JPH0242536B2 - - Google Patents
Info
- Publication number
- JPH0242536B2 JPH0242536B2 JP59186570A JP18657084A JPH0242536B2 JP H0242536 B2 JPH0242536 B2 JP H0242536B2 JP 59186570 A JP59186570 A JP 59186570A JP 18657084 A JP18657084 A JP 18657084A JP H0242536 B2 JPH0242536 B2 JP H0242536B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- clay
- acid
- vanadium
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 117
- 239000003054 catalyst Substances 0.000 claims description 95
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 47
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 239000002734 clay mineral Substances 0.000 claims description 23
- 150000003682 vanadium compounds Chemical class 0.000 claims description 20
- 229910052720 vanadium Inorganic materials 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 18
- MUBZPKHOEPUJKR-UHFFFAOYSA-N oxalic acid group Chemical group C(C(=O)O)(=O)O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 18
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 claims description 18
- 239000004927 clay Substances 0.000 claims description 15
- 239000003638 chemical reducing agent Substances 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 238000000746 purification Methods 0.000 claims description 8
- 150000003863 ammonium salts Chemical class 0.000 claims description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 7
- 239000011707 mineral Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 claims description 6
- 235000006408 oxalic acid Nutrition 0.000 claims description 6
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 5
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 2
- 239000007789 gas Substances 0.000 description 27
- 239000000463 material Substances 0.000 description 24
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 18
- 230000000694 effects Effects 0.000 description 18
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 17
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 16
- UUUGYDOQQLOJQA-UHFFFAOYSA-L vanadyl sulfate Chemical compound [V+2]=O.[O-]S([O-])(=O)=O UUUGYDOQQLOJQA-UHFFFAOYSA-L 0.000 description 16
- 229940041260 vanadyl sulfate Drugs 0.000 description 16
- 229910000352 vanadyl sulfate Inorganic materials 0.000 description 16
- 238000000034 method Methods 0.000 description 13
- 239000000203 mixture Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000428 dust Substances 0.000 description 10
