PL349318A1 - Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins - Google Patents
Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefinsInfo
- Publication number
- PL349318A1 PL349318A1 PL00349318A PL34931800A PL349318A1 PL 349318 A1 PL349318 A1 PL 349318A1 PL 00349318 A PL00349318 A PL 00349318A PL 34931800 A PL34931800 A PL 34931800A PL 349318 A1 PL349318 A1 PL 349318A1
- Authority
- PL
- Poland
- Prior art keywords
- olefins
- polymerization
- preparation
- metallocene compounds
- catalytic systems
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 title 1
- 150000001875 compounds Chemical class 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
- C07D333/78—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems condensed with rings other than six-membered or with ring systems containing such rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/08—Butenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/06—Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/461,858 US6444833B1 (en) | 1999-12-15 | 1999-12-15 | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL349318A1 true PL349318A1 (en) | 2002-07-15 |
Family
ID=23834210
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL00349318A PL349318A1 (en) | 1999-12-15 | 2000-12-07 | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US6444833B1 (https=) |
| EP (1) | EP1153047B1 (https=) |
| JP (1) | JP4838475B2 (https=) |
| KR (1) | KR100733755B1 (https=) |
| CN (1) | CN1161388C (https=) |
| AR (1) | AR027903A1 (https=) |
| AT (1) | ATE434631T1 (https=) |
| AU (1) | AU778205B2 (https=) |
| BR (1) | BR0010043A (https=) |
| CA (1) | CA2362093A1 (https=) |
| DE (1) | DE60042447D1 (https=) |
| PL (1) | PL349318A1 (https=) |
| RU (1) | RU2245341C2 (https=) |
| WO (1) | WO2001044318A1 (https=) |
| ZA (1) | ZA200106367B (https=) |
Families Citing this family (104)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL188107B1 (pl) * | 1996-11-15 | 2004-12-31 | Montell Technology Company Bv | Metalocen, układ katalityczny do polimeryzacji, kationowe metaloceny, ligand oraz sposób polimeryzacji |
| BR0014616A (pt) * | 1999-09-22 | 2002-06-18 | Basell Technology Co Bv | Sistema catalìtico e processo para a polimerização de olefinas |
| US6444833B1 (en) * | 1999-12-15 | 2002-09-03 | Basell Technology Company Bv | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
| JP4358470B2 (ja) * | 1999-12-28 | 2009-11-04 | バセル テクノロジー カンパニー ビー.ブイ. | メタロセン化合物、リガンド、触媒、ポリマーの製造方法及びプロピレンホモポリマー |
| WO2002100908A1 (en) * | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| JP4332029B2 (ja) * | 2001-06-12 | 2009-09-16 | バーゼル・ポリオレフィン・ゲーエムベーハー | 1−ブテンの重合方法 |
| DE60208683T2 (de) * | 2001-08-01 | 2006-11-02 | Basell Polyolefine Gmbh | Verfahren zur herstellung von heterocyclischen pentalen derivaten |
| DE10145453A1 (de) | 2001-09-14 | 2003-06-05 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus |
| ATE412016T1 (de) * | 2001-09-14 | 2008-11-15 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von olefinen |
| US7141637B2 (en) | 2001-11-30 | 2006-11-28 | Basell Polyolefine Gmbh | Metallocene compounds and process for the preparation of propylene polymers |
| JP4062929B2 (ja) * | 2002-02-08 | 2008-03-19 | 住友化学株式会社 | 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| AU2003242663A1 (en) * | 2002-06-26 | 2004-01-19 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
| RU2308470C2 (ru) * | 2002-06-26 | 2007-10-20 | Базелль Полиолефин Италия С.П.А. | Ударопрочные полиолефиновые композиции |
