JPH0733418B2 - 高吸水性重合体の製造方法 - Google Patents
高吸水性重合体の製造方法Info
- Publication number
- JPH0733418B2 JPH0733418B2 JP63098452A JP9845288A JPH0733418B2 JP H0733418 B2 JPH0733418 B2 JP H0733418B2 JP 63098452 A JP63098452 A JP 63098452A JP 9845288 A JP9845288 A JP 9845288A JP H0733418 B2 JPH0733418 B2 JP H0733418B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- polymer
- polymerization
- cross
- polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 229920000247 superabsorbent polymer Polymers 0.000 title claims description 5
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- -1 glycidyl compound Chemical class 0.000 claims abstract description 12
- 150000007942 carboxylates Chemical class 0.000 claims abstract description 9
- 210000001124 body fluid Anatomy 0.000 claims abstract 2
- 239000010839 body fluid Substances 0.000 claims abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 16
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 11
- 239000011780 sodium chloride Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- 229920006037 cross link polymer Polymers 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 24
- 238000010521 absorption reaction Methods 0.000 abstract description 8
- 239000003431 cross linking reagent Substances 0.000 abstract description 7
- 229920002845 Poly(methacrylic acid) Polymers 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000002504 physiological saline solution Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 description 32
- 238000006116 polymerization reaction Methods 0.000 description 15
- 239000000243 solution Substances 0.000 description 14
- 239000004971 Cross linker Substances 0.000 description 13
- 239000006096 absorbing agent Substances 0.000 description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000004132 cross linking Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 6
- 239000002250 absorbent Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 238000010557 suspension polymerization reaction Methods 0.000 description 5
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 4
- 229920001477 hydrophilic polymer Polymers 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 239000001856 Ethyl cellulose Substances 0.000 description 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920001249 ethyl cellulose Polymers 0.000 description 3
- 235000019325 ethyl cellulose Nutrition 0.000 description 3
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 3
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- SYEWHONLFGZGLK-UHFFFAOYSA-N 2-[1,3-bis(oxiran-2-ylmethoxy)propan-2-yloxymethyl]oxirane Chemical compound C1OC1COCC(OCC1OC1)COCC1CO1 SYEWHONLFGZGLK-UHFFFAOYSA-N 0.000 description 2
- DMQYPVOQAARSNF-UHFFFAOYSA-N 3-[2,3-bis(3-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OCCCOCC(OCCCOC(=O)C=C)COCCCOC(=O)C=C DMQYPVOQAARSNF-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical group OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229920003086 cellulose ether Polymers 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- RRPJQNOJVXGCKC-UHFFFAOYSA-M methyl-tris(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(CC=C)CC=C RRPJQNOJVXGCKC-UHFFFAOYSA-M 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 210000002700 urine Anatomy 0.000 description 2
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 description 1
