KR100733755B1 - 메탈로센 화합물, 그의 제조 방법 및 올레핀 중합을 위한촉매시스템에서의 그의 용도 - Google Patents

메탈로센 화합물, 그의 제조 방법 및 올레핀 중합을 위한촉매시스템에서의 그의 용도 Download PDF

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KR100733755B1
KR100733755B1 KR1020017010350A KR20017010350A KR100733755B1 KR 100733755 B1 KR100733755 B1 KR 100733755B1 KR 1020017010350 A KR1020017010350 A KR 1020017010350A KR 20017010350 A KR20017010350 A KR 20017010350A KR 100733755 B1 KR100733755 B1 KR 100733755B1
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methyl
zirconium dichloride
formula
delete delete
phenylcyclopentadienyl
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KR20010102158A (ko
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에웬존에이
엘더마이클제이
존스로버트엘
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바셀 테크놀로지 캄파니 비이브이
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/78—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems condensed with rings other than six-membered or with ring systems containing such rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/06—Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
KR1020017010350A 1999-12-15 2000-12-07 메탈로센 화합물, 그의 제조 방법 및 올레핀 중합을 위한촉매시스템에서의 그의 용도 Expired - Fee Related KR100733755B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/461,858 US6444833B1 (en) 1999-12-15 1999-12-15 Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
US09/461,858 1999-12-15

Publications (2)

Publication Number Publication Date
KR20010102158A KR20010102158A (ko) 2001-11-15
KR100733755B1 true KR100733755B1 (ko) 2007-06-29

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KR1020017010350A Expired - Fee Related KR100733755B1 (ko) 1999-12-15 2000-12-07 메탈로센 화합물, 그의 제조 방법 및 올레핀 중합을 위한촉매시스템에서의 그의 용도

Country Status (15)

Country Link
US (2) US6444833B1 (https=)
EP (1) EP1153047B1 (https=)
JP (1) JP4838475B2 (https=)
KR (1) KR100733755B1 (https=)
CN (1) CN1161388C (https=)
AR (1) AR027903A1 (https=)
AT (1) ATE434631T1 (https=)
AU (1) AU778205B2 (https=)
BR (1) BR0010043A (https=)
CA (1) CA2362093A1 (https=)
DE (1) DE60042447D1 (https=)
PL (1) PL349318A1 (https=)
RU (1) RU2245341C2 (https=)
WO (1) WO2001044318A1 (https=)
ZA (1) ZA200106367B (https=)

