JPS62216635A - 油中水および多価アルコ−ル型乳化組成物 - Google Patents
油中水および多価アルコ−ル型乳化組成物Info
- Publication number
- JPS62216635A JPS62216635A JP61059844A JP5984486A JPS62216635A JP S62216635 A JPS62216635 A JP S62216635A JP 61059844 A JP61059844 A JP 61059844A JP 5984486 A JP5984486 A JP 5984486A JP S62216635 A JPS62216635 A JP S62216635A
- Authority
- JP
- Japan
- Prior art keywords
- water
- oil
- polyhydric alcohol
- polyoxyalkylene
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 150000005846 sugar alcohols Polymers 0.000 title claims abstract description 33
- 239000000839 emulsion Substances 0.000 title claims abstract description 24
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229920002545 silicone oil Polymers 0.000 claims abstract description 21
- 239000002734 clay mineral Substances 0.000 claims abstract description 17
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 15
- 238000002156 mixing Methods 0.000 claims abstract description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 125000001453 quaternary ammonium group Chemical group 0.000 abstract 1
- 230000008961 swelling Effects 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 37
- 239000012071 phase Substances 0.000 description 21
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 9
- 235000011187 glycerol Nutrition 0.000 description 9
- 238000005342 ion exchange Methods 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 8
- 239000002202 Polyethylene glycol Substances 0.000 description 8
- 229960001617 ethyl hydroxybenzoate Drugs 0.000 description 8
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 description 8
- 239000004403 ethyl p-hydroxybenzoate Substances 0.000 description 8
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 description 8
- 229920001223 polyethylene glycol Polymers 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 239000004205 dimethyl polysiloxane Substances 0.000 description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 7
- -1 fatty acid ester Chemical class 0.000 description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 7
- 239000007762 w/o emulsion Substances 0.000 description 6
- 239000001993 wax Substances 0.000 description 6
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 229910021647 smectite Inorganic materials 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229940057995 liquid paraffin Drugs 0.000 description 3
- 239000010445 mica Substances 0.000 description 3
- 229910052618 mica group Inorganic materials 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- CHMUFDYNGNBLBQ-UHFFFAOYSA-N 18-methylnonadecyl(phenyl)azanium;chloride Chemical compound [Cl-].CC(C)CCCCCCCCCCCCCCCCC[NH2+]C1=CC=CC=C1 CHMUFDYNGNBLBQ-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229920002385 Sodium hyaluronate Polymers 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 238000004581 coalescence Methods 0.000 description 2
- NCQWPDAAKWLRTD-UHFFFAOYSA-M diethyl-methyl-tetradecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(CC)CC NCQWPDAAKWLRTD-UHFFFAOYSA-M 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229940094522 laponite Drugs 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 2
- 239000000845 maltitol Substances 0.000 description 2
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 2
- 235000010449 maltitol Nutrition 0.000 description 2
- 229940035436 maltitol Drugs 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000003883 ointment base Substances 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229940010747 sodium hyaluronate Drugs 0.000 description 2
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 2
- 229940032094 squalane Drugs 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical compound C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- YXVILNGKJGMMSX-UHFFFAOYSA-N 2,2-dihydroxyethyl(docosyl)azanium chloride Chemical compound [Cl-].C(CCCCCCCCCCCCCCCCCCCCC)[NH2+]CC(O)O YXVILNGKJGMMSX-UHFFFAOYSA-N 0.000 description 1