- CCTFAOUOYLVUFG-UHFFFAOYSA-N 2-(1-amino-1-imino-2-methylpropan-2-yl)azo-2-methylpropanimidamide Chemical compound NC(=N)C(C)(C)N=NC(C)(C)C(N)=N CCTFAOUOYLVUFG-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- LSWYGACWGAICNM-UHFFFAOYSA-N 2-(prop-2-enoxymethyl)oxirane Chemical compound C=CCOCC1CO1 LSWYGACWGAICNM-UHFFFAOYSA-N 0.000 description 1
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- ZWAPMFBHEQZLGK-UHFFFAOYSA-N 5-(dimethylamino)-2-methylidenepentanamide Chemical compound CN(C)CCCC(=C)C(N)=O ZWAPMFBHEQZLGK-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920000083 poly(allylamine) Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004583 superabsorbent polymers (SAPs) Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229940096522 trimethylolpropane triacrylate Drugs 0.000 description 1
- RSSHUWHSFGCSHG-UHFFFAOYSA-N tris(hydroxymethyl)azanium;chloride Chemical compound Cl.OCN(CO)CO RSSHUWHSFGCSHG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3713601.1 | 1987-04-23 | ||
| DE19873713601 DE3713601A1 (de) | 1987-04-23 | 1987-04-23 | Verfahren zur herstellung eines stark wasserabsorbierenden polymerisats |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6438406A JPS6438406A (en) | 1989-02-08 |
| JPH0733418B2 true JPH0733418B2 (ja) | 1995-04-12 |
Family
ID=6326138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63098452A Expired - Lifetime JPH0733418B2 (ja) | 1987-04-23 | 1988-04-22 | 高吸水性重合体の製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0288865B1 (show.php) |
| JP (1) | JPH0733418B2 (show.php) |
| AT (1) | ATE69451T1 (show.php) |
| DE (2) | DE3713601A1 (show.php) |
| ES (1) | ES2004857T3 (show.php) |
| GR (2) | GR890300042T1 (show.php) |
Families Citing this family (158)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2237276B (en) * | 1989-10-26 | 1993-12-15 | Ici Plc | Water-based autoxidisable air-drying coating composition and copolymers for use in it |
| US5264482A (en) * | 1989-10-26 | 1993-11-23 | The Glidden Company | Water-based autoxidisable coating composition |
| DE4015085C2 (de) * | 1990-05-11 | 1995-06-08 | Stockhausen Chem Fab Gmbh | Vernetztes, wasserabsorbierendes Polymer und Verwendung zur Herstellung von Hygieneartikeln, zur Bodenverbesserung und in Kabelummantelungen |
| US5385983A (en) * | 1992-11-12 | 1995-01-31 | The Dow Chemical Company | Process for preparing a water-absorbent polymer |
| DE4244548C2 (de) | 1992-12-30 | 1997-10-02 | Stockhausen Chem Fab Gmbh | Pulverförmige, unter Belastung wäßrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung in textilen Konstruktionen für die Körperhygiene |
| DE4333056C2 (de) * | 1993-09-29 | 1998-07-02 | Stockhausen Chem Fab Gmbh | Pulverförmige, wäßrige Flüssigkeiten absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung als Absorptionsmittel |
| US5674917A (en) * | 1995-03-30 | 1997-10-07 | Woodbridge Foam Corporation | Superabsorbent hydrophilic isocyanate-based foam and process for production thereof |
| US5719201A (en) * | 1995-03-30 | 1998-02-17 | Woodbridge Foam Corporation | Superabsorbent hydrophilic isocyanate-based foam and process for production thereof |
| DE19646484C2 (de) * | 1995-11-21 | 2000-10-19 | Stockhausen Chem Fab Gmbh | Flüssigkeitsabsorbierende Polymere, Verfahren zu deren Herstellung und deren Verwendung |
| DE19543368C2 (de) * | 1995-11-21 | 1998-11-26 | Stockhausen Chem Fab Gmbh | Wasserabsorbierende Polymere mit verbesserten Eigenschaften, Verfahren zu deren Herstellung und deren Verwendung |
| US5624971A (en) * | 1996-07-01 | 1997-04-29 | Woodbridge Foam Corporation | Foamed polymer and process for production thereof |
| US5744509A (en) * | 1996-07-01 | 1998-04-28 | Woodbridge Foam Corporation | Foamed polymer and process for production thereof |
