JPS6149654B2 - - Google Patents
Info
- Publication number
- JPS6149654B2 JPS6149654B2 JP9088382A JP9088382A JPS6149654B2 JP S6149654 B2 JPS6149654 B2 JP S6149654B2 JP 9088382 A JP9088382 A JP 9088382A JP 9088382 A JP9088382 A JP 9088382A JP S6149654 B2 JPS6149654 B2 JP S6149654B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- silver halide
- compound
- tetrazolium
- atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 claims description 139
- 229910052709 silver Inorganic materials 0.000 claims description 69
- 239000004332 silver Substances 0.000 claims description 69
- 239000000463 material Substances 0.000 claims description 46
- 150000001875 compounds Chemical class 0.000 claims description 45
- 239000000839 emulsion Substances 0.000 claims description 32
- 239000000084 colloidal system Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 20
- 125000003118 aryl group Chemical group 0.000 claims description 17
- 238000012545 processing Methods 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 125000001841 imino group Chemical group [H]N=* 0.000 claims description 4
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims description 4
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 4
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 125000004434 sulfur atom Chemical group 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 40
- 239000011248 coating agent Substances 0.000 description 34
- 238000000576 coating method Methods 0.000 description 34
- 239000000243 solution Substances 0.000 description 31
- 238000011161 development Methods 0.000 description 27
- 108010010803 Gelatin Proteins 0.000 description 17
- 239000008273 gelatin Substances 0.000 description 17
- 229920000159 gelatin Polymers 0.000 description 17
- 235000019322 gelatine Nutrition 0.000 description 17
- 235000011852 gelatine desserts Nutrition 0.000 description 17
- 239000007788 liquid Substances 0.000 description 17
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 239000000203 mixture Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000007864 aqueous solution Substances 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- 239000000975 dye Substances 0.000 description 9
- 230000035945 sensitivity Effects 0.000 description 9
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 8
- 239000000654 additive Substances 0.000 description 8
- 239000003112 inhibitor Substances 0.000 description 8
- 230000001681 protective effect Effects 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 7
- 125000003342 alkenyl group Chemical group 0.000 description 7
- 125000003277 amino group Chemical group 0.000 description 7
- 125000000623 heterocyclic group Chemical group 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 150000001450 anions Chemical class 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000011241 protective layer Substances 0.000 description 6
- 230000001235 sensitizing effect Effects 0.000 description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 125000003545 alkoxy group Chemical group 0.000 description 5
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 5
- 230000006866 deterioration Effects 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 5
- 125000003831 tetrazolyl group Chemical group 0.000 description 5
