JPS5841291B2 - 一成分型室温硬化性珪素末端重合体の製造法 - Google Patents
一成分型室温硬化性珪素末端重合体の製造法Info
- Publication number
- JPS5841291B2 JPS5841291B2 JP6524474A JP6524474A JPS5841291B2 JP S5841291 B2 JPS5841291 B2 JP S5841291B2 JP 6524474 A JP6524474 A JP 6524474A JP 6524474 A JP6524474 A JP 6524474A JP S5841291 B2 JPS5841291 B2 JP S5841291B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- polymer
- silicon
- parts
- terminated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 title claims description 80
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- -1 hydrosilicon compound Chemical class 0.000 claims description 35
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 27
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 16
- 229910052710 silicon Inorganic materials 0.000 claims description 15
- 239000010703 silicon Substances 0.000 claims description 10
- 125000004423 acyloxy group Chemical group 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- 229910052723 transition metal Inorganic materials 0.000 claims description 5
- 150000003624 transition metals Chemical class 0.000 claims description 5
- 150000002430 hydrocarbons Chemical group 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 42
- 238000000034 method Methods 0.000 description 38
- 238000006243 chemical reaction Methods 0.000 description 23
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 22
- 229910052757 nitrogen Inorganic materials 0.000 description 22
- 239000000203 mixture Substances 0.000 description 20
- 238000006459 hydrosilylation reaction Methods 0.000 description 19
- 239000012298 atmosphere Substances 0.000 description 18
- 229920000620 organic polymer Polymers 0.000 description 18
- 125000000524 functional group Chemical group 0.000 description 17
- 150000004756 silanes Chemical class 0.000 description 16
- 150000001336 alkenes Chemical group 0.000 description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 14
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 12
- 229910000019 calcium carbonate Inorganic materials 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 239000003963 antioxidant agent Substances 0.000 description 10
- 239000005028 tinplate Substances 0.000 description 10
- 230000003078 antioxidant effect Effects 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- KTQYJQFGNYHXMB-UHFFFAOYSA-N dichloro(methyl)silicon Chemical compound C[Si](Cl)Cl KTQYJQFGNYHXMB-UHFFFAOYSA-N 0.000 description 7
- 125000001475 halogen functional group Chemical group 0.000 description 7
- 229910052742 iron Inorganic materials 0.000 description 7
- 239000005048 methyldichlorosilane Substances 0.000 description 7
- 229910052697 platinum Inorganic materials 0.000 description 7
- 229920000570 polyether Polymers 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 6
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000004721 Polyphenylene oxide Substances 0.000 description 6
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 6
- PKTOVQRKCNPVKY-UHFFFAOYSA-N dimethoxy(methyl)silicon Chemical compound CO[Si](C)OC PKTOVQRKCNPVKY-UHFFFAOYSA-N 0.000 description 6