| DE60329691D1 (de) * | 2002-09-06 | 2009-11-26 | Basell Polyolefine Gmbh | Verfahren zur copolymerisation von ethylen |
| US7807769B2 (en) | 2002-09-20 | 2010-10-05 | Exxonmobil Chemical Patents Inc. | Isotactic polypropylene produced from supercritical polymerization process |
| US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
| AU2003291627A1 (en) * | 2002-09-20 | 2004-04-08 | Exxonmobil Chemical Patents Inc. | Supercritical polymerization process and polymers produced therefrom |
| US7569647B2 (en) * | 2002-10-10 | 2009-08-04 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
| DE10250062A1 (de) * | 2002-10-25 | 2004-05-06 | Basell Polyolefine Gmbh | Verfahren zur racemoselektiven Darstellung von verbrückten Metallocenkomplexen mit unsubstituierten oder 2-substituierten Indenylliganden |
| US7589160B2 (en) * | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| DE60329523D1 (de) * | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
| AU2003296585A1 (en) * | 2002-12-04 | 2004-06-23 | Basell Polyolefine Gmbh | 1-buten copolymers and process for preparing them |
| DE10260095A1 (de) * | 2002-12-19 | 2004-07-01 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von heterocyclischen Ketonen |
| US6927264B2 (en) | 2003-05-28 | 2005-08-09 | Dow Global Technologies Inc. | Metal complexes and polymerization process using same |
| CN101163723B (zh) | 2003-07-04 | 2010-12-22 | 巴塞尔聚烯烃股份有限公司 | 烯烃聚合方法 |
| KR20060133960A (ko) * | 2003-09-11 | 2006-12-27 | 바젤 폴리올레핀 게엠베하 | 헤테로페이스 프로필렌 공중합체의 제조를 위한 다단계공정 |
| DE602004018516D1 (de) * | 2003-09-11 | 2009-01-29 | Basell Polyolefine Gmbh | Mehrschrittverfahren zur herstellung von heterophasigen propylencopolymeren |
| JP2007505175A (ja) * | 2003-09-11 | 2007-03-08 | バセル ポリオレフィン ジーエムビーエイチ | ヘテロ相プロピレンコポリマーを製造するための多段方法 |
| EP1564226A1 (en) | 2004-02-16 | 2005-08-17 | Stichting Dutch Polymer Institute | Titanocene-based catalyst system |
| EP1735355B1 (en) * | 2004-03-12 | 2010-09-29 | Basell Polyolefine GmbH | Process for polymerizing 1-hexene or higher alpha-olefins |
| EP1723184A1 (en) | 2004-03-12 | 2006-11-22 | Basell Polyolefine GmbH | Process for polymerizing 1-hexene or higher alpha-olefins |
| BRPI0508155A (pt) | 2004-03-12 | 2007-08-07 | Basell Polyolefine Gmbh | sistema catalìtico para a polimerização de olefinas |
| JP4897670B2 (ja) * | 2004-05-04 | 2012-03-14 | バーゼル・ポリオレフィン・ゲーエムベーハー | アタクチック1−ブテンポリマー類の製造方法 |
| DE102004027332A1 (de) | 2004-06-04 | 2005-12-22 | Basell Polyolefine Gmbh | Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
| DE602005010255D1 (de) | 2004-07-08 | 2008-11-20 | Exxonmobil Chem Patents Inc | Katalysator system für die olefinpolymerisation und verfahren zu seiner verwendung |
| WO2006005648A1 (en) | 2004-07-13 | 2006-01-19 | Basell Polyolefine Gmbh | Metallocene compounds, ligands used in their preparation, preparation of 1-butene polymers and 1-butene polymers therefrom |
| EP1769009A1 (en) * | 2004-07-22 | 2007-04-04 | Basell Polyolefine GmbH | Process for producing fractionable 1-butene polymers |
| CA2573975A1 (en) * | 2004-07-22 | 2006-01-26 | Basell Polyolefine Gmbh | 1-butene polymers composition |
| ATE501183T1 (de) * | 2004-10-21 | 2011-03-15 | Basell Polyolefine Gmbh | 1-buten-polymer und herstellungsverfahren dafür |
| EP1655314A1 (en) * | 2004-11-09 | 2006-05-10 | Basell Polyolefine GmbH | Process for the preparation of 1-butene/propylene copolymers |