- 206010070834 Sensitisation Diseases 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- 229910021607 Silver chloride Inorganic materials 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000007888 film coating Substances 0.000 description 4
- 238000009501 film coating Methods 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000003672 processing method Methods 0.000 description 4
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 4
- 230000005070 ripening Effects 0.000 description 4
- 230000008313 sensitization Effects 0.000 description 4
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- QDVIEADSFRNGLY-UHFFFAOYSA-N 2-(5-dodecyl-3-phenyl-1h-tetrazol-1-ium-2-yl)-1,3-benzothiazole;bromide Chemical compound [Br-].N1C(CCCCCCCCCCCC)=N[NH+](C=2SC3=CC=CC=C3N=2)N1C1=CC=CC=C1 QDVIEADSFRNGLY-UHFFFAOYSA-N 0.000 description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 3
- KVWRURXFRFEOAA-UHFFFAOYSA-N 3-[4-[2,3-bis[4-(2-carboxyethyl)phenyl]-1h-tetrazol-1-ium-5-yl]phenyl]propanoic acid;chloride Chemical compound [Cl-].C1=CC(CCC(=O)O)=CC=C1N1[NH+](C=2C=CC(CCC(O)=O)=CC=2)N=C(C=2C=CC(CCC(O)=O)=CC=2)N1 KVWRURXFRFEOAA-UHFFFAOYSA-N 0.000 description 3
- LRUDIIUSNGCQKF-UHFFFAOYSA-N 5-methyl-1H-benzotriazole Chemical compound C1=C(C)C=CC2=NNN=C21 LRUDIIUSNGCQKF-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000011033 desalting Methods 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 150000002334 glycols Chemical class 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 239000006224 matting agent Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 3
- 235000019252 potassium sulphite Nutrition 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 229910001961 silver nitrate Inorganic materials 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 3
- NNVNAJGCZFCILW-UHFFFAOYSA-N 1'-methylspiro[3,4-dihydrochromene-2,4'-piperidine]-4-amine;hydrochloride Chemical compound Cl.C1CN(C)CCC21OC1=CC=CC=C1C(N)C2 NNVNAJGCZFCILW-UHFFFAOYSA-N 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- AUIKNBHTYGCEBL-UHFFFAOYSA-N 1-(2,3-diphenyl-1,3-dihydrotetrazol-3-ium-5-yl)ethanone;bromide Chemical compound [Br-].N1C(C(=O)C)=N[NH+](C=2C=CC=CC=2)N1C1=CC=CC=C1 AUIKNBHTYGCEBL-UHFFFAOYSA-N 0.000 description 2
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 2
- XIVWBKNPROLFNA-UHFFFAOYSA-N 1-[2,3-bis(4-ethoxyphenyl)-1,3-dihydrotetrazol-3-ium-5-yl]ethanone;bromide Chemical compound [Br-].C1=CC(OCC)=CC=C1N1[NH+](C=2C=CC(OCC)=CC=2)N=C(C(C)=O)N1 XIVWBKNPROLFNA-UHFFFAOYSA-N 0.000 description 2
- DCSVXNOJHXOKJQ-UHFFFAOYSA-N 2,3-diphenyl-1h-tetrazol-1-ium-5-carbonitrile;bromide Chemical compound [Br-].N1C(C#N)=N[NH+](C=2C=CC=CC=2)N1C1=CC=CC=C1 DCSVXNOJHXOKJQ-UHFFFAOYSA-N 0.000 description 2
- VSXBOKHHCCGVKJ-UHFFFAOYSA-N 2,3-diphenyl-1h-tetrazol-1-ium;chloride Chemical compound [Cl-].[NH2+]1C=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 VSXBOKHHCCGVKJ-UHFFFAOYSA-N 0.000 description 2
- CDNHHFDCGUXITF-UHFFFAOYSA-N 2,3-diphenyl-5-[4-(2,4,4-trimethylpentan-2-yloxy)phenyl]-1h-tetrazol-1-ium;chloride Chemical compound [Cl-].C1=CC(OC(C)(C)CC(C)(C)C)=CC=C1C1=NN(C=2C=CC=CC=2)N(C=2C=CC=CC=2)[NH2+]1 CDNHHFDCGUXITF-UHFFFAOYSA-N 0.000 description 2
- AQPVLFWWOYVUOV-UHFFFAOYSA-N 2,3-diphenyl-5-thiophen-2-yl-1,3-dihydrotetrazol-3-ium;chloride Chemical compound [Cl-].[NH2+]1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C1=CC=CS1 AQPVLFWWOYVUOV-UHFFFAOYSA-N 0.000 description 2