- 239000005350 fused silica glass Substances 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 159000000002 lithium salts Chemical class 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- 239000000565 sealant Substances 0.000 description 6
- 239000011521 glass Substances 0.000 description 5
- 229910003002 lithium salt Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 229920005862 polyol Polymers 0.000 description 5
- 150000003077 polyols Chemical class 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 4
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 4
- 125000002344 aminooxy group Chemical group [H]N([H])O[*] 0.000 description 4
- AONDIGWFVXEZGD-UHFFFAOYSA-N diacetyloxy(methyl)silicon Chemical compound CC(=O)O[Si](C)OC(C)=O AONDIGWFVXEZGD-UHFFFAOYSA-N 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 159000000001 potassium salts Chemical class 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
- 125000000746 allylic group Chemical group 0.000 description 3
- 125000003368 amide group Chemical group 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 3
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 3
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 3
- 239000012433 hydrogen halide Substances 0.000 description 3
- 229910000039 hydrogen halide Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920005906 polyester polyol Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000007086 side reaction Methods 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 3
- 239000005052 trichlorosilane Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- DMYOHQBLOZMDLP-UHFFFAOYSA-N 1-[2-(2-hydroxy-3-piperidin-1-ylpropoxy)phenyl]-3-phenylpropan-1-one Chemical compound C1CCCCN1CC(O)COC1=CC=CC=C1C(=O)CCC1=CC=CC=C1 DMYOHQBLOZMDLP-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229920001174 Diethylhydroxylamine Polymers 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical group NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- 229920001079 Thiokol (polymer) Polymers 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- PXAJQJMDEXJWFB-UHFFFAOYSA-N acetone oxime Chemical compound CC(C)=NO PXAJQJMDEXJWFB-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 150000002443 hydroxylamines Chemical class 0.000 description 2
- 239000012442 inert solvent Substances 0.000 description 2
- 150000003961 organosilicon compounds Chemical class 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 150000003141 primary amines Chemical class 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 239000012763 reinforcing filler Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- PYOKUURKVVELLB-UHFFFAOYSA-N trimethyl orthoformate Chemical compound COC(OC)OC PYOKUURKVVELLB-UHFFFAOYSA-N 0.000 description 2
- CWLUFVAFWWNXJZ-UHFFFAOYSA-N 1-hydroxypyrrolidine Chemical compound ON1CCCC1 CWLUFVAFWWNXJZ-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical group CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 1
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 1
- 102220474557 Connector enhancer of kinase suppressor of ras 1_C12S_mutation Human genes 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 1
