KR101136783B1 - 평형 제한 반응의 수행방법 - Google Patents

평형 제한 반응의 수행방법 Download PDF

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KR101136783B1
KR101136783B1 KR1020057016051A KR20057016051A KR101136783B1 KR 101136783 B1 KR101136783 B1 KR 101136783B1 KR 1020057016051 A KR1020057016051 A KR 1020057016051A KR 20057016051 A KR20057016051 A KR 20057016051A KR 101136783 B1 KR101136783 B1 KR 101136783B1
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product
reaction
zone
fraction
reactant
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Korean (ko)
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KR20050111337A (ko
Inventor
레아 에이. 패터슨
펑가우 엔엠엔 호
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알케마 인코포레이티드
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00Formation or introduction of functional groups containing oxygen
    • C07B41/12Formation or introduction of functional groups containing oxygen of carboxylic acid ester groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/08Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/30Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C07C67/327Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by elimination of functional groups containing oxygen only in singly bound form
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020057016051A 2003-02-28 2004-02-19 평형 제한 반응의 수행방법 Expired - Lifetime KR101136783B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US45074603P 2003-02-28 2003-02-28
US60/450,746 2003-02-28
PCT/US2004/004948 WO2004078679A2 (en) 2003-02-28 2004-02-19 Process for conducting equilibrium-limited reactions

Publications (2)

Publication Number Publication Date
KR20050111337A KR20050111337A (ko) 2005-11-24
KR101136783B1 true KR101136783B1 (ko) 2012-04-19

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KR1020057016051A Expired - Lifetime KR101136783B1 (ko) 2003-02-28 2004-02-19 평형 제한 반응의 수행방법

Country Status (9)

Country Link
US (1) US7569721B2 (enExample)
EP (1) EP1611082B1 (enExample)
JP (1) JP5059400B2 (enExample)
KR (1) KR101136783B1 (enExample)
CN (1) CN100345816C (enExample)
BR (1) BRPI0408043B1 (enExample)
DE (1) DE602004028591D1 (enExample)
MX (1) MX256948B (enExample)
WO (1) WO2004078679A2 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020106123A1 (ko) * 2018-11-23 2020-05-28 지에스칼텍스 주식회사 알킬 카르복실산 에스테르의 제조 방법 및 알킬 카르복실산 에스테르의 제조 장치

