JPS6249261B2 - - Google Patents
Info
- Publication number
- JPS6249261B2 JPS6249261B2 JP54070511A JP7051179A JPS6249261B2 JP S6249261 B2 JPS6249261 B2 JP S6249261B2 JP 54070511 A JP54070511 A JP 54070511A JP 7051179 A JP7051179 A JP 7051179A JP S6249261 B2 JPS6249261 B2 JP S6249261B2
- Authority
- JP
- Japan
- Prior art keywords
- nitrophthalic acid
- nitrophthalic
- acid
- separating
- base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- KFIRODWJCYBBHY-UHFFFAOYSA-N 3-nitrophthalic acid Chemical compound OC(=O)C1=CC=CC([N+]([O-])=O)=C1C(O)=O KFIRODWJCYBBHY-UHFFFAOYSA-N 0.000 claims abstract description 51
- SLBQXWXKPNIVSQ-UHFFFAOYSA-N 4-nitrophthalic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1C(O)=O SLBQXWXKPNIVSQ-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000000203 mixture Substances 0.000 claims abstract description 40
- 238000000034 method Methods 0.000 claims abstract description 32
- 239000002253 acid Substances 0.000 claims abstract description 17
- 150000003839 salts Chemical class 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 150000007522 mineralic acids Chemical group 0.000 claims abstract description 8
- 230000001376 precipitating effect Effects 0.000 claims abstract description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 20
- 239000002585 base Substances 0.000 claims description 20
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 15
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 10
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000000926 separation method Methods 0.000 claims description 9
- 238000006396 nitration reaction Methods 0.000 claims description 8
- -1 phthalic acid compound Chemical class 0.000 claims description 6
- 239000003495 polar organic solvent Substances 0.000 claims description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 5
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims description 3
- 125000005907 alkyl ester group Chemical group 0.000 claims description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 150000007529 inorganic bases Chemical class 0.000 claims description 2
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 2
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 2
- 239000011736 potassium bicarbonate Substances 0.000 claims description 2
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 2
- SLBQXWXKPNIVSQ-UHFFFAOYSA-L 4-nitrophthalate Chemical compound [O-]C(=O)C1=CC=C([N+]([O-])=O)C=C1C([O-])=O SLBQXWXKPNIVSQ-UHFFFAOYSA-L 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims 1
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 claims 1
- 229940086066 potassium hydrogencarbonate Drugs 0.000 claims 1
- 150000007513 acids Chemical class 0.000 abstract description 6
- 239000012429 reaction media Substances 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 8
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 7
- 238000002844 melting Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000007810 chemical reaction solvent Substances 0.000 description 6
- ZNAJNWHTCZMHMD-UHFFFAOYSA-M sodium;2-carboxy-3-nitrobenzoate Chemical compound [Na+].OC(=O)C1=C(C([O-])=O)C=CC=C1[N+]([O-])=O ZNAJNWHTCZMHMD-UHFFFAOYSA-M 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical class [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 4
- 239000012452 mother liquor Substances 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- ZTQDMERNJVPDBN-UHFFFAOYSA-M sodium;2-carboxy-5-nitrobenzoate Chemical compound [Na+].OC(=O)C1=CC=C([N+]([O-])=O)C=C1C([O-])=O ZTQDMERNJVPDBN-UHFFFAOYSA-M 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 150000008064 anhydrides Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- YLHUPYSUKYAIBW-UHFFFAOYSA-N 1-acetylpyrrolidin-2-one Chemical compound CC(=O)N1CCCC1=O YLHUPYSUKYAIBW-UHFFFAOYSA-N 0.000 description 1
- ROFZMKDROVBLNY-UHFFFAOYSA-N 4-nitro-2-benzofuran-1,3-dione Chemical compound [O-][N+](=O)C1=CC=CC2=C1C(=O)OC2=O ROFZMKDROVBLNY-UHFFFAOYSA-N 0.000 description 1
- MMVIDXVHQANYAE-UHFFFAOYSA-N 5-nitro-2-benzofuran-1,3-dione Chemical compound [O-][N+](=O)C1=CC=C2C(=O)OC(=O)C2=C1 MMVIDXVHQANYAE-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- ZIXLDMFVRPABBX-UHFFFAOYSA-N alpha-methylcyclopentanone Natural products CC1CCCC1=O ZIXLDMFVRPABBX-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 description 1
