AR027903A1 - Compuestos de metaloceno, procedimiento para su preparacion y uso en sistemas cataliticos para la polimerizacion de olefinas - Google Patents
Compuestos de metaloceno, procedimiento para su preparacion y uso en sistemas cataliticos para la polimerizacion de olefinasInfo
- Publication number
- AR027903A1 AR027903A1 ARP000106663A ARP000106663A AR027903A1 AR 027903 A1 AR027903 A1 AR 027903A1 AR P000106663 A ARP000106663 A AR P000106663A AR P000106663 A ARP000106663 A AR P000106663A AR 027903 A1 AR027903 A1 AR 027903A1
- Authority
- AR
- Argentina
- Prior art keywords
- procedure
- preparation
- olefin polymerization
- catalytic systems
- metalocene compounds
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
- C07D333/78—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems condensed with rings other than six-membered or with ring systems containing such rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/08—Butenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/06—Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/461,858 US6444833B1 (en) | 1999-12-15 | 1999-12-15 | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
Publications (1)
Publication Number | Publication Date |
---|---|
AR027903A1 true AR027903A1 (es) | 2003-04-16 |
Family
ID=23834210
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP000106663A AR027903A1 (es) | 1999-12-15 | 2000-12-15 | Compuestos de metaloceno, procedimiento para su preparacion y uso en sistemas cataliticos para la polimerizacion de olefinas |
Country Status (15)
Country | Link |
---|---|
US (2) | US6444833B1 (es) |
EP (1) | EP1153047B1 (es) |
JP (1) | JP4838475B2 (es) |
KR (1) | KR100733755B1 (es) |
CN (1) | CN1161388C (es) |
AR (1) | AR027903A1 (es) |
AT (1) | ATE434631T1 (es) |
AU (1) | AU778205B2 (es) |
BR (1) | BR0010043A (es) |
CA (1) | CA2362093A1 (es) |
DE (1) | DE60042447D1 (es) |
PL (1) | PL349318A1 (es) |
RU (1) | RU2245341C2 (es) |
WO (1) | WO2001044318A1 (es) |
ZA (1) | ZA200106367B (es) |
Families Citing this family (99)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR9715006B1 (pt) * | 1996-11-15 | 2011-06-28 | metalocenos heterocìclicos, ligantes, sistema catalìtico e processo para a polimerização de monÈmeros polimerizáveis por adição. | |
CN1374973A (zh) * | 1999-09-22 | 2002-10-16 | 巴塞尔技术有限公司 | 用于烯烃聚合的催化剂体系及方法 |
US6444833B1 (en) * | 1999-12-15 | 2002-09-03 | Basell Technology Company Bv | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
CA2363265A1 (en) * | 1999-12-28 | 2001-07-05 | Basell Technology Company B.V. | Heterocyclic metallocene compounds and use thereof in catalyst systems for producing olefin polymers |
WO2002100908A1 (en) * | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
ATE444975T1 (de) * | 2001-06-12 | 2009-10-15 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von buten-1 |
DE60208683T2 (de) * | 2001-08-01 | 2006-11-02 | Basell Polyolefine Gmbh | Verfahren zur herstellung von heterocyclischen pentalen derivaten |
DE50212940D1 (de) * | 2001-09-14 | 2008-12-04 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von olefinen |
DE10145453A1 (de) * | 2001-09-14 | 2003-06-05 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus |
