BRPI0607727A2 - processo para fabricar acroleìna - Google Patents

processo para fabricar acroleìna

Info

Publication number
BRPI0607727A2
BRPI0607727A2 BRPI0607727-7A BRPI0607727A BRPI0607727A2 BR PI0607727 A2 BRPI0607727 A2 BR PI0607727A2 BR PI0607727 A BRPI0607727 A BR PI0607727A BR PI0607727 A2 BRPI0607727 A2 BR PI0607727A2
Authority
BR
Brazil
Prior art keywords
acrolein
manufacturing
manufacturing acrolein
hammet
acidity
Prior art date
Application number
BRPI0607727-7A
Other languages
English (en)
Inventor
Christophe Duquenne
Wofgang Hoelderich
Jean-Luc Dubois
Original Assignee
Arkema France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France filed Critical Arkema France
Publication of BRPI0607727A2 publication Critical patent/BRPI0607727A2/pt
Publication of BRPI0607727B1 publication Critical patent/BRPI0607727B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C47/22—Acryaldehyde; Methacryaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C07C45/66—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups by dehydration

Abstract

PROCESSO PARA FABRICAR ACROLEINA. A presente invenção se refere a um processo para fabricar acroleina pela desidratação em fase gasosa de glicerol na presença de catalisadores sólidos fortemente ácidos com uma acidez de Hammet H0 de entre -9 e -18 e preferivelmente entre -10 e -16.
BRPI0607727-7A 2005-02-15 2006-01-06 Processo para fabricar acroleína BRPI0607727B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
FR0501499 2005-02-15
FR0501499A FR2882052B1 (fr) 2005-02-15 2005-02-15 Procede de deshydratation du glycerol en acroleine
US68939505P 2005-06-10 2005-06-10
US60/689.395 2005-06-10
PCT/EP2006/000735 WO2006087083A2 (en) 2005-02-15 2006-01-06 Process for dehydrating glycerol to acrolein

Publications (2)

Publication Number Publication Date
BRPI0607727A2 true BRPI0607727A2 (pt) 2009-10-06
BRPI0607727B1 BRPI0607727B1 (pt) 2015-08-04

Family

ID=35170070

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0607727-7A BRPI0607727B1 (pt) 2005-02-15 2006-01-06 Processo para fabricar acroleína

Country Status (11)

Country Link
US (1) US7396962B1 (pt)
EP (2) EP1853541B1 (pt)
JP (2) JP2008530150A (pt)
KR (1) KR101248262B1 (pt)
CN (1) CN101119955B (pt)
BR (1) BRPI0607727B1 (pt)
ES (1) ES2393273T3 (pt)
FR (1) FR2882052B1 (pt)
PL (1) PL1853541T3 (pt)
PT (1) PT1853541E (pt)
WO (1) WO2006087083A2 (pt)