- 150000001983 dialkylethers Chemical class 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000006053 organic reaction Methods 0.000 description 1
- 150000003022 phthalic acids Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000004809 thin layer chromatography Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/06—Preparation of nitro compounds
- C07C201/16—Separation; Purification; Stabilisation; Use of additives
Description
æ¬çºæã¯ãïŒâåã³ïŒâããããã¿ã«é
žæ··åç©
ã®æ°èŠåé¢æ¹æ³ã«é¢ãããã®ã§ããã ïŒâåã³ïŒâããããã¿ã«é žã¯ãé¡æãææå
ã³å¯å¡å€ãç¹ã«PVCãããªãšã¹ãã«ãããªã¢ã
ããããããã蟲æ¥çšæŽ»æ§ç©è³ªçããã€ãåœç¹èš±
æ现æžç¬¬824815å·ã第935964å·åã³ç¬¬936944å·ïŒ
ç±³åœç¹èš±æ现æžç¬¬2412817å·åã³ç¬¬2491455å·ïŒã±
ãã«ã«ã¢ãã¹ãã©ã¯ãïŒCAïŒã第47å·»9303d
ïŒ1953幎ïŒã第53å·»11290fïŒ1959幎ïŒã第66å·»
116023bïŒ1967幎ïŒã第69å·»107329råã³170330i
ïŒ1968幎ïŒãåç §ããã®éåžžã«å€çšãªèªå°äœã補é
ããããã®ç£æ¥äžéèŠãªäžéäœã§ãããããçã¯
äžè¬ã«ãç¡æ°Žãã¿ã«é žãæ¿ç¡«é žãçšããŠãããã
åããããšã«ãã€ãŠè£œé ãããããã®æ¹æ³ã«ãã
ãšãç°ãªãå²åã®ïŒâåã³ïŒâããããã¿ã«é žã
æããç°æ§äœæ··åç©ã圢æãããã è³éŠæããªã«ã«ãã³é žã®ç°æ§äœæ··åç©ãåé¢ã
ãããã®åŸæ¥å ¬ç¥ã®æ段ã¯ãäŸãã°ã¯ãããã°ã©
ãã€ãŒæ³ã®ããã«å Žåã«ãã€ãŠã¯ãããè€éãã
ãŠãå·¥æ¥çã«å€§èŠæš¡ã«å®æœããã«ã¯äžé©åœã§ã
ããåããçã®æ¹æ³ã«ãã€ãŠç®çã®ç°æ§äœãå®å š
ã«åé¢ããã®ã¯ãããããã ç±³åœç¹èš±æ现æžç¬¬2412817å·ã«ããã°ãïŒâå
ã³ïŒâããããã¿ã«é žã®æ··åç©ãã宀枩ã§æ°Žã«æž
æ¿ããŠæ¹æããç¶ããŠäžæº¶ç¶æ ã§ååšããïŒâã
ãããã¿ã«é žãæ¿Ÿåããããšã«ããåé¢ã§ããã
ïŒâããããã¿ã«é žã¯ç¢ºãã«ïŒâããããã¿ã«é ž
ããæ°Žã«å¯Ÿãã溶解æ§ãäœãããããæ°Žã«å šã溶
解ããªãããã§ã¯ãªãããããã€ãŠããã®æ¹æ³ã«
ãã€ãŠå®å šã«çŽç²ãªç°æ§äœã«åé¢ããããšã¯äžå¯
èœã§ããã ç±³åœç¹èš±æ现æžç¬¬3098095å·ã«å°ãªããšãïŒæ¹
ã¯ãç°äžã«ããïŒã€å¥ã®çœ®æåºããã€ãé žç¡æ°Žç©
圢ææ§è³éŠæããªã«ã«ãã³é žã®æ··åç©ããšãåã
ïŒâåã³ïŒâããããã¿ã«é žã®æ··åç©ã®åé¢æ¹æ³
ãé瀺ãããŠããããã®æ¹æ³ã§ã¯ãé žæ··åç©ãé©
åœãªæº¶åªäžã§ãè±æ°Žæž©åºŠã®äœãã«ã«ãã³é žã®ã«ã«
ãã³é žç¡æ°Žç©ãäž»ãšããŠåœ¢æãããŠãã枩床ãŸã§
å ç±ããäžæ¹ãä»æ¹ã®ã«ã«ãã³é žã®è±æ°Žçããã§
ããã ãäœãä¿ã€ãç¶ããŠäŸãã°é žç¡æ°Žç©ã«å¯ã
ãã©ã¯ã·ãšã³ã®æº¶åªæœåºãªã©ã«ãããé žç¡æ°Žç©å
ã³é žã«å¯ããã©ã¯ã·ãšã³ãã倫ã åé¢ããããã®
æ¹æ³ããŸããçŽç²ç°æ§äœã®å€§èŠæš¡ãªå·¥æ¥çç£ã«ã¯
äžé©åœã§ãããããã®çç±ã¯é«ãè±æ°Žæž©åºŠç¯å²ã
æããã«ã«ãã³é žã®ç¡æ°Žç©ãããªãåŸãããŠããŸ
ãããã§ãããåŸã€ãŠãäŸãã°ïŒâåã³ïŒâãã
ããã¿ã«é žã®å Žåã«ã¯ãé žç¡æ°Žç©ã«å¯ããã©ã¯ã·
ãšã³ã«ãäž»æåãšããŠã®ïŒâããããã¿ã«é žç¡æ°Ž
ç©ã®ä»ã«ïŒâããããã¿ã«é žç¡æ°Žç©ãçŽ8.5ïŒ å«
æãããŠããŸããæŽã«ããã®åå¿ã¯é«ã枩床ïŒçŽ
110â180âïŒããã³éåžžã«åžèãªç³»ã«ãããŠè¡ã
ãªããã°ãªããããããã®å åã®ããã«ãã®åå¿
ã®çµæžçå¹çã¯äœãã ãããã€ãŠãæ¬çºæã®ç®çã¯ãç°¡åãã€çµæžç
ã«ãããé«åçã§ïŒâåã³ïŒâããããã¿ã«é žã®
æ··åç©ãåç°æ§äœã«å®å šã«åé¢ã§ããæŽã«å€§èŠæš¡
ãªå·¥æ¥çç£ã«é©ããæ°èŠåé¢æ¹æ³ãæäŸããããš
ã§ããã ïŒâåã³ïŒâããããã¿ã«é žã®æ··åç©ãåé¢ã
ãããã®æ¬çºæã®æ¹æ³ã¯ãæ°ŽãïŒãªãã20容é
ïŒ ã奜ãŸããã¯ïŒãªãã10容éïŒ å«æããäžæŽ»æ§
ãªæ¥µæ§ææ©æº¶åªäžã§ããã¿ã«é žååç©ã®ãããå
åå¿ç±æ¥ã®ç¡æ©é žæ®åºãå«ãŸãªãïŒâåã³ïŒâã
ãããã¿ã«é žæ··åç©ã«ã20âãã100âã®éã®æž©
床ã§ããŸãã該åå¿æº¶åªã«å®è³ªçã«äžæº¶ãªïŒâå
ã³ïŒâããããã¿ã«é žå¡©ã圢æãããå¡©åºããPH
ãçŽ2.8ãšãªããŸã§å ããããšã«ãã€ãŠäž»ã«ïŒâ
ããããã¿ã«é žã¢ãå¡©ãããªãæ²æŸ±çæç©ãåé¢
ãããã®åŸæŽã«äžèšç¯å²ã®æž©åºŠã§äžèšå¡©åºãPHã
å°ãªããšãçŽ4.5ã«ãªããŸã§å ããããšã«ããäž»
ã«ïŒâããããã¿ã«é žå¡©ããæãçæç©ãæ²æ®¿ã
ããããšãããªã段éçãªå¡©åºåŠçãè¡ãªããæ
åŸã«ãåŸãããããããã¿ã«é žå¡©ãå¥ã ã«çžåœã
ãéé¢é žã«å€æãããããŠå Žåã«ãã€ãŠã¯ããç
ã粟補ããããšã«ããæãã æ¬çºæã®åé¢æ¹æ³ã«äœ¿çšãããææ©æº¶åªã¯ãäž
掻æ§ã®æ¥µæ§ææ©æº¶åªã§ãããç¹ã«å®€æž©ã§å€å°ã®äœ
ãäžå®éçéãŸã§ã®æ°Žã溶解ãåŸããã®ã§ããã
é©åœãªæº¶åªäŸãšããŠã¯ã¢ã»ãã³ãã¡ãã«ãšãã«ã±
ãã³ãã·ã¯ããã³ã¿ãã³åã³ã·ã¯ããããµãã³ã®
ãããªèèªæåã³èç°åŒã±ãã³ïŒããã©ãããã
ã©ã³ãããã©ããããã©ã³åã³ãžãªããµã³ã®ãã
ãªç°ç¶ãšãŒãã«ïŒïŒ®âã¡ãã«âïŒâãããªãã³ã
âã¢ã»ãã«âïŒâãããªãã³åã³ïŒ®âã¡ãã«â
εâã«ããã©ã¯ã¿ã ã®ãããªç°ç¶ã¢ããïŒãšãã¬
ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ããšãã¬ã³ã°ãª
ã³ãŒã«ã¢ããšãã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒã«
ã¢ãã€ãœãããã«ãšãŒãã«åã³ãšãã¬ã³ã°ãªã³ãŒ
ã«ã¢ãâïœâããã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒ
ã«ãžã¡ãã«ãšãŒãã«åã³ãšãã¬ã³ã°ãªã³ãŒã«ãžãš
ãã«ãšãŒãã«ãªã©ã®ãããªåã¢ã«ãã«éšã®ççŽ å
åæ°ãïŒãªããïŒã®ãšãã¬ã³ã°ãªã³ãŒã«ã¢ãâå
ã³ãžã¢ã«ãã«ãšãŒãã«ïŒã®é žåã¯é ¢é žã®ã¡ãã«ãš
ã¹ãã«ãã®é žåã¯é ¢é žã®ãšãã«ãšã¹ãã«ãåã³ã®
é žåã¯é ¢é žã®ïœâããã«ãšã¹ãã«ãªã©ã®ãããªç·
ççŽ ååæ°ã®ïŒãªããïŒã®èèªæã¢ãã«ã«ãã³é ž
ã®ã¢ã«ãã«ãšã¹ãã«ïŒã¡ã¿ããŒã«ããšã¿ããŒã«ã
ãããããŒã«ãã€ãœãããããŒã«ããã¿ããŒã«å
ã³ãã³ã¿ããŒã«ã®ãããªççŽ ååæ°ïŒãªããïŒã®
èèªæã¢ã«ã³ãŒã«ïŒãªã©ãæããããã 奜ãŸãã溶åªã¯åèšã®ã¢ã«ãã«ãšã¹ãã«åã³è
èªæã±ãã³ãç¹ã«é ¢é žãšãã«ãšã¹ãã«æãã¯ã¡ã
ã«ãšãã«ã±ãã³ã§ããã æ¬çºæã®æ¹æ³ã«äœ¿çšããå¡©åºãšããŠã¯ãåå¿æº¶
åªäžã«ãããŠïŒâåã³ïŒâããããã¿ã«é žãšå€«ã
