926A1 (en) * 2006-05-12 2007-11-22 Nippon Shokubai Co., Ltd. Production method of acrolein
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JP4224097B2 (ja) * 2006-12-01 2009-02-12 株式会社日本触媒 アクロレインの製造方法
JP5162128B2 (ja) * 2006-12-27 2013-03-13 株式会社日本触媒 グリセリンからのアクロレインの製造方法
JP5305614B2 (ja) * 2007-05-31 2013-10-02 株式会社日本触媒 アクロレインの製造方法
JP5139670B2 (ja) * 2006-12-01 2013-02-06 株式会社日本触媒 グリセリンからのアクロレインの製法
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FR2932804B1 (fr) * 2008-06-19 2010-07-30 Arkema France Polymere d'acroleine derive de matiere premiere renouvelable, son procede d'obtention et ses utilisations
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RU2522761C2 (ru) 2008-11-05 2014-07-20 Басф Се Способ получения n, n-замещенных 3-аминопропан-1-олов
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KR101629003B1 (ko) 2013-11-18 2016-06-09 주식회사 엘지화학 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법
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CN104892382B (zh) * 2015-05-28 2017-08-11 珠海凯美科技有限公司 甘油液相氧化制备丙烯醛的方法
CN106008188B (zh) * 2016-05-30 2018-05-29 浙江工业大学 一种甘油催化脱水制备丙烯醛的新方法
CN107812535A (zh) * 2016-09-12 2018-03-20 中国科学院青岛生物能源与过程研究所 一种适用于甘油脱水制丙烯醛反应中的抗结焦固体酸催化剂及其制备和应用
CN107141206B (zh) * 2017-06-29 2020-06-02 太原工业学院 一种甘油催化转化制备丙烯醛的方法
CN109304190B (zh) * 2017-07-28 2021-06-18 中国石油化工股份有限公司 甘油制丙烯醛用催化剂
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JP2008530150A (ja) 2008-08-07
JP2015017142A (ja) 2015-01-29
BRPI0607727B1 (pt) 2015-08-04
US7396962B1 (en) 2008-07-08
FR2882052A1 (fr) 2006-08-18
WO2006087083A3 (en) 2006-12-28
FR2882052B1 (fr) 2007-03-23
US20080146852A1 (en) 2008-06-19
PL1853541T3 (pl) 2013-03-29
CN101119955A (zh) 2008-02-06
EP2377842A1 (en) 2011-10-19
EP1853541A2 (en) 2007-11-14
JP6021878B2 (ja) 2016-11-09
CN101119955B (zh) 2011-06-22
BRPI0607727A2 (pt) 2009-10-06
WO2006087083A2 (en) 2006-08-24
ES2393273T3 (es) 2012-12-19

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