ATE434631T1 - Metallocenverbindungen, verfahren zur herstellung und verwendung als olefinpolymerisationskatalysatoren - Google Patents
Metallocenverbindungen, verfahren zur herstellung und verwendung als olefinpolymerisationskatalysatorenInfo
- Publication number
- ATE434631T1 ATE434631T1 AT00990680T AT00990680T ATE434631T1 AT E434631 T1 ATE434631 T1 AT E434631T1 AT 00990680 T AT00990680 T AT 00990680T AT 00990680 T AT00990680 T AT 00990680T AT E434631 T1 ATE434631 T1 AT E434631T1
- Authority
- AT
- Austria
- Prior art keywords
- production
- olefin polymerization
- polymerization catalysts
- metallocene compounds
- metallocene
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
- C07D333/78—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems condensed with rings other than six-membered or with ring systems containing such rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/08—Butenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/06—Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/461,858 US6444833B1 (en) | 1999-12-15 | 1999-12-15 | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
PCT/EP2000/012406 WO2001044318A1 (en) | 1999-12-15 | 2000-12-07 | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE434631T1 true ATE434631T1 (de) | 2009-07-15 |
Family
ID=23834210
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT00990680T ATE434631T1 (de) | 1999-12-15 | 2000-12-07 | Metallocenverbindungen, verfahren zur herstellung und verwendung als olefinpolymerisationskatalysatoren |
Country Status (15)
Country | Link |
---|---|
US (2) | US6444833B1 (de) |
EP (1) | EP1153047B1 (de) |
JP (1) | JP4838475B2 (de) |
KR (1) | KR100733755B1 (de) |
CN (1) | CN1161388C (de) |
AR (1) | AR027903A1 (de) |
AT (1) | ATE434631T1 (de) |
AU (1) | AU778205B2 (de) |
BR (1) | BR0010043A (de) |
CA (1) | CA2362093A1 (de) |
DE (1) | DE60042447D1 (de) |
PL (1) | PL349318A1 (de) |
RU (1) | RU2245341C2 (de) |
WO (1) | WO2001044318A1 (de) |
ZA (1) | ZA200106367B (de) |
Families Citing this family (100)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1327636B1 (de) * | 1996-11-15 | 2006-01-11 | Basell Polyolefine GmbH | Heterocyclische Metallocne und Polymerisationskatalysatoren |
KR20020034193A (ko) * | 1999-09-22 | 2002-05-08 | 간디 지오프레이 에이치. | 올레핀 중합을 위한 촉매 시스템 및 방법 |
US6444833B1 (en) * | 1999-12-15 | 2002-09-03 | Basell Technology Company Bv | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
ATE373669T1 (de) * | 1999-12-28 | 2007-10-15 | Basell Polyolefine Gmbh | Heterocyclische metallocene und ihre verwendung in katalysatorsystemen zur herstellung von olefin polymeren |
US7459511B2 (en) * | 2001-06-12 | 2008-12-02 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
JP4332029B2 (ja) * | 2001-06-12 | 2009-09-16 | バーゼル・ポリオレフィン・ゲーエムベーハー | 1−ブテンの重合方法 |
WO2003014107A1 (en) * | 2001-08-01 | 2003-02-20 | Basell Polyolefine Gmbh | Process for the preparation of heterocyclic pentalene derivatives |
DE10145453A1 (de) * | 2001-09-14 | 2003-06-05 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus |
US7834112B2 (en) * | 2001-09-14 | 2010-11-16 | Basell Polyolefine Gmbh | Method of polymerization of olefins |
ES2268126T3 (es) | 2001-11-30 | 2007-03-16 | Basell Polyolefine Gmbh | Compuestos de metaloceno y procedimiento para la preparacion de polimeros de propileno. |
JP4062929B2 (ja) * | 2002-02-08 | 2008-03-19 | 住友化学株式会社 | 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
US7572859B2 (en) * | 2002-06-26 | 2009-08-11 | Basell Polyolefine Italia S.R.L. | Impact-resistant polyolefin compositions |
