JPS59145552A - 複合物品 - Google Patents

複合物品

Info

Publication number
JPS59145552A
JPS59145552A JP59004654A JP465484A JPS59145552A JP S59145552 A JPS59145552 A JP S59145552A JP 59004654 A JP59004654 A JP 59004654A JP 465484 A JP465484 A JP 465484A JP S59145552 A JPS59145552 A JP S59145552A
Authority
JP
Japan
Prior art keywords
nickel
offshore
aluminum
alloy
steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP59004654A
Other languages
English (en)
Inventor
ジヨン・エフ・ブリ−デイス
ジユリウス・シ−・フイスタ−
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Olin Corp
Original Assignee
Olin Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Olin Corp filed Critical Olin Corp
Publication of JPS59145552A publication Critical patent/JPS59145552A/ja
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
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    • H01L24/42Wire connectors; Manufacturing methods related thereto
    • H01L24/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L24/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/001Interlayers, transition pieces for metallurgical bonding of workpieces
    • B23K35/002Interlayers, transition pieces for metallurgical bonding of workpieces at least one of the workpieces being of light metal
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/06Alloys based on copper with nickel or cobalt as the next major constituent
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    • H01L23/488Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor consisting of soldered or bonded constructions
    • H01L23/495Lead-frames or other flat leads
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Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。

