KR101206940B1 - 마그네슘 화합물 상에 담지된 비-메탈로센 촉매 및 이의 제조방법 - Google Patents

마그네슘 화합물 상에 담지된 비-메탈로센 촉매 및 이의 제조방법 Download PDF

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KR101206940B1
KR101206940B1 KR1020107003494A KR20107003494A KR101206940B1 KR 101206940 B1 KR101206940 B1 KR 101206940B1 KR 1020107003494 A KR1020107003494 A KR 1020107003494A KR 20107003494 A KR20107003494 A KR 20107003494A KR 101206940 B1 KR101206940 B1 KR 101206940B1
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magnesium compound
metallocene
magnesium
molar ratio
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KR20100105533A (ko
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유에펭 구
시아오리 야오
추안펭 리
종린 마
펭 구오
보 리우
야밍 왕
샤오후이 첸
시아오키앙 리
지예 바이
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시노펙 양지 페트로케미컬 컴퍼니 엘티디.
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Priority claimed from CN2007101626760A external-priority patent/CN101412768B/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
KR1020107003494A 2007-10-16 2008-10-15 마그네슘 화합물 상에 담지된 비-메탈로센 촉매 및 이의 제조방법 Active KR101206940B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CN2007101626671A CN101412766B (zh) 2007-10-16 2007-10-16 一种镁化合物负载型非茂金属催化剂及其制备方法
CN2007101626760A CN101412768B (zh) 2007-10-16 2007-10-16 一种镁化合物负载型非茂金属催化剂及其制备方法
CN200710162667.1 2007-10-16
CN200710162676.0 2007-10-16
PCT/CN2008/001739 WO2009052701A1 (en) 2007-10-16 2008-10-15 Non-metallocene catalyst supported on magnesium compound and its preparation method

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KR20100105533A KR20100105533A (ko) 2010-09-29
KR101206940B1 true KR101206940B1 (ko) 2012-11-30

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EP (1) EP2202246B1 (enExample)
JP (1) JP5480148B2 (enExample)
KR (1) KR101206940B1 (enExample)
WO (1) WO2009052701A1 (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101207294B1 (ko) * 2007-10-16 2012-12-03 시노펙 양지 페트로케미컬 컴퍼니 엘티디. 담지된 비-메탈로센 촉매 및 이의 제조방법
RU2567391C2 (ru) 2009-08-21 2015-11-10 Чайна Петролеум Энд Кемикал Корпорейшн Компонент катализатора для полимеризации этилена, приготовление такового и катализатор, включающий компонент катализатора
WO2011050566A1 (zh) * 2009-10-26 2011-05-05 中国石油化工股份有限公司 负载型非茂金属催化剂、其制备方法及其应用
JP5670460B2 (ja) 2009-10-26 2015-02-18 中国石油化工股▲ふん▼有限公司 担持型非メタロセン触媒、その製造方法およびその使用
WO2011057469A1 (zh) * 2009-11-13 2011-05-19 中国石油化工股份有限公司 负载型非茂金属催化剂、其制备方法及其应用
JP5670465B2 (ja) * 2009-11-13 2015-02-18 中國石油化工股▲分▼有限公司 担持型非メタロセン触媒、その製造方法およびその使用
CN103304694B (zh) * 2012-03-06 2016-02-24 中国石油化工股份有限公司 负载型非茂金属催化剂、其制备方法及其应用
KR102064629B1 (ko) * 2012-04-27 2020-01-08 더블유.알. 그레이스 앤드 캄파니-콘. 활성제 조성물, 이들의 제조, 및 촉매에서 이들의 용도
CN104903358B (zh) * 2012-09-30 2017-11-17 株式会社普利司通 有机金属催化剂络合物及采用其的聚合方法
SG2014001325A (en) * 2013-05-21 2014-12-30 China Petroleum & Chemical A supported nonmetallocene catalyst, preparation and use thereof
JP5902210B2 (ja) 2013-06-08 2016-04-13 中国石油化工股▲ふん▼有限公司 担持型非メタロセン触媒、その製造方法およびその使用
CN109485763A (zh) * 2017-09-11 2019-03-19 中国石油化工股份有限公司 负载型非茂金属催化剂、其制备方法及其应用
CN110964140B (zh) * 2018-09-28 2023-08-04 中国石油化工股份有限公司 一种原位负载型非茂金属催化剂、其制备方法及其应用
CN110964138B (zh) * 2018-09-28 2023-08-01 中国石油化工股份有限公司 镁单载体分段原位负载型非茂金属催化剂及其制备方法
CN110964136B (zh) * 2018-09-28 2023-08-04 中国石油化工股份有限公司 复合载体负载型非茂金属催化剂、其制备方法及其应用
CN110964132B (zh) * 2018-09-28 2023-08-04 中国石油化工股份有限公司 复合载体分段原位负载型非茂金属催化剂及其制备方法
CN110964139B (zh) * 2018-09-28 2023-05-16 中国石油化工股份有限公司 镁单载体原位负载型非茂金属催化剂、其制备方法及应用
CN110964137B (zh) * 2018-09-28 2023-08-01 中国石油化工股份有限公司 镁化合物负载型非茂金属催化剂、其制备方法及其应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100359370B1 (ko) * 1995-02-07 2003-02-11 미쓰이 가가쿠 가부시키가이샤 올레핀중합체의제조방법
CN101884253A (zh) * 2007-11-27 2010-11-10 海别得公司 用于对准等离子体电弧割炬的组件的方法和装置

