JP5564769B2 - 低級炭化水素芳香族化触媒及び芳香族化合物の製造方法 - Google Patents
低級炭化水素芳香族化触媒及び芳香族化合物の製造方法 Download PDFInfo
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- JP5564769B2 JP5564769B2 JP2008207757A JP2008207757A JP5564769B2 JP 5564769 B2 JP5564769 B2 JP 5564769B2 JP 2008207757 A JP2008207757 A JP 2008207757A JP 2008207757 A JP2008207757 A JP 2008207757A JP 5564769 B2 JP5564769 B2 JP 5564769B2
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- 239000003054 catalyst Substances 0.000 title claims description 49
- 229930195733 hydrocarbon Natural products 0.000 title claims description 34
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 34
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 26
- 150000001491 aromatic compounds Chemical class 0.000 title claims description 14
- 238000005899 aromatization reaction Methods 0.000 title claims description 13
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 36
- 239000013078 crystal Substances 0.000 claims description 21
- 239000010457 zeolite Substances 0.000 claims description 19
- 229910021536 Zeolite Inorganic materials 0.000 claims description 16
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 16
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 10
- 229910052750 molybdenum Inorganic materials 0.000 claims description 10
- 239000011733 molybdenum Substances 0.000 claims description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 54
- 238000006243 chemical reaction Methods 0.000 description 26
- 239000011148 porous material Substances 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 8
- 238000009792 diffusion process Methods 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 4
- 239000011609 ammonium molybdate Substances 0.000 description 4
- 229940010552 ammonium molybdate Drugs 0.000 description 4
- 235000018660 ammonium molybdate Nutrition 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- -1 biogas Chemical compound 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000002808 molecular sieve Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000004939 coking Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 239000012495 reaction gas Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 229930195734 saturated hydrocarbon Natural products 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- NMJORVOYSJLJGU-UHFFFAOYSA-N methane clathrate Chemical compound C.C.C.C.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O NMJORVOYSJLJGU-UHFFFAOYSA-N 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000007363 ring formation reaction Methods 0.000 description 2
- 230000036962 time dependent Effects 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000006057 reforming reaction Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
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-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B61/00—Other general methods
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/04—Benzene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
- C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
- C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- B01J35/23—
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C07C2529/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
Description
JOURNAL OF CATALYSIS,1997,pp.165,pp.150−161
ベンゼン収率(%)={(生成したベンゼン量)/(メタン改質反応に供されたメタン量)}×100 …(1)
(比較例1)
メタロシリケート担体として、市販の平均結晶径1μmのH型ZSM−5ゼオライト(SiO2/Al2O3=28)400gに、44.2gのモリブデン酸アンモニウムをイオン交換水1500mlに溶解した水溶液にて3時間室温で攪拌を行い、含浸担持した。触媒を乾燥させた後、550℃で8時間焼成することにより触媒を得た。
メタロシリケート担体として、平均結晶径の異なるゼオライトを用いた以外は、比較例1と同様に調製を行った。すなわち、メタロシリケート担体として、市販の平均結晶径70−80nmのH型ZSM−5ゼオライト(SiO2/Al2O3=28)400gに、44.2gのモリブデン酸アンモニウムをイオン交換水1500mlに溶解した水溶液にて3時間室温で攪拌を行い、含浸担持した。触媒を乾燥させた後、550℃で8時間焼成することにより触媒を得た。
メタロシリケート担体として、平均結晶径の異なるゼオライトを用いた以外は、比較例1と同様に調製を行った。すなわち、メタロシリケート担体として、市販の平均結晶径500nmのH型ZSM−5ゼオライト(SiO2/Al2O3=28)400gに、44.2gのモリブデン酸アンモニウムをイオン交換水1500mlに溶解した水溶液にて3時間室温で攪拌を行い、含浸担持した。触媒を乾燥させた後、550℃で8時間焼成することにより触媒を得た。
Claims (2)
- メタンを接触させて、芳香族化合物を生成する触媒であって、
前記触媒は、500nm以下の平均結晶径を有するZSM−5ゼオライトに、モリブデンを担持した触媒である
ことを特徴とする低級炭化水素芳香族化触媒。 - 500nm以下の平均結晶径を有するZSM−5ゼオライトに、モリブデンを担持した触媒にメタンを接触させて芳香族化合物を生成すること
を特徴とする芳香族化合物の製造方法。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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JP2008207757A JP5564769B2 (ja) | 2008-08-12 | 2008-08-12 | 低級炭化水素芳香族化触媒及び芳香族化合物の製造方法 |
PCT/JP2009/061070 WO2010018711A1 (ja) | 2008-08-12 | 2009-06-18 | 低級炭化水素芳香族化触媒及び芳香族化合物の製造方法 |