MXPA04012699A (es) * | 2002-06-26 | 2005-03-23 | Basell Poliolefine Spa | Composiciones de poliolefina resistentes a impactos. |
ATE445651T1 (de) * | 2002-09-06 | 2009-10-15 | Basell Polyolefine Gmbh | Verfahren zur copolymerisation von ethylen |
US7807769B2 (en) | 2002-09-20 | 2010-10-05 | Exxonmobil Chemical Patents Inc. | Isotactic polypropylene produced from supercritical polymerization process |
EP1539841B1 (de) | 2002-09-20 | 2012-08-01 | ExxonMobil Chemical Patents Inc. | Herstellung von polymeren unter überkritischen bedingungen |
US8058371B2 (en) | 2002-09-20 | 2011-11-15 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization |
US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
EP1549688A2 (de) * | 2002-10-10 | 2005-07-06 | Basell Polyolefine GmbH | Verfahren zur copolymerisation von ethylen |
DE10250062A1 (de) * | 2002-10-25 | 2004-05-06 | Basell Polyolefine Gmbh | Verfahren zur racemoselektiven Darstellung von verbrückten Metallocenkomplexen mit unsubstituierten oder 2-substituierten Indenylliganden |
JP2006509064A (ja) * | 2002-12-04 | 2006-03-16 | バセル ポリオレフィン ジーエムビーエイチ | 1−ブテンコポリマー類およびそれらの製造方法 |
US7534848B2 (en) * | 2002-12-04 | 2009-05-19 | Basell Polyolefine Gmbh | 1-butene copolymers and process for preparing them |
US7589160B2 (en) * | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
DE10260095A1 (de) * | 2002-12-19 | 2004-07-01 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von heterocyclischen Ketonen |
US6927264B2 (en) | 2003-05-28 | 2005-08-09 | Dow Global Technologies Inc. | Metal complexes and polymerization process using same |
EP1648946B1 (de) | 2003-07-04 | 2015-07-15 | Basell Polyolefine GmbH | Olefin-polymerisationsverfahren |
US20060287436A1 (en) * | 2003-09-11 | 2006-12-21 | Anteo Pelliconi | Multistep process for preparing heterophasic propylene copolymers |
US20070060727A1 (en) * | 2003-09-11 | 2007-03-15 | Basel Polyolefine Gmbh | Multistep process for preparing heterophasic propylene copolymers |
WO2005023889A1 (en) * | 2003-09-11 | 2005-03-17 | Basell Polyolefine Gmbh | Multistep process for preparing heterophasic propylene copolymers |
EP1564226A1 (de) | 2004-02-16 | 2005-08-17 | Stichting Dutch Polymer Institute | Katalysatorsystem auf Basis von Titanocene |
JP2007528924A (ja) | 2004-03-12 | 2007-10-18 | バセル ポリオレフィン ジーエムビーエイチ | オレフィンの重合用触媒システム |
WO2005095473A1 (en) * | 2004-03-12 | 2005-10-13 | Basell Polyolefine Gmbh | Process for polymerizing 1-hexene or higher alpha-olefins |
US7943716B2 (en) | 2004-03-12 | 2011-05-17 | Basell Polyolefine Gmbh | Process for polymerizing 1-hexene or higher alpha-olefins |
JP4897670B2 (ja) * | 2004-05-04 | 2012-03-14 | バーゼル・ポリオレフィン・ゲーエムベーハー | アタクチック1−ブテンポリマー類の製造方法 |
DE102004027332A1 (de) * | 2004-06-04 | 2005-12-22 | Basell Polyolefine Gmbh | Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
CN101023105A (zh) | 2004-07-13 | 2007-08-22 | 巴塞尔聚烯烃股份有限公司 | 金属茂化合物、它们制备中使用的配体,1-丁烯聚合物的制备和由此得到的1-丁烯聚合物 |
US7776978B2 (en) * | 2004-07-22 | 2010-08-17 | Basell Polyolefine Gmbh | Process for producing fractionable 1-butene polymers |
ATE388994T1 (de) * | 2004-07-22 | 2008-03-15 | Basell Polyolefine Gmbh | 1-butenpolymerzusammensetzung |
WO2006045687A1 (en) * | 2004-10-21 | 2006-05-04 | Basell Polyolefine Gmbh | 1-butene polymer and process for the preparation thereof |
EP1655314A1 (de) * | 2004-11-09 | 2006-05-10 | Basell Polyolefine GmbH | Polymerisationsverfahren von 1-buten mit propen |