| JP2008519151A (ja) * | 2004-11-09 | 2008-06-05 | バーゼル・ポリオレフィン・ゲーエムベーハー | 1−ブテン/プロピレンコポリマーの製造方法 |
| DE102004056104A1 (de) * | 2004-11-19 | 2006-05-24 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von niedermolekularen Olefinpolymeren, Organoübergangsmetallverbindungen, Biscyclopentadienylligandsysteme und Katalysatorsysteme |
| EP1814922A1 (en) * | 2004-11-22 | 2007-08-08 | Basell Polyolefine GmbH | Propylene based terpolymers |
| JP2008523231A (ja) * | 2004-12-13 | 2008-07-03 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ポリオレフィン繊維 |
| CN101087905B (zh) * | 2004-12-23 | 2010-12-15 | 巴塞尔聚烯烃意大利有限责任公司 | 具有弹性的纤维 |
| KR100753477B1 (ko) | 2005-01-31 | 2007-08-31 | 주식회사 엘지화학 | 혼합 담지 메탈로센 촉매, 그 제조방법 및 이를 이용하여제조된 폴리올레핀 및 그 제조 방법 |
| KR101293405B1 (ko) * | 2005-03-18 | 2013-08-05 | 바젤 폴리올레핀 게엠베하 | 메탈로센 화합물 |
| EP1858934B1 (en) * | 2005-03-18 | 2013-04-24 | Basell Polyolefine GmbH | Metallocene compounds |
| WO2006100258A1 (en) * | 2005-03-23 | 2006-09-28 | Basell Polyolefine Gmbh | Process for the polymerization of olefins |
| US7728086B2 (en) * | 2005-03-23 | 2010-06-01 | Basell Polyolefine Gmbh | Process for the polymerization of olefins |
| US7964679B2 (en) * | 2005-05-03 | 2011-06-21 | Basell Poliolefine Italia S.R.L. | Process for the polymerization of alpha olefins |
| EP1879959B1 (en) | 2005-05-11 | 2011-07-06 | Basell Poliolefine Italia S.r.l. | Polymerization process for preparing polyolefin blends |
| EP1902062B1 (en) * | 2005-06-30 | 2012-06-13 | Basell Polyolefine GmbH | Metallocene compounds |
| US8097681B2 (en) * | 2006-08-30 | 2012-01-17 | Basell Polyolefine Gmbh | 1-butene propylene copolymer compositions |
| KR101423946B1 (ko) * | 2006-08-30 | 2014-08-01 | 바젤 폴리올레핀 게엠베하 | 1-부텐 프로필렌 공중합체 조성물 |
| US8242237B2 (en) * | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
| US8143352B2 (en) | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
| US8080610B2 (en) | 2007-03-06 | 2011-12-20 | Exxonmobil Research And Engineering Company | Monomer recycle process for fluid phase in-line blending of polymers |
| JP2010529253A (ja) | 2007-06-04 | 2010-08-26 | エクソンモービル・ケミカル・パテンツ・インク | 非常に均一なプロピレンの溶液重合法 |
| DE102007036792A1 (de) * | 2007-08-03 | 2009-02-05 | Clariant International Limited | Hochkristalline Polypropylenwachse |
| CN101855249B (zh) | 2007-09-13 | 2013-02-13 | 埃克森美孚研究工程公司 | 在线生产增塑聚合物和增塑聚合物共混物的方法 |
| US7910637B2 (en) | 2007-09-13 | 2011-03-22 | Exxonmobil Research And Engineering Company | In-line blending of plasticizers with a base polymer |
| US8436114B2 (en) | 2010-10-21 | 2013-05-07 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
| US8431661B2 (en) | 2010-10-21 | 2013-04-30 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
| US7910679B2 (en) | 2007-12-20 | 2011-03-22 | Exxonmobil Research And Engineering Company | Bulk homogeneous polymerization process for ethylene propylene copolymers |
| CN103254513B (zh) | 2007-12-20 | 2015-08-26 | 埃克森美孚研究工程公司 | 全同立构聚丙烯和乙烯-丙烯共聚物的共混物 |
| EP2231779B1 (en) | 2007-12-20 | 2012-06-06 | ExxonMobil Research and Engineering Company | In-line process to produce pellet-stable polyolefins |
| US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| BRPI0908411B1 (pt) * | 2008-02-29 | 2018-10-30 | Basell Poliolefine Italia Srl | composições de poliolefinas |
| EP2559713B1 (en) | 2010-04-12 | 2016-08-10 | Lotte Chemical Corporation | Method for preparing polypropylene using a transition metal compound containing thiophene-fused cyclopentadienyl ligands |