Family Cites Families (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US574417A (en) 1897-01-05 George w
CA1268754A (en) 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5077255A (en) 1986-09-09 1991-12-31 Exxon Chemical Patents Inc. New supported polymerization catalyst
US4871705A (en) 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
CN1053673A (zh) 1989-07-12 1991-08-07 雷晓磊 改传统击发为电击发的枪枝及其子弹
GR1000753B (el) 1989-08-07 1992-12-30 Basf Ag Αποφυλλωτικο μεσο για τη βαμβακια.
IT1237812B (it) * 1989-12-22 1993-06-17 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
CA2032543A1 (en) 1989-12-26 1991-06-27 Robert Olds Hagerty Dimethylaluminum chloride-activated olefin polymerisation catalyst composition
IT1245249B (it) 1991-03-27 1994-09-13 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
CN1060179A (zh) 1991-09-29 1992-04-08 武学诗 全膜真空电容器和局部浸渍电容器
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
BE1007148A3 (fr) 1993-05-17 1995-04-11 Solvay Support pour catalyseurs, procede pour la fabrication d'un gel precurseur d'un support pour catalyseurs, procede de preparation d'un support pour catalyseurs, catalyseur pour la polymerisation d'olefines et procede pour la polymerisation d'olefines au moyen de ce catalyseur.
IT1264680B1 (it) 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori supportati per la polimerizzazione delle olefine
DE69409813T2 (de) 1993-08-09 1999-01-07 Livien Domien Antwerpen Ven Dampfkraftmaschine
ES2122394T3 (es) 1994-06-03 1998-12-16 Pcd Polymere Ag Soporte para catalizador, catalizadores soportados de metaloceno y su empleo para la obtencion de poliolefinas.
FR2725993B1 (fr) 1994-10-21 1996-11-29 Atochem Elf Sa Composante catalytique solide contenant du zirconium et des groupements cycloalcadienyles, son procede d'obtention et procede de polymerisation des olefines en sa presence
JPH08274669A (ja) 1995-03-30 1996-10-18 Sanyo Electric Co Ltd Ｆｍ受信機およびこれに用いられる信号処理装置
CN1049439C (zh) 1996-08-26 2000-02-16 中国石油化工总公司 负载型金属茂催化剂、其制备及应用
KR100223105B1 (ko) * 1996-10-09 1999-10-15 유현식 올레핀 중합용 촉매와 이를 이용한 올레핀 중합방법
CN1060179C (zh) 1998-05-08 2001-01-03 中国石油化工集团公司 一种负载型茂金属催化剂的制备方法
FI981148A7 (fi) 1998-05-25 1999-11-26 Borealis As Uusia aktivaattorijärjestelmä metalloseeniyhdisteitä varten
KR100430979B1 (ko) * 1999-02-04 2004-05-12 삼성아토피나주식회사 올레핀 중합용 킬레이트 촉매의 제조방법
EP1194432A1 (en) * 1999-06-30 2002-04-10 Union Carbide Chemicals & Plastics Technology Corporation Magnesium-zirconium alkoxide complexes and polymerization catalysts made therefrom
CN1363537A (zh) 2001-01-08 2002-08-14 柳忠奇 复合硼镁肥及其制备工艺
CN1136239C (zh) 2001-01-18 2004-01-28 中国石油化工股份有限公司 卤化镁/二氧化硅负载的半茂金属催化剂及其制备与应用