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 235000004936 Bromus mango Nutrition 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002683 Glycosaminoglycan Polymers 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 240000007228 Mangifera indica Species 0.000 description 1
- 235000014826 Mangifera indica Nutrition 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 235000009184 Spondias indica Nutrition 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- LDDUCKDUDZVHLN-UHFFFAOYSA-N [2-hydroxy-3-[2-hydroxy-3-(16-methylheptadecanoyloxy)propoxy]propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)COCC(O)COC(=O)CCCCCCCCCCCCCCC(C)C LDDUCKDUDZVHLN-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000003212 astringent agent Substances 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- OEKQQTGTHCSDPW-UHFFFAOYSA-N benzyl(22-methyltricosyl)azanium;chloride Chemical compound [Cl-].CC(C)CCCCCCCCCCCCCCCCCCCCC[NH2+]CC1=CC=CC=C1 OEKQQTGTHCSDPW-UHFFFAOYSA-N 0.000 description 1
- OCBHHZMJRVXXQK-UHFFFAOYSA-M benzyl-dimethyl-tetradecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 OCBHHZMJRVXXQK-UHFFFAOYSA-M 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000003842 bromide salts Chemical class 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
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- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- SXPWTBGAZSPLHA-UHFFFAOYSA-M cetalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SXPWTBGAZSPLHA-UHFFFAOYSA-M 0.000 description 1
- 229960000228 cetalkonium chloride Drugs 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910000152 cobalt phosphate Inorganic materials 0.000 description 1
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical group O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 229940061607 dibasic sodium phosphate Drugs 0.000 description 1
- OGROBAAGXAWUPN-UHFFFAOYSA-M diethyl-methyl-octadecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(CC)CC OGROBAAGXAWUPN-UHFFFAOYSA-M 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- AJUWSIZSFHYZIQ-UHFFFAOYSA-M docosyl-diethyl-methylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(CC)CC AJUWSIZSFHYZIQ-UHFFFAOYSA-M 0.000 description 1
- RRTYRGMBMQXLSX-UHFFFAOYSA-M docosyl-ethyl-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)CC RRTYRGMBMQXLSX-UHFFFAOYSA-M 0.000 description 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- RXHDXDIEHWVFOC-UHFFFAOYSA-M ethyl-dimethyl-octadecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC RXHDXDIEHWVFOC-UHFFFAOYSA-M 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- JCDAAXRCMMPNBO-UHFFFAOYSA-N iron(3+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Ti+4].[Fe+3].[Fe+3] JCDAAXRCMMPNBO-UHFFFAOYSA-N 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000005527 methyl sulfate group Chemical group 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- JXHZVHFODJSANQ-UHFFFAOYSA-N n-ethyl-n-methylethanamine;hydrochloride Chemical compound Cl.CCN(C)CC JXHZVHFODJSANQ-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- CEYYIKYYFSTQRU-UHFFFAOYSA-M trimethyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)C CEYYIKYYFSTQRU-UHFFFAOYSA-M 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Colloid Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61059844A JPS62216635A (ja) | 1986-03-18 | 1986-03-18 | 油中水および多価アルコ−ル型乳化組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61059844A JPS62216635A (ja) | 1986-03-18 | 1986-03-18 | 油中水および多価アルコ−ル型乳化組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62216635A true JPS62216635A (ja) | 1987-09-24 |
| JPH0512979B2 JPH0512979B2 (enrdf_load_stackoverflow) | 1993-02-19 |
Family