Description

【発明の詳細な説明】 本発明は電気的用途に特別の有用性を有する睦Jニッケ
ル合金に関するものである。
数多くの電子装置はシリコンチップ上に半辞体坂積回r
6を含むパッケージをオ]1用している。一般的には、
^1[記回路はリードフレーム乃MH’J−ド碑体のよ
うな別の′眠気部品へと1っ父ばそれより多いリードワ
イヤ2介して′山気的に接続されている。
往々にして、前記リードワイヤは金から形成されている
。何故ならば金は電気伝尋度及び結合部に1−ぐれてい
るからである。しかしながら、金は高1出であるため、
リードワイヤとしてアルミニウム及びその合金のような
代替物質ケ用いようとする傾向がある。
リードフレームとカップの間に゛ル、気的徽続をもたら
′1−のに% MiJ記リードワイヤは一般的には該チ
ップの表面上の金属パッドに結合される。前記パッドは
チッソ0上に7%>、 イ”fさJしる金又はアルミニ
ウムのスポットから形成1−ることが出来る。
当業界においては釜リードワイヤのような余部相かアル
ミニウムパッドのようなアルミニウム部。
相に結合される時に、適七゛件の間融があることか9・
]]られている。高温度にさらされた時アルミニウムと
金の組合せはある檎の金属間化合物を形成し、この化合
物が両部相間の冶金学的結合部の強度及び信頼性χ劣丁
させる可能性がある。この現象は紫疫(purplep
lague )と呼はれている。
この問題を防止するために多くの異なるアプローチか試
みられてきた。1つのアブローナにおいて、アルミニウ
ム・リードワイヤのみがアルミニウムパッド又はストラ
イプに結合され、金のリードワイヤのみがメッキされた
金パッド又q金ストライフ″′に結合される。場合によ
ってはワイヤタイツ0のものはリードフレーム金属乃至
合金には結合されない。
望ましくない金属間化合物の形hlvケ防止1−るため
のよりありふれた技法は結合されるへき部品の少なくと
も一方ンニッケル又はニッケルーωカ素のような逆当な
バリア物ノ員で被惨コーティングすることであった。前
記バリア物質は結合さハた怖朴間の拡散の結果とし℃金
属間化合物か形成さノ′シることq vr J)ニーa
−る。ギャリ氏盾による木国和許m3,781.596
号はそのよウナニツケルパリア層がアルミニウムパッド
及び金托間に弾入されているのケf11示している、そ
のようなバリアjvは望ずしくない金属間化合物lの形
成を防止するのに有効であるが、互いに結合さ!しるへ
き部材の一つ又はそれ以上に保護コーティング’l 1
1tS加するのに関連する伺カロ的費用が高いためにこ
のアノ0ローチは実用的ではない。加えるに、コーチイ
ンクの非−様性及びメンキされたコーティング内に少量
のメッキ溶液がとりこまれてこれが後にあぶく及び他の
欠陥2生ずるという間馳が存在する。史には、バリア物
質としてニッケルが用いられる時には、核ニッケルが高
温度にさらされた時にニッケル酸化物か形成され、これ
がきわめて除去しにくぐ、γ1iIa足にろつf□Jけ
されないとい5問題が生ずる。
別のアプローチはリードワイヤ、リードフレーム、バ′
ツド及びその類いに用いる物質として金及びアルミニウ
ム以外の物質7探イことであった。
J穎もひんはんにh及される上記ll勿質の中にはニッ
ケル及びその合金、鈷及びその合金、コバルト及びその
合金部ひに鋼及びその合金が含まれろ、例えは、ホワイ
ト氏による米国l(す計第3.217.401号VCお
いては、ニッケル又は銅リードワイヤかアルミニウムで
被援され次に半導体装置のシリコン層に対して(′II
+圧されている。ペイライン民等による米国〕持f?+
′第4.CI 96.983号においては、アルミナセ
ラミック基紙体上の金膜に銅ワイヤリードン結合する方
法か開示されている。
リードフレーム又はリード導体及び他の電気部品Yコパ
ールのようなニッケル、鉄及び/又はコバルトの合金部
びに釦j合金c72500及びニッケル銀のようなリン
青砲、赤黄外1、駅銅及び鋼ニッケルを含む鉋の合金か
ら形成せしめることが提案されている、シバタ氏の米国
特許第3.!:168.301号、コックスジュニア氏
のi 3.689,684 号、オリファントジュニア
氏の第3.832.769号及びアリタ氏の第4,36
7.0’89号並びにNlckelTopics誌(第
8頁)の記事「ストライプ状σ)OA725(9%ニッ
ケル)は金の代りになり仕事の貿用馨〃1」約する」に
はこノtらの眠気部品VC用いられた種々の物質が例示
さハている。
不幸なことに、銘1及び銅合金部材をアルミニウム含有
部′4ソに結合才ると銅−アルはニウム金属間化合物を
形成することになる。こ11らの鯖−アルミニウム金属