| KR20000022356A (ko) | 1996-07-06 | 2000-04-25 | 헬무트 클림멕 | 흡수성 삽입물, 그 제조 방법 및 용도 |
| US5817703A (en) * | 1996-09-30 | 1998-10-06 | Woodbridge Foam Corporation | Rebond foam and process for production thereof |
| DE19716657A1 (de) | 1997-04-21 | 1998-10-22 | Stockhausen Chem Fab Gmbh | Superabsorber mit kontrollierter Absorptionsgeschwindigkeit |
| JPH1143503A (ja) * | 1997-07-25 | 1999-02-16 | Nippon Mektron Ltd | 変性アクリル系ゴムの製造法 |
| JPH11279287A (ja) | 1998-03-31 | 1999-10-12 | Nippon Shokubai Co Ltd | 吸水剤組成物および吸水剤の製造方法 |
| DE19854573A1 (de) | 1998-11-26 | 2000-05-31 | Basf Ag | Verfahren zur Nachvernetzung von Hydrogelen mit 2-Oxo-tetrahydro-1,3-oxazinen |
| JP4550256B2 (ja) * | 1999-11-19 | 2010-09-22 | 三洋化成工業株式会社 | 吸水性樹脂の製造法 |
| DE10043710B4 (de) | 2000-09-04 | 2015-01-15 | Evonik Degussa Gmbh | Verwendung pulverförmiger an der Oberfläche nachvernetzter Polymerisate und Hygieneartikel |
| DE10212866A1 (de) | 2002-03-22 | 2003-10-09 | Beiersdorf Ag | Narbenreduktionspflaster |
| WO2003082937A2 (en) * | 2002-03-28 | 2003-10-09 | Huntsman Advanced Materials (Switzerland) Gmbh | Polymerisable composition |
| DE10225943A1 (de) | 2002-06-11 | 2004-01-08 | Basf Ag | Verfahren zur Herstellung von Estern von Polyalkoholen |
| KR100518793B1 (ko) * | 2002-10-01 | 2005-10-04 | 주식회사 케이씨씨 | 하이솔리드 폴리에스테르 수지 및 이의 제조방법 |
| DE102004061406A1 (de) | 2004-12-21 | 2006-07-06 | Bayer Innovation Gmbh | Infektionsresistente Polyurethanschäume, Verfahren zu ihrer Herstellung und Verwendung in antiseptisch ausgestatteten Wundauflagen |
| DE102005010198A1 (de) | 2005-03-05 | 2006-09-07 | Degussa Ag | Hydrolysestabile, nachvernetzte Superabsorber |
| BRPI0610075B8 (pt) | 2005-04-22 | 2021-06-22 | Evonik Degussa Gmbh | estruturas de poliméro de absorção de água, seus usos, processos para tratamento da superfície das mesmas, compostos, processos para produção dos mesmos, produtos compreendendo as estruturas poliméricas e usos de combinações de óxidos de metal e sais de metal de cátion de metal bivalente ou trivalente |
| DE102005018924A1 (de) | 2005-04-22 | 2006-10-26 | Stockhausen Gmbh | Wasserabsorbierende Polymergebilde mit verbesserten Absorptionseigenschaften |
| EP1736508A1 (en) | 2005-06-22 | 2006-12-27 | Basf Aktiengesellschaft | Hydrogel-forming polymers with increased permeability and high absorption capacity |
| DE102005055497A1 (de) | 2005-11-18 | 2007-05-31 | Stockhausen Gmbh | Geruchsbindende superabsorbierende Zusammensetzung |
| US8829107B2 (en) | 2006-02-28 | 2014-09-09 | Evonik Degussa Gmbh | Biodegradable superabsorbent polymer composition with good absorption and retention properties |
| BRPI0711452B8 (pt) | 2006-04-21 | 2021-06-22 | Evonik Degussa Gmbh | processo para a preparação de uma estrutura polimérica absorvente de água, estrutura polimérica absorvente de água, compósito, processo para a preparação de um compósito, uso da estrutura polimérica absorvente de água ou uso do compósito e uso de um sal |
| DE102006019157A1 (de) | 2006-04-21 | 2007-10-25 | Stockhausen Gmbh | Herstellung von hochpermeablen, superabsorbierenden Polymergebilden |
| DE102006060156A1 (de) | 2006-12-18 | 2008-06-19 | Evonik Stockhausen Gmbh | Wasserabsorbierende Polymergebilde, welche unter Einsatz von Polymerdispersionen hergestellt wurden |
| DE102007007203A1 (de) | 2007-02-09 | 2008-08-14 | Evonik Stockhausen Gmbh | Wasserabsorbierendes Polymergebilde mit hoher Ammoniak-Bindekapazität |