ID=13124925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61059844A Granted JPS62216635A (ja) | 1986-03-18 | 1986-03-18 | 油中水および多価アルコ−ル型乳化組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62216635A (enrdf_load_stackoverflow) |
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63216815A (ja) * | 1987-03-06 | 1988-09-09 | Terumo Corp | 皮膚保護剤 |
| JPH01180237A (ja) * | 1988-01-12 | 1989-07-18 | Shiseido Co Ltd | 油中水型乳化組成物 |
| JPH0344309A (ja) * | 1989-06-29 | 1991-02-26 | Unilever Nv | 美容組成物 |
| JPH0593136A (ja) * | 1991-10-01 | 1993-04-16 | Shin Etsu Chem Co Ltd | 油中水型シリコ−ン乳化組成物 |
| WO2001000140A1 (en) * | 1999-06-25 | 2001-01-04 | Unilever Plc | Water-in-oil hair conditioner with lamellar dispersion in water phase |
| JP2001139990A (ja) * | 1999-08-31 | 2001-05-22 | Lion Corp | シリコーン及び水膨潤性粘土鉱物を含有する乳化組成物の製造方法及びその乳化組成物を含有する洗浄剤組成物 |
| JP2001506608A (ja) * | 1996-11-27 | 2001-05-22 | ザ、プロクター、エンド、ギャンブル、カンパニー | 改良された耐用性および美観の利点を有するマスカラ組成物 |
| EP1114635A1 (en) * | 1998-09-14 | 2001-07-11 | General Electric Company | Water-in-oil type silicone emulsion compositions |
| US6538019B1 (en) * | 2000-03-29 | 2003-03-25 | Japan As Represented By Director Of National Food Research Institute, Ministry Of Agriculture, Forestry And Fisheries | Functional emulsions |
| JP2006321725A (ja) * | 2005-05-17 | 2006-11-30 | Pola Chem Ind Inc | 乳化剤形の皮膚外用剤 |
| JP2007308381A (ja) * | 2006-05-16 | 2007-11-29 | Pola Chem Ind Inc | 油中水乳化剤形の皮膚外用剤 |
| JP2008524115A (ja) * | 2004-12-22 | 2008-07-10 | ポーラ化成工業株式会社 | 変性されたクレーを含む炎症予防皮膚外用剤 |
| US7771709B2 (en) | 2003-07-07 | 2010-08-10 | Shin-Etsu Chemical Co., Ltd. | Alternating copolymer of organopolysiloxane with grycerol derivative and a cosmetic comprising the same |
| WO2011049248A1 (ja) | 2009-10-23 | 2011-04-28 | 東レ・ダウコーニング株式会社 | 新規な共変性オルガノポリシロキサン |
| JP2011105681A (ja) * | 2009-11-20 | 2011-06-02 | Noevir Co Ltd | 油中水型乳化化粧料 |
| WO2011137212A1 (en) | 2010-04-29 | 2011-11-03 | Dow Corning Corporation | Cosmetic raw material |
| WO2011136389A2 (en) | 2010-04-28 | 2011-11-03 | Dow Corning Toray Co., Ltd. | Cosmetic and topical skin preparation comprising higher alcohol-modified silicone |
| JP2011528731A (ja) * | 2008-07-22 | 2011-11-24 | ダウ コーニング（シャンハイ）カンパニー リミテッド | 乳化組成物、乳化組成物を用いて線維構造を軟化させる方法、および乳化組成物を用いて処理された線維状基材 |
| EP2301522A4 (en) * | 2010-02-12 | 2013-07-03 | Shiseido Co Ltd | WATER IN OIL EMULSION COSMETIC PREPARATION |
| US9133309B2 (en) | 2009-10-23 | 2015-09-15 | Dow Corning Toray Co., Ltd. | Organopolysiloxane copolymer |
| US9580600B2 (en) | 2009-10-23 | 2017-02-28 | Dow Conring Toray Co., Ltd. | Thickening or gelling agent for oily raw materials |
| EP3168255A1 (en) | 2015-11-16 | 2017-05-17 | Shin-Etsu Chemical Co., Ltd. | Novel silicone compound and cosmetic containing thereof |
| WO2018012072A1 (ja) | 2016-07-14 | 2018-01-18 | 信越化学工業株式会社 | 新規シリコーン化合物およびこれを含む化粧料 |
| US10406092B2 (en) | 2012-12-28 | 2019-09-10 | Dow Silicones Corporation | Method for producing transparent or semi-transparent liquid glycerin-derivative-modified silicone composition |
| WO2021235274A1 (ja) | 2020-05-22 | 2021-11-25 | 信越化学工業株式会社 | 乳化剤及び乳化剤を含む乳化組成物 |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5575685B2 (ja) | 2011-03-29 | 2014-08-20 | 信越化学工業株式会社 | オルガノポリシロキサン及びそれを含む化粧料 |
| JP6560151B2 (ja) | 2016-03-28 | 2019-08-14 | 信越化学工業株式会社 | オルガノポリシロキサン、化粧料、及びオルガノポリシロキサンの製造方法 |
-
1986
- 1986-03-18 JP JP61059844A patent/JPS62216635A/ja active Granted
Cited By (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63216815A (ja) * | 1987-03-06 | 1988-09-09 | Terumo Corp | 皮膚保護剤 |
| JPH01180237A (ja) * | 1988-01-12 | 1989-07-18 | Shiseido Co Ltd | 油中水型乳化組成物 |
| JPH0344309A (ja) * | 1989-06-29 | 1991-02-26 | Unilever Nv | 美容組成物 |
| JPH0593136A (ja) * | 1991-10-01 | 1993-04-16 | Shin Etsu Chem Co Ltd | 油中水型シリコ−ン乳化組成物 |