間化合物は脆fヒし易く、部材間Q〕結合の一体性ン劣
下せしめろ。こitらの化合物は又結合された部材の電
気伝導度特性にも悪影N乞与える。これら□の望ましく
ない金属間化合物のプレ欣を防止するために、半嗜体寮
造業者はリードワイヤ+7) ヨ57.Cアルミニウム
部相がリードフレームのようン、C卸11部拐に結合さ
ノしる領域に欽メッキされたストライフ’ Y f、>
力11シてきた。蝉(メツキスドライブの代りにニッケ
ルメッキ表面も又用いられてきた。
本発明の1つの目的はアルミニウム官有部材に結合1−
ることの出来る剰1リベース合金部相であってell−
アルミニウム全1f+5間化合物の形成か少ない銅ベー
ス合金部朴ンJ8供することである。
本ヴへ明の別の目的はアルばニウム倉有部拐に結合さi
tjる劇ベース合金部枳であって、改−倶された9Dr
度及び一体(9Eを特命とする結合1qミ乞有する用ベ
ース合金f113徊を提供1〜ることである。
本発明の別の目的はアルミニウム含有部相に結合出来る
前述の附ベース合金であって、!侍に串、気B’i J
fJ途に有用性7有マろ物品を形成出来るような釦jベ
ース合金Z提供することである。
これらの目的及び史に別の目的は以下の説明及び付図か
ら明らかになるであろう。
本発明によれば、アルミニウム官有部材に結合され、得
る鋼ベース合金であって形成される鋼−アルミニウム金
属間化合物のレベルがl」・さい帽ベース合金が開示さ
れている。約1b%又はそれ以上のニッケルを格5力!
、+−fること((より望茹しぐないシーーアルミニウ
ム金属1’、Aj化合物の核発生靭1度及びその後の成
長速度か抑?tiljされるというごとか4−11明し
ている。
アルミニウム¥!i!lIに結合さ!しるへ゛き鋼部相
か約15%から約30弼のニッケルケ含む卸すベース合
金から形成される時′に良好な結果が得られることが判
明している。丙−ましい実施例においては、地部材は約
19係から約26%のニッケルン含む矩ベース合金から
形成される。
本発明は畔]部和かアルミニウム含有部わVこ結合され
るよ5な集積回路組立体にお℃・て特別の有用性を備え
ていることか伯1明した。例えは、R1I記鋼部側はア
ルミニウムリードワイヤに結合されるリードフレームと
することが出来ろ。ここvc M I#」されろニッケ
ル含有鋼ベース合金は生碑体パッケージのためのリード
フレーム、リードワイヤ及び/又はビームリードテーラ
0ン形成するのに用いることが出ンSろ。
アルミニウム部相に結合されるh1f記釦1部林はニッ
ケル含有銀合金単体から形成しても良いし、ニッケル“
含有胎合金ン含む沖合材から形成1−ることも出来る。
沖合宿迄体の一部として用いらゎ、る時tLは、1Vj
I記ニッケル自有剣1合金はクラッチゝイング牧)質又
はコア物質のいづれとしても用いろことが出来る。
以下句図をh照して本発明のより具体的7f祝明を行な
う。
本発明[よf’Lは、前述の目的及びオリ点は容易に達
成びtjる。
次に第1図ン参照′″′4−ると、集積回路組立体1゜
がレリ示さJlて(・る、、前記ボ目立体1oは金〃゛
蝋ベース14上に装着さえした集積1回路チップ12ン
1.(mえてイル。前記チップ12けシリコン5!、は
ケ8ルマニウムのような洒当な1勿質から形成1−るこ
とが出来、例えは凄着剤の如き適酒な方法によってベー
ス14に鋲7!ir1〜ることか出来る。ソー1フレー
ム18からの一枕数個のり−ド16も又ベース14に装
着さ]する。前記リード16はそれらン訪電体物質15
に結合することにより4−スに装着することが可能であ
り、当該物質15はベース14vcu合される。
抑数個のリードワイヤ20かチップ12及びリード16
に結合され、これらの間に重気的徽続部を形成している
。前記リードワイヤ2oは例えはサーモンニックボンヂ
イング、熱圧縮ボンディング、超旨鼓ボンディング等の
〕加当な慣用技法を用いて前記チップ12及びリード1
6に結合することか出来る。一般的には、h;J記す−
 ドヮイヤ2゜はチップ12の表面24上の複数イ向の
パッド22に結合さり、る。
集積回路=n立体の棹々の部品には多ぐの異なる物質か
月4いられている。例えは、前Sピ1)−1’i6及び
リードフレーム18は刻]り及び銅合金から形5Vされ
てセリ、リードワイヤ2υはアルミニウムンイヤであり
、パッド22は表面24上にメッキされた金のスポット
であった。これらの物質で組立体ビ刑成1〜る時の生鰻
なj■」趙点はφ1(リーアルdニウム金如聞化合物及
び金−アルミニウム金属間化合物のような= −t L
−<ない金属間化合物の形成であり、こねらの化合物は
前配袖々の部品間の冶金学的結合部σ)Ti気伝褥〃(