| DE102007024080A1 (de) | 2007-05-22 | 2008-11-27 | Evonik Stockhausen Gmbh | Verfahren zum schonenden Mischen und Beschichten von Superabsorbern |
| US7816426B2 (en) | 2007-07-16 | 2010-10-19 | Evonik Stockhausen, Llc | Superabsorbent polymer compositions having color stability |
| DE102007045724B4 (de) | 2007-09-24 | 2012-01-26 | Evonik Stockhausen Gmbh | Superabsorbierende Zusammensetzung mit Tanninen zur Geruchskontrolle, Verfahren zu deren Herstellung und Verwendung |
| DE102007053619A1 (de) | 2007-11-08 | 2009-05-20 | Evonik Stockhausen Gmbh | Wasserabsorbierende Polymergebilde mit verbesserter Farbstabilität |
| EP2072063A1 (en) | 2007-12-22 | 2009-06-24 | Bayer Innovation GmbH | Infection-resistant cellular hydrophilic prepolymer based polyurethane foams, methods for producing the same and use thereof in antiseptic wound dressings |
| TWI455973B (zh) | 2008-03-05 | 2014-10-11 | Evonik Degussa Gmbh | 用於氣味控制的具有水楊酸鋅的超吸收性組合物 |
| JP5490130B2 (ja) | 2008-11-07 | 2014-05-14 | ビーエーエスエフ ソシエタス・ヨーロピア | 吸水ポリマー粒子の製造方法 |
| US8608096B2 (en) | 2009-02-18 | 2013-12-17 | Basf Se | Method for the production of water-absorbing polymer particles |
| US20100247916A1 (en) | 2009-03-24 | 2010-09-30 | Basf Se | Process for Producing Surface Postcrosslinked Water-Absorbing Polymer Particles |
| DE102009016404A1 (de) | 2009-04-07 | 2010-10-21 | Evonik Stockhausen Gmbh | Verwendung von Hohlkörpern zur Herstellung wasserabsorbierender Polymergebilde |
| WO2010124954A1 (de) | 2009-04-30 | 2010-11-04 | Basf Se | Verfahren zur abtrennung metallischer verunreinigungen |
| WO2010133529A2 (de) | 2009-05-20 | 2010-11-25 | Basf Se | Wasserabsorbierende speicherschichten |
| WO2010149735A1 (de) | 2009-06-26 | 2010-12-29 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel mit geringer verbackungsneigung und hoher absorption unter druck |
| EP2470221B1 (de) | 2009-08-26 | 2016-03-23 | Basf Se | Geruchsinhibierende zusammensetzungen |
| US8481159B2 (en) | 2009-09-04 | 2013-07-09 | Basf Se | Water-absorbent porous polymer particles having specific sphericity and high bulk density |
| DE102009040949A1 (de) | 2009-09-11 | 2011-03-31 | Evonik Stockhausen Gmbh | Plasmamodifizierung wasserabsorbierender Polymergebilde |
| US20120175556A1 (en) | 2009-09-18 | 2012-07-12 | Basf Se | Open-Cell Foams Having Superabsorbers |
| JP5871803B2 (ja) | 2009-10-09 | 2016-03-01 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 表面後架橋された吸水性ポリマー粒子の後給湿方法 |
| US9328207B2 (en) | 2009-10-09 | 2016-05-03 | Basf Se | Method for re-wetting surface post-cross-linked, water-absorbent polymer particles |
| EP2485773B1 (de) | 2009-10-09 | 2013-12-11 | Basf Se | Verwendung von heizdampfkondensat zur herstellung wasserabsorbierender polymerpartikel |
| JP5591339B2 (ja) | 2009-10-09 | 2014-09-17 | ビーエーエスエフ ソシエタス・ヨーロピア | 吸水性ポリマー粒子の連続製造法 |
| WO2011054784A1 (de) | 2009-11-06 | 2011-05-12 | Basf Se | Verbesserte superabsorber enthaltende textilien |
| CN102665772B (zh) | 2009-11-23 | 2016-08-03 | 巴斯夫欧洲公司 | 制备吸水性聚合物泡沫的方法 |
| WO2011061315A1 (de) | 2009-11-23 | 2011-05-26 | Basf Se | Verfahren zur herstellung wasserabsorbierender, aufgeschäumter polymerpartikel |
| JP2013511608A (ja) | 2009-11-23 | 2013-04-04 | ビーエーエスエフ ソシエタス・ヨーロピア | 色安定性が改善された吸水性ポリマー粒子の製造方法 |
| CN102791298B (zh) | 2010-01-27 | 2015-02-18 | 巴斯夫欧洲公司 | 抑制气味的吸水复合物 |
| WO2011104152A1 (de) | 2010-02-24 | 2011-09-01 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel |
| WO2011104139A1 (de) | 2010-02-24 | 2011-09-01 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel |
| BR112012023050A2 (pt) | 2010-03-15 | 2016-05-17 | Basf Se | processo para produzir partículas de polímero que absorvem água, partículas de polímero que absorvem água, e, artigo que absorve fluido |
| US8703876B2 (en) | 2010-03-15 | 2014-04-22 | Basf Se | Process for producing water absorbing polymer particles with improved color stability |
| EP2550304B2 (de) | 2010-03-24 | 2018-09-19 | Basf Se | Verfahren zur entfernung von restmonomeren aus wasserabsorbierenden polymerpartikeln |
| WO2011117187A1 (en) | 2010-03-24 | 2011-09-29 | Basf Se | Ultrathin fluid-absorbent cores |
| EP2550306B1 (en) | 2010-03-24 | 2014-07-02 | Basf Se | A process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution |
| JP2013523903A (ja) | 2010-03-25 | 2013-06-17 | ビーエーエスエフ ソシエタス・ヨーロピア | 吸水性ポリマー粒子の製造方法 |
| EP2371869A1 (en) | 2010-03-30 | 2011-10-05 | Evonik Stockhausen GmbH | A process for the production of a superabsorbent polymer |
| WO2011131526A1 (de) | 2010-04-19 | 2011-10-27 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel |
| KR20130096218A (ko) | 2010-06-14 | 2013-08-29 | 바스프 에스이 | 개선된 색 안정성을 갖는 수분-흡수 중합체 입자 |
| US9962459B2 (en) | 2010-07-02 | 2018-05-08 | Basf Se | Ultrathin fluid-absorbent cores |
| US9089624B2 (en) | 2010-08-23 | 2015-07-28 | Basf Se | Ultrathin fluid-absorbent cores comprising adhesive and having very low dry SAP loss |
| JP6138056B2 (ja) | 2011-02-07 | 2017-05-31 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 高い膨潤速度を有する吸水性ポリマー粒子の製造法 |
| WO2012107344A1 (de) | 2011-02-07 | 2012-08-16 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel |
| CN103415553B (zh) | 2011-03-08 | 2015-07-08 | 巴斯夫欧洲公司 | 用于制备具有改进渗透性的吸水性聚合物颗粒的方法 |
| JP6073292B2 (ja) | 2011-05-06 | 2017-02-01 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 吸水性ポリマー粒子の製造法 |
| JP6124874B2 (ja) | 2011-05-18 | 2017-05-10 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 血液及び／又は月経液を吸収するための吸水性ポリマー粒子の使用 |
| US8987545B2 (en) | 2011-05-18 | 2015-03-24 | The Procter & Gamble Company | Feminine hygiene absorbent articles comprising water-absorbing polymer particles |
| US20120296297A1 (en) | 2011-05-18 | 2012-11-22 | Achille Di Cintio | Feminine hygiene absorbent articles comprising water-absorbing polymeric foams |
| WO2012156386A1 (de) | 2011-05-18 | 2012-11-22 | Basf Se | Verwendung wasserabsorbierender polymerpartikel zur entwässerung von fäkalien |
| WO2012159949A1 (de) | 2011-05-26 | 2012-11-29 | Basf Se | Verfahren zur kontinuierlichen herstellung wasserabsorbierender polymerpartikel |
| WO2012160174A1 (de) | 2011-05-26 | 2012-11-29 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel |
| WO2012163995A1 (de) | 2011-06-01 | 2012-12-06 | Basf Se | Geruchsinhibierende mischungen für inkontinenzartikel |
| WO2012164081A1 (de) | 2011-06-03 | 2012-12-06 | Basf Se | Verfahren zur kontinuierlichen herstellung wasserabsorbierender polymerpartikel |
| JP6053762B2 (ja) | 2011-06-03 | 2016-12-27 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 吸水性ポリマー粒子の連続的な製造法 |
| JP5980325B2 (ja) | 2011-07-14 | 2016-08-31 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 高い膨潤速度を有する吸水性ポリマー粒子の製造法 |
| WO2013045163A1 (en) | 2011-08-12 | 2013-04-04 | Basf Se | A process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution |
| EP2768456B2 (en) | 2011-10-18 | 2024-06-26 | Basf Se | Fluid-absorbent article |
| EP2586410A1 (en) | 2011-10-24 | 2013-05-01 | Bostik SA | Novel process for preparing an absorbent article |
| EP2586412A1 (en) | 2011-10-24 | 2013-05-01 | Bostik SA | New absorbent article and process for making it |