溶åªãã«ããå¡©ãããã³äžæŽ»æ§ã®å¡©ã圢æãåŸã
ææ©æãã¯ç¡æ©ååç©ãªããããã䜿çšããããš
ãã§ãããç¡æ©å¡©åºã奜ãŸããç¹ã«ãããªãŠã ã
ã«ãªãŠã ããã°ãã·ãŠã ãã«ã«ã·ãŠã ãªã©ã®ãã
ãªã¢ã«ã«ãªéå±åã³ã¢ã«ã«ãªåé¡éå±ã®æ°Žé žå
ç©ãçé žå¡©åã³çé žæ°ŽçŽ å¡©ã䜿çšããããçé žæ°Ž
çŽ ãããªãŠã ãšçé žæ°ŽçŽ ã«ãªãŠã ãç¹ã«å¥œãŸã
ãã å¡©çæã®ããã®åå¿æž©åºŠã¯çŽ30ãã50âã®éã
奜ãŸããã åèšã®ãšãããæåã®æ®µéã§å¡©åºã¯PHãçŽ2.8
ãšãªããŸã§å ããããããŠãã®éã«äŸç¶ãšããŠåŸ®
éã®ïŒâããããã¿ã«é žã¢ãå¡©ãå«æããïŒâã
ãããã¿ã«é žã¢ãå¡©ãäž»ã«åœ¢æããããçŽ2.8ã®
PHå€ã¯ãåœéããå ãã«å°ãªãå¡©åºã奜ãŸããã¯
åºçºæ··åç©ã«ååšããå šãŠã®ïŒâããããã¿ã«é ž
ããã¢ãå¡©ãšããŠæ²æ®¿ãããã«å¿ èŠãªçè«éã«å¯Ÿ
ããŠçŽ90ãªãã95ïŒ ã®å¡©åºãå ããããšã«ãã€ãŠ
åŸãããã å Žåã«ãã€ãŠã¯ãæ®äœã®ïŒâããããã¿ã«é žã
ã¢ãå¡©ã®åœ¢ã§æ²æ®¿ãããã«å¿ èŠãªçè«éã«éãã
ãŸã§å¡©åºãæŽã«å ããããšã«ãã€ãŠãPHãçŽ3.4
ã«äžããããšãã§ããããã«ãã€ãŠäž»ã«ïŒâç°æ§
äœããæãå°éã®ããããã¿ã«é žã¢ãå¡©ãåã³æ²
殿ããããã®äžéçæç©ã®ãã©ã¯ã·ãšã³ã¯å ã®ã
ã©ã¯ã·ãšã³ãšäžç·ã«ããŠãè¯ãããã®ãŸãŸå ã®å
é¢æäœã«é²ããããšãã§ããã äž»ã«ïŒâããããã¿ã«é žãããªãæ®äœã®ããã
ãã¿ã«é žãå¡©ã®åœ¢ã§æ²æ®¿ãããããã«ãå ããå¡©
åºã¯ãå³å¯ã§ãªãããã®æ®µéã§ã¯çŽ4.5ã®PHå€ã
åŸããããŸã§å¡©åºãå ãããåã¯æ®äœã®ãããã
ã¿ã«é žãå šãŠã¢ãå¡©ãšããŠæ²æ®¿ãããããšãã§ã
ãå®è³ªçååŠéè«éãå ããã塩圢æçµäºåŸæ®ã€
ãæ°Žæ§ææ©åå¿æº¶åªã¯ååãšããŠäœãåŠçããã«
çŽæ¥æ¬¡åã®åå¿ã«äœ¿çšããããšãã§ããããã®äº
ã¯ã第ïŒæ®µéã§å¡©åºãåœéããå°ãªã䜿çšããå Ž
åãæãã¯éå°ã«çšããå ŽåããããŠåå¿æº¶åªã
ãªãæ®äœããããã¿ã«é žåã¯æªåå¿å¡©åºãå«æã
ãŠããå Žåã«ãåæ§ã«å¯èœã§ãããæ°ããåºçºç°
æ§äœæ··åç©ããã³å¿ èŠãªãã°å¡©åºãããã«å ãã
å Žåãæåã®åå¿æ®µéã«ãããPHçŽ2.8ã®å€ãè¶
ããªãããã«ããå¿ èŠãªãã°åå¿æº¶åªã®æ°Žå«éã
調æŽããç¹ã«çæããã ãã§ããã ããããæ¬çºæã®æ¹æ³ã¯ãé£ç¶åã¯åé£ç¶çæ
äœã«ãéåžžã«é©ããã æ¬çºæã®æ¹æ³ã«ããåé¢ãã¹ãïŒâããããã¿
ã«é žãšïŒâããããã¿ã«é žãããªãåºçºç°æ§äœæ··
åç©äžã«ã該ç°æ§äœä»¥å€ã®é žã®æ®åºãå«ãŸããŠã
ããšã該ç°æ§äœãšäžç·ã«æ²æŸ±ããŠããŸããåç°æ§
äœãçŽç²ãªåœ¢ã§åŸãããªããããåºçºç°æ§äœæ··å
ç©äžã«ã¯è©²ç°æ§äœä»¥å€ã®é žã®æ®åºãå«ãŸããŠããŠ
ã¯ãªããªããæ¬çºæã®æ¹æ³ã«ããåé¢ãã¹ããã
ããã¿ã«é žã®è£œé ã¯ãçžåœãããã¿ã«é žã®ããã
åã«ããè¡ãªããããããåŸãããããããã¿ã«
é žã®ç°æ§äœæ··åç©äžã«ã¯ããããåã«é垞䜿çšã
ããæ¿ç¡«é žåã³æ¿ç¡é žã®æ®åºãååšãããåŸã€
ãŠãåºçºç°æ§äœæ··åç©äžã®ç¡æ©é žæ®åºãšããŠã¯ã
äž»ã«ãããã®æ¿ç¡«é žåã³æ¿ç¡é žã®æ®åºãåé¡ãšãª
ããåé¢ãè¡ãªãåã«ãããã®ç¡æ©é žæ®åºãé€å»
ããŠãããªããã°ãªããªãããã®çš®ã®ç¡æ©é žæ®åº
ã®é€å»ã¯ä»»æã®æ¹æ³ã«ãã€ãŠæããåŸãããé©åœ
ãªå¡©åºãå ããããšã«ãã€ãŠãç¡åºé žå¡©ãæ²æ®¿ã
ãããæ¹æ³ãæå©ã§ãããé žæ®æž£ã®é€å»ã¯ãæ¬çº
æã«ããïŒâåã³ïŒâããããã¿ã«é žå¡©ã®æ®µéç
æ²æ®¿æäœãè¡ãªããã®ãšåãåå¿æº¶åªäžã«ãã
ãŠã奜ãŸããã¯ã¢ã«ã«ãªéå±æ°Žé žåç©æã¯ã¢ã«ã«
ãªåé¡éå±æ°Žé žåç©ãç¹ã«æ°Žé žåãããªãŠã åã¯
æ°Žé žåã«ãªãŠã ãç¡æ©é žå¡©ã®çæçšã®å¡©åºãšããŠ
çšããŠãæå©ã«è¡ãªãåŸããããããæ¬çºæã®æ¹
æ³ã«ããã°ãç¹å¥ãªåšå ·ãäžéåé¢æäœãªã©ãèŠ
ããã«ãç¡æ°Žãã¿ã«é žã®ãããåã«ããçããç²
粟補ããããã¿ã«é žæ··åç©ã䜿çšããããšãå¯èœ
ã§ãããããã«ããæè¡çãªãã³ã«çµæžçãªç°¡ç¥
åãéæãããã ïŒâåã³ïŒâããããã¿ã«é žå¡©ã®çžåœããéé¢
é žãžã®å€æã¯ãäŸãã°å¡©é žåã¯ç¡«é žã®ãããªæ°Žæ§
ç¡æ©é žã«ããåŠçã«ãã€ãŠéåžžã®æ¹æ³ã§è¡ããã
ã®å€æãåçµæ¶æ³ã§è¡ãªãå Žåã«ã¯ãç®çå€ã®ç°
æ§äœãå ãæ··å ¥ããŠãããšããŠããåæã«é€å»ã
ããã ãããåŸãããïŒâåã¯ïŒâããããã¿ã«é žäž
ã«ããããå¡©ãæ®çããŠããå Žåã¯ãäžè¬çæ¹
æ³ãäŸãã°é©åœãªäžæŽ»æ§ææ©æº¶åªã§ïŒâåã¯ïŒâ
ããããã¿ã«é žãæœåºãããããªæ¹æ³ã§åæ§ã«é€
å»ããããšãã§ããã æ¬çºæã®åé¢æ¹æ³ã«ããã°ãïŒâåã³ïŒâãã
ããã¿ã«é žãç°¡åãªæäœã§ãçŽç²ãªéé¢ç°æ§äœã®
圢ã§ãããŠéåžžã«é«åçã§åŸãããšãã§ãããå
å¿æéã¯æ¯èŒççããæäœã¯ç©ããã«æ¡ä»¶äžã§è¡
ãªãããšãã§ããæŽã«çæ åŠç芳ç¹ãããå®å šãª
æ¹æ³ã§ããã å®æœäŸ ïŒ æ¹¿ã€ãããããã¿ã«é žæ··åç©395ïœãç¡æ°Žãã¿
ã«é ž222.2ïœïŒ1.5ã¢ã«ïŒããããåããŠè£œé ïŒïŒ
âåã³ïŒâããããã¿ã«é žã®æ¯ãçŽ48ïŒ52ã®æ··å
ç©ããæ¹æè£ çœ®ãéæµè£ 眮ã枩床èšåã³PH枬å®é»
極ãåãã2.5âãªããã«ã®ãã©ã¹ã³äžã§åžè²©ã®
ã¡ãã«ãšãã«ã±ãã³1215ïœã«æžæ¿ãããããã®æ··
åç©ã«æ°Ž90ïœãå ãã枩床ã40âãŸã§äžããã圢
æãããéæãªé»è²æº¶æ¶²ã¯PHïŒã瀺ããã次ã«æ¿
ããæ¹æããªãããæ··åç©ã®PHã1.2ã«ããã®ã«
å åãªéã®30ïŒ æ°Žé žåãããªãŠã 溶液ããå ã
ããç¶ããŠæ°Žæ§ã®éæãªç²¥ç¶ç©ãåé¢ãããããŠ
ææ©æº¶åªãåã容åšã«ãã©ãããåã³40âã«å æž©
ããåŸãåžè²©ã®çé žæ°ŽçŽ ãããªãŠã 58.8ïœïŒ0.7
ã¢ã«ïŒã匷ãæ¹æããªããå°ããã€æ·»å ããã
CO2ã®çºçããããŸã€ãåŸãæ··åç©ã®PHã2.8ã«
äžãããšãïŒâããããã¿ã«é žã¢ããããªãŠã å¡©
ãçµåãšããŠæ²æ®¿ãããïŒâã«å·åŽåŸããã®å¡©ã
åžåŒæ¿Ÿéããããããæéã«ãªããŸã§ã80âã§ä¹Ÿ
ç¥ãããåéã¯ïŒâããããã¿ã«é žã®ã¢ããããª
ãŠã å¡©154.1ïœã§ãã€ãïŒäœ¿çšããç¡æ°Žãã¿ã«é ž
ãåºæºã«ããŠçè«éã®44.1ïŒ ã§ãã€ãïŒã æ¯æ¶²ãåã³åã容åšãžååãã40âã«å æž©ã
ãããã®åŸãçé žæ°ŽçŽ ãããªãŠã 67.2ïœïŒ0.8ã¢
ã«ïŒãåŸã ã«æ·»å ããã®éCO2ã®çºçããããŸã€
ãåŸãæ··åç©ã®PHã4.5ãŸã§äžæãããšãïŒâã
ãããã¿ã«é žã®ã¢ããããªãŠã å¡©ãçµæ¶ãšããŠæ²
殿ãããïŒâã«å·åŽåŸããã®å¡©ãåžåŒæ¿Ÿéã80â
ã§æéã«ãªããŸã§ä¹Ÿç¥ãããåéã¯ïŒâãããã
ã¿ã«é žã®ã¢ããããªãŠã å¡©172.6ïœã§ãã€ãïŒãª
ãçé žæ°ŽçŽ ãããªãŠã ããŸã ãããã«æ··å ¥ããŠã
ãç¶æ ã§ã䜿çšããç¡æ°Žãã¿ã«é žãåºæºã«ããŠç
è«å€ã®54.5ïŒ ã§ãã€ãïŒã 25ïŒ å¡©é ž1000ïœã§ïŒâããããã¿ã«é žã¢ããã