| JP2001506608A (ja) * | 1996-11-27 | 2001-05-22 | ザ、プロクター、エンド、ギャンブル、カンパニー | 改良された耐用性および美観の利点を有するマスカラ組成物 |
| EP1114635A1 (en) * | 1998-09-14 | 2001-07-11 | General Electric Company | Water-in-oil type silicone emulsion compositions |
| AU767673B2 (en) * | 1999-06-25 | 2003-11-20 | Unilever Plc | Water-in-oil hair conditioner with lamellar dispersion in water phase |
| WO2001000140A1 (en) * | 1999-06-25 | 2001-01-04 | Unilever Plc | Water-in-oil hair conditioner with lamellar dispersion in water phase |
| JP2001139990A (ja) * | 1999-08-31 | 2001-05-22 | Lion Corp | シリコーン及び水膨潤性粘土鉱物を含有する乳化組成物の製造方法及びその乳化組成物を含有する洗浄剤組成物 |
| US6538019B1 (en) * | 2000-03-29 | 2003-03-25 | Japan As Represented By Director Of National Food Research Institute, Ministry Of Agriculture, Forestry And Fisheries | Functional emulsions |
| US7771709B2 (en) | 2003-07-07 | 2010-08-10 | Shin-Etsu Chemical Co., Ltd. | Alternating copolymer of organopolysiloxane with grycerol derivative and a cosmetic comprising the same |
| US8741323B2 (en) | 2004-12-22 | 2014-06-03 | Pola Chemical Industries Inc. | External skin agent comprising modified clay for preventing inflammation |
| JP2008524115A (ja) * | 2004-12-22 | 2008-07-10 | ポーラ化成工業株式会社 | 変性されたクレーを含む炎症予防皮膚外用剤 |
| JP2006321725A (ja) * | 2005-05-17 | 2006-11-30 | Pola Chem Ind Inc | 乳化剤形の皮膚外用剤 |
| JP2007308381A (ja) * | 2006-05-16 | 2007-11-29 | Pola Chem Ind Inc | 油中水乳化剤形の皮膚外用剤 |
| JP2011528731A (ja) * | 2008-07-22 | 2011-11-24 | ダウ コーニング（シャンハイ）カンパニー リミテッド | 乳化組成物、乳化組成物を用いて線維構造を軟化させる方法、および乳化組成物を用いて処理された線維状基材 |
| WO2011049248A1 (ja) | 2009-10-23 | 2011-04-28 | 東レ・ダウコーニング株式会社 | 新規な共変性オルガノポリシロキサン |
| US9580600B2 (en) | 2009-10-23 | 2017-02-28 | Dow Conring Toray Co., Ltd. | Thickening or gelling agent for oily raw materials |
| US8784787B2 (en) | 2009-10-23 | 2014-07-22 | Dow Corning Toray Co., Ltd. | Co-modified organopolysiloxane |
| US9133309B2 (en) | 2009-10-23 | 2015-09-15 | Dow Corning Toray Co., Ltd. | Organopolysiloxane copolymer |
| JP2011105681A (ja) * | 2009-11-20 | 2011-06-02 | Noevir Co Ltd | 油中水型乳化化粧料 |
| EP2301522A4 (en) * | 2010-02-12 | 2013-07-03 | Shiseido Co Ltd | WATER IN OIL EMULSION COSMETIC PREPARATION |
| JP5814117B2 (ja) * | 2010-02-12 | 2015-11-17 | 株式会社 資生堂 | Ｗ／ｏ乳化化粧料 |
| US9283164B2 (en) | 2010-04-28 | 2016-03-15 | Dow Corning Toray Co., Ltd. | Cosmetic and topical skin preparation comprising higher alcohol-modified silicone |
| WO2011136389A2 (en) | 2010-04-28 | 2011-11-03 | Dow Corning Toray Co., Ltd. | Cosmetic and topical skin preparation comprising higher alcohol-modified silicone |
| WO2011137212A1 (en) | 2010-04-29 | 2011-11-03 | Dow Corning Corporation | Cosmetic raw material |
| US10406092B2 (en) | 2012-12-28 | 2019-09-10 | Dow Silicones Corporation | Method for producing transparent or semi-transparent liquid glycerin-derivative-modified silicone composition |
| EP3168255A1 (en) | 2015-11-16 | 2017-05-17 | Shin-Etsu Chemical Co., Ltd. | Novel silicone compound and cosmetic containing thereof |
| KR20170057143A (ko) | 2015-11-16 | 2017-05-24 | 신에쓰 가가꾸 고교 가부시끼가이샤 | 신규 실리콘 화합물 및 이것을 포함하는 화장료 |
| US9890252B2 (en) | 2015-11-16 | 2018-02-13 | Shin-Etsu Chemical Co., Ltd. | Silicone compound and cosmetic containing thereof |
| WO2018012072A1 (ja) | 2016-07-14 | 2018-01-18 | 信越化学工業株式会社 | 新規シリコーン化合物およびこれを含む化粧料 |
| KR20190028702A (ko) | 2016-07-14 | 2019-03-19 | 신에쓰 가가꾸 고교 가부시끼가이샤 | 신규 실리콘 화합물 및 이것을 포함하는 화장료 |
| US10787544B2 (en) | 2016-07-14 | 2020-09-29 | Shin-Etsu Chemical Co., Ltd. | Silicone compound and cosmetic containing the same |
| WO2021235274A1 (ja) | 2020-05-22 | 2021-11-25 | 信越化学工業株式会社 | 乳化剤及び乳化剤を含む乳化組成物 |
| KR20230015945A (ko) | 2020-05-22 | 2023-01-31 | 신에쓰 가가꾸 고교 가부시끼가이샤 | 유화제 및 유화제를 포함하는 유화 조성물 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0512979B2 (enrdf_load_stackoverflow) | 1993-02-19 |
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