Families Citing this family (104)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL188107B1 (pl) * 1996-11-15 2004-12-31 Montell Technology Company Bv Metalocen, układ katalityczny do polimeryzacji, kationowe metaloceny, ligand oraz sposób polimeryzacji
BR0014616A (pt) * 1999-09-22 2002-06-18 Basell Technology Co Bv Sistema catalìtico e processo para a polimerização de olefinas
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
JP4358470B2 (ja) * 1999-12-28 2009-11-04 バセル テクノロジー カンパニー ビー．ブイ． メタロセン化合物、リガンド、触媒、ポリマーの製造方法及びプロピレンホモポリマー
WO2002100908A1 (en) * 2001-06-12 2002-12-19 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
JP4332029B2 (ja) * 2001-06-12 2009-09-16 バーゼル・ポリオレフィン・ゲーエムベーハー １−ブテンの重合方法
DE60208683T2 (de) * 2001-08-01 2006-11-02 Basell Polyolefine Gmbh Verfahren zur herstellung von heterocyclischen pentalen derivaten
DE10145453A1 (de) 2001-09-14 2003-06-05 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus
ATE412016T1 (de) * 2001-09-14 2008-11-15 Basell Polyolefine Gmbh Verfahren zur polymerisation von olefinen
US7141637B2 (en) 2001-11-30 2006-11-28 Basell Polyolefine Gmbh Metallocene compounds and process for the preparation of propylene polymers
JP4062929B2 (ja) * 2002-02-08 2008-03-19 住友化学株式会社 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
AU2003242663A1 (en) * 2002-06-26 2004-01-19 Basell Poliolefine Italia S.P.A. Impact-resistant polyolefin compositions
RU2308470C2 (ru) * 2002-06-26 2007-10-20 Базелль Полиолефин Италия С.П.А. Ударопрочные полиолефиновые композиции
DE60329691D1 (de) * 2002-09-06 2009-11-26 Basell Polyolefine Gmbh Verfahren zur copolymerisation von ethylen
US7807769B2 (en) 2002-09-20 2010-10-05 Exxonmobil Chemical Patents Inc. Isotactic polypropylene produced from supercritical polymerization process
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
AU2003291627A1 (en) * 2002-09-20 2004-04-08 Exxonmobil Chemical Patents Inc. Supercritical polymerization process and polymers produced therefrom
US7569647B2 (en) * 2002-10-10 2009-08-04 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
DE10250062A1 (de) * 2002-10-25 2004-05-06 Basell Polyolefine Gmbh Verfahren zur racemoselektiven Darstellung von verbrückten Metallocenkomplexen mit unsubstituierten oder 2-substituierten Indenylliganden
US7589160B2 (en) * 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
DE60329523D1 (de) * 2002-12-04 2009-11-12 Basell Polyolefine Gmbh 1-Buten-Copolymere und Herstellungsverfahren dafür
AU2003296585A1 (en) * 2002-12-04 2004-06-23 Basell Polyolefine Gmbh 1-buten copolymers and process for preparing them
DE10260095A1 (de) * 2002-12-19 2004-07-01 Basell Polyolefine Gmbh Verfahren zur Herstellung von heterocyclischen Ketonen
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
CN101163723B (zh) 2003-07-04 2010-12-22 巴塞尔聚烯烃股份有限公司 烯烃聚合方法
KR20060133960A (ko) * 2003-09-11 2006-12-27 바젤 폴리올레핀 게엠베하 헤테로페이스 프로필렌 공중합체의 제조를 위한 다단계공정
DE602004018516D1 (de) * 2003-09-11 2009-01-29 Basell Polyolefine Gmbh Mehrschrittverfahren zur herstellung von heterophasigen propylencopolymeren
JP2007505175A (ja) * 2003-09-11 2007-03-08 バセル ポリオレフィン ジーエムビーエイチ ヘテロ相プロピレンコポリマーを製造するための多段方法
EP1564226A1 (en) 2004-02-16 2005-08-17 Stichting Dutch Polymer Institute Titanocene-based catalyst system
EP1735355B1 (en) * 2004-03-12 2010-09-29 Basell Polyolefine GmbH Process for polymerizing 1-hexene or higher alpha-olefins
EP1723184A1 (en) 2004-03-12 2006-11-22 Basell Polyolefine GmbH Process for polymerizing 1-hexene or higher alpha-olefins
BRPI0508155A (pt) 2004-03-12 2007-08-07 Basell Polyolefine Gmbh sistema catalìtico para a polimerização de olefinas
JP4897670B2 (ja) * 2004-05-04 2012-03-14 バーゼル・ポリオレフィン・ゲーエムベーハー アタクチック１−ブテンポリマー類の製造方法
DE102004027332A1 (de) 2004-06-04 2005-12-22 Basell Polyolefine Gmbh Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