ãªãŠã å¡©ãåŠçããããšã«ãã€ãŠãèç¹207â
ïŒå解ïŒã®ç°æ§äœãå«ãŸã¬ç²ç²Ÿè£œïŒâããããã¿
ã«é ž131.2ïœãåŸãã å¡©æ®æž£é€å»ã®ç®çã§ãåŸãããç²ïŒâãããã
ã¿ã«é ž130ïœãã¢ã»ãã³400ïœã«å ãããåå¿æ··å
ç©ãå ç±éæµããå æž©æ¿ŸéãããããŠåŸããã溶
液ãèžç也ç¥ãããšãèç¹213â214âïŒå解ïŒã®
ç°æ§äœãå«ãŸã¬çŽç²ãªïŒâããããã¿ã«é ž123ïœ
ãçãããããã¯äœ¿çšããç¡æ°Žãã¿ã«é žãåºæºã«
ããŠãçè«å€ã®39ïŒ ã®åéã«çžåœããã åæ§ãªæ¹æ³ã§ãïŒâããããã¿ã«é žã¢ããããª
ãŠã å¡©ã25ïŒ å¡©é ž560ïœã§åŠçããããšã«ãã€ãŠ
ïŒâããããã¿ã«é žã«å€æãããçæç©ã¯èç¹
162â164âïŒå解ïŒã®ç°æ§äœãå«ãŸã¬ç²ïŒâãã
ããã¿ã«é ž157.6ïœã§ãã€ããïŒâããããã¿ã«
é žã«ã€ããŠåèšããåŠãæ®çç¡æ©å¡©ã®é€å»æäœã
è¡ã€ããšãããèç¹172â173âïŒå解ïŒã®ç°æ§äœ
ãå«ãŸã¬çŽç²ãªïŒâããããã¿ã«é ž123ïœãåŸã
ãããããã¯äœ¿çšããç¡æ°Žãã¿ã«é žãåºæºã«ã
ãŠãçè«å€ã®39ïŒ ã®åéã«çžåœããã å®æœäŸ ïŒ å®æœäŸïŒã«èšèŒããæ¹æ³ãè¡ãªã€ããããããª
ããããããååå¿ç±æ¥ã®é žæ®æž£ãé€å»ããåŸã
çé žæ°ŽçŽ ãããªãŠã 56.7ïœïŒ0.675ã¢ã«ïŒã®ã¿ã
å ãããšãããïŒâããããã¿ã«é žã¢ããããªãŠ
ã å¡©149.9ïœãæ²æ®¿ãããå®æœäŸïŒã«èšèŒããæ¹
æ³ã§ãã®å¡©ãåé¢ããåŸãæ¯æ¶²ã«æŽã«çé žæ°ŽçŽ ã
ããªãŠã ã6.3ïœïŒ0.075ã¢ã«ïŒå ãããšãæ··åç©
ã®PHã¯3.4ã«äžæããäž»ã«ïŒâç°æ§äœã«å«æãã
ããããã¿ã«é žã¢ããããªãŠã å¡©æ··åç©10.7ïœã
æ²æ®¿ããããã®çµæ¶éšåãæŽã«æ¯æ¶²ããåé¢ã次
ã®åé¢æäœã«äœ¿çšããã å®æœäŸïŒã«èšèŒããåŠããçé žæ°ŽçŽ ãããªãŠã
63ïœïŒ0.75ã¢ã«ïŒãå ããããšã«ãã€ãŠïŒâãã
ããã¿ã«é žã¢ããããªãŠã å¡©169.5ïœãæ²æ®¿ã
ãã å®æœäŸïŒã«èšèŒããæ¹æ³ãšåæ§ã®æ¹æ³ã§ïŒçš®ã®
ããããã¿ã«é žã¢ããããªãŠã å¡©ç°æ§äœãå¡©é žã§
åŠçããããšã«ãã€ãŠãèç¹209âïŒå解ïŒã®ç°
æ§äœãå«ãŸãªãç²ïŒâããããã¿ã«é ž126.1ïœå
ã³èç¹164â166âïŒå解ïŒã®ç°æ§äœãå«ãŸãªãçµ
ïŒâããããã¿ã«é ž154.3ïœãåŸããããçã®ïŒ
çš®ã®çæç©ã¯å¡©åãããªãŠã ããŸã å°ãå«æããŠ
ãããããã®å¡©ã¯å®æœäŸïŒã§èšèŒããæ¹æ³ã§åæ§
ã«é€å»ããããšãã§ããã å®æœäŸ ïŒ ç²Ÿè£œïŒïŒïŒâããããã¿ã«é žæ··åç©211ïœïŒ1.0
ã¢ã«ïŒãæ¹æè£ çœ®ãéæµè£ 眮åã³æž©åºŠèšãåãã
2.5ãªããã«ãã©ã¹ã³ã«å ¥ããããã®æ··åç©äžã®
ç°æ§äœæ¯ã¯ïŒâããããã¿ã«é ž48.7ééïŒ ãïŒâ
ããããã¿ã«é ž51.3ééïŒ ã§ãããšããããã枬
å®ããŠãã€ãããã®æ··åç©ã«åžè²©ã®ã¡ãã«ãšãã«
ã±ãã³840ïœåã³æ°Ž42ïœãå ãããæ¹æããªãã
枩床ã35âã«äžãããšããéæãªæº¶æ¶²ãçæã
ãã15åéã§çé žæ°ŽçŽ ãããªãŠã 37.8ïœïŒ0.45ã¢
ã«ïŒããã®æº¶æ¶²ã«å°ããã€æ·»å ãããCO2ã®çºç
ããããŸã€ãåŸ35âã§æŽã«15åéæ¹æãç¶ããã
ããã枩床ãïŒâãŸã§äžãããç ç¶ã®çµæ¶æ²ç©ç©
ãåžåŒæ¿Ÿéããæéã«ãªããŸã§80âã§ä¹Ÿç¥ããã
çæç©ã¯æ·¡ãã€è²ç²æ«110.1ïœã§ãã€ãïŒïŒâã
ãããã¿ã«é žã¢ããããªãŠã å¡©ïŒã æ¯æ¶²ãåã³åèšå®¹åšã«ååããããã35âã«å
æž©ãããçé žæ°ŽçŽ ãããªãŠã ã46.2ïœïŒ0.55ã¢
ã«ïŒãå ãããšããïŒâããããã¿ã«é žã¢ããã
ãªãŠã å¡©ãæ²æ®¿ããã®ã§ããããåžåŒæ¿Ÿéã也ç¥
ãããçæç©ã¯æ·¡ãã€è²ã®ç²æ«107.6ïœã§ãã€
ãã ãã®åŸïŒâããããã¿ã«é žã¢ããããªãŠã å¡©ã
15ïŒ å¡©é ž210ïœããåçµæ¶ããïŒâããããã¿ã«
é žã¢ããããªãŠã å¡©ã15ïŒ å¡©é ž140ïœããåçµæ¶
ãããäž¡çæç©ãåã ã¢ã»ãã³200ïœäžã«å ãã
å ç±éæµãäžæº¶æåãæ¿Ÿå»ãã溶液ãèžçºä¹Ÿç¥ã
ãã 以äžã®æ¹æ³ã«ãã€ãŠèç¹216âïŒå解ïŒã®ïŒâ
ããããã¿ã«é žã82.3ïœåŸãããã¯çè«å€ã®80ïŒ
ã«çžåœãããæŽã«èç¹172â173âïŒå解ïŒã®ïŒâ
ããããã¿ã«é žã78.8ïœåŸãããã¯çè«å€ã®74.8
ïŒ ã«çžåœãããäž¡çæç©ã¯èå±€ã¯ãããã°ã©ãã€
ãŒã«ããã°çŽåã§ãã€ãã å®æœäŸ ïŒâ11 å®æœäŸïŒã«èšèŒããæ¹æ³ã«ãã€ãŠç¡æ°Žãã¿ã«é ž
29.6ïœïŒ0.2ã¢ã«ïŒããããåãããç¡æ©é žæ®åº
ãé€å»ãããšãçŽç²ãªïŒâïŒïŒâããããã¿ã«é ž
æ··åç©26ïœãæ®ã€ãããããå®æœäŸïŒã«èšèŒãã
æ¹æ³ã«ããåç°æ§äœã«åé¢ããåŸãããïŒâåã³
ïŒâããããã¿ã«é žå¡©ãå®æœäŸïŒèšèŒãšåæ§ã«ã
éé¢é žã«å€æããããã®ä»ã®åå¿æ¡ä»¶åã³ïŒâå
ã³ïŒâããããã¿ã«é žã®åçã以äžã®è¡šã«ç€ºãã
ã®æ°èŠåé¢æ¹æ³ã«é¢ãããã®ã§ããã ïŒâåã³ïŒâããããã¿ã«é žã¯ãé¡æãææå
ã³å¯å¡å€ãç¹ã«PVCãããªãšã¹ãã«ãããªã¢ã
ããããããã蟲æ¥çšæŽ»æ§ç©è³ªçããã€ãåœç¹èš±
æ现æžç¬¬824815å·ã第935964å·åã³ç¬¬936944å·ïŒ
ç±³åœç¹èš±æ现æžç¬¬2412817å·åã³ç¬¬2491455å·ïŒã±
ãã«ã«ã¢ãã¹ãã©ã¯ãïŒCAïŒã第47å·»9303d
ïŒ1953幎ïŒã第53å·»11290fïŒ1959幎ïŒã第66å·»
116023bïŒ1967幎ïŒã第69å·»107329råã³170330i
ïŒ1968幎ïŒãåç §ããã®éåžžã«å€çšãªèªå°äœã補é
ããããã®ç£æ¥äžéèŠãªäžéäœã§ãããããçã¯
äžè¬ã«ãç¡æ°Žãã¿ã«é žãæ¿ç¡«é žãçšããŠãããã
åããããšã«ãã€ãŠè£œé ãããããã®æ¹æ³ã«ãã
ãšãç°ãªãå²åã®ïŒâåã³ïŒâããããã¿ã«é žã
æããç°æ§äœæ··åç©ã圢æãããã è³éŠæããªã«ã«ãã³é žã®ç°æ§äœæ··åç©ãåé¢ã
ãããã®åŸæ¥å ¬ç¥ã®æ段ã¯ãäŸãã°ã¯ãããã°ã©
ãã€ãŒæ³ã®ããã«å Žåã«ãã€ãŠã¯ãããè€éãã
ãŠãå·¥æ¥çã«å€§èŠæš¡ã«å®æœããã«ã¯äžé©åœã§ã
ããåããçã®æ¹æ³ã«ãã€ãŠç®çã®ç°æ§äœãå®å š
ã«åé¢ããã®ã¯ãããããã ç±³åœç¹èš±æ现æžç¬¬2412817å·ã«ããã°ãïŒâå
ã³ïŒâããããã¿ã«é žã®æ··åç©ãã宀枩ã§æ°Žã«æž
æ¿ããŠæ¹æããç¶ããŠäžæº¶ç¶æ ã§ååšããïŒâã
ãããã¿ã«é žãæ¿Ÿåããããšã«ããåé¢ã§ããã
ïŒâããããã¿ã«é žã¯ç¢ºãã«ïŒâããããã¿ã«é ž
ããæ°Žã«å¯Ÿãã溶解æ§ãäœãããããæ°Žã«å šã溶
解ããªãããã§ã¯ãªãããããã€ãŠããã®æ¹æ³ã«
ãã€ãŠå®å šã«çŽç²ãªç°æ§äœã«åé¢ããããšã¯äžå¯
èœã§ããã ç±³åœç¹èš±æ现æžç¬¬3098095å·ã«å°ãªããšãïŒæ¹
ã¯ãç°äžã«ããïŒã€å¥ã®çœ®æåºããã€ãé žç¡æ°Žç©
圢ææ§è³éŠæããªã«ã«ãã³é žã®æ··åç©ããšãåã
ïŒâåã³ïŒâããããã¿ã«é žã®æ··åç©ã®åé¢æ¹æ³
ãé瀺ãããŠããããã®æ¹æ³ã§ã¯ãé žæ··åç©ãé©
åœãªæº¶åªäžã§ãè±æ°Žæž©åºŠã®äœãã«ã«ãã³é žã®ã«ã«
ãã³é žç¡æ°Žç©ãäž»ãšããŠåœ¢æãããŠãã枩床ãŸã§