Families Citing this family (114)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5006507B2 (ja) * 2004-01-30 2012-08-22 株式会社日本触媒 アクリル酸の製造方法
FR2882053B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
TWI438187B (zh) * 2005-02-28 2014-05-21 Evonik Degussa Gmbh 丙烯酸和基於可再生原料之吸水聚合物結構及二者之製備方法
WO2007058221A1 (ja) * 2005-11-15 2007-05-24 Nippon Shokubai Co., Ltd. 多価アルコールの脱水方法
JP2008088149A (ja) * 2006-01-04 2008-04-17 Nippon Shokubai Co Ltd アクロレイン製造用触媒及びそれを用いたアクロレイン製造方法
JP4041512B2 (ja) * 2006-03-30 2008-01-30 株式会社日本触媒 グリセリン脱水用触媒、グリセリン脱水用触媒の製造方法、アクロレインの製造方法、およびアクロレイン誘導体の製造方法
WO2007119528A1 (ja) * 2006-03-30 2007-10-25 Nippon Shokubai Co., Ltd. アクロレインの製造方法
JP5162123B2 (ja) * 2006-12-01 2013-03-13 株式会社日本触媒 グリセリン脱水によるアクロレインの製造方法
JP4791247B2 (ja) * 2006-05-12 2011-10-12 株式会社日本触媒 グリセリン脱水用触媒、およびアクロレインの製造方法
JP4791246B2 (ja) * 2006-05-12 2011-10-12 株式会社日本触媒 グリセリン脱水用触媒、およびアクロレインの製造方法
EP2018360A4 (en) * 2006-05-12 2011-06-15 Nippon Catalytic Chem Ind PROCESS FOR PRODUCING ACROLEIN
DE102006039205A1 (de) * 2006-08-22 2008-03-20 Stockhausen Gmbh Auf nachwachsenden Rohstoffen basierende Acrylsäure und wasserabsorbierende Polymergebilde sowie Verfahren zu deren Herstellung mittels Dehydratisierung
JP2008110298A (ja) * 2006-10-30 2008-05-15 Nippon Shokubai Co Ltd グリセリン脱水用触媒の再生方法
WO2008052993A2 (en) * 2006-11-01 2008-05-08 Bioecon International Holding N.V. Process for production of acrolein and other oxygenated compounds from glycerol in a transported bed reactor
JP2008115103A (ja) 2006-11-02 2008-05-22 Nippon Shokubai Co Ltd アクリル酸の製造方法、アクリル酸製造用装置、およびアクリル酸製造用組成物
DE102006054519A1 (de) * 2006-11-20 2008-05-21 Evonik Degussa Gmbh Verfahren zur Herstellung von Fettsäurealkylestern und Acrolein aus Triglyceriden
JP4224097B2 (ja) * 2006-12-01 2009-02-12 株式会社日本触媒 アクロレインの製造方法
JP2008195643A (ja) * 2007-02-13 2008-08-28 Nippon Shokubai Co Ltd グリセリンからのアクロレインの製造方法
JP5305614B2 (ja) * 2007-05-31 2013-10-02 株式会社日本触媒 アクロレインの製造方法
JP5162128B2 (ja) * 2006-12-27 2013-03-13 株式会社日本触媒 グリセリンからのアクロレインの製造方法
JP5139670B2 (ja) * 2006-12-01 2013-02-06 株式会社日本触媒 グリセリンからのアクロレインの製法
EP2103590A4 (en) * 2006-12-01 2013-10-16 Nippon Catalytic Chem Ind METHOD FOR PRODUCING AN ACROLEINE AND GLYCERINE-CONTAINING COMPOSITION
FR2909999B1 (fr) * 2006-12-19 2009-04-03 Arkema France Procede de preparation d'acide acrylique a partir de glycerol
DE102007004350A1 (de) * 2007-01-29 2008-07-31 Evonik Degussa Gmbh Verfahren zur Regenerierung eines Katalysators
DE102007004351A1 (de) * 2007-01-29 2008-07-31 Evonik Degussa Gmbh Neue Katalysatoren und Verfahren zur Dehydratisierung von Glycerin
DE102007006647A1 (de) * 2007-02-06 2008-08-07 Basf Se Verfahren zur Regenerierung eines im Rahmen einer heterogen katalysierten partiellen Dehydrierung eines Kohlenwasserstoffs deaktivierten Katalysatorbetts
FR2912742B1 (fr) * 2007-02-16 2010-03-05 Arkema France Procede de synthese d'acrylonitrile a partir de glycerol
FR2913974A1 (fr) * 2007-03-19 2008-09-26 Arkema France Procede de vaporisation de glycerol
EP2162416B8 (en) 2007-05-18 2018-12-19 BioFuel-Solution i Malmö AB Gas phase process for monoalcohol production from glycerol
US7872159B2 (en) 2007-08-24 2011-01-18 Battelle Memorial Institute Chemical production processes, systems, and catalyst compositions