- FDFBKUYVYSKJKX-UHFFFAOYSA-N 2-(2,3-diphenyl-1,3-dihydrotetrazol-3-ium-5-yl)-1,3-benzoxazole;bromide Chemical compound [Br-].N1=C(C=2OC3=CC=CC=C3N=2)NN(C=2C=CC=CC=2)[NH+]1C1=CC=CC=C1 FDFBKUYVYSKJKX-UHFFFAOYSA-N 0.000 description 2
- WXECHSIKEZXOTL-UHFFFAOYSA-N 2-(2,3-diphenyl-1,3-dihydrotetrazol-3-ium-5-yl)quinoline;bromide Chemical compound [Br-].N1=C(C=2N=C3C=CC=CC3=CC=2)NN(C=2C=CC=CC=2)[NH+]1C1=CC=CC=C1 WXECHSIKEZXOTL-UHFFFAOYSA-N 0.000 description 2
- YAZMEKFTTBGDCH-UHFFFAOYSA-N 2-(3,5-diphenyl-1h-tetrazol-1-ium-2-yl)-1h-triazine;chloride Chemical compound [Cl-].N1C=CC=NN1N1N(C=2C=CC=CC=2)N=C(C=2C=CC=CC=2)[NH2+]1 YAZMEKFTTBGDCH-UHFFFAOYSA-N 0.000 description 2
- NBWRJAOOMGASJP-UHFFFAOYSA-N 2-(3,5-diphenyl-1h-tetrazol-1-ium-2-yl)-4,5-dimethyl-1,3-thiazole;bromide Chemical compound [Br-].S1C(C)=C(C)N=C1N1N(C=2C=CC=CC=2)N=C(C=2C=CC=CC=2)[NH2+]1 NBWRJAOOMGASJP-UHFFFAOYSA-N 0.000 description 2
- MIPQDTFFRSHLQU-UHFFFAOYSA-N 2-(4-iodophenyl)-3,5-diphenyl-1,3-dihydrotetrazol-3-ium;chloride Chemical compound [Cl-].C1=CC(I)=CC=C1N1[NH+](C=2C=CC=CC=2)N=C(C=2C=CC=CC=2)N1 MIPQDTFFRSHLQU-UHFFFAOYSA-N 0.000 description 2
- CWPXEQXAHVKIPE-UHFFFAOYSA-N 2-[2-(4-methoxyphenyl)-5-phenyl-1,3-dihydrotetrazol-3-ium-3-yl]-1,3-benzothiazole;bromide Chemical compound [Br-].C1=CC(OC)=CC=C1N1[NH+](C=2SC3=CC=CC=C3N=2)N=C(C=2C=CC=CC=2)N1 CWPXEQXAHVKIPE-UHFFFAOYSA-N 0.000 description 2
- KRKQPRJQBTVZNQ-UHFFFAOYSA-N 2-[2-(4-methylphenyl)-5-phenyl-1,3-dihydrotetrazol-3-ium-3-yl]-1,3-benzothiazole;bromide Chemical compound [Br-].C1=CC(C)=CC=C1N1[NH+](C=2SC3=CC=CC=C3N=2)N=C(C=2C=CC=CC=2)N1 KRKQPRJQBTVZNQ-UHFFFAOYSA-N 0.000 description 2
- KAOXCMHGMWDTBV-UHFFFAOYSA-N 2-[5-(2-chlorophenyl)-2-phenyl-1,3-dihydrotetrazol-3-ium-3-yl]-1,3-benzothiazole;bromide Chemical compound [Br-].ClC1=CC=CC=C1C1=N[NH+](C=2SC3=CC=CC=C3N=2)N(C=2C=CC=CC=2)N1 KAOXCMHGMWDTBV-UHFFFAOYSA-N 0.000 description 2
- BLWMNAXCPBTEKO-UHFFFAOYSA-N 2-[5-(4-chlorophenyl)-2-(4-nitrophenyl)-1,3-dihydrotetrazol-3-ium-3-yl]-1,3-benzothiazole;chloride Chemical compound [Cl-].C1=CC([N+](=O)[O-])=CC=C1N1[NH+](C=2SC3=CC=CC=C3N=2)N=C(C=2C=CC(Cl)=CC=2)N1 BLWMNAXCPBTEKO-UHFFFAOYSA-N 0.000 description 2
- LPYUENQFPVNPHY-UHFFFAOYSA-N 3-methoxycatechol Chemical compound COC1=CC=CC(O)=C1O LPYUENQFPVNPHY-UHFFFAOYSA-N 0.000 description 2
- UAYRQYDAMDWXHD-UHFFFAOYSA-N 4-(2,3-diphenyl-1,3-dihydrotetrazol-3-ium-5-yl)benzonitrile;chloride Chemical compound [Cl-].C1=CC(C#N)=CC=C1C1=N[NH+](C=2C=CC=CC=2)N(C=2C=CC=CC=2)N1 UAYRQYDAMDWXHD-UHFFFAOYSA-N 0.000 description 2
- PFYCIJQCNQPOTG-UHFFFAOYSA-N 4-(5-methyl-2-phenyl-1h-tetrazol-1-ium-3-yl)phenol;bromide Chemical compound [Br-].N1C(C)=N[NH+](C=2C=CC=CC=2)N1C1=CC=C(O)C=C1 PFYCIJQCNQPOTG-UHFFFAOYSA-N 0.000 description 2
- XCTSQILHZOXJKI-UHFFFAOYSA-N 4-[5-(4-nitrophenyl)-3-phenyl-1,3-dihydrotetrazol-3-ium-2-yl]phenol;chloride Chemical compound [Cl-].C1=CC(O)=CC=C1N1[NH+](C=2C=CC=CC=2)N=C(C=2C=CC(=CC=2)[N+]([O-])=O)N1 XCTSQILHZOXJKI-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 2
- LTRYTFOYRKRJLU-UHFFFAOYSA-N 5-(3,4-dimethoxyphenyl)-2-(2-ethoxyphenyl)-3-(4-methoxyphenyl)-1,3-dihydrotetrazol-3-ium;chloride Chemical compound [Cl-].CCOC1=CC=CC=C1N1[NH+](C=2C=CC(OC)=CC=2)N=C(C=2C=C(OC)C(OC)=CC=2)N1 LTRYTFOYRKRJLU-UHFFFAOYSA-N 0.000 description 2