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- MZFBKHCHWCYNSO-UHFFFAOYSA-N [acetyloxy(phenyl)silyl] acetate Chemical compound CC(=O)O[SiH](OC(C)=O)C1=CC=CC=C1 MZFBKHCHWCYNSO-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- HXBPYFMVGFDZFT-UHFFFAOYSA-N allyl isocyanate Chemical compound C=CCN=C=O HXBPYFMVGFDZFT-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- QABCGOSYZHCPGN-UHFFFAOYSA-N chloro(dimethyl)silicon Chemical compound C[Si](C)Cl QABCGOSYZHCPGN-UHFFFAOYSA-N 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- HKYGSMOFSFOEIP-UHFFFAOYSA-N dichloro(dichloromethoxy)methane Chemical compound ClC(Cl)OC(Cl)Cl HKYGSMOFSFOEIP-UHFFFAOYSA-N 0.000 description 1
- OSXYHAQZDCICNX-UHFFFAOYSA-N dichloro(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](Cl)(Cl)C1=CC=CC=C1 OSXYHAQZDCICNX-UHFFFAOYSA-N 0.000 description 1
- XNAFLNBULDHNJS-UHFFFAOYSA-N dichloro(phenyl)silicon Chemical compound Cl[Si](Cl)C1=CC=CC=C1 XNAFLNBULDHNJS-UHFFFAOYSA-N 0.000 description 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 1
- CIQDYIQMZXESRD-UHFFFAOYSA-N dimethoxy(phenyl)silane Chemical compound CO[SiH](OC)C1=CC=CC=C1 CIQDYIQMZXESRD-UHFFFAOYSA-N 0.000 description 1
- QKIUAMUSENSFQQ-UHFFFAOYSA-N dimethylazanide Chemical compound C[N-]C QKIUAMUSENSFQQ-UHFFFAOYSA-N 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- MAWLKRJXJGHDRD-UHFFFAOYSA-N ethene;platinum Chemical group [Pt].C=C MAWLKRJXJGHDRD-UHFFFAOYSA-N 0.000 description 1
- 239000012765 fibrous filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000005003 food packaging material Substances 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000005805 hydroxylation reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000005055 methyl trichlorosilane Substances 0.000 description 1
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- VMESOKCXSYNAKD-UHFFFAOYSA-N n,n-dimethylhydroxylamine Chemical compound CN(C)O VMESOKCXSYNAKD-UHFFFAOYSA-N 0.000 description 1
- HHTXZECVRBDEPA-UHFFFAOYSA-N n-methylacetamide;sodium Chemical compound [Na].CNC(C)=O HHTXZECVRBDEPA-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000005054 phenyltrichlorosilane Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical class Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- CAEWJEXPFKNBQL-UHFFFAOYSA-N prop-2-enyl carbonochloridate Chemical compound ClC(=O)OCC=C CAEWJEXPFKNBQL-UHFFFAOYSA-N 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 229940080818 propionamide Drugs 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 125000005371 silicon functional group Chemical group 0.000 description 1
- 229910052990 silicon hydride Inorganic materials 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- XININPZNFAAMHI-UHFFFAOYSA-N sodium;1-methoxyethanolate Chemical compound [Na+].COC(C)[O-] XININPZNFAAMHI-UHFFFAOYSA-N 0.000 description 1
- UIICPZFWHBJNIG-UHFFFAOYSA-N sodium;2-methoxyethanolate Chemical compound [Na+].COCC[O-] UIICPZFWHBJNIG-UHFFFAOYSA-N 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- ORVMIVQULIKXCP-UHFFFAOYSA-N trichloro(phenyl)silane Chemical compound Cl[Si](Cl)(Cl)C1=CC=CC=C1 ORVMIVQULIKXCP-UHFFFAOYSA-N 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
- GKASDNZWUGIAMG-UHFFFAOYSA-N triethyl orthoformate Chemical compound CCOC(OCC)OCC GKASDNZWUGIAMG-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 239000005051 trimethylchlorosilane Substances 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Polyethers (AREA)