US7872158B2 (en) * 2007-08-24 2011-01-18 Battelle Memorial Institute Chemical production processes, systems, and catalyst compositions
US20090054694A1 (en) * 2007-08-24 2009-02-26 Peterson Thomas H Chemical production processes, systems, and catalyst compositions
FR2920767B1 (fr) * 2007-09-06 2009-12-18 Arkema France Procede de vaporisation reactive de glycerol
US8070836B2 (en) 2007-10-16 2011-12-06 Wayne State University Combined homogeneous and heterogeneous catalytic transesterification process for biodiesel production
FR2925490B1 (fr) * 2007-12-20 2009-12-25 Arkema France Procede de synthese d'acroleine a partir de glycerol
WO2009127889A1 (en) * 2008-04-16 2009-10-22 Arkema France Process for manufacturing acrolein from glycerol
BRPI0910458A2 (pt) 2008-04-16 2018-03-27 Arkema France catalisador para preparar acroleína ou ácido acrílico por reação de desidratação de glicerina e método para produzir o mesmo
CN102026956B (zh) 2008-05-13 2014-05-28 巴斯夫欧洲公司 生产n，n-取代的1，3-丙二胺的方法
US8975426B2 (en) 2008-05-19 2015-03-10 Wayne State University ZnO nanoparticle catalysts for use in transesterification and esterification reactions and method of making
WO2009143159A1 (en) 2008-05-19 2009-11-26 Wayne State University Methods and catalysts for making biodiesel from the transesterification and esterification of unrefined oils
US8895764B2 (en) 2008-05-19 2014-11-25 Wayne State University ZnO nanoparticle catalysts for use in biodiesel production and method of making
JP2008280349A (ja) * 2008-06-02 2008-11-20 Nippon Shokubai Co Ltd アクリル酸の製造方法、アクリル酸製造用装置、およびアクリル酸製造用組成物
FR2931820B1 (fr) * 2008-06-03 2010-05-14 Arkema France Procede de fabrication d'acroleine par deshydratation du glycerol
FR2932804B1 (fr) * 2008-06-19 2010-07-30 Arkema France Polymere d'acroleine derive de matiere premiere renouvelable, son procede d'obtention et ses utilisations
FR2934264B1 (fr) 2008-07-22 2012-07-20 Arkema France Fabrication d'esters de vinyle a partir de matieres renouvelables, esters de vinyle obtenus et utilisations
FR2934261B1 (fr) * 2008-07-25 2015-04-10 Arkema France Procede de synthese d'esters de l'acide acrylique
DE102008038273A1 (de) 2008-08-18 2010-03-04 Evonik Stockhausen Gmbh Ein Verfahren zur Herstellung von Acrylsäure und daraus herstellbaren Verbindungen basierend auf Glycerin mit Wechselkatalysator
FR2935148B1 (fr) * 2008-08-25 2010-08-27 Arkema France Procede de fabrication de fibres de carbone.
JP5305827B2 (ja) * 2008-10-17 2013-10-02 株式会社日本触媒 アクロレイン及びアクリル酸の製造方法
EP2179981A1 (en) * 2008-10-24 2010-04-28 Arkema France Process for manufacturing acrolein from glycerol
JP2010099596A (ja) 2008-10-24 2010-05-06 Arkema France グリセリンの脱水反応によるアクロレイン及びアクリル酸の製造用触媒と、その製造法
US20110224470A1 (en) * 2008-11-05 2011-09-15 Biofuel-Solution Ab Process for preparing lower hydrocarbons from glycerol
ES2590457T3 (es) 2008-11-05 2016-11-22 Basf Se Procedimiento para la producción de 3-aminopropano-1-oles N,N-sustituidos
FR2938535B1 (fr) * 2008-11-20 2012-08-17 Arkema France Procede de fabrication de methylmercaptopropionaldehyde et de methionine a partir de matieres renouvelables