DE602005010255D1 (de) 2004-07-08 2008-11-20 Exxonmobil Chem Patents Inc Katalysator system für die olefinpolymerisation und verfahren zu seiner verwendung
WO2006005648A1 (en) 2004-07-13 2006-01-19 Basell Polyolefine Gmbh Metallocene compounds, ligands used in their preparation, preparation of 1-butene polymers and 1-butene polymers therefrom
EP1769009A1 (en) * 2004-07-22 2007-04-04 Basell Polyolefine GmbH Process for producing fractionable 1-butene polymers
CA2573975A1 (en) * 2004-07-22 2006-01-26 Basell Polyolefine Gmbh 1-butene polymers composition
ATE501183T1 (de) * 2004-10-21 2011-03-15 Basell Polyolefine Gmbh 1-buten-polymer und herstellungsverfahren dafür
EP1655314A1 (en) * 2004-11-09 2006-05-10 Basell Polyolefine GmbH Process for the preparation of 1-butene/propylene copolymers
JP2008519151A (ja) * 2004-11-09 2008-06-05 バーゼル・ポリオレフィン・ゲーエムベーハー １−ブテン／プロピレンコポリマーの製造方法
DE102004056104A1 (de) * 2004-11-19 2006-05-24 Basell Polyolefine Gmbh Verfahren zur Herstellung von niedermolekularen Olefinpolymeren, Organoübergangsmetallverbindungen, Biscyclopentadienylligandsysteme und Katalysatorsysteme
EP1814922A1 (en) * 2004-11-22 2007-08-08 Basell Polyolefine GmbH Propylene based terpolymers
JP2008523231A (ja) * 2004-12-13 2008-07-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ ポリオレフィン繊維
CN101087905B (zh) * 2004-12-23 2010-12-15 巴塞尔聚烯烃意大利有限责任公司 具有弹性的纤维
KR100753477B1 (ko) 2005-01-31 2007-08-31 주식회사 엘지화학 혼합 담지 메탈로센 촉매, 그 제조방법 및 이를 이용하여제조된 폴리올레핀 및 그 제조 방법
KR101293405B1 (ko) * 2005-03-18 2013-08-05 바젤 폴리올레핀 게엠베하 메탈로센 화합물
EP1858934B1 (en) * 2005-03-18 2013-04-24 Basell Polyolefine GmbH Metallocene compounds
WO2006100258A1 (en) * 2005-03-23 2006-09-28 Basell Polyolefine Gmbh Process for the polymerization of olefins
US7728086B2 (en) * 2005-03-23 2010-06-01 Basell Polyolefine Gmbh Process for the polymerization of olefins
US7964679B2 (en) * 2005-05-03 2011-06-21 Basell Poliolefine Italia S.R.L. Process for the polymerization of alpha olefins
EP1879959B1 (en) 2005-05-11 2011-07-06 Basell Poliolefine Italia S.r.l. Polymerization process for preparing polyolefin blends
EP1902062B1 (en) * 2005-06-30 2012-06-13 Basell Polyolefine GmbH Metallocene compounds
US8097681B2 (en) * 2006-08-30 2012-01-17 Basell Polyolefine Gmbh 1-butene propylene copolymer compositions
KR101423946B1 (ko) * 2006-08-30 2014-08-01 바젤 폴리올레핀 게엠베하 1-부텐 프로필렌 공중합체 조성물
US8242237B2 (en) * 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
US8143352B2 (en) 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
US8080610B2 (en) 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
JP2010529253A (ja) 2007-06-04 2010-08-26 エクソンモービル・ケミカル・パテンツ・インク 非常に均一なプロピレンの溶液重合法
DE102007036792A1 (de) * 2007-08-03 2009-02-05 Clariant International Limited Hochkristalline Polypropylenwachse
CN101855249B (zh) 2007-09-13 2013-02-13 埃克森美孚研究工程公司 在线生产增塑聚合物和增塑聚合物共混物的方法
US7910637B2 (en) 2007-09-13 2011-03-22 Exxonmobil Research And Engineering Company In-line blending of plasticizers with a base polymer
US8436114B2 (en) 2010-10-21 2013-05-07 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US8431661B2 (en) 2010-10-21 2013-04-30 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US7910679B2 (en) 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
CN103254513B (zh) 2007-12-20 2015-08-26 埃克森美孚研究工程公司 全同立构聚丙烯和乙烯-丙烯共聚物的共混物
EP2231779B1 (en) 2007-12-20 2012-06-06 ExxonMobil Research and Engineering Company In-line process to produce pellet-stable polyolefins
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
BRPI0908411B1 (pt) * 2008-02-29 2018-10-30 Basell Poliolefine Italia Srl composições de poliolefinas
EP2559713B1 (en) 2010-04-12 2016-08-10 Lotte Chemical Corporation Method for preparing polypropylene using a transition metal compound containing thiophene-fused cyclopentadienyl ligands