- Paints Or Removers (AREA)
- Sealing Material Composition (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6524474A JPS5841291B2 (ja) | 1974-06-07 | 1974-06-07 | 一成分型室温硬化性珪素末端重合体の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6524474A JPS5841291B2 (ja) | 1974-06-07 | 1974-06-07 | 一成分型室温硬化性珪素末端重合体の製造法 |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21037482A Division JPS5921893B2 (ja) | 1982-11-30 | 1982-11-30 | 一成分型室温硬化性珪素末端重合体の製造法 |
| JP9336484A Division JPS606747A (ja) | 1984-05-09 | 1984-05-09 | 室温硬化性組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS50156599A JPS50156599A (enExample) | 1975-12-17 |
| JPS5841291B2 true JPS5841291B2 (ja) | 1983-09-10 |
Family
ID=13281293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6524474A Expired JPS5841291B2 (ja) | 1974-06-07 | 1974-06-07 | 一成分型室温硬化性珪素末端重合体の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5841291B2 (enExample) |
Families Citing this family (72)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS546096A (en) * | 1977-06-15 | 1979-01-17 | Kanegafuchi Chem Ind Co Ltd | Preparation of silyl-terminated polymer |
| JPS546097A (en) * | 1977-06-15 | 1979-01-17 | Kanegafuchi Chem Ind Co Ltd | Room termperature curing composition |
| JPS591423B2 (ja) * | 1977-12-29 | 1984-01-12 | 鐘淵化学工業株式会社 | 室温硬化性組成物 |
| JPS5582123A (en) * | 1978-12-18 | 1980-06-20 | Shin Etsu Chem Co Ltd | Polyoxyalkylene polyether having terminal silanol group |
| JPS5667366A (en) * | 1979-11-05 | 1981-06-06 | Kanegafuchi Chem Ind Co Ltd | Curable composition |
| JPS5682867A (en) * | 1979-12-08 | 1981-07-06 | Osaka Gas Co Ltd | Sealant for screw joint part |
| JPS57126823A (en) * | 1981-01-31 | 1982-08-06 | Kanegafuchi Chem Ind Co Ltd | Silyl-terminated polymer and its production |
| JPS57174341A (en) * | 1981-04-20 | 1982-10-27 | Kanegafuchi Chem Ind Co Ltd | Composition having excellent weather resistance |
| EP0302712B1 (en) * | 1987-08-04 | 1996-11-13 | Asahi Kasei Kogyo Kabushiki Kaisha | Novel copolycarbonate |
| JP2676355B2 (ja) * | 1988-02-25 | 1997-11-12 | 鐘淵化学工業株式会社 | 改良された複層仕上方法 |
| JP2995568B2 (ja) * | 1989-05-09 | 1999-12-27 | 旭硝子株式会社 | ポリアルキレンオキシド誘導体の製造法 |
| US6280562B1 (en) | 1990-02-13 | 2001-08-28 | Cemedine Company, Ltd | Contact adhering method |
| JPH072828B2 (ja) * | 1990-04-03 | 1995-01-18 | 鐘淵化学工業株式会社 | 硬化性樹脂組成物 |
| US5910555A (en) * | 1996-05-16 | 1999-06-08 | Kaneka Corporation | Curable resin composition with improved adhesion of coatings |
| CA2221389C (en) * | 1996-11-18 | 2009-01-27 | Kenrick M. Lewis | Treatment of polyethers prior to hydrosilylation |
| JP3803998B2 (ja) | 1999-04-22 | 2006-08-02 | 横浜ゴム株式会社 | 一液型湿気硬化性組成物 |
| EP1288247B1 (en) | 2000-05-24 | 2008-07-16 | Kaneka Corporation | Curable compositions and compatibilizing agent |
| US7176269B2 (en) | 2000-07-25 | 2007-02-13 | Mitsui Chemicals, Inc. | Curable composition and its use |
| JP4101632B2 (ja) * | 2002-11-01 | 2008-06-18 | 株式会社カネカ | 硬化性組成物および復元性、クリープ性改善方法 |
| TW200512268A (en) | 2003-07-18 | 2005-04-01 | Konishi Co Ltd | Curable resin composition and ambient temperature curable adhesive |