DE102008060888A1 (de) * 2008-12-09 2010-06-10 Evonik Stockhausen Gmbh Verfahren zur Herstellung von Acrolein umfassend die Aufarbeitung einer Rohglycerin-Phase
FR2939791B1 (fr) * 2008-12-16 2011-01-14 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
US8198477B2 (en) * 2008-12-24 2012-06-12 Rohm And Haas Company Process for production of acrolein from glycerol
US8404887B2 (en) 2008-12-26 2013-03-26 Nippon Shokubai Co., Ltd. Process for producing acrylic acid
DE102009006777A1 (de) 2009-01-30 2010-08-05 Wolfgang F. Prof. Dr. Hölderich Verfahren zur Herstellung von Fettsäureestern und Glycerin durch Umesterung von pflanzlichen und tierischen Fetten und Ölen
MY152961A (en) 2009-05-15 2014-12-15 Nippon Catalytic Chem Ind Process for producing (meth)acrylic acid
JP5580812B2 (ja) 2009-05-15 2014-08-27 株式会社日本触媒 （メタ）アクリル酸の製造方法
US8592627B2 (en) 2009-05-15 2013-11-26 Nippon Shokubai Co., Ltd. Process for producing (meth)acrylic acid and crystallization system
FR2946052B1 (fr) 2009-05-28 2011-05-27 Arkema France Polymere adhesif sensible a la pression contenant du methacrylate de tetrahydrofurfuryle.
DE102009027420A1 (de) 2009-07-02 2011-01-05 Evonik Degussa Gmbh Verfahren zur Herstellung von Acrolein
FR2948366B1 (fr) * 2009-07-22 2012-08-17 Arkema France Procede de fabrication d'acide acrylique bio-ressource a partir de glycerol
FR2948365B1 (fr) 2009-07-22 2011-09-09 Arkema France Procede de fabrication d'acide acrylique bio-ressource a partir de glycerol
CN102731275B (zh) * 2009-09-18 2015-06-10 阿克马法国公司 用于通过甘油脱水反应制备丙烯醛和/或丙烯酸的催化剂和方法
CN102655931A (zh) 2009-09-18 2012-09-05 日本化药株式会社 用于通过甘油脱水反应制备丙烯醛和/或丙烯酸的催化剂和方法
JP5684818B2 (ja) * 2009-10-15 2015-03-18 日本化薬株式会社 グリセリンの脱水反応によって不飽和アルデヒドおよび／または不飽和カルボン酸を製造するのに使用する触媒の製造方法と、この方法で得られる触媒
FR2952057B1 (fr) 2009-11-04 2011-11-18 Arkema France Procede de synthese de pyridine et picolines bioressourcees
FR2952056B1 (fr) 2009-11-04 2013-01-25 Arkema France Glutaraldehyde bioressource et ses procedes de fabrication
FR2953829B1 (fr) 2009-12-14 2011-12-09 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
FR2953830B1 (fr) 2009-12-14 2012-01-20 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
CN102781577A (zh) * 2009-12-18 2012-11-14 巴特勒纪念研究院 多羟基化合物脱水系统、催化剂组合物、和方法
FR2954312B1 (fr) * 2009-12-21 2012-02-10 Adisseo France Sas Procede de preparation d'acroleine par deshydratation catalytique de glycerol ou glycerine
FR2954311B1 (fr) * 2009-12-22 2012-02-03 Arkema France Procede de synthese perfectionne d'acroleine a partir de glycerol
KR101148995B1 (ko) 2010-03-09 2012-05-22 아주대학교산학협력단 글리세롤의 기상 탈수화 반응을 통한 아크롤레인 및 이의 제조방법
FR2957594B1 (fr) * 2010-03-18 2013-04-26 Arkema France Procede de fabrication d'acide acrylique bio-ressource de grade polymere a partir de glycerol
FR2961507B1 (fr) 2010-06-17 2016-03-04 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine
JP5846388B2 (ja) 2010-07-09 2016-01-20 国立大学法人北海道大学 新規なグリセリン脱水用触媒とその製造方法
WO2012010923A1 (en) 2010-07-19 2012-01-26 Arkema France Process for manufacturing acrolein from glycerol
FR2966456B1 (fr) * 2010-10-26 2013-03-15 Adisseo France Sas Procede d'obtention d'acroleine par deshydratation catalytique de glycerol ou de glycerine
EP2468709A1 (en) 2010-11-30 2012-06-27 BioFuel-Solution AB A process for producing acrolein