KR100986301B1 (ko) 2010-04-12 2010-10-07 아주대학교산학협력단 테트라하이드로퀴놀린 유도체로부터 유래한 티오펜-축합고리 싸이클로펜타디에닐 4족 금속 화합물 및 이를 이용한 올레핀 중합
US9062025B2 (en) 2010-04-12 2015-06-23 Lotte Chemical Corporation Supported catalyst for olefin polymerization and preparation method for polyolefin using the same
EP2559714B1 (en) 2010-04-12 2016-08-10 Lotte Chemical Corporation Method for preparing olefin-diene copolymer using transition metal compound including thiophene-condensed ring cyclopentadienyl ligand
JP5567208B2 (ja) 2010-04-12 2014-08-06 ロッテ ケミカル コーポレーション オレフィン重合用触媒組成物およびこれを用いたポリオレフィンの製造方法
WO2012096698A2 (en) * 2010-10-21 2012-07-19 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
EP3022238B1 (en) 2013-07-17 2017-09-20 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
EP3848401A1 (en) 2013-07-17 2021-07-14 ExxonMobil Chemical Patents Inc. Isotactic propylene polymers
ES2703344T3 (es) 2013-07-17 2019-03-08 Exxonmobil Chemical Patents Inc Metalocenos y composiciones catalíticas derivadas de ellos
US9834628B2 (en) 2013-07-17 2017-12-05 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
JP2016531978A (ja) 2013-07-17 2016-10-13 エクソンモービル ケミカル パテンツ インコーポレイテッド 置換メタロセン触媒
CN104558058B (zh) * 2013-10-12 2017-08-08 中国科学院长春应用化学研究所 茂金属配合物及其制备方法、催化剂组合物
US9321854B2 (en) 2013-10-29 2016-04-26 Exxonmobil Chemical Patents Inc. Aluminum alkyl with C5 cyclic and pendent olefin polymerization catalyst
WO2015065784A1 (en) * 2013-10-29 2015-05-07 Exxonmobil Chemical Patents Inc. Novel aluminum alkyl with c5 cyclic and pendent olefin polymerization catalyst
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10570219B2 (en) 2015-06-05 2020-02-25 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
WO2016196334A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
WO2016196331A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
EP3424937B1 (en) * 2016-03-04 2020-06-10 Japan Polyethylene Corporation Metallocene compound, catalyst component for olefin polymerization including same, catalyst for olefin polymerization including metallocene compound, and method for producing olefin polymer by using catalyst for olefin polymerization
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
EP3694811B1 (en) 2017-10-11 2024-04-03 Basell Polyolefine GmbH Supported catalyst system
CN110655623A (zh) * 2019-09-19 2020-01-07 天津大学 采用链穿梭聚合的方法制备无规聚丙烯-等规聚丙烯立构嵌段聚合物
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
JP7676863B2 (ja) * 2020-03-24 2025-05-15 日本ポリプロ株式会社 オレフィン重合用担持系触媒、及び、当該オレフィン重合用担持系触媒を用いたプロピレン系重合体の製造方法
CN114702532B (zh) * 2021-01-01 2024-08-06 中国石油化工股份有限公司 一种茂金属、含有其的催化剂及其合成和应用
CN116410238B (zh) * 2021-12-31 2026-01-20 中国石油天然气股份有限公司 含硫手性桥联茂金属化合物及其制备和应用
CN116410385B (zh) * 2021-12-31 2025-11-18 中国石油天然气股份有限公司 一种聚烯烃弹性体及其制备方法与所用茂金属催化剂
CN114507305A (zh) * 2022-01-27 2022-05-17 吉林大学 一种茂锆型烯烃聚合催化剂的合成方法
EP4501975A4 (en) 2022-03-24 2025-08-06 Japan Polypropylene Corp PROPYLENE-BASED BRANCHED POLYMER
CN116948069A (zh) * 2022-04-15 2023-10-27 中国石油天然气股份有限公司 一种高熔指聚丙烯的制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998022486A1 (en) * 1996-11-15 1998-05-28 Montell Technology Company B.V. Heterocyclic metallocenes and polymerization catalysts

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
JP3293927B2 (ja) 1993-02-19 2002-06-17 三菱化学株式会社 α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
AU1870999A (en) * 1997-11-12 1999-05-31 Montell Technology Company B.V. Metallocenes and catalysts for olefin-polymerisation
DE19804970A1 (de) * 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
EP1074557A3 (de) * 1999-07-31 2003-02-26 Basell Polyolefine GmbH Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998022486A1 (en) * 1996-11-15 1998-05-28 Montell Technology Company B.V. Heterocyclic metallocenes and polymerization catalysts

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