- YUUSISNBOVSHOI-UHFFFAOYSA-N 5-(4-bromophenyl)-3-phenyl-2-(2,4,6-trichlorophenyl)-1,3-dihydrotetrazol-3-ium;chloride Chemical compound [Cl-].ClC1=CC(Cl)=CC(Cl)=C1N1[NH+](C=2C=CC=CC=2)N=C(C=2C=CC(Br)=CC=2)N1 YUUSISNBOVSHOI-UHFFFAOYSA-N 0.000 description 2
- QGOXSINMNRFRIG-UHFFFAOYSA-N 5-[2,3-diphenyl-4-(1h-tetrazol-1-ium-5-yl)butyl]-2,3-diphenyl-1h-tetrazol-1-ium;dibromide Chemical compound [Br-].[Br-].N=1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)[NH2+]C=1CC(C=1C=CC=CC=1)C(C=1C=CC=CC=1)CC=1N=NN[NH+]=1 QGOXSINMNRFRIG-UHFFFAOYSA-N 0.000 description 2
- CGVKBQYLTCVWCQ-UHFFFAOYSA-N 5-[2,3-diphenyl-4-(2h-tetrazol-1-ium-5-yl)phenyl]-2,3-diphenyl-1h-tetrazol-1-ium;dibromide Chemical compound [Br-].[Br-].[NH2+]1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C(C(=C1C=2C=CC=CC=2)C=2C=CC=CC=2)=CC=C1C=1N=NN[NH+]=1 CGVKBQYLTCVWCQ-UHFFFAOYSA-N 0.000 description 2
- DCWMUNBEDANGRF-UHFFFAOYSA-N 5-ethyl-2,3-diphenyl-1h-tetrazol-1-ium;bromide Chemical compound [Br-].N1C(CC)=N[NH+](C=2C=CC=CC=2)N1C1=CC=CC=C1 DCWMUNBEDANGRF-UHFFFAOYSA-N 0.000 description 2
- HNFYQHZMFHWWGF-UHFFFAOYSA-N 5-hexyl-2,3-diphenyl-1h-tetrazol-1-ium;bromide Chemical compound [Br-].N1C(CCCCCC)=N[NH+](C=2C=CC=CC=2)N1C1=CC=CC=C1 HNFYQHZMFHWWGF-UHFFFAOYSA-N 0.000 description 2
- RFZVUKSHEUPSMN-UHFFFAOYSA-N 5-methyl-2,3-diphenyl-1,3-dihydrotetrazol-3-ium;chloride Chemical compound [Cl-].[NH2+]1C(C)=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 RFZVUKSHEUPSMN-UHFFFAOYSA-N 0.000 description 2
- WSGURAYTCUVDQL-UHFFFAOYSA-N 5-nitro-1h-indazole Chemical compound [O-][N+](=O)C1=CC=C2NN=CC2=C1 WSGURAYTCUVDQL-UHFFFAOYSA-N 0.000 description 2
- XPAZGLFMMUODDK-UHFFFAOYSA-N 6-nitro-1h-benzimidazole Chemical compound [O-][N+](=O)C1=CC=C2N=CNC2=C1 XPAZGLFMMUODDK-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- DFQVGTFDFGVTGK-KVVVOXFISA-M ClC(C(=O)[O-])CCCCCC\C=C/CCCCCCCC.[K+] Chemical compound ClC(C(=O)[O-])CCCCCC\C=C/CCCCCCCC.[K+] DFQVGTFDFGVTGK-KVVVOXFISA-M 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
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- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
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- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- AJPXTSMULZANCB-UHFFFAOYSA-N chlorohydroquinone Chemical compound OC1=CC=C(O)C(Cl)=C1 AJPXTSMULZANCB-UHFFFAOYSA-N 0.000 description 1
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- DCZFGQYXRKMVFG-UHFFFAOYSA-N cyclohexane-1,4-dione Chemical compound O=C1CCC(=O)CC1 DCZFGQYXRKMVFG-UHFFFAOYSA-N 0.000 description 1
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- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
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- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
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- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N hydroquinone methyl ether Natural products COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
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- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
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- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
- QQPSGKLPTFKHCN-UHFFFAOYSA-N n-(4-benzamido-2,5-dihydroxyphenyl)benzamide Chemical compound OC=1C=C(NC(=O)C=2C=CC=CC=2)C(O)=CC=1NC(=O)C1=CC=CC=C1 QQPSGKLPTFKHCN-UHFFFAOYSA-N 0.000 description 1