| KR100986301B1 (ko) | 2010-04-12 | 2010-10-07 | 아주대학교산학협력단 | 테트라하이드로퀴놀린 유도체로부터 유래한 티오펜-축합고리 싸이클로펜타디에닐 4족 금속 화합물 및 이를 이용한 올레핀 중합 |
| US9062025B2 (en) | 2010-04-12 | 2015-06-23 | Lotte Chemical Corporation | Supported catalyst for olefin polymerization and preparation method for polyolefin using the same |
| EP2559714B1 (en) | 2010-04-12 | 2016-08-10 | Lotte Chemical Corporation | Method for preparing olefin-diene copolymer using transition metal compound including thiophene-condensed ring cyclopentadienyl ligand |
| JP5567208B2 (ja) | 2010-04-12 | 2014-08-06 | ロッテ ケミカル コーポレーション | オレフィン重合用触媒組成物およびこれを用いたポリオレフィンの製造方法 |
| WO2012096698A2 (en) * | 2010-10-21 | 2012-07-19 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
| US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
| EP3022238B1 (en) | 2013-07-17 | 2017-09-20 | ExxonMobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| EP3848401A1 (en) | 2013-07-17 | 2021-07-14 | ExxonMobil Chemical Patents Inc. | Isotactic propylene polymers |
| ES2703344T3 (es) | 2013-07-17 | 2019-03-08 | Exxonmobil Chemical Patents Inc | Metalocenos y composiciones catalíticas derivadas de ellos |
| US9834628B2 (en) | 2013-07-17 | 2017-12-05 | Exxonmobil Chemical Patents Inc. | Cyclopropyl substituted metallocene catalysts |
| JP2016531978A (ja) | 2013-07-17 | 2016-10-13 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 置換メタロセン触媒 |
| CN104558058B (zh) * | 2013-10-12 | 2017-08-08 | 中国科学院长春应用化学研究所 | 茂金属配合物及其制备方法、催化剂组合物 |
| US9321854B2 (en) | 2013-10-29 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Aluminum alkyl with C5 cyclic and pendent olefin polymerization catalyst |
| WO2015065784A1 (en) * | 2013-10-29 | 2015-05-07 | Exxonmobil Chemical Patents Inc. | Novel aluminum alkyl with c5 cyclic and pendent olefin polymerization catalyst |
| US10329360B2 (en) | 2015-06-05 | 2019-06-25 | Exxonmobil Chemical Patents Inc. | Catalyst system comprising supported alumoxane and unsupported alumoxane particles |
| US10294316B2 (en) | 2015-06-05 | 2019-05-21 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
| US10570219B2 (en) | 2015-06-05 | 2020-02-25 | Exxonmobil Chemical Patents Inc. | Production of heterophasic polymers in gas or slurry phase |
| US10280235B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers |
| WO2016196334A1 (en) | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Single reactor production of polymers in gas or slurry phase |
| US9809664B2 (en) | 2015-06-05 | 2017-11-07 | Exxonmobil Chemical Patents Inc. | Bimodal propylene polymers and sequential polymerization |
| US10280233B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst systems and methods of making and using the same |
| WO2016196331A1 (en) | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Supported metallocene catalyst systems for polymerization |
| EP3424937B1 (en) * | 2016-03-04 | 2020-06-10 | Japan Polyethylene Corporation | Metallocene compound, catalyst component for olefin polymerization including same, catalyst for olefin polymerization including metallocene compound, and method for producing olefin polymer by using catalyst for olefin polymerization |
| US11059918B2 (en) | 2016-05-27 | 2021-07-13 | Exxonmobil Chemical Patents Inc. | Metallocene catalyst compositions and polymerization process therewith |
| EP3694811B1 (en) | 2017-10-11 | 2024-04-03 | Basell Polyolefine GmbH | Supported catalyst system |