- 229910052815 sulfur oxide Inorganic materials 0.000 description 9
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 8
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 8
- 235000011130 ammonium sulphate Nutrition 0.000 description 8
- 238000000465 moulding Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 230000010718 Oxidation Activity Effects 0.000 description 6
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 150000003609 titanium compounds Chemical class 0.000 description 6
- 239000004408 titanium dioxide Substances 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- -1 nitrogen oxides Chemical class 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 3
- 239000000440 bentonite Substances 0.000 description 3
- 229910000278 bentonite Inorganic materials 0.000 description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 150000004676 glycans Chemical class 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052622 kaolinite Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 206010022000 influenza Diseases 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- ALTWGIIQPLQAAM-UHFFFAOYSA-N metavanadate Chemical compound [O-][V](=O)=O ALTWGIIQPLQAAM-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- VLOPEOIIELCUML-UHFFFAOYSA-L vanadium(2+);sulfate Chemical compound [V+2].[O-]S([O-])(=O)=O VLOPEOIIELCUML-UHFFFAOYSA-L 0.000 description 1
- PSDQQCXQSWHCRN-UHFFFAOYSA-N vanadium(4+) Chemical compound [V+4] PSDQQCXQSWHCRN-UHFFFAOYSA-N 0.000 description 1
- ZFMRDIPUJPGRCY-UHFFFAOYSA-J vanadium(4+);disulfate Chemical compound [V+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZFMRDIPUJPGRCY-UHFFFAOYSA-J 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biomedical Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Catalysts (AREA)
Description
ãç£æ¥äžã®å©çšåéã
æ¬çºæã¯ãæ°Žã«äžæº¶æ§ã®ç¡«é
žãããžã«ïŒÎ²â
VOSO4ïŒãç¡«é žããªãŠã ããã¿ã³ååç©ããã³ç²
åé±ç©ãå«æããããã«ã ç¶ã®çªçŽ é žåç©æµåçš
觊åªã®è£œæ³ã«é¢ãããã æŽã«è©³ããã¯ãæ¬çºæã¯ãçªçŽ é žåç©ãå«æã
ãæã¬ã¹ç¹ã«çªçŽ é žåç©ãšãšãã«ç¡«é»é žåç©ãã
ã³ãã¹ãå«ææã¬ã¹äžã®çªçŽ é žåç©ãéå æµåã
ãã®ã«é©ããçªçŽ é žåç©æµåçšè§Šåªã®è£œæ³ã«é¢ã
ãã ãåŸæ¥ã®æè¡ã ãã€ã©ãŒãçºé»æã補éæãªã©ãã¯ãããåçš®
å·¥å Žã®åºå®ççŒè£ 眮ããæåºãããäžé žåçªçŽ
ïŒNOïŒãäºé žåçªçŽ ïŒNO2ïŒãªã©ã®çªçŽ é žåç©
ïŒNOxïŒãããã«ã¯NOxãšãšãã«äºé žåç¡«é»
ïŒSO2ïŒãäžé žåç¡«é»ïŒSO3ïŒãªã©ã®ç¡«é»é žåç©
ïŒSOxïŒããã¹ããå«æããæã¬ã¹äžã®NOxãã