å ç±ããäžæ¹ãä»æ¹ã®ã«ã«ãã³é žã®è±æ°Žçããã§
ããã ãäœãä¿ã€ãç¶ããŠäŸãã°é žç¡æ°Žç©ã«å¯ã
ãã©ã¯ã·ãšã³ã®æº¶åªæœåºãªã©ã«ãããé žç¡æ°Žç©å
ã³é žã«å¯ããã©ã¯ã·ãšã³ãã倫ã åé¢ããããã®
æ¹æ³ããŸããçŽç²ç°æ§äœã®å€§èŠæš¡ãªå·¥æ¥çç£ã«ã¯
äžé©åœã§ãããããã®çç±ã¯é«ãè±æ°Žæž©åºŠç¯å²ã
æããã«ã«ãã³é žã®ç¡æ°Žç©ãããªãåŸãããŠããŸ
ãããã§ãããåŸã€ãŠãäŸãã°ïŒâåã³ïŒâãã
ããã¿ã«é žã®å Žåã«ã¯ãé žç¡æ°Žç©ã«å¯ããã©ã¯ã·
ãšã³ã«ãäž»æåãšããŠã®ïŒâããããã¿ã«é žç¡æ°Ž
ç©ã®ä»ã«ïŒâããããã¿ã«é žç¡æ°Žç©ãçŽ8.5ïŒ å«
æãããŠããŸããæŽã«ããã®åå¿ã¯é«ã枩床ïŒçŽ
110â180âïŒããã³éåžžã«åžèãªç³»ã«ãããŠè¡ã
ãªããã°ãªããããããã®å åã®ããã«ãã®åå¿
ã®çµæžçå¹çã¯äœãã ãããã€ãŠãæ¬çºæã®ç®çã¯ãç°¡åãã€çµæžç
ã«ãããé«åçã§ïŒâåã³ïŒâããããã¿ã«é žã®
æ··åç©ãåç°æ§äœã«å®å šã«åé¢ã§ããæŽã«å€§èŠæš¡
ãªå·¥æ¥çç£ã«é©ããæ°èŠåé¢æ¹æ³ãæäŸããããš
ã§ããã ïŒâåã³ïŒâããããã¿ã«é žã®æ··åç©ãåé¢ã
ãããã®æ¬çºæã®æ¹æ³ã¯ãæ°ŽãïŒãªãã20容é
ïŒ ã奜ãŸããã¯ïŒãªãã10容éïŒ å«æããäžæŽ»æ§
ãªæ¥µæ§ææ©æº¶åªäžã§ããã¿ã«é žååç©ã®ãããå
åå¿ç±æ¥ã®ç¡æ©é žæ®åºãå«ãŸãªãïŒâåã³ïŒâã
ãããã¿ã«é žæ··åç©ã«ã20âãã100âã®éã®æž©
床ã§ããŸãã該åå¿æº¶åªã«å®è³ªçã«äžæº¶ãªïŒâå
ã³ïŒâããããã¿ã«é žå¡©ã圢æãããå¡©åºããPH
ãçŽ2.8ãšãªããŸã§å ããããšã«ãã€ãŠäž»ã«ïŒâ
ããããã¿ã«é žã¢ãå¡©ãããªãæ²æŸ±çæç©ãåé¢
ãããã®åŸæŽã«äžèšç¯å²ã®æž©åºŠã§äžèšå¡©åºãPHã
å°ãªããšãçŽ4.5ã«ãªããŸã§å ããããšã«ããäž»
ã«ïŒâããããã¿ã«é žå¡©ããæãçæç©ãæ²æ®¿ã
ããããšãããªã段éçãªå¡©åºåŠçãè¡ãªããæ
åŸã«ãåŸãããããããã¿ã«é žå¡©ãå¥ã ã«çžåœã
ãéé¢é žã«å€æãããããŠå Žåã«ãã€ãŠã¯ããç
ã粟補ããããšã«ããæãã æ¬çºæã®åé¢æ¹æ³ã«äœ¿çšãããææ©æº¶åªã¯ãäž
掻æ§ã®æ¥µæ§ææ©æº¶åªã§ãããç¹ã«å®€æž©ã§å€å°ã®äœ
ãäžå®éçéãŸã§ã®æ°Žã溶解ãåŸããã®ã§ããã
é©åœãªæº¶åªäŸãšããŠã¯ã¢ã»ãã³ãã¡ãã«ãšãã«ã±
ãã³ãã·ã¯ããã³ã¿ãã³åã³ã·ã¯ããããµãã³ã®
ãããªèèªæåã³èç°åŒã±ãã³ïŒããã©ãããã
ã©ã³ãããã©ããããã©ã³åã³ãžãªããµã³ã®ãã
ãªç°ç¶ãšãŒãã«ïŒïŒ®âã¡ãã«âïŒâãããªãã³ã
âã¢ã»ãã«âïŒâãããªãã³åã³ïŒ®âã¡ãã«â
εâã«ããã©ã¯ã¿ã ã®ãããªç°ç¶ã¢ããïŒãšãã¬
ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ããšãã¬ã³ã°ãª
ã³ãŒã«ã¢ããšãã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒã«
ã¢ãã€ãœãããã«ãšãŒãã«åã³ãšãã¬ã³ã°ãªã³ãŒ
ã«ã¢ãâïœâããã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒ
ã«ãžã¡ãã«ãšãŒãã«åã³ãšãã¬ã³ã°ãªã³ãŒã«ãžãš
ãã«ãšãŒãã«ãªã©ã®ãããªåã¢ã«ãã«éšã®ççŽ å
åæ°ãïŒãªããïŒã®ãšãã¬ã³ã°ãªã³ãŒã«ã¢ãâå
ã³ãžã¢ã«ãã«ãšãŒãã«ïŒã®é žåã¯é ¢é žã®ã¡ãã«ãš
ã¹ãã«ãã®é žåã¯é ¢é žã®ãšãã«ãšã¹ãã«ãåã³ã®
é žåã¯é ¢é žã®ïœâããã«ãšã¹ãã«ãªã©ã®ãããªç·
ççŽ ååæ°ã®ïŒãªããïŒã®èèªæã¢ãã«ã«ãã³é ž
ã®ã¢ã«ãã«ãšã¹ãã«ïŒã¡ã¿ããŒã«ããšã¿ããŒã«ã
ãããããŒã«ãã€ãœãããããŒã«ããã¿ããŒã«å
ã³ãã³ã¿ããŒã«ã®ãããªççŽ ååæ°ïŒãªããïŒã®
èèªæã¢ã«ã³ãŒã«ïŒãªã©ãæããããã 奜ãŸãã溶åªã¯åèšã®ã¢ã«ãã«ãšã¹ãã«åã³è
èªæã±ãã³ãç¹ã«é ¢é žãšãã«ãšã¹ãã«æãã¯ã¡ã
ã«ãšãã«ã±ãã³ã§ããã æ¬çºæã®æ¹æ³ã«äœ¿çšããå¡©åºãšããŠã¯ãåå¿æº¶
åªäžã«ãããŠïŒâåã³ïŒâããããã¿ã«é žãšå€«ã
溶åªãã«ããå¡©ãããã³äžæŽ»æ§ã®å¡©ã圢æãåŸã
ææ©æãã¯ç¡æ©ååç©ãªããããã䜿çšããããš
ãã§ãããç¡æ©å¡©åºã奜ãŸããç¹ã«ãããªãŠã ã
ã«ãªãŠã ããã°ãã·ãŠã ãã«ã«ã·ãŠã ãªã©ã®ãã
ãªã¢ã«ã«ãªéå±åã³ã¢ã«ã«ãªåé¡éå±ã®æ°Žé žå
ç©ãçé žå¡©åã³çé žæ°ŽçŽ å¡©ã䜿çšããããçé žæ°Ž
çŽ ãããªãŠã ãšçé žæ°ŽçŽ ã«ãªãŠã ãç¹ã«å¥œãŸã
ãã å¡©çæã®ããã®åå¿æž©åºŠã¯çŽ30ãã50âã®éã
奜ãŸããã åèšã®ãšãããæåã®æ®µéã§å¡©åºã¯PHãçŽ2.8
ãšãªããŸã§å ããããããŠãã®éã«äŸç¶ãšããŠåŸ®
éã®ïŒâããããã¿ã«é žã¢ãå¡©ãå«æããïŒâã
ãããã¿ã«é žã¢ãå¡©ãäž»ã«åœ¢æããããçŽ2.8ã®
PHå€ã¯ãåœéããå ãã«å°ãªãå¡©åºã奜ãŸããã¯
åºçºæ··åç©ã«ååšããå šãŠã®ïŒâããããã¿ã«é ž
ããã¢ãå¡©ãšããŠæ²æ®¿ãããã«å¿ èŠãªçè«éã«å¯Ÿ
ããŠçŽ90ãªãã95ïŒ ã®å¡©åºãå ããããšã«ãã€ãŠ
åŸãããã å Žåã«ãã€ãŠã¯ãæ®äœã®ïŒâããããã¿ã«é žã
ã¢ãå¡©ã®åœ¢ã§æ²æ®¿ãããã«å¿ èŠãªçè«éã«éãã
ãŸã§å¡©åºãæŽã«å ããããšã«ãã€ãŠãPHãçŽ3.4
ã«äžããããšãã§ããããã«ãã€ãŠäž»ã«ïŒâç°æ§
äœããæãå°éã®ããããã¿ã«é žã¢ãå¡©ãåã³æ²
殿ããããã®äžéçæç©ã®ãã©ã¯ã·ãšã³ã¯å ã®ã
ã©ã¯ã·ãšã³ãšäžç·ã«ããŠãè¯ãããã®ãŸãŸå ã®å
é¢æäœã«é²ããããšãã§ããã äž»ã«ïŒâããããã¿ã«é žãããªãæ®äœã®ããã
ãã¿ã«é žãå¡©ã®åœ¢ã§æ²æ®¿ãããããã«ãå ããå¡©
åºã¯ãå³å¯ã§ãªãããã®æ®µéã§ã¯çŽ4.5ã®PHå€ã
åŸããããŸã§å¡©åºãå ãããåã¯æ®äœã®ãããã
ã¿ã«é žãå šãŠã¢ãå¡©ãšããŠæ²æ®¿ãããããšãã§ã
ãå®è³ªçååŠéè«éãå ããã塩圢æçµäºåŸæ®ã€
ãæ°Žæ§ææ©åå¿æº¶åªã¯ååãšããŠäœãåŠçããã«
çŽæ¥æ¬¡åã®åå¿ã«äœ¿çšããããšãã§ããããã®äº
ã¯ã第ïŒæ®µéã§å¡©åºãåœéããå°ãªã䜿çšããå Ž
åãæãã¯éå°ã«çšããå ŽåããããŠåå¿æº¶åªã
ãªãæ®äœããããã¿ã«é žåã¯æªåå¿å¡©åºãå«æã
ãŠããå Žåã«ãåæ§ã«å¯èœã§ãããæ°ããåºçºç°
æ§äœæ··åç©ããã³å¿ èŠãªãã°å¡©åºãããã«å ãã
å Žåãæåã®åå¿æ®µéã«ãããPHçŽ2.8ã®å€ãè¶
ããªãããã«ããå¿ èŠãªãã°åå¿æº¶åªã®æ°Žå«éã
調æŽããç¹ã«çæããã ãã§ããã ããããæ¬çºæã®æ¹æ³ã¯ãé£ç¶åã¯åé£ç¶çæ
äœã«ãéåžžã«é©ããã æ¬çºæã®æ¹æ³ã«ããåé¢ãã¹ãïŒâããããã¿
ã«é žãšïŒâããããã¿ã«é žãããªãåºçºç°æ§äœæ··
åç©äžã«ã該ç°æ§äœä»¥å€ã®é žã®æ®åºãå«ãŸããŠã
ããšã該ç°æ§äœãšäžç·ã«æ²æŸ±ããŠããŸããåç°æ§
äœãçŽç²ãªåœ¢ã§åŸãããªããããåºçºç°æ§äœæ··å
ç©äžã«ã¯è©²ç°æ§äœä»¥å€ã®é žã®æ®åºãå«ãŸããŠããŠ
ã¯ãªããªããæ¬çºæã®æ¹æ³ã«ããåé¢ãã¹ããã
ããã¿ã«é žã®è£œé ã¯ãçžåœãããã¿ã«é žã®ããã
åã«ããè¡ãªããããããåŸãããããããã¿ã«