EP1229055A1 (en) * 2001-02-06 2002-08-07 BP Chemicals S.N.C. Process for the gas-phase (co)-polymerisation of olefins in a fluidised bed reactor
EP1426385B1 (en) 2001-07-23 2012-08-22 Shanghai Institute Of Organic Chemistry, Chinese Academy Of Sciences Catalyst for polymerization or copolymerization of olefins, preparation and use of the same
CN1218970C (zh) 2002-02-09 2005-09-14 中国科学院上海有机化学研究所 新型烯烃聚合催化剂
CN1256351C (zh) 2001-07-23 2006-05-17 中国科学院上海有机化学研究所 烯烃聚合及共聚合催化剂、合成方法及其用途
CN1160380C (zh) 2001-09-03 2004-08-04 中国石油天然气股份有限公司 一种合成负载型茂金属催化剂的方法
CN1137909C (zh) 2001-10-26 2004-02-11 中国科学院长春应用化学研究所 插层型负载茂金属催化剂及其催化烯烃聚合
JP2005511801A (ja) 2001-11-30 2005-04-28 エクソンモービル・ケミカル・パテンツ・インク 高活性のバイメタル触媒
EP1461151A4 (en) 2001-11-30 2010-03-24 Univation Tech Llc PROCESS FOR MANUFACTURING ZIEGLER-NATTA / METALLOCENE MIXED CATALYSTS
CN1179982C (zh) 2002-12-13 2004-12-15 中国科学院上海有机化学研究所 烯烃聚合催化剂、合成方法及其用途
KR100491627B1 (ko) 2002-12-31 2005-05-27 삼성토탈 주식회사 카르보디이미드계열 리간드에 의해 킬레이트 결합된촉매를 이용한 에틸렌 중합 및 공중합방법
CN1281634C (zh) 2003-10-29 2006-10-25 扬子石油化工股份有限公司 复合载体负载的非茂金属催化剂的负载化方法和聚合应用
CN1269852C (zh) 2003-10-29 2006-08-16 扬子石油化工股份有限公司 负载型非茂金属催化剂的负载化方法和聚合应用
CN101372520B (zh) 2003-11-20 2010-12-08 联合碳化化学及塑料技术有限责任公司 喷雾干燥的混合金属齐格勒催化剂组合物
CN1789291A (zh) 2004-12-17 2006-06-21 扬子石油化工股份有限公司 负载型非茂金属催化剂的烯烃聚合和共聚合方法
CN100362024C (zh) 2004-12-17 2008-01-16 扬子石油化工股份有限公司 非茂金属催化剂的高活性负载化方法
EP1829897B1 (en) * 2004-12-17 2014-12-10 Yangzi Petrochemical Company Co., Ltd. Supported non-metallocene olefin polymerization catalyst, and preparation and use thereof
CN1789292A (zh) 2004-12-17 2006-06-21 扬子石油化工股份有限公司 负载型非茂金属催化剂在淤浆法乙烯聚合工艺中的应用方法
US7491781B2 (en) * 2005-03-08 2009-02-17 Ineos Usa Llc Propylene polymer catalyst donor component
CN100569808C (zh) * 2005-03-31 2009-12-16 中国石油化工股份有限公司 一种负载型非茂金属催化剂及其制备方法
CN100460423C (zh) 2005-06-30 2009-02-11 中国石油化工股份有限公司 原位合成的负载型钒系非茂聚烯烃催化剂及制备与应用
CN1962702B (zh) 2005-11-10 2010-10-27 中国石化扬子石油化工有限公司 一种负载型非茂金属烯烃聚合催化剂、其制备方法及其应用
CN100569734C (zh) 2006-05-22 2009-12-16 中国科学院上海有机化学研究所 一类含杂原子的有机化合物及其在齐格勒-纳塔催化剂中的应用
CN100482697C (zh) 2006-05-22 2009-04-29 中国科学院上海有机化学研究所 一类单活性中心齐格勒-纳塔烯烃聚合催化剂
KR101207294B1 (ko) * 2007-10-16 2012-12-03 시노펙 양지 페트로케미컬 컴퍼니 엘티디. 담지된 비-메탈로센 촉매 및 이의 제조방법

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100359370B1 (ko) * 1995-02-07 2003-02-11 미쓰이 가가쿠 가부시키가이샤 올레핀중합체의제조방법
CN101884253A (zh) * 2007-11-27 2010-11-10 海别得公司 用于对准等离子体电弧割炬的组件的方法和装置

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KR20100105533A (ko) 2010-09-29
JP2011500901A (ja) 2011-01-06
US20110237764A1 (en) 2011-09-29
US8716416B2 (en) 2014-05-06
EP2202246A4 (en) 2012-08-08
WO2009052701A1 (en) 2009-04-30
EP2202246A1 (en) 2010-06-30
EP2202246B1 (en) 2016-06-15
JP5480148B2 (ja) 2014-04-23

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