| EP2586409A1 (en) | 2011-10-24 | 2013-05-01 | Bostik SA | New absorbent article and process for making it |
| DE102011086522A1 (de) | 2011-11-17 | 2013-05-23 | Evonik Degussa Gmbh | Superabsorbierende Polymere für hochgefüllte oder faserfreie Hygieneartikel |
| WO2013117496A1 (de) | 2012-02-06 | 2013-08-15 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel |
| WO2013120722A1 (de) | 2012-02-15 | 2013-08-22 | Basf Se | Wasserabsorbierende polymerpartikel mit hoher quellgeschwindigkeit und hoher permeabilität |
| DE102013102665A1 (de) | 2012-03-15 | 2013-09-19 | Sachtleben Pigment Gmbh | Verfahren zur Granulierung von teilchenhaltigem Material aus industriellen Prozessen, das so hergestellte Granulat und dessen Verwendung |
| DE102012102473A1 (de) | 2012-03-22 | 2013-09-26 | Xtract Gmbh | Verfahren zur Behandlung von Klärschlamm |
| JP2015512990A (ja) | 2012-03-30 | 2015-04-30 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 逆スクリューヘリックスを備えたドラム型熱交換器中で熱表面後架橋する方法 |
| WO2013156281A1 (en) | 2012-04-17 | 2013-10-24 | Basf Se | Process for producing surface postcrosslinked water-absorbing polymer particles |
| EP2838573A1 (en) | 2012-04-17 | 2015-02-25 | Basf Se | Process for producing surface postcrosslinked water-absorbing polymer particles |
| WO2013182469A2 (en) | 2012-06-08 | 2013-12-12 | Basf Se | Odour-control superabsorbent |
| WO2013186176A1 (de) | 2012-06-13 | 2013-12-19 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel in einem polymerisationsreaktor mit mindestens zwei achsparallel rotierenden wellen |
| CN104411731B (zh) | 2012-06-19 | 2016-06-15 | 巴斯夫欧洲公司 | 用于制备吸水性聚合物颗粒的方法 |
| EP2870183B2 (de) | 2012-07-03 | 2024-11-27 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel mit verbessertem eigenschaftsprofil |
| WO2014019813A1 (de) | 2012-07-30 | 2014-02-06 | Basf Se | Geruchsinhibierende mischungen für inkontinenzartikel |
| EP2888296B1 (en) | 2012-08-27 | 2016-08-10 | Basf Se | Process for producing water-absorbing polymer particles |
| EP2897994B1 (en) | 2012-09-19 | 2016-11-23 | Basf Se | Process for producing water-absorbing polymer particles |
| DE102012220400A1 (de) | 2012-11-09 | 2014-05-15 | Evonik Industries Ag | Superabsorber für Kabelanwendungen |
| JP6433908B2 (ja) | 2012-11-21 | 2018-12-05 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 表面後架橋された吸水性ポリマー粒子の製造方法 |
| CN104812418B (zh) | 2012-11-26 | 2019-02-19 | 巴斯夫欧洲公司 | 基于可再生原料制备超吸收剂的方法 |
| CN104936989B (zh) | 2013-01-29 | 2019-04-16 | 巴斯夫欧洲公司 | 制备具有高自由溶胀率、高离心保留容量和高溶胀凝胶床渗透性的吸水性聚合物颗粒的方法 |
| KR20150113129A (ko) | 2013-01-30 | 2015-10-07 | 바스프 에스이 | 물 흡수성 폴리머 입자로부터의 잔류 모노머의 제거 방법 |
| CN105683226B (zh) | 2013-08-26 | 2018-08-17 | 巴斯夫欧洲公司 | 流体吸收制品 |
| WO2015036273A1 (de) | 2013-09-12 | 2015-03-19 | Basf Se | Verfahren zur herstellung von acrylsäure |
| US20160280825A1 (en) | 2013-10-30 | 2016-09-29 | Basf Se | Method for Producing Water-Absorbing Polymer Particles by Suspension Polymerization |
| KR102323010B1 (ko) | 2013-11-22 | 2021-11-05 | 바스프 에스이 | 물-흡수성 폴리머 입자의 제조 방법 |
| JP2016028116A (ja) | 2014-07-11 | 2016-02-25 | 住友精化株式会社 | 吸水性樹脂及び吸収性物品 |
| JP5719078B1 (ja) * | 2014-07-11 | 2015-05-13 | 住友精化株式会社 | 吸水性樹脂の製造方法 |
| JP5766344B1 (ja) | 2014-07-11 | 2015-08-19 | 住友精化株式会社 | 吸水性樹脂及び吸収性物品 |
| JP5893116B2 (ja) | 2014-07-11 | 2016-03-23 | 住友精化株式会社 | 吸水性樹脂及び吸水性樹脂の製造方法 |
| JP5689204B1 (ja) | 2014-07-11 | 2015-03-25 | 住友精化株式会社 | 吸水性樹脂の製造方法、吸水性樹脂、吸水剤、吸収性物品 |
| JP5719079B1 (ja) * | 2014-07-11 | 2015-05-13 | 住友精化株式会社 | 吸水性樹脂及び吸収性物品 |
| JP5893117B2 (ja) | 2014-07-11 | 2016-03-23 | 住友精化株式会社 | 吸水性樹脂及び吸収性物品 |