é žã®ç°æ§äœæ··åç©äžã«ã¯ããããåã«é垞䜿çšã
ããæ¿ç¡«é žåã³æ¿ç¡é žã®æ®åºãååšãããåŸã€
ãŠãåºçºç°æ§äœæ··åç©äžã®ç¡æ©é žæ®åºãšããŠã¯ã
äž»ã«ãããã®æ¿ç¡«é žåã³æ¿ç¡é žã®æ®åºãåé¡ãšãª
ããåé¢ãè¡ãªãåã«ãããã®ç¡æ©é žæ®åºãé€å»
ããŠãããªããã°ãªããªãããã®çš®ã®ç¡æ©é žæ®åº
ã®é€å»ã¯ä»»æã®æ¹æ³ã«ãã€ãŠæããåŸãããé©åœ
ãªå¡©åºãå ããããšã«ãã€ãŠãç¡åºé žå¡©ãæ²æ®¿ã
ãããæ¹æ³ãæå©ã§ãããé žæ®æž£ã®é€å»ã¯ãæ¬çº
æã«ããïŒâåã³ïŒâããããã¿ã«é žå¡©ã®æ®µéç
æ²æ®¿æäœãè¡ãªããã®ãšåãåå¿æº¶åªäžã«ãã
ãŠã奜ãŸããã¯ã¢ã«ã«ãªéå±æ°Žé žåç©æã¯ã¢ã«ã«
ãªåé¡éå±æ°Žé žåç©ãç¹ã«æ°Žé žåãããªãŠã åã¯
æ°Žé žåã«ãªãŠã ãç¡æ©é žå¡©ã®çæçšã®å¡©åºãšããŠ
çšããŠãæå©ã«è¡ãªãåŸããããããæ¬çºæã®æ¹
æ³ã«ããã°ãç¹å¥ãªåšå ·ãäžéåé¢æäœãªã©ãèŠ
ããã«ãç¡æ°Žãã¿ã«é žã®ãããåã«ããçããç²
粟補ããããã¿ã«é žæ··åç©ã䜿çšããããšãå¯èœ
ã§ãããããã«ããæè¡çãªãã³ã«çµæžçãªç°¡ç¥
åãéæãããã ïŒâåã³ïŒâããããã¿ã«é žå¡©ã®çžåœããéé¢
é žãžã®å€æã¯ãäŸãã°å¡©é žåã¯ç¡«é žã®ãããªæ°Žæ§
ç¡æ©é žã«ããåŠçã«ãã€ãŠéåžžã®æ¹æ³ã§è¡ããã
ã®å€æãåçµæ¶æ³ã§è¡ãªãå Žåã«ã¯ãç®çå€ã®ç°
æ§äœãå ãæ··å ¥ããŠãããšããŠããåæã«é€å»ã
ããã ãããåŸãããïŒâåã¯ïŒâããããã¿ã«é žäž
ã«ããããå¡©ãæ®çããŠããå Žåã¯ãäžè¬çæ¹
æ³ãäŸãã°é©åœãªäžæŽ»æ§ææ©æº¶åªã§ïŒâåã¯ïŒâ
ããããã¿ã«é žãæœåºãããããªæ¹æ³ã§åæ§ã«é€
å»ããããšãã§ããã æ¬çºæã®åé¢æ¹æ³ã«ããã°ãïŒâåã³ïŒâãã
ããã¿ã«é žãç°¡åãªæäœã§ãçŽç²ãªéé¢ç°æ§äœã®
圢ã§ãããŠéåžžã«é«åçã§åŸãããšãã§ãããå
å¿æéã¯æ¯èŒççããæäœã¯ç©ããã«æ¡ä»¶äžã§è¡
ãªãããšãã§ããæŽã«çæ åŠç芳ç¹ãããå®å šãª
æ¹æ³ã§ããã å®æœäŸ ïŒ æ¹¿ã€ãããããã¿ã«é žæ··åç©395ïœãç¡æ°Žãã¿
ã«é ž222.2ïœïŒ1.5ã¢ã«ïŒããããåããŠè£œé ïŒïŒ
âåã³ïŒâããããã¿ã«é žã®æ¯ãçŽ48ïŒ52ã®æ··å
ç©ããæ¹æè£ çœ®ãéæµè£ 眮ã枩床èšåã³PH枬å®é»
極ãåãã2.5âãªããã«ã®ãã©ã¹ã³äžã§åžè²©ã®
ã¡ãã«ãšãã«ã±ãã³1215ïœã«æžæ¿ãããããã®æ··
åç©ã«æ°Ž90ïœãå ãã枩床ã40âãŸã§äžããã圢
æãããéæãªé»è²æº¶æ¶²ã¯PHïŒã瀺ããã次ã«æ¿
ããæ¹æããªãããæ··åç©ã®PHã1.2ã«ããã®ã«
å åãªéã®30ïŒ æ°Žé žåãããªãŠã 溶液ããå ã
ããç¶ããŠæ°Žæ§ã®éæãªç²¥ç¶ç©ãåé¢ãããããŠ
ææ©æº¶åªãåã容åšã«ãã©ãããåã³40âã«å æž©
ããåŸãåžè²©ã®çé žæ°ŽçŽ ãããªãŠã 58.8ïœïŒ0.7
ã¢ã«ïŒã匷ãæ¹æããªããå°ããã€æ·»å ããã
CO2ã®çºçããããŸã€ãåŸãæ··åç©ã®PHã2.8ã«
äžãããšãïŒâããããã¿ã«é žã¢ããããªãŠã å¡©
ãçµåãšããŠæ²æ®¿ãããïŒâã«å·åŽåŸããã®å¡©ã
åžåŒæ¿Ÿéããããããæéã«ãªããŸã§ã80âã§ä¹Ÿ
ç¥ãããåéã¯ïŒâããããã¿ã«é žã®ã¢ããããª
ãŠã å¡©154.1ïœã§ãã€ãïŒäœ¿çšããç¡æ°Žãã¿ã«é ž
ãåºæºã«ããŠçè«éã®44.1ïŒ ã§ãã€ãïŒã æ¯æ¶²ãåã³åã容åšãžååãã40âã«å æž©ã
ãããã®åŸãçé žæ°ŽçŽ ãããªãŠã 67.2ïœïŒ0.8ã¢
ã«ïŒãåŸã ã«æ·»å ããã®éCO2ã®çºçããããŸã€
ãåŸãæ··åç©ã®PHã4.5ãŸã§äžæãããšãïŒâã
ãããã¿ã«é žã®ã¢ããããªãŠã å¡©ãçµæ¶ãšããŠæ²
殿ãããïŒâã«å·åŽåŸããã®å¡©ãåžåŒæ¿Ÿéã80â
ã§æéã«ãªããŸã§ä¹Ÿç¥ãããåéã¯ïŒâãããã
ã¿ã«é žã®ã¢ããããªãŠã å¡©172.6ïœã§ãã€ãïŒãª
ãçé žæ°ŽçŽ ãããªãŠã ããŸã ãããã«æ··å ¥ããŠã
ãç¶æ ã§ã䜿çšããç¡æ°Žãã¿ã«é žãåºæºã«ããŠç
è«å€ã®54.5ïŒ ã§ãã€ãïŒã 25ïŒ å¡©é ž1000ïœã§ïŒâããããã¿ã«é žã¢ããã
ãªãŠã å¡©ãåŠçããããšã«ãã€ãŠãèç¹207â
ïŒå解ïŒã®ç°æ§äœãå«ãŸã¬ç²ç²Ÿè£œïŒâããããã¿
ã«é ž131.2ïœãåŸãã å¡©æ®æž£é€å»ã®ç®çã§ãåŸãããç²ïŒâãããã
ã¿ã«é ž130ïœãã¢ã»ãã³400ïœã«å ãããåå¿æ··å
ç©ãå ç±éæµããå æž©æ¿ŸéãããããŠåŸããã溶
液ãèžç也ç¥ãããšãèç¹213â214âïŒå解ïŒã®
ç°æ§äœãå«ãŸã¬çŽç²ãªïŒâããããã¿ã«é ž123ïœ
ãçãããããã¯äœ¿çšããç¡æ°Žãã¿ã«é žãåºæºã«
ããŠãçè«å€ã®39ïŒ ã®åéã«çžåœããã åæ§ãªæ¹æ³ã§ãïŒâããããã¿ã«é žã¢ããããª
ãŠã å¡©ã25ïŒ å¡©é ž560ïœã§åŠçããããšã«ãã€ãŠ
ïŒâããããã¿ã«é žã«å€æãããçæç©ã¯èç¹
162â164âïŒå解ïŒã®ç°æ§äœãå«ãŸã¬ç²ïŒâãã
ããã¿ã«é ž157.6ïœã§ãã€ããïŒâããããã¿ã«
é žã«ã€ããŠåèšããåŠãæ®çç¡æ©å¡©ã®é€å»æäœã
è¡ã€ããšãããèç¹172â173âïŒå解ïŒã®ç°æ§äœ
ãå«ãŸã¬çŽç²ãªïŒâããããã¿ã«é ž123ïœãåŸã
ãããããã¯äœ¿çšããç¡æ°Žãã¿ã«é žãåºæºã«ã
ãŠãçè«å€ã®39ïŒ ã®åéã«çžåœããã å®æœäŸ ïŒ å®æœäŸïŒã«èšèŒããæ¹æ³ãè¡ãªã€ããããããª
ããããããååå¿ç±æ¥ã®é žæ®æž£ãé€å»ããåŸã
çé žæ°ŽçŽ ãããªãŠã 56.7ïœïŒ0.675ã¢ã«ïŒã®ã¿ã
å ãããšãããïŒâããããã¿ã«é žã¢ããããªãŠ
ã å¡©149.9ïœãæ²æ®¿ãããå®æœäŸïŒã«èšèŒããæ¹
æ³ã§ãã®å¡©ãåé¢ããåŸãæ¯æ¶²ã«æŽã«çé žæ°ŽçŽ ã
ããªãŠã ã6.3ïœïŒ0.075ã¢ã«ïŒå ãããšãæ··åç©
ã®PHã¯3.4ã«äžæããäž»ã«ïŒâç°æ§äœã«å«æãã
ããããã¿ã«é žã¢ããããªãŠã å¡©æ··åç©10.7ïœã
æ²æ®¿ããããã®çµæ¶éšåãæŽã«æ¯æ¶²ããåé¢ã次
ã®åé¢æäœã«äœ¿çšããã å®æœäŸïŒã«èšèŒããåŠããçé žæ°ŽçŽ ãããªãŠã
63ïœïŒ0.75ã¢ã«ïŒãå ããããšã«ãã€ãŠïŒâãã
ããã¿ã«é žã¢ããããªãŠã å¡©169.5ïœãæ²æ®¿ã
ãã å®æœäŸïŒã«èšèŒããæ¹æ³ãšåæ§ã®æ¹æ³ã§ïŒçš®ã®
ããããã¿ã«é žã¢ããããªãŠã å¡©ç°æ§äœãå¡©é žã§
åŠçããããšã«ãã€ãŠãèç¹209âïŒå解ïŒã®ç°
æ§äœãå«ãŸãªãç²ïŒâããããã¿ã«é ž126.1ïœå
ã³èç¹164â166âïŒå解ïŒã®ç°æ§äœãå«ãŸãªãçµ
ïŒâããããã¿ã«é ž154.3ïœãåŸããããçã®ïŒ
çš®ã®çæç©ã¯å¡©åãããªãŠã ããŸã å°ãå«æããŠ
ãããããã®å¡©ã¯å®æœäŸïŒã§èšèŒããæ¹æ³ã§åæ§
ã«é€å»ããããšãã§ããã å®æœäŸ ïŒ ç²Ÿè£œïŒïŒïŒâããããã¿ã«é žæ··åç©211ïœïŒ1.0
ã¢ã«ïŒãæ¹æè£ çœ®ãéæµè£ 眮åã³æž©åºŠèšãåãã
2.5ãªããã«ãã©ã¹ã³ã«å ¥ããããã®æ··åç©äžã®
ç°æ§äœæ¯ã¯ïŒâããããã¿ã«é ž48.7ééïŒ ãïŒâ
ããããã¿ã«é ž51.3ééïŒ ã§ãããšããããã枬
å®ããŠãã€ãããã®æ··åç©ã«åžè²©ã®ã¡ãã«ãšãã«
ã±ãã³840ïœåã³æ°Ž42ïœãå ãããæ¹æããªãã
枩床ã35âã«äžãããšããéæãªæº¶æ¶²ãçæã