JP5881620B2 (ja) 2011-01-28 2016-03-09 日本化薬株式会社 飽和アルデヒドを選択的に低減させる触媒と、その製造方法
WO2012101471A1 (en) 2011-01-28 2012-08-02 Arkema France Improved process for manufacturing acrolein/acrylic acid
KR101322678B1 (ko) * 2011-04-14 2013-10-30 서울대학교산학협력단 글리세롤의 탈수반응을 통한 아크롤레인 생산 반응용 촉매 및 그 제조방법
FR2975922B1 (fr) 2011-06-06 2013-05-31 Arkema France Reacteur a plaques avec injection in situ
FR2977809B1 (fr) 2011-07-12 2016-01-08 Arkema France Regeneration de catalyseur en continu dans un reacteur a lit fluidise
WO2013008279A1 (en) 2011-07-14 2013-01-17 Nippon Kayaku Kabushiki Kaisha Process for preparing catalyst used in production of acrolein and/or acrylic acid and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
WO2013017904A1 (en) 2011-07-29 2013-02-07 Arkema France Improved process of dehydration reactions
FR2989684B1 (fr) 2012-04-18 2014-10-31 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
FR2991596B1 (fr) * 2012-06-08 2015-08-07 Arkema France Reaction catalytique avec regeneration en flux inverse
JP2013040179A (ja) * 2012-09-14 2013-02-28 Nippon Kayaku Co Ltd グリセリンの脱水反応によってアクロレインおよび／またはアクリル酸を製造するための触媒および方法
US9120718B1 (en) 2013-06-27 2015-09-01 Lg Chem, Ltd. Method for preparing allyl alcohol
KR101679717B1 (ko) 2013-06-27 2016-11-25 주식회사 엘지화학 알릴 알코올의 제조방법 및 이에 의하여 제조된 알릴 알코올
US9546124B2 (en) 2013-06-27 2017-01-17 Lg Chem, Ltd. Method for producing acrylic acid from glycerol
KR101616528B1 (ko) * 2013-07-16 2016-04-28 주식회사 엘지화학 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법
KR101629003B1 (ko) * 2013-11-18 2016-06-09 주식회사 엘지화학 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법
FR3017617B1 (fr) 2014-02-19 2016-02-12 Arkema France Procede de production d'acide acrylique bio-source
FR3019545B1 (fr) 2014-04-04 2016-03-11 Arkema France Procede de synthese directe de (meth)acroleine a partir d'ethers et/ou acetals
WO2015168683A1 (en) * 2014-05-02 2015-11-05 University Of Tennessee Research Foundation Novel glycerol dehydration methods and products thereof
WO2016026763A1 (en) * 2014-08-18 2016-02-25 Basf Se Process for preparing acrylic acid using a heterogeneous alumina catalyst
CN105435848B (zh) * 2015-02-15 2017-10-10 浙江永太科技股份有限公司 一种沸石催化剂
CN104892382B (zh) * 2015-05-28 2017-08-11 珠海凯美科技有限公司 甘油液相氧化制备丙烯醛的方法
KR102052708B1 (ko) 2015-12-22 2019-12-09 주식회사 엘지화학 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법
KR102044428B1 (ko) * 2015-12-23 2019-12-02 주식회사 엘지화학 글리세린으로부터 아크릴산의 제조방법
CN106008188B (zh) * 2016-05-30 2018-05-29 浙江工业大学 一种甘油催化脱水制备丙烯醛的新方法
CN107812535A (zh) * 2016-09-12 2018-03-20 中国科学院青岛生物能源与过程研究所 一种适用于甘油脱水制丙烯醛反应中的抗结焦固体酸催化剂及其制备和应用
CN107141206B (zh) * 2017-06-29 2020-06-02 太原工业学院 一种甘油催化转化制备丙烯醛的方法
CN109304190B (zh) * 2017-07-28 2021-06-18 中国石油化工股份有限公司 甘油制丙烯醛用催化剂
US10647928B2 (en) 2017-11-20 2020-05-12 Ecolab Usa Inc. In-line chemical heating for in-situ generation of active chemicals
CN107952484B (zh) * 2017-11-24 2019-12-31 江苏大学 一种以Nafion薄膜负载稀土金属催化剂的制备方法及其应用
WO2023105430A1 (en) 2021-12-08 2023-06-15 Trillium Renewable Chemicals, Inc. Integrated process for the conversion of glycerol to acrylonitrile
NL2030511B1 (en) 2022-01-12 2023-07-17 Trillium Renewable Chemicals Inc Integrated process for the conversion of glycerol to acrylonitrile