DE60213452T2 (de) * | 2001-11-30 | 2007-08-23 | Basell Polyolefine Gmbh | Metallocene und verfahren zur herstellung von propylenpolymeren |
JP4062929B2 (ja) * | 2002-02-08 | 2008-03-19 | 住友化学株式会社 | 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
EP1517954B1 (en) * | 2002-06-26 | 2014-05-28 | Basell Poliolefine Italia S.r.l. | Impact-resistant polyolefin compositions |
CA2487517A1 (en) * | 2002-06-26 | 2004-01-08 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
WO2004022613A1 (en) * | 2002-09-06 | 2004-03-18 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
US7807769B2 (en) | 2002-09-20 | 2010-10-05 | Exxonmobil Chemical Patents Inc. | Isotactic polypropylene produced from supercritical polymerization process |
US8058371B2 (en) | 2002-09-20 | 2011-11-15 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization |
CN101041701B (zh) | 2002-09-20 | 2013-02-27 | 埃克森美孚化学专利公司 | 包括丙烯的聚合物及其应用 |
WO2004033510A2 (en) * | 2002-10-10 | 2004-04-22 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
DE10250062A1 (de) * | 2002-10-25 | 2004-05-06 | Basell Polyolefine Gmbh | Verfahren zur racemoselektiven Darstellung von verbrückten Metallocenkomplexen mit unsubstituierten oder 2-substituierten Indenylliganden |
DE60329523D1 (de) * | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
US7589160B2 (en) * | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
JP2006509064A (ja) * | 2002-12-04 | 2006-03-16 | バセル ポリオレフィン ジーエムビーエイチ | 1−ブテンコポリマー類およびそれらの製造方法 |
DE10260095A1 (de) * | 2002-12-19 | 2004-07-01 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von heterocyclischen Ketonen |
US6927264B2 (en) | 2003-05-28 | 2005-08-09 | Dow Global Technologies Inc. | Metal complexes and polymerization process using same |
KR101167877B1 (ko) | 2003-07-04 | 2012-07-23 | 바젤 폴리올레핀 게엠베하 | 올레핀 중합 방법 |
WO2005023889A1 (en) * | 2003-09-11 | 2005-03-17 | Basell Polyolefine Gmbh | Multistep process for preparing heterophasic propylene copolymers |
JP2007505175A (ja) * | 2003-09-11 | 2007-03-08 | バセル ポリオレフィン ジーエムビーエイチ | ヘテロ相プロピレンコポリマーを製造するための多段方法 |
EP1664140B1 (en) * | 2003-09-11 | 2008-12-17 | Basell Polyolefine GmbH | Multistep process for preparing heterophasic propylene copolymers |
EP1564226A1 (en) | 2004-02-16 | 2005-08-17 | Stichting Dutch Polymer Institute | Titanocene-based catalyst system |
EP1735355B1 (en) | 2004-03-12 | 2010-09-29 | Basell Polyolefine GmbH | Process for polymerizing 1-hexene or higher alpha-olefins |
KR20070004712A (ko) | 2004-03-12 | 2007-01-09 | 바젤 폴리올레핀 게엠베하 | 올레핀 중합용 촉매 시스템 |
US7943716B2 (en) | 2004-03-12 | 2011-05-17 | Basell Polyolefine Gmbh | Process for polymerizing 1-hexene or higher alpha-olefins |
ATE445650T1 (de) * | 2004-05-04 | 2009-10-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von ataktischen 1- butenpolymeren |
DE102004027332A1 (de) * | 2004-06-04 | 2005-12-22 | Basell Polyolefine Gmbh | Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
JP5006783B2 (ja) | 2004-07-13 | 2012-08-22 | バーゼル・ポリオレフィン・ゲーエムベーハー | メタロセン化合物、それらの調製で使用される配位子、1−ブテンポリマーの調製法、およびその方法から得られる1−ブテンポリマー |
PL1769030T3 (pl) * | 2004-07-22 | 2008-08-29 | Basell Polyolefine Gmbh | Kompozycja polimerów 1-butenu |