、ろうイqけ悦1、延性、一体す1三及 びイ3 累I
J1≦トにp基ζ力七シり叶 3七・ツクは−1−。
少/、cくとも約15%のニッヶルン含む餉ベース台ぐ
かアルミニウムリッチを花材に矛古合されると、酒d(
合金か者しく低いレベルの餉−アルミニウム金属間化合
物しか形成しないと(ミう拐〈べきη、実が判ゆ」した
。この結果、前述の;i:h合性の14J題?7版少さ
ゼる明がDJ能であり、とえ金MYメッキしたり金の部
ai’+ ’(用いるという方法がいらなくなる。例え
ば、集積[q1路組立体の前記リードフレーム及び/ン
は+7−ドワイヤはここに説ゆ4さとるニッケル含有゛
卸合金から形成’−tろことか出来る。カeえろに、チ
ツフ′上の金リードワイヤ及び/父は金パツドはアルミ
ニウムリードワイヤ〃び/又はパッド装置4翼大ろこと
が出来る。
少なくとも約15%のニッケル蔭加物な含む姉す合金は
アルミニウムリッチな金属1…化合物形成作用ケ抑制′
fることが出来ろ。^11訃:合金内のニッケルは銅の
拡散速度ケ碌連せしめることによりこれらの望ましく/
Xい金属間化合物の杉発生迭114″及び成長速度ン判
+ 1)11−1−ろものと力えら尤;る。そσ)結果
、9ib・1とアルミニウム含有iη(≦H間に形成さ
れる結合部には改−+−?き、f7た弘贋、市気的伝痔
1y、ろ5rJヒ)性及び1幾樫1均一1本性が借られ
4)。
本発明に脩るt:o、j @金は約15%から約30%
の節回のニラクル含有率馨有しているべきである。
好ましぐは、部1hピニッケル含有率は約19%から約
26%σ)n・1囲にある。前記七省内には1つ又はそ
れ以」二の4+ 7−+p +的j九プζか存在してい
てもRいか、゛ 当該元素(・まニッケル添力1]元素
の役割ンD害ぜ1°、(1jlの望ましい和性に危く#
勧乞及丙さないことが前十是粂注である。門トカ1]す
ることσ)出来るう己素には」乙釦、・マンガン、鉄、
錫、クローム及びモリブチ8ンか含まれろ。こ11もの
元素は以下のレベルにおいて存在していても良い。ji
’1.lちMi+嚢書ま約25係速いマンガンは約6%
迄、鉄は約1%迄、炬・は約1%迄、クロームは約5雀
迄及びモリブデンは約2雀迄である。力11えるに、ア
ルミニウム及び/又はケイ素ンハ1■紀ニッケル含有台
金に添力1j して1IIII酸化性ン改善し、より商
度の強黒及び剛曲げ疲労強度乞提伊−イーることが出来
る。q+、l Nf金合金約1雀迄のアルεニウム及び
/又は約1雀迄のケイ素を含むことが出来る。ここでは
、表示の自分率は也漏・自分イ・(%)ケ示している。
説明されたニッケル10i4j合金は任かの1ハ用の方
法で錫J造1−ることか出来る。棺ボの勧進方法はり身
に決力!的/工都1月では7jぐ、1θ接チル父は理絖
納造のような泊I当な方法ン採用1−ること力)出来ろ
1造の後、Mi+記合金合金当な処理手順に従って加工
することが出来る。用いられる加工プロセスは当該合金
に句与すべき特性とその用途に依存1−る。
例えは、nil記ニッケル含有銅合金は適当な開始温度
を以って熱間圧延することか出来る。熱間圧姑の後、前
記合金は少なくとも一回の中間yt、釜ψン施1−か施
さないで1つ父ばそれ以上のステップで最終の板塊迄冷
間圧処−4−ろことか出来る・宵を終機厚に仕上げられ
た後Mi記全合金それにハr望の調質カI果に与えるた
めにiβ1当な熱射8!ンMIJりす手が出来る。
種々の処理段階を当業界周知の態様で゛実施1−ること
か出来る。
所望の和゛性及び/又はル4躍、川を・晦えるよう処理
された供前記ニッケル包有矩合金は所望の壊・1品に製
作1″ることか出来る。例えは前記@金はリードフレー
ム18、リードワイヤ20、リードフームテーフ026
又は10シの物品へと形成することか出来る。こ才′シ
らσ)Dt望の物ノ品’r J+;成1−ろのに当粟界
で周矢IJ O)弘当な製作ナヌ法を用いることか出え
ろ。
Q+望とあらば、前記ニッケル含有拒合釜(・エアルミ
ニウム剖拐ン結合1−べき抄・合構造体の一梢として月
1℃・ることが出来ろ。前記ケ合惚ん体はクラツディン
グ又はコア物質乞)し欣1−るニッケル含有チ5合金に
より二車又は二車にクラッドされることか可能である。
もしも01丁記麹合偵造体か、リードフレーム父はビー
ムリードテープとして月・いらハろ時にはnJ記ニッケ
ル含有デ凹合金はyすましくはクラツディング物質とし
て用いらハ、一方前討コア物黄は蜘1合金015100
、(363800゜063810、C110Ll[J及
び019400のような適当な金属又は合金から形成寸
ゐことが出来る。ハ1[記ニッケル含有銅合金火りラツ
ディングq勿)f荘として月1いることにより、アルシ
