KR100969263B1 - 방향족 탄화수소 화합물 제조용 촉매 - Google Patents

방향족 탄화수소 화합물 제조용 촉매 Download PDF

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KR100969263B1
KR100969263B1 KR1020087016853A KR20087016853A KR100969263B1 KR 100969263 B1 KR100969263 B1 KR 100969263B1 KR 1020087016853 A KR1020087016853 A KR 1020087016853A KR 20087016853 A KR20087016853 A KR 20087016853A KR 100969263 B1 KR100969263 B1 KR 100969263B1
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South Korea
Prior art keywords
zeolite
catalyst
group
aromatic hydrocarbon
raw material
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KR1020087016853A
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English (en)
Korean (ko)
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KR20080081032A (ko
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요시카즈 다카마츠
미츠히로 세키구치
Original Assignee
아사히 가세이 케미칼즈 가부시키가이샤
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Publication of KR20080081032A publication Critical patent/KR20080081032A/ko
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/415—Catalytic processes with metals
    • C07C5/417—Catalytic processes with metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020087016853A 2006-01-31 2007-01-22 방향족 탄화수소 화합물 제조용 촉매 KR100969263B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006022013 2006-01-31
JPJP-P-2006-00022013 2006-01-31

Publications (2)

Publication Number Publication Date
KR20080081032A KR20080081032A (ko) 2008-09-05
KR100969263B1 true KR100969263B1 (ko) 2010-07-09

Family

ID=38327324

Family Applications (1)

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KR1020087016853A KR100969263B1 (ko) 2006-01-31 2007-01-22 방향족 탄화수소 화합물 제조용 촉매

Country Status (10)

Country Link
US (1) US20100234657A1 (de)
EP (1) EP1980319A4 (de)
JP (1) JP5179882B2 (de)
KR (1) KR100969263B1 (de)
CN (1) CN101378835A (de)
BR (1) BRPI0706770A2 (de)
MY (1) MY144070A (de)
RU (1) RU2398630C2 (de)
TW (1) TWI345486B (de)
WO (1) WO2007088745A1 (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5228064B2 (ja) * 2008-01-28 2013-07-03 エクソンモービル・ケミカル・パテンツ・インク メタンからの芳香族化合物の製造
JP5564769B2 (ja) * 2008-08-12 2014-08-06 株式会社明電舎 低級炭化水素芳香族化触媒及び芳香族化合物の製造方法
WO2011143303A2 (en) * 2010-05-12 2011-11-17 Shell Oil Company Methane aromatization catalyst, method of making and method of using the catalyst
RU2446883C1 (ru) * 2010-10-21 2012-04-10 Российская Федерация, От Имени Которой Выступает Министерство Образования И Науки Российской Федерации Цеолитсодержащий катализатор, способ его получения и способ превращения прямогонной бензиновой фракции в высокооктановый компонент бензина с пониженным содержанием бензола
US10519387B2 (en) * 2014-03-31 2019-12-31 Hindustan Petroleum Corporation Ltd. Catalyst composition for converting light naphtha to aromatic compounds and a process thereof
TWI628003B (zh) * 2015-11-04 2018-07-01 艾克頌美孚化學專利股份有限公司 燃管轉化系統及方法
US9873647B2 (en) 2015-11-04 2018-01-23 Exxonmobil Chemical Patents Inc. Processes and systems for converting hydrocarbons to cyclopentadiene
JP6728351B2 (ja) * 2015-11-04 2020-07-22 エクソンモービル ケミカル パテンツ インコーポレイテッド 非環式ｃ５化合物の生成
US10011539B2 (en) 2015-11-04 2018-07-03 Exxonmobil Chemical Patents Inc. Process for conversion of acyclic C5 compounds to cyclic C5 compounds and catalyst composition for use therein
JP6640365B2 (ja) * 2015-11-04 2020-02-05 エクソンモービル ケミカル パテンツ インコーポレイテッド 炭化水素をシクロペンタジエンに転化する方法およびシステム
WO2017078895A1 (en) * 2015-11-04 2017-05-11 Exxonmobil Chemical Patents Inc. Processes and systems for converting hydrocarbons to cyclopentadiene
CN108349842A (zh) * 2015-11-04 2018-07-31 埃克森美孚化学专利公司 将烃转化为环戊二烯的方法和系统
TWI610905B (zh) * 2015-11-04 2018-01-11 艾克頌美孚化學專利股份有限公司 用於將烴類轉化為環戊二烯的方法與系統
US10611705B2 (en) * 2017-05-03 2020-04-07 Exxonmobil Chemical Patents Inc. Process for conversion of acyclic C5 compounds to cyclic C5 compounds and formulated catalyst compositions used therein
JP7396052B2 (ja) 2020-01-09 2023-12-12 東ソー株式会社 芳香族化合物製造用触媒

Citations (1)

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WO1996013331A1 (fr) * 1994-10-28 1996-05-09 Asahi Kasei Kogyo Kabushiki Kaisha Catalyseur de conversion d'hydrocarbure et procede de conversion catalytique avec ce catalyseur

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US4128504A (en) * 1973-02-05 1978-12-05 Mobil Oil Corporation Stabilized zinc-containing zeolites
US3843741A (en) * 1973-07-31 1974-10-22 Mobil Oil Corp Aromatization process and catalyst therefor
NZ205859A (en) * 1982-10-15 1986-04-11 Mobil Oil Corp Organic conversion using zeolite catalyst
US4845063A (en) * 1982-10-15 1989-07-04 Mobil Oil Corporation Zeolite catalyst of improved hydrothermal stability
US4550218A (en) * 1984-03-05 1985-10-29 Mobil Oil Corporation Hydrocarbon synthesis with zeolite catalyst of improved hydrothermal stability
JPS62285987A (ja) * 1986-06-03 1987-12-11 Res Assoc Util Of Light Oil 軽質パラフインの転化法
US4804801A (en) * 1986-09-08 1989-02-14 Mobil Oil Corporation Process for converting C2 to C8 aliphatics to aromatics over a metal-activated zeolite
GB8803112D0 (en) * 1988-02-11 1988-03-09 British Petroleum Co Plc Zeolite catalysts suitable for hydrocarbon conversion
JPH05310415A (ja) * 1991-05-17 1993-11-22 Asahi Chem Ind Co Ltd ゼオライト微粒子体の製造方法
JPH06346063A (ja) * 1993-06-04 1994-12-20 Asahi Chem Ind Co Ltd 軽質炭化水素の接触変換法
DE19623609A1 (de) * 1996-06-13 1997-12-18 Basf Ag Oxidationskatalysator und Verfahren zur Herstellung von Epoxiden aus Olefinen, Wasserstoff und Sauerstoff unter Verwendung des Oxidationskatalysators
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Also Published As

Publication number Publication date
RU2398630C2 (ru) 2010-09-10
US20100234657A1 (en) 2010-09-16
JP5179882B2 (ja) 2013-04-10
EP1980319A4 (de) 2009-04-01
MY144070A (en) 2011-08-15
BRPI0706770A2 (pt) 2011-04-05
RU2008135327A (ru) 2010-03-10
KR20080081032A (ko) 2008-09-05
WO2007088745A1 (ja) 2007-08-09
JPWO2007088745A1 (ja) 2009-06-25
EP1980319A1 (de) 2008-10-15
CN101378835A (zh) 2009-03-04
TWI345486B (en) 2011-07-21
TW200744752A (en) 2007-12-16

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