AU2005263671A1 (en) * | 2004-07-22 | 2006-01-26 | Basell Polyolefine Gmbh | Process for producing fractionable 1-butene polymers |
US7534841B2 (en) * | 2004-10-21 | 2009-05-19 | Basell Polyolefine Gmbh | 1-butene polymer and process for the preparation thereof |
DE602005015479D1 (de) * | 2004-11-09 | 2009-08-27 | Basell Polyolefine Gmbh | Verfahren zur herstellung von 1-buten/propylen-copolymeren |
EP1655314A1 (en) * | 2004-11-09 | 2006-05-10 | Basell Polyolefine GmbH | Process for the preparation of 1-butene/propylene copolymers |
DE102004056104A1 (de) * | 2004-11-19 | 2006-05-24 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von niedermolekularen Olefinpolymeren, Organoübergangsmetallverbindungen, Biscyclopentadienylligandsysteme und Katalysatorsysteme |
KR20070093058A (ko) * | 2004-11-22 | 2007-09-17 | 바젤 폴리올레핀 게엠베하 | 프로필렌 기재 삼중합체 |
US20080160862A1 (en) * | 2004-12-13 | 2008-07-03 | Basell Poliolefine Italia S.R.L. | Polyolefin Composition, Fibres and Nonwoven Fabrics |
ATE414804T1 (de) * | 2004-12-23 | 2008-12-15 | Basell Poliolefine Srl | Fasern mit elastischen eigenschaften |
KR100753477B1 (ko) | 2005-01-31 | 2007-08-31 | 주식회사 엘지화학 | 혼합 담지 메탈로센 촉매, 그 제조방법 및 이를 이용하여제조된 폴리올레핀 및 그 제조 방법 |
WO2006097500A1 (en) * | 2005-03-18 | 2006-09-21 | Basell Polyolefine Gmbh | Metallocene compounds |
RU2410388C2 (ru) * | 2005-03-18 | 2011-01-27 | Базелль Полиолефине Гмбх | Металлоценовые соединения |
EP1861435B1 (en) * | 2005-03-23 | 2016-01-13 | Basell Polyolefine GmbH | Process for the polymerization of olefins |
KR101289946B1 (ko) * | 2005-03-23 | 2013-07-26 | 바젤 폴리올레핀 게엠베하 | 올레핀의 중합 방법 |
WO2006117285A1 (en) * | 2005-05-03 | 2006-11-09 | Basell Polyolefine Gmbh | Process for the polymerization of alpha olefins |
WO2006120177A2 (en) | 2005-05-11 | 2006-11-16 | Basell Poliolefine Itatia S.R.L. | Polymerization process for preparing polyolefin blends |
WO2007003528A2 (en) * | 2005-06-30 | 2007-01-11 | Basell Polyolefine Gmbh | Metallocene compounds |
DE602007003743D1 (de) * | 2006-08-30 | 2010-01-21 | Basell Polyolefine Gmbh | 1-buten-propylen-copolymer-zusammensetzungen |
KR101374142B1 (ko) * | 2006-08-30 | 2014-03-17 | 바젤 폴리올레핀 게엠베하 | 1-부텐 프로필렌 공중합체 조성물 |
US8143352B2 (en) | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
US8242237B2 (en) * | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
US8080610B2 (en) | 2007-03-06 | 2011-12-20 | Exxonmobil Research And Engineering Company | Monomer recycle process for fluid phase in-line blending of polymers |
DE102007036792A1 (de) * | 2007-08-03 | 2009-02-05 | Clariant International Limited | Hochkristalline Polypropylenwachse |
EP2201042B1 (en) | 2007-09-13 | 2012-06-27 | ExxonMobil Research and Engineering Company | In-line blending of plasticizers with a base polymer |
CN101855249B (zh) | 2007-09-13 | 2013-02-13 | 埃克森美孚研究工程公司 | 在线生产增塑聚合物和增塑聚合物共混物的方法 |
US8431661B2 (en) | 2010-10-21 | 2013-04-30 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
US8436114B2 (en) | 2010-10-21 | 2013-05-07 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
US7910679B2 (en) | 2007-12-20 | 2011-03-22 | Exxonmobil Research And Engineering Company | Bulk homogeneous polymerization process for ethylene propylene copolymers |