DE602005015479D1 (de) * | 2004-11-09 | 2009-08-27 | Basell Polyolefine Gmbh | Verfahren zur herstellung von 1-buten/propylen-copolymeren |
DE102004056104A1 (de) * | 2004-11-19 | 2006-05-24 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von niedermolekularen Olefinpolymeren, Organoübergangsmetallverbindungen, Biscyclopentadienylligandsysteme und Katalysatorsysteme |
CN101061142B (zh) * | 2004-11-22 | 2012-04-18 | 巴塞尔聚烯烃股份有限公司 | 基于丙烯的三元共聚物 |
JP2008523231A (ja) * | 2004-12-13 | 2008-07-03 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ポリオレフィン繊維 |
US20080021165A1 (en) * | 2004-12-23 | 2008-01-24 | Franco Sartori | Fibres Having Elastic Properties |
KR100753477B1 (ko) | 2005-01-31 | 2007-08-31 | 주식회사 엘지화학 | 혼합 담지 메탈로센 촉매, 그 제조방법 및 이를 이용하여제조된 폴리올레핀 및 그 제조 방법 |
JP2008536813A (ja) * | 2005-03-18 | 2008-09-11 | バーゼル・ポリオレフィン・ゲーエムベーハー | メタロセン化合物 |
EP1858907B1 (de) * | 2005-03-18 | 2008-10-15 | Basell Polyolefine GmbH | Metallocenverbindungen |
WO2006100258A1 (en) * | 2005-03-23 | 2006-09-28 | Basell Polyolefine Gmbh | Process for the polymerization of olefins |
RU2392283C2 (ru) * | 2005-03-23 | 2010-06-20 | Базелль Полиолефине Гмбх | Способ полимеризации олефинов |
EP1877453A1 (de) * | 2005-05-03 | 2008-01-16 | Basell Polyolefine GmbH | Verfahren zur polymerisation von alpha-olefinen |
EP1879959B1 (de) | 2005-05-11 | 2011-07-06 | Basell Poliolefine Italia S.r.l. | Polymerisationsverfahren zur herstellung von polyolefinblends |
JP5004954B2 (ja) * | 2005-06-30 | 2012-08-22 | バーゼル・ポリオレフィン・ゲーエムベーハー | メタロセン化合物 |
US8097681B2 (en) * | 2006-08-30 | 2012-01-17 | Basell Polyolefine Gmbh | 1-butene propylene copolymer compositions |
JP5580590B2 (ja) * | 2006-08-30 | 2014-08-27 | バーゼル・ポリオレフィン・ゲーエムベーハー | 1−ブテンプロピレンコポリマー組成物 |
US8242237B2 (en) * | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
US8143352B2 (en) | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
US8080610B2 (en) | 2007-03-06 | 2011-12-20 | Exxonmobil Research And Engineering Company | Monomer recycle process for fluid phase in-line blending of polymers |
DE102007036792A1 (de) * | 2007-08-03 | 2009-02-05 | Clariant International Limited | Hochkristalline Polypropylenwachse |
CN101855250B (zh) | 2007-09-13 | 2013-01-02 | 埃克森美孚研究工程公司 | 增塑剂与基础聚合物的在线共混 |
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KR100986301B1 (ko) * | 2010-04-12 | 2010-10-07 | 아주대학교산학협력단 | 테트라하이드로퀴놀린 유도체로부터 유래한 티오펜-축합고리 싸이클로펜타디에닐 4족 금속 화합물 및 이를 이용한 올레핀 중합 |
JP5546678B2 (ja) | 2010-04-12 | 2014-07-09 | ロッテ ケミカル コーポレーション | チオフェン−縮合環シクロペンタジエニルリガンドを含む遷移金属化合物を使用したポリプロピレンの製造方法 |
US9062025B2 (en) | 2010-04-12 | 2015-06-23 | Lotte Chemical Corporation | Supported catalyst for olefin polymerization and preparation method for polyolefin using the same |
CN103261239B (zh) * | 2010-10-21 | 2016-04-06 | 尤尼威蒂恩技术有限责任公司 | 聚乙烯及其生产方法 |
US9464145B2 (en) | 2013-07-17 | 2016-10-11 | Exxonmobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
EP3848401A1 (de) | 2013-07-17 | 2021-07-14 | ExxonMobil Chemical Patents Inc. | Isotaktische propylenpolymere |
SG10201802959WA (en) | 2013-07-17 | 2018-05-30 | Exxonmobil Chemical Patents Inc | Cyclopropyl substituted metallocene catalysts |
EP3022234B1 (de) | 2013-07-17 | 2018-12-26 | ExxonMobil Chemical Patents Inc. | Substituierte metallocenkatalysatoren |
US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
CN105358589B (zh) | 2013-07-17 | 2018-07-03 | 埃克森美孚化学专利公司 | 金属茂和由其衍生的催化剂组合物 |
CN104558058B (zh) * | 2013-10-12 | 2017-08-08 | 中国科学院长春应用化学研究所 | 茂金属配合物及其制备方法、催化剂组合物 |
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US10294316B2 (en) | 2015-06-05 | 2019-05-21 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