ãã15åéã§çé žæ°ŽçŽ ãããªãŠã 37.8ïœïŒ0.45ã¢
ã«ïŒããã®æº¶æ¶²ã«å°ããã€æ·»å ãããCO2ã®çºç
ããããŸã€ãåŸ35âã§æŽã«15åéæ¹æãç¶ããã
ããã枩床ãïŒâãŸã§äžãããç ç¶ã®çµæ¶æ²ç©ç©
ãåžåŒæ¿Ÿéããæéã«ãªããŸã§80âã§ä¹Ÿç¥ããã
çæç©ã¯æ·¡ãã€è²ç²æ«110.1ïœã§ãã€ãïŒïŒâã
ãããã¿ã«é žã¢ããããªãŠã å¡©ïŒã æ¯æ¶²ãåã³åèšå®¹åšã«ååããããã35âã«å
æž©ãããçé žæ°ŽçŽ ãããªãŠã ã46.2ïœïŒ0.55ã¢
ã«ïŒãå ãããšããïŒâããããã¿ã«é žã¢ããã
ãªãŠã å¡©ãæ²æ®¿ããã®ã§ããããåžåŒæ¿Ÿéã也ç¥
ãããçæç©ã¯æ·¡ãã€è²ã®ç²æ«107.6ïœã§ãã€
ãã ãã®åŸïŒâããããã¿ã«é žã¢ããããªãŠã å¡©ã
15ïŒ å¡©é ž210ïœããåçµæ¶ããïŒâããããã¿ã«
é žã¢ããããªãŠã å¡©ã15ïŒ å¡©é ž140ïœããåçµæ¶
ãããäž¡çæç©ãåã ã¢ã»ãã³200ïœäžã«å ãã
å ç±éæµãäžæº¶æåãæ¿Ÿå»ãã溶液ãèžçºä¹Ÿç¥ã
ãã 以äžã®æ¹æ³ã«ãã€ãŠèç¹216âïŒå解ïŒã®ïŒâ
ããããã¿ã«é žã82.3ïœåŸãããã¯çè«å€ã®80ïŒ
ã«çžåœãããæŽã«èç¹172â173âïŒå解ïŒã®ïŒâ
ããããã¿ã«é žã78.8ïœåŸãããã¯çè«å€ã®74.8
ïŒ ã«çžåœãããäž¡çæç©ã¯èå±€ã¯ãããã°ã©ãã€
ãŒã«ããã°çŽåã§ãã€ãã å®æœäŸ ïŒâ11 å®æœäŸïŒã«èšèŒããæ¹æ³ã«ãã€ãŠç¡æ°Žãã¿ã«é ž
29.6ïœïŒ0.2ã¢ã«ïŒããããåãããç¡æ©é žæ®åº
ãé€å»ãããšãçŽç²ãªïŒâïŒïŒâããããã¿ã«é ž
æ··åç©26ïœãæ®ã€ãããããå®æœäŸïŒã«èšèŒãã
æ¹æ³ã«ããåç°æ§äœã«åé¢ããåŸãããïŒâåã³
ïŒâããããã¿ã«é žå¡©ãå®æœäŸïŒèšèŒãšåæ§ã«ã
éé¢é žã«å€æããããã®ä»ã®åå¿æ¡ä»¶åã³ïŒâå
ã³ïŒâããããã¿ã«é žã®åçã以äžã®è¡šã«ç€ºãã
ãè¡šã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ°ŽãïŒãªãã20容éïŒ å«æããäžæŽ»æ§ãªæ¥µæ§
ææ©æº¶åªäžã§ããã¿ã«é žååç©ã®ãããååå¿ç±
æ¥ã®ç¡æ©é žæ®åºãå«ãŸãªãïŒâåã³ïŒâãããã
ã¿ã«é žæ··åç©ã«ã20ãã100âã®éã®æž©åºŠã§ã ãŸãã該åå¿æº¶åªã«å®è³ªçã«äžæº¶ãªïŒâåã³ïŒ
âããããã¿ã«é žå¡©ã圢æãããå¡©åºããPHãçŽ
2.8ãšãªããŸã§å ããããšã«ãã€ãŠäž»ã«ïŒâãã
ããã¿ã«é žã¢ãå¡©ãããªãæ²æŸ±çæç©ãåé¢ãã ãã®åŸæŽã«äžèšç¯å²ã®æž©åºŠã§äžèšå¡©åºãPHãå°
ãªããšãçŽ4.5ã«ãªããŸã§å ããããšã«ãã€ãŠã
äž»ã«ïŒâããããã¿ã«é žå¡©ãããªãçæç©ãæ²æŸ±
ãããããšãããªã段éçãªå¡©åºåŠçãè¡ãªãã æåŸã«ãåŸãããããããã¿ã«é žå¡©ãå¥ã ã«çž
åœããéé¢é žã«å€æãããããŠå Žåã«ãã€ãŠã¯ã
ãçã粟補ããããšãããªãïŒâåã³ïŒâããã
ãã¿ã«é žæ··åç©ã®åé¢æ¹æ³ã ïŒ æ°ŽãïŒãªãã10容éïŒ å«æããäžæŽ»æ§ãªæ¥µæ§
ææ©æº¶åªäžã§åå¿ãè¡ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èš
èŒã®ïŒâåã³ïŒâããããã¿ã«é žæ··åç©ã®åé¢æ¹
æ³ã ïŒ äžæŽ»æ§ãªæ¥µæ§ææ©æº¶åªãšããŠèèªæã±ãã³å
ã¯ç·ççŽ ååæ°ïŒãªããïŒã®èèªæã¢ãã«ã«ãã³
é žã®ã¢ã«ãã«ãšã¹ãã«ã䜿çšããç¹èš±è«æ±ã®ç¯å²
第ïŒé ãŸãã¯ç¬¬ïŒé ã®ããããïŒé ã«èšèŒã®ïŒâ
åã³ïŒâããããã¿ã«é žæ··åç©ã®åé¢æ¹æ³ã ïŒ äžæŽ»æ§ãªæ¥µæ§ææ©æº¶åªãšããŠã¡ãã«ãšãã«ã±
ãã³åã¯é ¢é žãšãã«ã䜿çšããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé èšèŒã®ïŒâåã³ïŒâããããã¿ã«é žæ··åç©ã®
åé¢æ¹æ³ã ïŒ ç¡æ©å¡©åºã䜿çšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãª
ãã第ïŒé ã®ããããïŒé ã«èšèŒã®ïŒâåã³ïŒâ
ããããã¿ã«é žæ··åç©ã®åé¢æ¹æ³ã ïŒ å¡©åºãšããŠãã¢ã«ã«ãªéå±åã¯ã¢ã«ã«ãªåé¡
éå±ã®æ°Žé žåç©ãçé žå¡©åã¯çé žæ°ŽçŽ å¡©ã䜿çšã
ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ïŒâåã³ïŒâãã
ããã¿ã«é žæ··åç©ã®åé¢æ¹æ³ã ïŒ å¡©åºãšããŠçé žæ°ŽçŽ ãããªãŠã åã¯çé žæ°ŽçŽ
ã«ãªãŠã ã䜿çšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®
ïŒâåã³ïŒâããããã¿ã«é žæ··åç©ã®åé¢æ¹æ³ã ïŒ 30ãã50âã®éã®æž©åºŠã§å¡©ã圢æãããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé ãªãã第ïŒé ã®ããããïŒé ã«
èšèŒã®ïŒâåã³ïŒâããããã¿ã«é žæ··åç©ã®åé¢
æ¹æ³ã
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH613578A CH635065A5 (de) | 1978-06-05 | 1978-06-05 | Verfahren zum trennen von gemischen aus 3- und 4-nitrophthalsaeure. |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS54160334A JPS54160334A (en) | 1979-12-19 |
JPS6249261B2 true JPS6249261B2 (ja) | 1987-10-19 |
Family
ID=4304824
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7051179A Granted JPS54160334A (en) | 1978-06-05 | 1979-06-05 | Separation of 33and 44nitrophthalic acid mixture |
Country Status (8)
Country | Link |
---|---|
US (1) | US4284797A (ja) |
JP (1) | JPS54160334A (ja) |
BR (1) | BR7903493A (ja) |
CA (1) | CA1101883A (ja) |
CH (1) | CH635065A5 (ja) |
DE (1) | DE2922519A1 (ja) |
FR (1) | FR2428025A1 (ja) |
GB (1) | GB2022584B (ja) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3308460A1 (de) * | 1983-03-10 | 1984-09-13 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von m-nitrobenzoesaeuremethylester |
US6054609A (en) * | 1997-03-21 | 2000-04-25 | Sumikin Chemical Co., Ltd. | Method of separating isomers of nitrotoluic acid |
CN100432042C (zh) * | 2004-12-01 | 2008-11-12 | å¢å®ªæ¥ | 4-ç¡åºé»è¯äºç²é žçæçº¯å·¥èº |
CN1308677C (zh) * | 2004-12-29 | 2007-04-04 | åäº¬å€§åŠ | 3ïŒç¡åºæ4ïŒç¡åºé»è¯äºç²é žåå ¶æ莚çé«æ液çžè²è°±åææ³ |
CN1321972C (zh) * | 2005-06-27 | 2007-06-20 | æœå¥ | ä»è¯é ç¡åå¶å€3ïŒç¡åºé»è¯äºç²é žçååºæ¯æ¶²äžå¶å€4ïŒç¡åºé»è¯äºç²é žçæ¹æ³ |