EP2450403A1 (en) | 2007-12-20 | 2012-05-09 | ExxonMobil Research and Engineering Company | Polypropylene ethylene-propylene copolymer blends and in-line process to produce them |
US7994237B2 (en) | 2007-12-20 | 2011-08-09 | Exxonmobil Research And Engineering Company | In-line process to produce pellet-stable polyolefins |
US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
BRPI0908411B1 (pt) * | 2008-02-29 | 2018-10-30 | Basell Poliolefine Italia Srl | composições de poliolefinas |
ES2596717T3 (es) | 2010-04-12 | 2017-01-11 | Lotte Chemical Corporation | Composición de catalizador para la polimerización de olefina y procedimiento de preparación de poliolefina usando la misma |
KR100986301B1 (ko) | 2010-04-12 | 2010-10-07 | 아주대학교산학협력단 | 테트라하이드로퀴놀린 유도체로부터 유래한 티오펜-축합고리 싸이클로펜타디에닐 4족 금속 화합물 및 이를 이용한 올레핀 중합 |
WO2011129592A2 (ko) | 2010-04-12 | 2011-10-20 | 호남석유화학 주식회사 | 올레핀 중합용 담지 촉매 및 이를 사용한 폴리올레핀의 제조방법 |
KR101384412B1 (ko) | 2010-04-12 | 2014-04-25 | 롯데케미칼 주식회사 | 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 폴리프로필렌의 제조방법 |
CN102892797A (zh) | 2010-04-12 | 2013-01-23 | 湖南石油化学株式会社 | 使用包含噻吩稠合的环戊二烯基配体的过渡金属化合物制备烯烃-二烯共聚物的方法 |
EP2915826B1 (en) * | 2010-10-21 | 2024-02-28 | Univation Technologies, LLC | Polyethylene and process for production thereof |
EP3022238B1 (en) | 2013-07-17 | 2017-09-20 | ExxonMobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
EP3301119B1 (en) | 2013-07-17 | 2021-03-17 | ExxonMobil Chemical Patents Inc. | Isotactic propylene polymers |
CN110845546A (zh) | 2013-07-17 | 2020-02-28 | 埃克森美孚化学专利公司 | 取代的茂金属催化剂 |
WO2015009472A1 (en) | 2013-07-17 | 2015-01-22 | Exxonmobil Chemcal Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
SG11201508750SA (en) | 2013-07-17 | 2015-11-27 | Exxonmobil Chem Patents Inc | Cyclopropyl substituted metallocene catalysts |
CN104558058B (zh) * | 2013-10-12 | 2017-08-08 | 中国科学院长春应用化学研究所 | 茂金属配合物及其制备方法、催化剂组合物 |
WO2015065784A1 (en) * | 2013-10-29 | 2015-05-07 | Exxonmobil Chemical Patents Inc. | Novel aluminum alkyl with c5 cyclic and pendent olefin polymerization catalyst |
US9321854B2 (en) | 2013-10-29 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Aluminum alkyl with C5 cyclic and pendent olefin polymerization catalyst |
US9809664B2 (en) | 2015-06-05 | 2017-11-07 | Exxonmobil Chemical Patents Inc. | Bimodal propylene polymers and sequential polymerization |
WO2016196331A1 (en) | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Supported metallocene catalyst systems for polymerization |
US10294316B2 (en) | 2015-06-05 | 2019-05-21 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
EP3885373A1 (en) | 2015-06-05 | 2021-09-29 | ExxonMobil Chemical Patents Inc. | Production of heterophasic polymers in gas or slurry phase |
US10329360B2 (en) | 2015-06-05 | 2019-06-25 | Exxonmobil Chemical Patents Inc. | Catalyst system comprising supported alumoxane and unsupported alumoxane particles |
US10280235B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers |
US10280233B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst systems and methods of making and using the same |
US10759886B2 (en) | 2015-06-05 | 2020-09-01 | Exxonmobil Chemical Patents Inc. | Single reactor production of polymers in gas or slurry phase |