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EP3885373A1 (de) | 2015-06-05 | 2021-09-29 | ExxonMobil Chemical Patents Inc. | Herstellung von heterophasischen polymeren in gas- oder schlämmephase |
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CN114702532B (zh) * | 2021-01-01 | 2024-08-06 | 中国石油化工股份有限公司 | 一种茂金属、含有其的催化剂及其合成和应用 |
CN116410238A (zh) * | 2021-12-31 | 2023-07-11 | 中国石油天然气股份有限公司 | 含硫手性桥联茂金属化合物及其制备和应用 |
CN114507305A (zh) * | 2022-01-27 | 2022-05-17 | 吉林大学 | 一种茂锆型烯烃聚合催化剂的合成方法 |
KR20240148431A (ko) | 2022-03-24 | 2024-10-11 | 닛폰포리프로가부시키가이샤 | 분지상 프로필렌계 중합체 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
JP3293927B2 (ja) | 1993-02-19 | 2002-06-17 | 三菱化学株式会社 | α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法 |
EP1327636B1 (de) | 1996-11-15 | 2006-01-11 | Basell Polyolefine GmbH | Heterocyclische Metallocne und Polymerisationskatalysatoren |
US6559252B1 (en) | 1997-10-29 | 2003-05-06 | Basell Technology Company Bv | Catalysts and processes for the polymerization of olefins |
KR100583931B1 (ko) * | 1997-11-12 | 2006-05-26 | 바셀 테크놀로지 캄파니 비이브이 | 메탈로센 및 올레핀 중합용 촉매 |
DE19804970A1 (de) * | 1998-02-07 | 1999-08-12 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem |
EP1074557A3 (de) * | 1999-07-31 | 2003-02-26 | Basell Polyolefine GmbH | Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen |
US6444833B1 (en) * | 1999-12-15 | 2002-09-03 | Basell Technology Company Bv | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
-
1999
- 1999-12-15 US US09/461,858 patent/US6444833B1/en not_active Expired - Lifetime
-
2000
- 2000-12-07 BR BR0010043-9A patent/BR0010043A/pt not_active Application Discontinuation
- 2000-12-07 CN CNB008062439A patent/CN1161388C/zh not_active Expired - Fee Related
- 2000-12-07 AU AU30079/01A patent/AU778205B2/en not_active Ceased
- 2000-12-07 EP EP00990680A patent/EP1153047B1/de not_active Expired - Lifetime
- 2000-12-07 DE DE60042447T patent/DE60042447D1/de not_active Expired - Lifetime
- 2000-12-07 JP JP2001544805A patent/JP4838475B2/ja not_active Expired - Fee Related
- 2000-12-07 RU RU2001125425/04A patent/RU2245341C2/ru not_active IP Right Cessation
- 2000-12-07 CA CA002362093A patent/CA2362093A1/en not_active Abandoned
- 2000-12-07 PL PL00349318A patent/PL349318A1/xx not_active Application Discontinuation
- 2000-12-07 AT AT00990680T patent/ATE434631T1/de not_active IP Right Cessation
- 2000-12-07 KR KR1020017010350A patent/KR100733755B1/ko not_active IP Right Cessation
- 2000-12-07 WO PCT/EP2000/012406 patent/WO2001044318A1/en active Application Filing
- 2000-12-07 US US09/913,742 patent/US6635779B1/en not_active Expired - Lifetime
- 2000-12-15 AR ARP000106663A patent/AR027903A1/es not_active Application Discontinuation
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BR0010043A (pt) | 2002-01-22 |
CN1161388C (zh) | 2004-08-11 |
CN1347424A (zh) | 2002-05-01 |
JP4838475B2 (ja) | 2011-12-14 |
AU3007901A (en) | 2001-06-25 |
KR100733755B1 (ko) | 2007-06-29 |
US6444833B1 (en) | 2002-09-03 |
ZA200106367B (en) | 2002-11-04 |
EP1153047A1 (de) | 2001-11-14 |
US6635779B1 (en) | 2003-10-21 |
JP2003517010A (ja) | 2003-05-20 |
EP1153047B1 (de) | 2009-06-24 |
AR027903A1 (es) | 2003-04-16 |
CA2362093A1 (en) | 2001-06-21 |
WO2001044318A1 (en) | 2001-06-21 |
RU2245341C2 (ru) | 2005-01-27 |
KR20010102158A (ko) | 2001-11-15 |
PL349318A1 (en) | 2002-07-15 |
DE60042447D1 (de) | 2009-08-06 |
AU778205B2 (en) | 2004-11-25 |
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