| EP2995323B1 (de) | 2014-09-15 | 2019-02-27 | Evonik Degussa GmbH | Aminopolycarboxylsäuren als Prozesshilfsmittel bei der Superabsorberherstellung |
| EP2995322B1 (de) | 2014-09-15 | 2017-03-01 | Evonik Degussa GmbH | Geruchsadsorptionsmittel |
| WO2016050397A1 (de) | 2014-09-30 | 2016-04-07 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel |
| EP3009474B1 (de) | 2014-10-16 | 2017-09-13 | Evonik Degussa GmbH | Herstellverfahren für wasserlösliche Polymere |
| WO2016135020A1 (de) | 2015-02-24 | 2016-09-01 | Basf Se | Verfahren zur kontinuierlichen dehydratisierung von 3-hydroxypropionsäure zu acrylsäure |
| JP6993878B2 (ja) * | 2015-03-16 | 2022-01-14 | 住友精化株式会社 | 吸水性樹脂および吸水剤 |
| US10857256B2 (en) | 2015-04-07 | 2020-12-08 | Basf Se | Method for producing super absorber particles |
| WO2016162175A1 (de) | 2015-04-07 | 2016-10-13 | Basf Se | Verfahren zur dehydratisierung von 3-hydroxypropionsäure zu acrylsäure |
| WO2016162218A1 (de) | 2015-04-07 | 2016-10-13 | Basf Se | Verfahren zur agglomeration von superabsorberpartikeln |
| WO2016180597A1 (de) | 2015-05-08 | 2016-11-17 | Basf Se | Herstellungsverfahren zur herstellung wasserabsorbierender polymerartikel und bandtrockner |
| WO2016207444A1 (en) | 2015-06-26 | 2016-12-29 | Bostik Inc. | New absorbent article comprising an acquisition/distribution layer and process for making it |
| US10806640B2 (en) | 2016-03-30 | 2020-10-20 | Basf Se | Ultrathin fluid-absorbent article |
| US10881555B2 (en) | 2016-03-30 | 2021-01-05 | Basf Se | Fluid-absorbent article |
| US20170281425A1 (en) | 2016-03-30 | 2017-10-05 | Basf Se | Fluid-absorbent article |
| JP6991161B2 (ja) | 2016-05-31 | 2022-01-13 | ビーエーエスエフ ソシエタス・ヨーロピア | 超吸収体の製造方法 |
| KR102576889B1 (ko) | 2016-08-10 | 2023-09-11 | 바스프 에스이 | 초흡수제의 제조 방법 |
| US20190255514A1 (en) | 2016-10-26 | 2019-08-22 | Basf Se | Method for discharging superabsorbent particles from a silo and filling them into bulk containers |
| ES2932273T3 (es) | 2017-02-06 | 2023-01-17 | Basf Se | Artículo absorbente de fluidos |
| EP3582734B1 (en) | 2017-02-17 | 2021-12-01 | Basf Se | Fluid-absorbent article |
| WO2019011793A1 (en) | 2017-07-12 | 2019-01-17 | Basf Se | PROCESS FOR PRODUCING SUPERABSORBENT POLYMER PARTICLES |
| CN110799275A (zh) | 2017-07-31 | 2020-02-14 | 巴斯夫欧洲公司 | 超吸收性聚合物颗粒的分级方法 |
| JP7275121B2 (ja) | 2017-10-18 | 2023-05-17 | ビーエーエスエフ ソシエタス・ヨーロピア | 超吸収体を製造する方法 |
| WO2019137833A1 (de) | 2018-01-09 | 2019-07-18 | Basf Se | Superabsorbermischungen |
| WO2019154652A1 (de) | 2018-02-06 | 2019-08-15 | Basf Se | Verfahren zur pneumatischen förderung von superabsorberpartikeln |
| JP7337823B2 (ja) | 2018-02-22 | 2023-09-04 | ビーエーエスエフ ソシエタス・ヨーロピア | 超吸収体粒子を製造する方法 |
| WO2019201668A1 (en) | 2018-04-20 | 2019-10-24 | Basf Se | Thin fluid absorbent core-absorbent paper |
| JP7362653B2 (ja) | 2018-04-20 | 2023-10-17 | ビーエーエスエフ ソシエタス・ヨーロピア | 超吸収体を製造する方法 |
| EP3827031B1 (de) | 2018-07-24 | 2025-02-26 | Basf Se | Verfahren zur herstellung von superabsorbern |
| WO2020025401A1 (en) | 2018-08-01 | 2020-02-06 | Basf Se | Fluid-absorbent core |
| EP3829507A1 (en) | 2018-08-01 | 2021-06-09 | Basf Se | Feminine hygiene absorbent article |
| CN112533692B (zh) | 2018-08-20 | 2023-03-28 | 巴斯夫欧洲公司 | 制备超吸收剂的方法 |
| JP7578586B2 (ja) | 2018-09-28 | 2024-11-06 | ベーアーエスエフ・エスエー | 超吸収体の製造の方法 |
| CN113166430B (zh) | 2018-10-29 | 2024-12-24 | 巴斯夫欧洲公司 | 制备长期颜色稳定的超吸收性聚合物颗粒的方法 |
| WO2022058190A1 (en) | 2020-09-17 | 2022-03-24 | Basf Se | Process for producing superabsorbent polymer particles |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1060711A (en) * | 1963-03-21 | 1967-03-08 | Beck Koller And Company Ltd | The preparation of hydroxyl-containing copolymers |