| CN110655623A (zh) * | 2019-09-19 | 2020-01-07 | 天津大学 | 采用链穿梭聚合的方法制备无规聚丙烯-等规聚丙烯立构嵌段聚合物 |
| US11472828B2 (en) | 2019-10-11 | 2022-10-18 | Exxonmobil Chemical Patents Inc. | Indacene based metallocene catalysts useful in the production of propylene polymers |
| JP7676863B2 (ja) * | 2020-03-24 | 2025-05-15 | 日本ポリプロ株式会社 | オレフィン重合用担持系触媒、及び、当該オレフィン重合用担持系触媒を用いたプロピレン系重合体の製造方法 |
| CN114702532B (zh) * | 2021-01-01 | 2024-08-06 | 中国石油化工股份有限公司 | 一种茂金属、含有其的催化剂及其合成和应用 |
| CN116410238B (zh) * | 2021-12-31 | 2026-01-20 | 中国石油天然气股份有限公司 | 含硫手性桥联茂金属化合物及其制备和应用 |
| CN116410385B (zh) * | 2021-12-31 | 2025-11-18 | 中国石油天然气股份有限公司 | 一种聚烯烃弹性体及其制备方法与所用茂金属催化剂 |
| CN114507305A (zh) * | 2022-01-27 | 2022-05-17 | 吉林大学 | 一种茂锆型烯烃聚合催化剂的合成方法 |
| EP4501975A4 (en) | 2022-03-24 | 2025-08-06 | Japan Polypropylene Corp | PROPYLENE-BASED BRANCHED POLYMER |
| CN116948069A (zh) * | 2022-04-15 | 2023-10-27 | 中国石油天然气股份有限公司 | 一种高熔指聚丙烯的制备方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| JP3293927B2 (ja) | 1993-02-19 | 2002-06-17 | 三菱化学株式会社 | α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法 |
| PL188107B1 (pl) | 1996-11-15 | 2004-12-31 | Montell Technology Company Bv | Metalocen, układ katalityczny do polimeryzacji, kationowe metaloceny, ligand oraz sposób polimeryzacji |
| US6559252B1 (en) | 1997-10-29 | 2003-05-06 | Basell Technology Company Bv | Catalysts and processes for the polymerization of olefins |
| AU1870999A (en) * | 1997-11-12 | 1999-05-31 | Montell Technology Company B.V. | Metallocenes and catalysts for olefin-polymerisation |
| DE19804970A1 (de) * | 1998-02-07 | 1999-08-12 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem |
| EP1074557A3 (de) * | 1999-07-31 | 2003-02-26 | Basell Polyolefine GmbH | Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen |
| US6444833B1 (en) * | 1999-12-15 | 2002-09-03 | Basell Technology Company Bv | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
-
1999
- 1999-12-15 US US09/461,858 patent/US6444833B1/en not_active Expired - Lifetime
-
2000
- 2000-12-07 JP JP2001544805A patent/JP4838475B2/ja not_active Expired - Fee Related
- 2000-12-07 CA CA002362093A patent/CA2362093A1/en not_active Abandoned
- 2000-12-07 CN CNB008062439A patent/CN1161388C/zh not_active Expired - Fee Related
- 2000-12-07 DE DE60042447T patent/DE60042447D1/de not_active Expired - Lifetime
- 2000-12-07 WO PCT/EP2000/012406 patent/WO2001044318A1/en not_active Ceased
- 2000-12-07 BR BR0010043-9A patent/BR0010043A/pt not_active Application Discontinuation
- 2000-12-07 US US09/913,742 patent/US6635779B1/en not_active Expired - Lifetime
- 2000-12-07 KR KR1020017010350A patent/KR100733755B1/ko not_active Expired - Fee Related
- 2000-12-07 EP EP00990680A patent/EP1153047B1/en not_active Expired - Lifetime
- 2000-12-07 AU AU30079/01A patent/AU778205B2/en not_active Ceased
- 2000-12-07 AT AT00990680T patent/ATE434631T1/de not_active IP Right Cessation
- 2000-12-07 PL PL00349318A patent/PL349318A1/xx not_active Application Discontinuation
- 2000-12-07 RU RU2001125425/04A patent/RU2245341C2/ru not_active IP Right Cessation
- 2000-12-15 AR ARP000106663A patent/AR027903A1/es not_active Application Discontinuation
-
2001
- 2001-08-02 ZA ZA200106367A patent/ZA200106367B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US6635779B1 (en) | 2003-10-21 |
| KR100733755B1 (ko) | 2007-06-29 |
| WO2001044318A1 (en) | 2001-06-21 |
| JP4838475B2 (ja) | 2011-12-14 |
| ATE434631T1 (de) | 2009-07-15 |