ミニウム音13拐にFi’i合1−ろことの出来る溺足
な表面が提イμされろ。
本発明を例示1−るために5つの秩合拐か用急された。
これらのれ金相はアルミニウム合金1100のストリッ
プを次のコア物質にクラッド結合させたものからなって
いる。 CIIZiJ合KO110Cj[Jのストリン
ツブ、(2)基本H′−Jに約10%のニッケルと残余
θ)基本1」9に制用とからなる鎗合金のストリップ、
(3)基本的に1.i 2 []%のニッケル及び残余
の基本的に餉とからなる卸1合金のストリップ、(41
基本的に約60%のニッケル及び残余の基本的にtl「
;とから/fる静す合金のストリップ0、並びに(5)
ニッケル合金200のストリレツブである。前記ネル合
相は登録Hy標PO8工T−BONDボンディング方法
乞用(・て形成された。
各松合わの試料は200℃、3.00℃及び400℃に
おいて焼鈍された。炉、銚時間は62時間迄にわたって
いた。その後前記試料は金属間化合物があるかどうか金
属組織学的に吟味された〇各焼鈍条件において各桐相試
片内に峰められたん太の金属間化合物ノリ賭が表1に要
約されている。
表 1 最大の金属間化合物J卑吐(μm) 時  間  (h) 初台徊 γ品度 2  4  8  16  32AL
Vc1100   200  [J、39 0.39 
0.78  tJ、78 0.78んMOu、t−1O
Ni   200   [J   U、39 0.78
  (3,69[J、78A、VC!u+2ONi  
  200    fJ      OOOoろ9  
0.39Ai/Cu+3ONi     20口   
 0[J[J[J[JAi21N12[JOO000L
I Q、5   1   2  4   B   ’+6A
JVCIIO30[J  1.61.6  2.3 3
.1 3.13.ソAJ!/10u+IQNi    
300  1.6  1.6   2.3  2.3 
  ろ、1 4.7Ai/10u+2QNi     
ろ00     [J      IJ、78   1
.6   2.3   2.33.1A410u+3O
Ni     300     0        C
111口      0     UA」少イNi  
          30oociauo。
Q、b124816 Ak/c110    400  6.2  7   
 シ、310.9 16 21.8A4/cu+10t
vi   400  5.4  7  11.7 16
 20.227.2A7/Cu+2ONi   400
  3−9 5.4  7.810.1 14.4 1
6AjvCu+3ONi    400  1.6 0
.78  2.3  2.3  5.4  6.2Mハ
i      400  0−39[J、78  L6
 2.3 2.3 4.7このデータは不発1力に従う
ニッケル添力ll!l勿か餉用−アルミニウム金漢間化
合物形成速1j3’: Y 1目的に抑11ilI し
ていろということケ示して(・ろ。
[)tJ M12ニッケル含有合金は集積回路組立体の
ための部品用として部門されてきたが、当該合金はli
a部拐かアルミニウム部セに結合され、銅−アルミニウ
ム金が、間化合物のjp Iiンipi小に押えたいと
いう1]1シの用途にも用いることか出来る。
炉1図においては制別のタイプの11−積[I−1]路
糾立体が例示さJtだか、本発明の銅合金部イソはイ1
1フのタイプ0の片41″(回路組や体にも用いる事か
出来る。例えは、本会111合金部わば1つ又はそれ以
上のアルミニウム又はアルミニウム合金ワイヤによって
チップに’f’j:気的に接続される支柱電気部品又は
佃の電気部品ケ構成するq」が出来る、 本発明によれは、不明細刊において述べた目8す、手段
及び第1」カン十分満足する、銅−アルミニウム金属間
化合物の成長ケ抑制出沫る動・1合金か提供されている
ことは明白でル)る。本発明はその特定の実施f14と
1lili合せて酸1明されてきたが、teil址の説
明より当業渚には多くの代替例、イレ整例及び変史例が
汁んでくることは明らかて゛ある。従って、そのような
全ての代替例、(l、+」タイプ11及び亥史例(ま徒
W「誼求の筋」四のね神に含まれろものと理′Mされた
い。
【図面の簡単な説明】
第1図は年積回路組泣体の1!1)T面図であり、外積
回路チップの表面上のパッド’Y IJ−ドフレームの
DJ ?31Sと連結しているワイヤ溶体7示して℃・
る、第2図はリードフレームの平raJ図、第6図はビ
ームリードテープの平面図である。 18・・リードフレーム、20・・リードワイヤ、12
・半導体チップ、22・・パッド 代理人 浅 村   皓