| US3453246A (en) * | 1966-03-14 | 1969-07-01 | Gulf Research Development Co | Thermosettable composition composed of a polyanhydride and a mono-oxirane compound and method of producing |
| DE2166551C3 (de) * | 1970-12-26 | 1982-03-18 | Asahi Kasei Kogyo K.K., Osaka | Copolymerisate mit äthylenisch ungesättigten Seitenketten und deren Verwendung |
| DE2336517A1 (de) * | 1973-07-18 | 1975-02-06 | Licentia Gmbh | Strahlungsempfindliches material |
| DE2746683A1 (de) * | 1977-10-18 | 1979-04-26 | Goodrich Co B F | Verfahren zur herstellung von endstaendige vinylidengruppen enthaltenden fluessigen polymerisaten |
| GB2126591B (en) * | 1982-09-02 | 1986-07-30 | Kao Corp | Process for producing highly water absorptive polymer |
| ES535037A0 (es) * | 1983-08-10 | 1985-12-01 | Kao Corp | Un procedimiento para preparar una resina absorbente de agua y muy reactiva |
| JPS6044348A (ja) * | 1983-08-23 | 1985-03-09 | Tokai Shoji Kk | スクリ−ン印刷機におけるスキ−ジ，ドクタ−の上下動反転駆動装置 |
| US4690980A (en) * | 1985-07-17 | 1987-09-01 | Ppg Industries, Inc. | Acrylic modified polymers |
-
1987
- 1987-04-23 DE DE19873713601 patent/DE3713601A1/de active Granted
-
1988
- 1988-04-19 ES ES198888106172T patent/ES2004857T3/es not_active Expired - Lifetime
- 1988-04-19 AT AT88106172T patent/ATE69451T1/de not_active IP Right Cessation
- 1988-04-19 DE DE8888106172T patent/DE3866153D1/de not_active Expired - Lifetime
- 1988-04-19 EP EP88106172A patent/EP0288865B1/de not_active Expired - Lifetime
- 1988-04-22 JP JP63098452A patent/JPH0733418B2/ja not_active Expired - Lifetime
-
1989
- 1989-05-25 GR GR89300042T patent/GR890300042T1/el unknown
-
1992
- 1992-01-08 GR GR910401168T patent/GR3003519T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES2004857T3 (es) | 1992-06-01 |
| DE3713601A1 (de) | 1988-11-10 |
| GR3003519T3 (show.php) | 1993-03-16 |
| ATE69451T1 (de) | 1991-11-15 |
| EP0288865B1 (de) | 1991-11-13 |
| ES2004857A4 (es) | 1989-02-16 |
| DE3866153D1 (de) | 1991-12-19 |
| GR890300042T1 (en) | 1989-05-25 |
| DE3713601C2 (show.php) | 1989-07-13 |
| EP0288865A3 (en) | 1989-05-31 |
| EP0288865A2 (de) | 1988-11-02 |
| JPS6438406A (en) | 1989-02-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0733418B2 (ja) | 高吸水性重合体の製造方法 | |
| US4446261A (en) | Process for preparation of high water-absorbent polymer beads | |
| JP3045422B2 (ja) | 吸水性樹脂の製造方法 | |
| CA1109052A (en) | Highly absorbent polymeric compositions from polyhydroxy polymer graft copolymers | |
| US4727097A (en) | Process for preparing highly reactive, water-absorptive resin | |
| US4497930A (en) | Process for producing highly water absorptive polymer | |
| JP2877255B2 (ja) | 耐久性の優れた吸水性樹脂の製造方法 | |
| JPH01207327A (ja) | 吸水性樹脂の表面処理方法 | |
| JPH06345819A (ja) | 高吸水性樹脂の製造法 | |
| JPS634843B2 (show.php) | ||
| WO2003059961A1 (fr) | Procede de prevention de la coloration d'une resine absorbant l'eau | |
| GB2179663A (en) | Absorptive resins | |
| JP3259143B2 (ja) | 吸水性樹脂の製造方法 | |
| JP3005124B2 (ja) | 不定形重合体粒子の製造方法 | |
| JPH0826085B2 (ja) | 耐久性の優れた吸水性樹脂の製造方法 | |
| JPH0639487B2 (ja) | 高吸水性樹脂の製法 | |
| JP3349768B2 (ja) | アクリル酸塩系ポリマーの製造方法および組成物 | |
| JPH01113406A (ja) | 高吸水性ポリマーの製造方法 | |
| JP3321209B2 (ja) | 架橋型カルボキシル基含有重合体の製造方法 | |
| JP2611125B2 (ja) | アクリルモノマーの逆懸濁重合による粉末吸水性樹脂の製造に於ける改良 | |
| JP3368939B2 (ja) | 新規な架橋水吸収性樹脂 | |
| JPH08157606A (ja) | 高吸水性樹脂の製造法 | |
| JPS634845B2 (show.php) | ||
| JPH0848721A (ja) | 吸水性樹脂の製造方法 | |
| JPH0726026A (ja) | 表面架橋された吸水性ポリマーの製造方法 |