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR695931A (fr) * 1929-06-15 1930-12-23 Schering Kahlbaum Ag Procédé de fabrication d'acroléine
US2558520A (en) * 1948-01-29 1951-06-26 Us Ind Chemicals Inc Production of acrolein from glycerol
DE2436818C3 (de) 1974-07-31 1985-05-09 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Acrylsäure durch Oxidation von Propylen mit Sauerstoff enthaltenden Gasen in zwei getrennten Oxidationsstufen
DE4238493C1 (de) * 1992-11-14 1994-04-21 Degussa Verfahren zur Herstellung von Acrolein und dessen Verwendung
DE4238492C2 (de) * 1992-11-14 1995-06-14 Degussa Verfahren zur Herstellung von 1,2- und 1,3-Propandiol
JPH09100244A (ja) 1995-10-03 1997-04-15 Maruzen Petrochem Co Ltd オレフィン類の製造方法およびこれに用いる脱水反応触媒
TW476746B (en) 1997-07-23 2002-02-21 Shell Int Research Hydrogenolysis of glycerol
DE19848208A1 (de) 1998-10-20 2000-04-27 Deg Engineering Gmbh Reaktor für die katalytische Umsetzung von Reaktionsmedien, insbesondere von gasförmigen Reaktionsmedien
DE10019381B4 (de) 2000-04-19 2006-05-18 Daun, Klaus-Dieter, Dipl.-Ing. Reaktor für die katalytische Umsetzung von Reaktionsmedien, insbesondere von gasförmigen Reaktionsmedien
JP4871441B2 (ja) 2000-08-07 2012-02-08 株式会社日本触媒 反応器のスタートアップ方法
CN1394839A (zh) 2001-07-05 2003-02-05 嘉年生化产品有限公司 从甘油化学合成乳特宁的方法
DE10232482A1 (de) 2002-07-17 2004-01-29 Basf Ag Verfahren zum sicheren Betreiben einer kontinuierlichen heterogen katalysierten Gasphasen-Partialoxidation wenigstens einer organischen Verbindung
US7268254B2 (en) 2003-07-24 2007-09-11 Basf Aktiengesellschaft Preparation of (meth)acrolein and/or (meth)acrylic acid by heterogeneously catalyzed partial oxidation of C3 and/or C4 precursor compounds in a reactor having thermoplate modules
JP5006507B2 (ja) * 2004-01-30 2012-08-22 株式会社日本触媒 アクリル酸の製造方法
FR2882053B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene

Also Published As

Publication number Publication date
ES2393273T3 (es) 2012-12-19
PT1853541E (pt) 2012-11-06
WO2006087083A2 (en) 2006-08-24
FR2882052B1 (fr) 2007-03-23
EP1853541B1 (en) 2012-08-08
CN101119955B (zh) 2011-06-22
CN101119955A (zh) 2008-02-06
BRPI0607727B1 (pt) 2015-08-04
JP6021878B2 (ja) 2016-11-09
US7396962B1 (en) 2008-07-08
WO2006087083A3 (en) 2006-12-28
EP2377842A1 (en) 2011-10-19
PL1853541T3 (pl) 2013-03-29
US20080146852A1 (en) 2008-06-19
FR2882052A1 (fr) 2006-08-18
EP1853541A2 (en) 2007-11-14
KR20070104412A (ko) 2007-10-25
JP2008530150A (ja) 2008-08-07
JP2015017142A (ja) 2015-01-29
KR101248262B1 (ko) 2013-03-27

Similar Documents

Publication Publication Date Title
BRPI0607727A2 (pt) processo para fabricar acroleìna
BRPI0607726A2 (pt) processo para fabricar acroleìna
CL2008000735A1 (es) Composicion que comprende una proteina de cereal parcialmente hidrolizada; proceso para la produccion de dicha composicion; uso de dicha composicion como componente de suplementos nutricionales, bebidas deportivas, bebidas o productos alimenticios; y
CL2014001123A1 (es) Anticuerpos anti-il 36r; composicion farmaceutica que lo contiene; polinucleotido aislado que codifica el anticuerpo; metodo para la produccion del anticuerpo; kit de diagnostico que lo contiene.
BRPI0910454A2 (pt) processo para produção de uma proteína policlonal
BRPI1013974A2 (pt) processo para recuperação de óleo a partir de uma formação contendo petróleo, composição para uso na recuperação de óleo a partir de uma formação contendo petróleo e derivados sulfonado de uma ou mais olefinas internas.
BRPI0716597A2 (pt) Método para o isolamento de um produto; produto preparado pelo método; método para o isolamento de um anticorpo; método para reduzir a turvação de um eluído compreendendo em produto; e método para reduzir a turvação e impurezas de um eluído compreendendo um produto
AR053948A1 (es) Deteccion de un antigeno diana independientemente de la presencia o ausencia de un anticuerpo terapeutico correspondiente
BR112015031174A2 (pt) processo para a preparação de butadieno
PL2018184T3 (pl) Przeciwciało Anty-VEGF-B do stosowania w leczeniu lub profilaktyce cukrzycy typu II lub zespołu metabolicznego
EA201391028A1 (ru) Гиполипидемическое противодиабетическое средство
BR112013000623A2 (pt) purificação de proteína.
BR112012002954A2 (pt) metodo para diagnosticar um disturbio de tireoide, metodo para determinar a capacidade de um composto de induzir um disturbio da tireoide metodo para identificar uma substancia para tratar um disturbio da tireoide, dispositivo para diagnosticar um disturbio da tireoide e uso de pelo menos um analito
BRPI1014574A2 (pt) Compostos inéditos de imitadores de ligação revesa, método para fabricar os mesmos e uso destes
BRPI0813292A2 (pt) Método de fabricação de gel de sílica cáustico compósito e géis produzidos pelo referido método.
DK1893030T3 (da) Fremgangsmåde til fremstilling af fødevarer ved ko-ekstrudering, især pølser, og fødevarer, der opnås ved denne fremgangsmåde
WO2010087594A3 (ko) 시디９３ 또는 이의 가용성 단편의 용도
BR112014009223A2 (pt) método para o diagnóstico da doença de niemann-pick
BRPI0907063A2 (pt) Método para a fabricação de produto alimentício coberto tendo cobertura suscetível ao calor
BR112014033119A2 (pt) método e plataforma para determinar uma direção para um objeto emissor de sinal
BR112013007871A2 (pt) quantificação e caracterização de alérgenos
NO20090532L (no) Fremgangsmate for fremstilling av diener ved hydroimersiering
WO2008117027A3 (en) Altered mitochondrial activity in diseases resulting from oxidative stress
BRPI0914961A2 (pt) catalisador para oxidação de hidrocarboneto por contado em fase gasossa, método para sua preparação e método de oxidação em fase gasosa de hidrocarboneto utilizando o catalisador.
CL2008000365A1 (es) Compuestos derivados de indol-2-il piperazina-1-il- metanona; proceso para la obtencion de dichos compuestos; composicion farmaceutica que comprende a dichos compuestos; y su uso para tratar diabetes, obesidad y dislipidemia.

Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 06/01/2006, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 14A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2547 DE 29-10-2019 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.