CN200980131097.7A CN102119054A (zh) | 2008-08-12 | 2009-06-18 | 低级烃芳构化催化剂及芳香族化合物的制备方法 |
US13/058,413 US20110172478A1 (en) | 2008-08-12 | 2009-06-18 | Catalyst for aromatization of lower hydrocarbon, and process for production of aromatic compound |
GB1104197.7A GB2474822B (en) | 2008-08-12 | 2009-06-18 | Molybdenum carried on ZSM-5 Zeolite for aromatisation of methane |
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JP2008207757A JP5564769B2 (ja) | 2008-08-12 | 2008-08-12 | 低級炭化水素芳香族化触媒及び芳香族化合物の製造方法 |
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JP2010042348A JP2010042348A (ja) | 2010-02-25 |
JP5564769B2 true JP5564769B2 (ja) | 2014-08-06 |
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US (1) | US20110172478A1 (ja) |
JP (1) | JP5564769B2 (ja) |
CN (1) | CN102119054A (ja) |
GB (1) | GB2474822B (ja) |
WO (1) | WO2010018711A1 (ja) |
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BR112012028770A2 (pt) * | 2010-05-12 | 2017-07-11 | Shell Int Research | catalisador de aromatização de metano, e, processos para preparar um catalisador de aromatização de metano e para produzir hidrocarbonetos aromáticos |
JP5949069B2 (ja) * | 2012-04-03 | 2016-07-06 | 株式会社明電舎 | 低級炭化水素芳香族化触媒の製造方法 |
PT3484619T (pt) | 2016-07-13 | 2020-07-20 | Shell Int Research | Composição de catalisador compreendendo zeólito de tipo con e zeólito de tipo zsm-5, preparação e processo que utiliza tal composição |
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US3926782A (en) * | 1973-02-09 | 1975-12-16 | Mobil Oil Corp | Hydrocarbon conversion |
NL190156C (nl) * | 1979-03-14 | 1993-11-16 | Shell Int Research | Werkwijze voor de bereiding van een aromatisch koolwaterstofmengsel. |
US5242675A (en) * | 1985-10-15 | 1993-09-07 | Exxon Research & Engineering Company | Zeolite L |
GB8525404D0 (en) * | 1985-10-15 | 1985-11-20 | Exxon Chemical Patents Inc | Zeolite l |
US5160500A (en) * | 1985-10-21 | 1992-11-03 | Mobil Oil Corporation | Zeolite synthesis using an alcohol or like molecules |
US5063038A (en) * | 1985-10-21 | 1991-11-05 | Mobil Oil Corp. | Zeolite synthesis using an alcohol or like molecule |
US5486498A (en) * | 1986-10-14 | 1996-01-23 | Exxon Research & Engineering Company | Zeolite L |
IN171677B (ja) * | 1987-08-31 | 1992-12-05 | Mobil Oil Corp | |
US5233112A (en) * | 1987-08-31 | 1993-08-03 | Mobil Oil Corp | Catalytic conversion over specially synthesized crystalline porous chalcogenides |
US5147838A (en) * | 1987-08-31 | 1992-09-15 | Mobil Oil Corporation | Temperature programmed synthesis or crystalline porous chalcogenides |
JPH055335A (ja) * | 1991-06-26 | 1993-01-14 | Taisei Corp | スライド式開閉屋根 |
JPH10122919A (ja) * | 1996-10-17 | 1998-05-15 | Mitsubishi Heavy Ind Ltd | 計測用回転トラバース装置 |
ES2251249T3 (es) * | 1998-11-16 | 2006-04-16 | Shell Internationale Research Maatschappij B.V. | Procedimiento de desparafinado catalitico. |
US6793911B2 (en) * | 2002-02-05 | 2004-09-21 | Abb Lummus Global Inc. | Nanocrystalline inorganic based zeolite and method for making same |
US7361797B2 (en) * | 2002-02-05 | 2008-04-22 | Abb Lummus Global Inc. | Hydrocarbon conversion using nanocrystalline zeolite Y |
EP1661859A1 (en) * | 2004-11-26 | 2006-05-31 | Total France | Zeolite compositions and preparation and use thereof |
EP1980319A4 (en) * | 2006-01-31 | 2009-04-01 | Asahi Kasei Chemicals Corp | CATALYST FOR PRODUCING AN AROMATIC HYDROCARBON CONNECTION |
US8841227B2 (en) * | 2008-01-28 | 2014-09-23 | Exxonmobil Chemical Patents Inc. | Production of aromatics from methane |
FR2931706B1 (fr) * | 2008-05-28 | 2010-12-24 | Inst Francais Du Petrole | Catalyseur a base d'un materiau cristallise comprenant du silicium a porosite hierarchisee et organisee et procede ameliore de traitement de charges hydrocarbonees |
-
2008
- 2008-08-12 JP JP2008207757A patent/JP5564769B2/ja active Active
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2009
- 2009-06-18 CN CN200980131097.7A patent/CN102119054A/zh active Pending
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- 2009-06-18 GB GB1104197.7A patent/GB2474822B/en not_active Expired - Fee Related
- 2009-06-18 WO PCT/JP2009/061070 patent/WO2010018711A1/ja active Application Filing
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GB2474822B (en) | 2013-05-01 |
CN102119054A (zh) | 2011-07-06 |
GB201104197D0 (en) | 2011-04-27 |
US20110172478A1 (en) | 2011-07-14 |
GB2474822A (en) | 2011-04-27 |
JP2010042348A (ja) | 2010-02-25 |
WO2010018711A1 (ja) | 2010-02-18 |
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