| US6444833B1 (en) | 2002-09-03 |
| ZA200106367B (en) | 2002-11-04 |
| EP1153047B1 (en) | 2009-06-24 |
| RU2245341C2 (ru) | 2005-01-27 |
| CN1347424A (zh) | 2002-05-01 |
| AU3007901A (en) | 2001-06-25 |
| AR027903A1 (es) | 2003-04-16 |
| EP1153047A1 (en) | 2001-11-14 |
| CA2362093A1 (en) | 2001-06-21 |
| CN1161388C (zh) | 2004-08-11 |
| KR20010102158A (ko) | 2001-11-15 |
| JP2003517010A (ja) | 2003-05-20 |
| BR0010043A (pt) | 2002-01-22 |
| DE60042447D1 (de) | 2009-08-06 |
| AU778205B2 (en) | 2004-11-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| PL349318A1 (en) | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins | |
| FI963759L (fi) | Metalloseeniyhdisteitä, menetelmä niiden valmistamiseksi ja niiden käyttö olefiinien polymerointiin tarkoitetuissa katalyyteissä | |
| AU7288200A (en) | Catalyst system and process for the polymerization of olefins | |
| AU3334299A (en) | Olefin polymerization catalyst component, its preparation and use | |
| HUP0103083A3 (en) | Components and catalysts for the polymerization of olefins | |
| IL95549A0 (en) | Metallocene compounds,processes for the preparation thereof and catalyst systems for olefin polymerization utilizing the same | |
| ZA943595B (en) | Supported metallocene catalyst systems for the polymerization of olefins preparation and use thereof | |
| PL356214A1 (en) | Transition metal compound, ligand system, catalyst system and the use of the latter for the polymerisation and copolymerisation of olefins | |
| ITMI940645A0 (it) | Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine | |
| SG88774A1 (en) | Ethylene/alpha-olefin copolymer, method for producing the same, and use thereof | |
| ZA200007040B (en) | Catalyst modifiers and their use in the polymerization of olefin(s). | |
| HUP0001325A3 (en) | Catalysts and process for the polymerization of olefins | |
| HUP0203425A3 (en) | Quinazoline derivatives, process for their preparation and their use | |
| ZA97766B (en) | Heteroatom substituted metallocene compounds for olefin polymerization catalyst systems and methods for preparing thereof. | |
| AU2184600A (en) | Olefin polymerization catalysts, their production and use | |
| ZA200300068B (en) | Catalyst and process for the preparation of hydrocarbons. | |
| SG91813A1 (en) | Olefin polymerization catalyst and polymerization process | |
| SG87786A1 (en) | Ethylene/alpha-olefin copolymer and process for preparing the same | |
| HUP0203866A3 (en) | Polymerization process, composition and catalyst | |
| IL137158A0 (en) | Bridged metallocenes, preparation, and use in catalytic systems | |
| AU9464198A (en) | Supported metallocene catalyst, process for preparing the same, and process for producing olefin polymers | |
| AU2003202834A1 (en) | Solid catalytic component and catalytic system of the ziegler-natta type, process for their preparation and their use in the polymerisation of alk-1-enes | |
| AU1778799A (en) | Catalyst, process for its preparation, and its use in the synthesis of 1,2-dichloroethane | |
| AU4932999A (en) | Mu-oxobismetallocene complexes, catalyst for olefin polymerization containing the same, and polymerization method | |
| EA199900265A3 (ru) | Способ получения катализатора циглера-натта для полимеризации альфа-олефинов в растворе |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| REFS | Decisions on refusal to grant patents (taken after the publication of the particulars of the applications) |