| WO2005087865A1 (ja) * | 2004-03-12 | 2005-09-22 | Cemedine Co., Ltd. | 湿気硬化型組成物及び接着方法 |
| US20070208108A1 (en) | 2004-04-01 | 2007-09-06 | Katsuyu Wakabayashi | Single-Component Curable Composition |
| US8067498B2 (en) | 2004-04-05 | 2011-11-29 | Kaneka Corporation | Curable composition |
| EP2546307B1 (en) | 2004-11-10 | 2018-03-14 | Kaneka Corporation | Curable composition |
| US8013079B2 (en) | 2005-09-30 | 2011-09-06 | Kaneka Corporation | Curable composition |
| US20090281253A1 (en) | 2005-09-30 | 2009-11-12 | Kaneka Corporation | Curable composition improved in curability and storage stability |
| EP1930376B2 (en) | 2005-09-30 | 2016-09-07 | Kaneka Corporation | Curable composition |
| JP5226324B2 (ja) | 2006-01-18 | 2013-07-03 | 株式会社カネカ | 硬化性組成物 |
| JP5420893B2 (ja) | 2006-02-16 | 2014-02-19 | 株式会社カネカ | 硬化性組成物 |
| EP2011833A4 (en) | 2006-04-19 | 2014-05-28 | Kaneka Corp | CURABLE RESIN COMPOSITION |
| CN101426859B (zh) | 2006-04-20 | 2012-03-21 | 株式会社钟化 | 固化性组合物 |
| WO2007142067A1 (ja) | 2006-06-02 | 2007-12-13 | Kaneka Corporation | 硬化性組成物 |
| JP5222467B2 (ja) * | 2006-08-11 | 2013-06-26 | 綜研化学株式会社 | 組成物 |
| JP5500824B2 (ja) | 2006-09-13 | 2014-05-21 | 株式会社カネカ | ＳｉＦ基を有する湿分硬化性重合体およびそれを含有する硬化性組成物 |
| CN102443162B (zh) | 2006-11-01 | 2015-05-13 | 株式会社钟化 | 固化性有机聚合物及其制造方法以及含该聚合物的固化性组合物 |
| EP2088173B1 (en) | 2006-11-22 | 2012-02-22 | Kaneka Corporation | Curable composition and catalyst composition |
| EP2100923B1 (en) | 2006-12-25 | 2013-03-13 | Kaneka Corporation | Curable composition |
| EP2123720B1 (en) | 2007-01-12 | 2017-06-14 | Kaneka Corporation | Curable composition |
| JPWO2009011329A1 (ja) | 2007-07-19 | 2010-09-24 | 株式会社カネカ | 硬化性組成物 |
| JP5547641B2 (ja) | 2008-09-29 | 2014-07-16 | 株式会社カネカ | 硬化性組成物およびその硬化物 |
| JP5592273B2 (ja) | 2009-01-16 | 2014-09-17 | 株式会社カネカ | 硬化性組成物およびその硬化物 |
| JP4973699B2 (ja) | 2009-07-06 | 2012-07-11 | 横浜ゴム株式会社 | タイヤホイール組立体及びその分解方法 |
| KR101838533B1 (ko) | 2010-01-19 | 2018-04-26 | 카네카 코포레이션 | 경화성 조성물 |
| JP5953234B2 (ja) | 2010-10-27 | 2016-07-20 | 株式会社カネカ | 硬化性組成物 |
| CN103827226B (zh) | 2011-03-02 | 2016-12-07 | 株式会社钟化 | 固化性组合物 |
| EP2698481B1 (en) | 2011-04-15 | 2017-04-05 | Kaneka Corporation | Cladding material for construction |
| WO2013042702A1 (ja) | 2011-09-22 | 2013-03-28 | 株式会社カネカ | 硬化性組成物およびその硬化物 |
| CN104350084B (zh) | 2012-05-31 | 2016-10-12 | 株式会社钟化 | 具有有多个反应性硅基的末端结构的聚合物及其制造方法和利用 |
| US9969843B2 (en) | 2012-05-31 | 2018-05-15 | Kaneka Corporation | Polymer having terminal structure including plurality of reactive silicon groups, method for manufacturing same, and use for same |
| WO2014050592A1 (ja) | 2012-09-28 | 2014-04-03 | 株式会社カネカ | 構造体 |
| WO2014121007A2 (en) | 2013-02-01 | 2014-08-07 | 3M Innovative Properties Company | Coating compositions and articles made therefrom |
| KR102175447B1 (ko) | 2013-07-11 | 2020-11-06 | 세메다인 가부시키 가이샤 | 도전성 경화물의 제조 방법 및 펄스광 경화성 조성물의 경화 방법 |
| CN105392845B (zh) | 2013-07-18 | 2020-10-20 | 思美定株式会社 | 光固化性组合物 |
| JP6409784B2 (ja) | 2013-12-13 | 2018-10-24 | セメダイン株式会社 | 接着性を有する光硬化性組成物 |
| US20160326344A1 (en) | 2013-12-26 | 2016-11-10 | Kaneka Corporation | Curable composition and cured product thereof |
| CA2939914C (en) | 2014-02-18 | 2022-06-28 | 3M Innovative Properties Company | Self sealing articles |