JP6787188B2 (ja) * | 2016-03-04 | 2020-11-18 | 日本ポリエチレン株式会社 | メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法 |
US11059918B2 (en) | 2016-05-27 | 2021-07-13 | Exxonmobil Chemical Patents Inc. | Metallocene catalyst compositions and polymerization process therewith |
WO2019072695A1 (en) | 2017-10-11 | 2019-04-18 | Basell Polyolefine Gmbh | CATALYST SUPPORTED SYSTEM |
CN110655623A (zh) * | 2019-09-19 | 2020-01-07 | 天津大学 | 采用链穿梭聚合的方法制备无规聚丙烯-等规聚丙烯立构嵌段聚合物 |
US11472828B2 (en) | 2019-10-11 | 2022-10-18 | Exxonmobil Chemical Patents Inc. | Indacene based metallocene catalysts useful in the production of propylene polymers |
CN114702532A (zh) * | 2021-01-01 | 2022-07-05 | 中国石油化工股份有限公司 | 一种茂金属、含有其的催化剂及其合成和应用 |
CN116410238A (zh) * | 2021-12-31 | 2023-07-11 | 中国石油天然气股份有限公司 | 含硫手性桥联茂金属化合物及其制备和应用 |
CN114507305A (zh) * | 2022-01-27 | 2022-05-17 | 吉林大学 | 一种茂锆型烯烃聚合催化剂的合成方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
JP3293927B2 (ja) | 1993-02-19 | 2002-06-17 | 三菱化学株式会社 | α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法 |
BR9715006B1 (pt) | 1996-11-15 | 2011-06-28 | metalocenos heterocìclicos, ligantes, sistema catalìtico e processo para a polimerização de monÈmeros polimerizáveis por adição. | |
US6559252B1 (en) | 1997-10-29 | 2003-05-06 | Basell Technology Company Bv | Catalysts and processes for the polymerization of olefins |
AU1870999A (en) * | 1997-11-12 | 1999-05-31 | Montell Technology Company B.V. | Metallocenes and catalysts for olefin-polymerisation |
DE19804970A1 (de) * | 1998-02-07 | 1999-08-12 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem |
EP1074557A3 (de) * | 1999-07-31 | 2003-02-26 | Basell Polyolefine GmbH | Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen |
US6444833B1 (en) * | 1999-12-15 | 2002-09-03 | Basell Technology Company Bv | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
-
1999
- 1999-12-15 US US09/461,858 patent/US6444833B1/en not_active Expired - Lifetime
-
2000
- 2000-12-07 AU AU30079/01A patent/AU778205B2/en not_active Ceased
- 2000-12-07 RU RU2001125425/04A patent/RU2245341C2/ru not_active IP Right Cessation
- 2000-12-07 JP JP2001544805A patent/JP4838475B2/ja not_active Expired - Fee Related
- 2000-12-07 WO PCT/EP2000/012406 patent/WO2001044318A1/en active Application Filing
- 2000-12-07 CN CNB008062439A patent/CN1161388C/zh not_active Expired - Fee Related
- 2000-12-07 PL PL00349318A patent/PL349318A1/xx not_active Application Discontinuation
- 2000-12-07 KR KR1020017010350A patent/KR100733755B1/ko not_active IP Right Cessation
- 2000-12-07 CA CA002362093A patent/CA2362093A1/en not_active Abandoned
- 2000-12-07 EP EP00990680A patent/EP1153047B1/en not_active Expired - Lifetime
- 2000-12-07 BR BR0010043-9A patent/BR0010043A/pt not_active Application Discontinuation
- 2000-12-07 AT AT00990680T patent/ATE434631T1/de not_active IP Right Cessation
- 2000-12-07 DE DE60042447T patent/DE60042447D1/de not_active Expired - Lifetime
- 2000-12-07 US US09/913,742 patent/US6635779B1/en not_active Expired - Lifetime
- 2000-12-15 AR ARP000106663A patent/AR027903A1/es not_active Application Discontinuation
-
2001
- 2001-08-02 ZA ZA200106367A patent/ZA200106367B/en unknown