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10357222A1 (de) * 2003-12-08 2005-06-30 Basf Ag Anschlussstutzen für Messgeräte und mit einem solchen Anschlussstutzen versehene Messsonde
DE102005043719A1 (de) * 2005-09-13 2007-03-15 Röhm Gmbh Vorrichtung und Verfahren für kontinuierlich durchgeführte Gleichgewichtsreaktionen
EP2643288B1 (en) 2010-11-22 2016-04-06 Rohm and Haas Company Acrylate production process
CN105324163B (zh) 2013-06-28 2017-10-31 陶氏环球技术有限责任公司 用于制造化合物的防积垢蒸馏塔和方法
FR3014870B1 (fr) * 2013-12-13 2015-12-11 Arkema France Procede de production d'esters (meth)acryliques
US9963419B2 (en) 2014-10-31 2018-05-08 Dow Global Technologies Llc Process for in situ water removal from an oxidative esterification reaction using a coupled reactor-distillation system
WO2022270495A1 (ja) * 2021-06-21 2022-12-29 旭化成株式会社 反応システム及び反応方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09110789A (ja) * 1995-09-28 1997-04-28 Basf Ag (メタ)アクリル酸のアルキルエステルを連続的に製造するための方法及び装置
WO2000078702A1 (en) 1999-06-17 2000-12-28 Union Carbide Chemicals & Plastics Processes for conducting equilibrium-limited reactions
JP2002507194A (ja) 1997-05-20 2002-03-05 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー コーポレイション アクリル酸ブチルの精製方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3776947A (en) * 1972-10-10 1973-12-04 Nippon Catalytic Chem Ind Continuous esterification process
DE2548561C2 (de) * 1975-10-30 1983-09-29 Hoechst Ag, 6230 Frankfurt Verfahren zur kontinuierlichen Herstellung dioctylätherfreien 2-Äthyl- hexylacrylats
JPS6317844A (ja) * 1986-07-09 1988-01-25 Nippon Shokubai Kagaku Kogyo Co Ltd 不飽和カルボン酸エステルの製造方法
DE4019781A1 (de) * 1990-06-21 1992-01-02 Basf Ag Verfahren zur herstellung von monoethylenisch ungesaettigten carbonsaeureestern
US5231222A (en) * 1991-07-02 1993-07-27 Union Carbide Chemicals & Plastics Technology Corporation Esterification process
JP3346822B2 (ja) * 1993-03-31 2002-11-18 三菱化学株式会社 アクリル酸エステル又はメタクリル酸エステルの製造法
FR2721313B1 (fr) * 1994-06-17 1996-07-19 Atochem Elf Sa Procédé de fabrication d'acrylates d'alkyle par estérification directe.
DE19536191A1 (de) * 1995-09-28 1997-04-03 Basf Ag Verfahren zum Verestern von (Meth)acrylsäure mit einem Alkanol
DE19604253A1 (de) * 1996-02-06 1997-08-07 Basf Ag Verfahren zur kontinuierlichen Herstellung von Alkylestern der (Meth)acrylsäure
DE19604267A1 (de) * 1996-02-06 1997-08-07 Basf Ag Verfahren zur kontinuierlichen Herstellung von Alkylestern der (Meth)acrylsäure
WO1998052903A1 (en) * 1997-05-20 1998-11-26 Union Carbide Chemicals & Plastics Technology Corporation Processes for conducting equilibrium-limited reactions
CN1113849C (zh) * 1997-10-31 2003-07-09 国际人造丝公司 丙烯酸酯物流的脱硫方法
JP4242964B2 (ja) * 1999-03-09 2009-03-25 株式会社日本触媒 (メタ)アクリル酸および/またはそのエステルの精製方法
JP3782607B2 (ja) * 1999-04-20 2006-06-07 株式会社日本触媒 エステル化物の製造方法
US6482976B1 (en) * 1999-06-17 2002-11-19 Union Carbide Chemicals & Plastics Technology Corporation Processes for conducting equilibrium-limited reactions

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09110789A (ja) * 1995-09-28 1997-04-28 Basf Ag (メタ)アクリル酸のアルキルエステルを連続的に製造するための方法及び装置
JP2002507194A (ja) 1997-05-20 2002-03-05 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー コーポレイション アクリル酸ブチルの精製方法
WO2000078702A1 (en) 1999-06-17 2000-12-28 Union Carbide Chemicals & Plastics Processes for conducting equilibrium-limited reactions

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020106123A1 (ko) * 2018-11-23 2020-05-28 지에스칼텍스 주식회사 알킬 카르복실산 에스테르의 제조 방법 및 알킬 카르복실산 에스테르의 제조 장치
KR20200061219A (ko) * 2018-11-23 2020-06-02 지에스칼텍스 주식회사 알킬 카르복실산 에스테르의 제조 방법 및 알킬 카르복실산 에스테르의 제조 장치
KR102151747B1 (ko) 2018-11-23 2020-09-03 지에스칼텍스 주식회사 알킬 카르복실산 에스테르의 제조 방법 및 알킬 카르복실산 에스테르의 제조 장치
US11608307B2 (en) 2018-11-23 2023-03-21 Gs Caltex Corporation Method for preparing alkyl carboxylic acid ester and apparatus for preparing alkyl carboxylic acid ester

Also Published As

Publication number Publication date
KR20050111337A (ko) 2005-11-24
DE602004028591D1 (de) 2010-09-23
WO2004078679A3 (en) 2004-12-09
JP2006519257A (ja) 2006-08-24
CN1753859A (zh) 2006-03-29
JP5059400B2 (ja) 2012-10-24
US7569721B2 (en) 2009-08-04
MX256948B (es) 2008-05-07
BRPI0408043A (pt) 2006-02-14
EP1611082A2 (en) 2006-01-04
BRPI0408043B1 (pt) 2015-08-18
EP1611082B1 (en) 2010-08-11
WO2004078679A2 (en) 2004-09-16
CN100345816C (zh) 2007-10-31
US20060094895A1 (en) 2006-05-04
MXPA05009158A (es) 2005-10-20

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