- NPKFETRYYSUTEC-UHFFFAOYSA-N n-[2-(4-amino-n-ethyl-3-methylanilino)ethyl]methanesulfonamide Chemical compound CS(=O)(=O)NCCN(CC)C1=CC=C(N)C(C)=C1 NPKFETRYYSUTEC-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000006611 nonyloxy group Chemical group 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- COWNFYYYZFRNOY-UHFFFAOYSA-N oxazolidinedione Chemical compound O=C1COC(=O)N1 COWNFYYYZFRNOY-UHFFFAOYSA-N 0.000 description 1
- 125000002971 oxazolyl group Chemical group 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 239000000473 propyl gallate Substances 0.000 description 1
- 229940075579 propyl gallate Drugs 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 125000000714 pyrimidinyl group Chemical group 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical compound O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- IYKVLICPFCEZOF-UHFFFAOYSA-N selenourea Chemical compound NC(N)=[Se] IYKVLICPFCEZOF-UHFFFAOYSA-N 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- 235000010378 sodium ascorbate Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 1
- 229960005055 sodium ascorbate Drugs 0.000 description 1
- FZHLWVUAICIIPW-UHFFFAOYSA-M sodium gallate Chemical compound [Na+].OC1=CC(C([O-])=O)=CC(O)=C1O FZHLWVUAICIIPW-UHFFFAOYSA-M 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 150000003459 sulfonic acid esters Chemical class 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
- CBDKQYKMCICBOF-UHFFFAOYSA-N thiazoline Chemical compound C1CN=CS1 CBDKQYKMCICBOF-UHFFFAOYSA-N 0.000 description 1
- 125000000335 thiazolyl group Chemical group 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 125000005628 tolylene group Chemical group 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 125000006839 xylylene group Chemical group 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/29—Development processes or agents therefor
- G03C5/305—Additives other than developers
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
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Claims (1)
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ååã®ãšãã¯ïœã¯ïŒã§ãããïŒ
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9088382A JPS58207039A (ja) | 1982-05-27 | 1982-05-27 | ããã²ã³åéåçæå ææããã³ãã®åŠçæ¹æ³ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9088382A JPS58207039A (ja) | 1982-05-27 | 1982-05-27 | ããã²ã³åéåçæå ææããã³ãã®åŠçæ¹æ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58207039A JPS58207039A (ja) | 1983-12-02 |
| JPS6149654B2 true JPS6149654B2 (ja) | 1986-10-30 |
Family
ID=14010832
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9088382A Granted JPS58207039A (ja) | 1982-05-27 | 1982-05-27 | ããã²ã³åéåçæå ææããã³ãã®åŠçæ¹æ³ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58207039A (ja) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62111253A (ja) * | 1985-11-08 | 1987-05-22 | Konishiroku Photo Ind Co Ltd | ç»å圢ææ¹æ³ |
| JPS62134641A (ja) * | 1985-12-06 | 1987-06-17 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéåçæå ææ |
| JPS63314541A (ja) * | 1988-01-06 | 1988-12-22 | Fuji Photo Film Co Ltd | ç»å圢ææ¹æ³ |
| JP2649717B2 (ja) * | 1988-12-13 | 1997-09-03 | ã³ãã«æ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææ |
-
1982
- 1982-05-27 JP JP9088382A patent/JPS58207039A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58207039A (ja) | 1983-12-02 |
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