CN101134728B (zh) * | 2007-09-27 | 2012-07-11 | æ¬å·å€§åŠ | ç¡åºé»è¯äºç²é žåååŒæäœæ··åç©çå犻æ¹æ³ |
US9045417B2 (en) | 2011-01-14 | 2015-06-02 | Celgene Corporation | Isotopologues of isoindole derivatives |
CN104974044A (zh) * | 2015-06-04 | 2015-10-14 | æ±èæ°žå®åå·¥æéå ¬åž | äžç§3-ç¡åºé»è¯äºç²é žçæ纯æ¹æ³ |
CN109180493B (zh) * | 2018-10-15 | 2021-09-03 | æ²³åéž¿æç¿è¯äžæéå ¬åž | ç±æ··ç¡åºé»è¯äºç²é žå¶å€3-ç¡åºé»è¯äºç²é žäž4-ç¡åºé»è¯äºç²é žçæ¹æ³ |
CN114634417B (zh) * | 2022-03-09 | 2023-05-05 | æ²³åæµ·åæè¿æ°ææè¡ä»œæéå ¬åž | äžç§ç¡åºé»è¯äºç²é žçå¶å€æ¹æ³ |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1549885A (en) * | 1925-04-01 | 1925-08-18 | Commercial Solvents Corp | Production of 3-nitrophthalic acid |
GB374010A (en) * | 1931-02-24 | 1932-05-24 | William Blythe And Company Ltd | Improvements in and relating to the resolution of mixtures of phenolic substances into their components |
GB427251A (en) | 1933-08-18 | 1935-04-18 | Ici Ltd | Manufacture of intermediates for dyes |
DE824815C (de) * | 1950-04-19 | 1951-12-13 | Cassella Farbwerke Mainkur Ag | Verfahren zur Herstellung eines sauren Wollfarbstoffs |
DE936944C (de) | 1952-04-02 | 1955-12-22 | Basf Ag | Verfahren zur Herstellung von Kondensationsprodukten |
DE935964C (de) | 1952-08-03 | 1955-12-01 | Hoechst Ag | Verfahren zur Erzeugung ueberfaerbeechter Faerbungen auf Fasergut aus Acetylcellulose sowie linearen Polyamiden oder Polyurethanen |
GB736974A (en) | 1952-09-11 | 1955-09-14 | Monsanto Chemicals | Process for the separation of some aromatic acids and esters |
DE1224731B (de) | 1964-12-16 | 1966-09-15 | Hoechst Ag | Verfahren zur Herstellung von Nitroterephthal-saeure |
GB1165637A (en) | 1967-07-19 | 1969-10-01 | Coalite Chem Prod Ltd | Production of Nitrophenols. |
-
1978
- 1978-06-05 CH CH613578A patent/CH635065A5/de not_active IP Right Cessation
-
1979
- 1979-05-31 US US06/044,122 patent/US4284797A/en not_active Expired - Lifetime
- 1979-06-01 DE DE19792922519 patent/DE2922519A1/de not_active Withdrawn
- 1979-06-01 CA CA328,928A patent/CA1101883A/en not_active Expired
- 1979-06-04 BR BR7903493A patent/BR7903493A/pt unknown
- 1979-06-04 GB GB7919469A patent/GB2022584B/en not_active Expired
- 1979-06-05 FR FR7914295A patent/FR2428025A1/fr active Granted
- 1979-06-05 JP JP7051179A patent/JPS54160334A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
FR2428025A1 (fr) | 1980-01-04 |
FR2428025B1 (ja) | 1983-11-10 |
GB2022584A (en) | 1979-12-19 |
CA1101883A (en) | 1981-05-26 |
US4284797A (en) | 1981-08-18 |
CH635065A5 (de) | 1983-03-15 |
DE2922519A1 (de) | 1979-12-06 |
GB2022584B (en) | 1982-09-08 |
JPS54160334A (en) | 1979-12-19 |
BR7903493A (pt) | 1980-01-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPH0742290B2 (ja) | ïŒïŒïŒâãžãããâïŒïŒšâããããïŒïŒïŒâαããããŒã«âïŒâã«ã«ãã³é žãšã¹ãã«ã®ïŒäœã®ã¢ãã€ã«åæ¹æ³ | |
JPS6249261B2 (ja) | ||
US4327215A (en) | Preparation of erythio-αpiperid-2-yl-2,8-bis-trifluoro-methyl)-quinolin-4-yl-methanol | |
JPS6034954B2 (ja) | ïŒïŒïŒâã¡ãã¬ã³ãžãªãã·ãã³ãã«é žã®è£œé æ³ | |
JPS6024781B2 (ja) | ã·ã¹âïŒâããããã·âïŒâããšãã«âïœâïŒâã·ã¯ããããµã³ã«ã«ãã³é žã®è£œé æ³ | |
JP3378745B2 (ja) | ïŒâã¢ã·ã«ã¢ããâïŒïŒïŒïŒïŒïŒïŒâããã©ã¡ãã«ãããªãžã³ã®è£œé æ¹æ³ | |
EP0000301B1 (fr) | Procédé de préparation de thiéno(2,3-c) et thiéno(3,2-c) pyridines | |
JPS5850240B2 (ja) | ã¢ã³ããã¹ã¿ã³ç³»ã®æ°èŠãªãžãšã³èªå°äœã®è£œé æ³ | |
KR840000115B1 (ko) | 칎ë°ì¡ž ì ë첎ì ì ì¡°ë°©ë² | |
US3023210A (en) | Production of carboxy-substituted heterocyclic compounds | |
HU178581B (en) | Process for producing 6-chloro-alpha-methyl-carbasole-2-acetic acid | |
JPH0557265B2 (ja) | ||
JP3291987B2 (ja) | ïŒïœâãžã¡ãã«âïœâã¢ã»ãã«ãã¹ãã«ã¢ããããªãšãŒãã®ç²Ÿè£œæ³ | |
EP0359474B1 (en) | Pyridazinone manufacture | |
Carmichael | CCCIV.âElectro-synthesis of azelaic and thapsic acids | |
JPS5919545B2 (ja) | æ°èŠäžç°åŒããç¶ã¢ãã³ååç© | |
US2993051A (en) | Process for making nicotinamide | |
JP3523661B2 (ja) | ïŒâã¢ã«ãã«âïŒâããã²ãâïŒâãã«ãã«ã€ãããŸãŒã«ã®ç²Ÿè£œæ¹æ³ | |
JPH0259142B2 (ja) | ||
JPH01213289A (ja) | ãã§ãã»ã³ã®è£œé æ¹æ³ | |
JPH06100512A (ja) | ã±ãé žã®è£œé æ¹æ³ | |
US3047578A (en) | Substituted reserpine and process of making the same | |
JPH06199809A (ja) | ïŒïŒïŒâãžããã¢ããªããžã³ã®è£œé æ³ | |
JPS6143177A (ja) | ïŒÂ±ïŒïŒâïŒâ²âïŒïœâãã«ãªãããšãã«ïŒâïŒâ²âãã³ãŸããµãŸãªã«ïŒœâããããªã³é žã®åå²æ³ | |
JPS5857335A (ja) | ïŒâïŒïŒâã€ã³ããã€ã«ïŒé ¢é žé¡ã®è£œé æ¹æ³ |