Also Published As
Publication number | Publication date |
---|---|
DE60042447D1 (de) | 2009-08-06 |
BR0010043A (pt) | 2002-01-22 |
RU2245341C2 (ru) | 2005-01-27 |
ATE434631T1 (de) | 2009-07-15 |
KR100733755B1 (ko) | 2007-06-29 |
CN1347424A (zh) | 2002-05-01 |
EP1153047A1 (en) | 2001-11-14 |
CA2362093A1 (en) | 2001-06-21 |
PL349318A1 (en) | 2002-07-15 |
KR20010102158A (ko) | 2001-11-15 |
CN1161388C (zh) | 2004-08-11 |
US6444833B1 (en) | 2002-09-03 |
AU778205B2 (en) | 2004-11-25 |
EP1153047B1 (en) | 2009-06-24 |
WO2001044318A1 (en) | 2001-06-21 |
JP4838475B2 (ja) | 2011-12-14 |
US6635779B1 (en) | 2003-10-21 |
ZA200106367B (en) | 2002-11-04 |
JP2003517010A (ja) | 2003-05-20 |
AU3007901A (en) | 2001-06-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AR027903A1 (es) | Compuestos de metaloceno, procedimiento para su preparacion y uso en sistemas cataliticos para la polimerizacion de olefinas | |
FI980788A (fi) | Olefiinipolymeroinnin katalysaattorikomponentti, sen valmistus ja käyttö | |
ID28200A (id) | Komponen katalis untuk polimerisasi olefin | |
BR0015241B1 (pt) | processo para polimerização de olefina(s) na presença de uma sistema catalisador, sistemas catalisadores e uso de um composto catalisador. | |
BRPI0407755B1 (pt) | composiÇço catalÍtica, sua preparaÇço e uso | |
AU2003206610A1 (en) | Solid catalyst component for polymerization of olefins, catalyst comprising the same and use thereof | |
ATE194629T1 (de) | Hochlösliches aktivierungsmittel für olefinpolymerisationskatalysator | |
HUP0401513A3 (en) | High-activity isomerization catalyst and processes for its preparation and use | |
DE60135643D1 (de) | Katalysatorbestandteile zur olefinpolymerisation | |
ATE280185T1 (de) | Polymerisationskatalysatoren | |
DE69918684D1 (de) | Polymerisationskatalysatoren | |
ID23021A (id) | Komponen-komponen katalis prapolimerisasi untuk polimerisasi olefin | |
TR199600720T1 (tr) | Metalosen bilesikleri, bunlarin hazirlanmasi icin islemler ve olefinlerin polimerizasyonu icin katalizörde kullanimlari. | |
IT1273420B (it) | Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine | |
ID27764A (id) | Katalis-katalis polimerisasi | |
NO20022098L (no) | Polymerisasjonskatalysatorsystem, fremgangsmåte for fremstilling og anvendelse derav | |
DE69737776D1 (de) | Katalysatorbestandteil zur Olefinpolymerisation | |
DE60002566D1 (de) | Katalysatorsysteme | |
IL137158A0 (en) | Bridged metallocenes, preparation, and use in catalytic systems | |
BR0016134B1 (pt) | compostos, catalisador para a polimerizaÇço de olefinas e processos a preparaÇço de compostos e de um catalisador e para a polimerizaÇço de olefinas. | |
BR9802489A (pt) | Suporte para uso em sistemas de alimentação descartaveis | |
FI990140A0 (fi) | Korkea-aktiivinen olefiinipolymerointikatalysaattori, sen valmistus, katalysaattorisysteemi ja käyttö | |
DE60008248D1 (de) | Polymerisationskatalysatoren | |
AU2002212287A1 (en) | Catalyst support, production and use thereof in the polymerization of olefins | |
IT1303771B1 (it) | Catalizzatori al vanadio, loro preparazione ed uso nella (co)polimerizzazione di alfa-olefine. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FA | Abandonment or withdrawal |