| US10704254B2 (en) | 2014-02-18 | 2020-07-07 | 3M Innovative Properties Company | Easy to apply air and water barrier articles |
| CA2956944A1 (en) | 2014-08-01 | 2016-02-04 | 3M Innovative Properties Company | Self sealing permeable air barrier compositions |
| EP3237699A1 (en) | 2014-12-22 | 2017-11-01 | 3M Innovative Properties Company | Air and water barrier articles |
| CA2995965C (en) | 2015-08-18 | 2024-02-13 | 3M Innovative Properties Company | Self-sealing articles including elastic porous layer |
| WO2017112756A1 (en) | 2015-12-22 | 2017-06-29 | 3M Innovative Properties Company | Roll including air and water barrier article and method of using the same |
| JP6527599B2 (ja) | 2015-12-24 | 2019-06-05 | 株式会社カネカ | 積層体の製造方法、および積層体 |
| CA3054558A1 (en) | 2017-02-23 | 2018-08-30 | 3M Innovative Properties Company | Air and water barrier article including inelastic porous layer |
| US11634523B2 (en) | 2017-08-24 | 2023-04-25 | Soken Chemical & Engineering Co., Ltd. | (Meth)acrylic acid alkyl ester polymer and use thereof |
| EP3753984B1 (en) | 2018-02-13 | 2022-08-24 | Kaneka Corporation | Single-component curable composition for working joint |
| JP7194734B2 (ja) | 2018-06-07 | 2022-12-22 | 株式会社カネカ | 発泡体用樹脂組成物、発泡体、及び発泡体の製造方法 |
| CN114127156B (zh) | 2019-02-28 | 2025-01-21 | 钟化美洲控股公司 | 可湿固化粘合剂组合物 |
| EP4010184A1 (en) | 2019-08-07 | 2022-06-15 | 3M Innovative Properties Company | Tape, article including tape and composite layer, and related methods |
| WO2022191084A1 (ja) | 2021-03-12 | 2022-09-15 | Ａｇｃ株式会社 | 硬化性組成物及び硬化物 |
| JPWO2023048186A1 (enExample) | 2021-09-24 | 2023-03-30 | ||
| WO2024029615A1 (ja) | 2022-08-04 | 2024-02-08 | 株式会社カネカ | 硬化性組成物 |
| EP4656672A1 (en) | 2023-01-23 | 2025-12-03 | Kaneka Corporation | Method for producing curable composition |
-
1974
- 1974-06-07 JP JP6524474A patent/JPS5841291B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS50156599A (enExample) | 1975-12-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS5841291B2 (ja) | 一成分型室温硬化性珪素末端重合体の製造法 | |
| JP4173807B2 (ja) | アルコキシ架橋性一成分系湿分硬化性材料 | |
| JP5090623B2 (ja) | 制御可能な硬化速度を有するアルコキシシラン末端ポリマーをベースとするポリマー材料 | |
| JP4221301B2 (ja) | アルコキシシランを末端基とするポリマーを含有している架橋性ポリマーブレンド | |
| JPH02133490A (ja) | シリコーンシーラント製造方法 | |
| US20100197855A1 (en) | Two-component curable polymer materials | |
| JPS6118582B2 (enExample) | ||
| JP2015531802A (ja) | オルガニルオキシシラン末端を有する重合体を基剤とする多成分架橋性組成物 | |
| CN106232732A (zh) | 基于有机基‑氧基硅烷封端的聚合物的可交联材料 | |
| JP2782406B2 (ja) | 室温硬化性組成物 | |
| JPWO2017187762A1 (ja) | 末端シラノール基含有ポリオキシアルキレン系化合物及びその製造方法、室温硬化性組成物、シーリング材並びに物品 | |
| JP3308977B2 (ja) | 反応性オルガノポリシロキサン | |
| JPH01100181A (ja) | ポリアルコキシシリルアルキレンジシラザン及びその製法 | |
| JP3121245B2 (ja) | 含フッ素有機ケイ素化合物及びその製造方法並びにそれを含有する室温硬化性シリコーン組成物 | |
| JPS624724A (ja) | アルコキシ末端基を有するポリ（ジオルガノシロキサン）の製造方法 | |
| JPH045685B2 (enExample) | ||
| JPS6129379B2 (enExample) | ||
| JP2811140B2 (ja) | 室温硬化性組成物 | |
| JPS5921893B2 (ja) | 一成分型室温硬化性珪素末端重合体の製造法 | |
| JP3350347B2 (ja) | 室温硬化性組成物 | |
| JPS6337820B2 (enExample) | ||
| JPH0822963B2 (ja) | 湿気硬化性−液型ポリシロキサン組成物 | |
| JPS5810430B2 (ja) | 室温硬化性組成物 | |
| JP3020382B2 (ja) | オルガノポリシロキサン組成物 | |
| JPH04359061A (ja) | 室温硬化性オルガノポリシロキサン組成物およびその硬化物 |