Claims (1)

  1. 【特許請求の範囲】 (1)  アルミニウム含有物買から形成された第1の
    部材(20)と、銅含有q9/J質から形成された第2
    の部材(18,22)とを有し、前記第1及び第2の部
    材は互いに結合されている沖合物品において、前記第2
    の部材(18,22)は少なくとも15%のニッケル及
    び残余の基本的に鋤とからなる銅ベース合金によって形
    成されており、iji記紳リベすス合金は側rj−アル
    ミニウム金属間化合物のルy長乞抑制していることン特
    普とする沖合物品。 (2)  特許請求の範囲第1項に記載の沖合物品にお
    いて、前記鋼ベース合金か4本的に約15%から約30
    %σ)ニッケルと残余の基本的に鋼とからなっているこ
    とを特徴とする沖合物品。 (3)特許請求の範囲第1項に記載の沖合物品[おいて
    、前記鋼ベース合金は基本的に約19%から約26%の
    ニッケル及び残余の基本的[納とからなっていること乞
    %徴とする沖合物品。 (4)特許請求の範囲第1項に記載の沖合物品において
    、該物品は集積回路組立体ケ有しており、前記第2の部
    材はυ〜ドフレームC1C13)しており、前記第1の
    部材は前記リードフレームに結合されたリードワイヤ(
    20)v有していることを%徴とてる沖合物品、 (5)Ill′81′許請求の範囲第1項に記載の沖合
    物品において、該物品は半導体チップ(12)’Y備え
    た集積回路組や体を臀しており、前記第1の部材は前記
    チップ0の表面上にパッド(22)v有しており、前記
    第2の部材は前記パッドに結合されたリードワイヤ(2
    0)Y有していること乞特徴とする沖合物品。 (6)  %計請求の範囲第1項に記載の初台物1品に
    おいて、該沖合物品は半導体チップ(12)を備えた年
    積回路組立体を有しており、前記第2の部υは電気的に
    導電性の部材(18,22)を有しており、前記第1の
    部材は前記チップ及び前記第2の部材間に接続部を形成
    でる少なくとも1本のワイヤ(20)2有していること
    乞特徴とてるネぷ合勺勿品。 (7)特許請求の範囲第1項に81載の沖合物品におい
    て、前記第2の部徊はクラツディング物質としての前記
    銅ベース合金と金属又は合金のコアと乞備えた沖合構造
    体ケ有していることを%葎と1−るネ〃合物品。 (8)特許請求の」リシ囲第1項に1戦の初合物品にお
    いてtqIJ記剰1」ベース合金は約1%迄のアルミニ
    ウムを含んでいること乞特徴とする伏合物ノ晶。 (9+  t+> g’r g青水の!i) la」m
     1 mに記載の初会9勿品において、14il記鋼ベ
    一ス合金は約1%迄のケイ系を含んでいることン斗寺り
    と才る初@9勿品。 0())  アルミニウム含有部N4 (20) [結
    合された銅含有部拐(18,22)を備えた物品におけ
    ろ胎−アルミニウム金属1出化合物の成長を用ノ制する
    方法であって、該方法は前記附含有部相(18゜22)
    Y基本1」9に少なくとも約15係のニッケルと残余の
    基本的に鋼とからなる鉋ベース合金から形成する段1竹
    と、前記鋼ベース合金娶前記アルミニウム含有部材に結
    合1−る段階とを有イろことン特徴とする沖合物品。 θ1)特許請求の範囲第10項に記載の方法において、
    前記銅ベース合金が基本的に約15係から約60%のニ
    ッケル及び残余の基本的に銅とからなることン特徴とす
    る方法。 (12)  特許請求の範囲第10項に記載の方法にお
    いて、前記鋼ベース合金か基本的に約19%から約26
    %のニッケル及び)A金の基本的に蛸とからなること乞
    特徴とする方法。
JP59004654A 1983-01-13 1984-01-13 複合物品 Pending JPS59145552A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US457605 1983-01-13
US06/457,605 US4498121A (en) 1983-01-13 1983-01-13 Copper alloys for suppressing growth of Cu-Al intermetallic compounds

Publications (1)

Publication Number Publication Date
JPS59145552A true JPS59145552A (ja) 1984-08-21

Family

ID=23817391

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59004654A Pending JPS59145552A (ja) 1983-01-13 1984-01-13 複合物品

Country Status (4)

Country Link
US (1) US4498121A (ja)
EP (1) EP0116844A3 (ja)
JP (1) JPS59145552A (ja)
CA (1) CA1219104A (ja)

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Also Published As

Publication number Publication date
EP0116844A3 (en) 1985-01-30
CA1219104A (en) 1987-03-17
US4498121A (en) 1985-02-05
EP0116844A2 (en) 1984-08-29

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