次åŒã«ç€ºãããã«ã¢ã³ã¢ãã¢ã®åŠãéå æ§ç©è³ªã®
ååšäžã«éå ããŠæµåããæ¹æ³ããã³ãã®éã«äœ¿
çšããçªçŽ é žåç©éå æµåçšè§Šåªã«ã€ããŠã¯ãã
ã§ã«å€æ°ç¥ãããŠããã 4NOïŒ4NH3ïŒO2â6H2OïŒ4N2 6NOïŒ4NH3â5N2ïŒ6H2O 6NO2ïŒ8NH3â7N2ïŒ12H2O 代衚çãªçªçŽ é žåç©æµåçšè§ŠåªãšããŠã¯ãéã
é ããããžãŠã ãªã©ã®é žåç©ã掻æ§æåãšããã
ãããã¢ã«ããïŒãã¿ãã¢ãªã©ã®æ äœã«æ æãã
ããã®ãããããããã®è§Šåªã§ãV2O5âTio2觊
åªã¯ãäœæž©ïŒ300âååŸïŒã§ãé«æŽ»æ§ã§èSOxæ§
ã倧ããããããã觊åªã§ããããSO2ãSO3ã«
é žåãã掻æ§ã倧ãããããSO3ãå€éã«è§Šåªäž
ã§çæãããããæ·»å ããéå æ§ç©è³ªã®ã¢ã³ã¢ã
ã¢ãšçµåããŠè§Šåªè¡šé¢ã«èç©ããããç±äº€æåšã
ç éãªã©ã«é žæ§ç¡«é žã¢ã³ã¢ããŠã ã®ãããªç¡«é»å
åç©ãä»çå ç©ãããããŠã觊åªã®å£åãè£ çœ®ã®
è èãªã©ãã¯ãããçš®ã ã®é転äžã®ãã©ãã«ãåŒ
ãããããšããæ¬ ç¹ãããã ãŸãæ äœããã³ïŒãŸãã¯æŽ»æ§æåãšããŠéå±ç¡«
é žå¡©ã䜿çšããçªçŽ é žåç©æµåçšè§Šåªã«ã€ããŠã
ãã§ã«å€æ°ç¥ãããŠããããããã®è§Šåªã¯ãè
SOxæ§ããã³å¯¿åœã®ç¹ã§æ¯èŒçãããã觊åªã§ã
ãããæã¬ã¹äžã®ãã¹ããªã©ã®ä»çã«ããæ±æã
ãã觊åªãæ°ŽæŽã«ããåçããããšããå Žåãé
転äžã«æ°Žã觊åªã«ããã€ããããå Žåãªã©æŽ»æ§æ
åã溶åºãããã觊åªã厩å£ãããããŠããŸãã»
ãã«äœæž©ïŒ300âååŸïŒã§ã®æŽ»æ§ãäœããšããé£
ç¹ãããã ãŸãç¹éæ51â103869å·å ¬å ±ã®ç¹èš±è«æ±ã®ç¯å²
ã«ã¯ãéåžžã«å€ãã®éå±ç¡«é žå¡©è§Šåªã«ã€ããŠã®èš
èŒããããããã®å ¬å ±ã«èšèŒã®è§Šåªã¯ããã®ç¬¬ïŒ
ããŒãžãå·Šæ¬ã第20è¡ãåããŒãžãå³æ¬ã第ïŒè¡
ã®è§Šåªèª¿è£œæã«çŒæããå¿ èŠã¯ãªãã掻æ§æåã
æ°ŽæŽã«ãã€ãŠå®¹æã«åé¢ã§ãããšã®èšèŒãããæ
ããã§ããããã«ã觊åªã®èæ°Žæ§ã«ãããŠå€§ããª
é£ç¹ããããæ°ŽæŽã«ãã€ãŠè§Šåªãåçããããšã
ããšã觊åªã厩å£ãããã掻æ§æåã溶åºããŠã
ãŸã€ããããã æ¬åºé¡äººã®åºé¡ã«ä¿ãç¹å ¬æ56â32020å·å ¬å ±
ïŒè¥¿ãã€ãå ¬éç¹èš±å ¬å ±ç¬¬2842147å·ïŒã«ã¯ãç¡«é ž
ããªãŠã ãšæ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ãšãããªã
觊åªãèšèŒãããŠãããè©²å ¬å ±ã«èšèŒã®è§Šåªã¯ã
èæ°Žæ§ããã³èSOxæ§ã«ããããSO2ãSO3ã«é ž
åãã掻æ§ïŒSO2é žå掻æ§ïŒãäœããæ¯èŒçäœæž©
ã§NOxé€å»æŽ»æ§ãé«ããšããç¹é·ãæããŠããã
ãŸããç¹éæ59â59249å·å ¬å ±ã«ã¯ããããžãŠã
ã®åå䟡ãïŒäŸ¡ã®ãããžãŠã ååç©ã«æ°Žã®ååšäž
ã§éå æ§ç©è³ªãå ããŠãããžãŠã ã®åå䟡ãïŒäŸ¡
ããå°ããåå䟡ã«éå ãããããžãŠã ååç©ã®
溶液ãç¡«é žãŸãã¯ç¡«é žã®ã¢ã³ã¢ããŠã å¡©ãç¡«é žã
ãªãŠã ãããã³æ°Žé žåãã¿ã³ãæ··åããåŸãçŒæ
ããããšãç¹åŸŽãšãããã¿ã³ååç©ãç¡«é žããªãŠ
ã ããã³æ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ãããªãçªçŽ
é žåç©éå æµåçšè§Šåªã®è£œæ³ãèšèŒãããŠããã
è©²å ¬å ±ã«èšèŒã®æ¹æ³ã«ãã觊åªã¯ãNH3ïŒNO
ïŒã¢ã«æ¯ïŒãïŒä»¥äžã«ããŠ300ã340âã§æã¬ã¹ã
åŠçããå Žåã®NOxé€å»æŽ»æ§ãé«ããè±ç¡åŸã®
æã¬ã¹äžã«æ®çããã¢ã³ã¢ãã¢ãå°ãªããSO2é ž
å掻æ§ãäœããšããç¹é·ãæããŠããã ç¹å ¬æ56â32020å·å ¬å ±ãç¹éæ59â59249å·å ¬
å ±ãªã©ã«èšèŒã®æ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ãå«æ
ãã觊åªã¯ãåèšãããããªããããç¹é·ãæã
ãŠãããããããã®å ¬å ±ã«ã¯ã觊åªãããã«ã ç¶
ã«æ圢ããæ¹æ³ããã³ããã«ã ç¶ã«æ圢ãã觊åª
ã®è±ç¡è©ŠéšäŸã«ã€ããŠã¯å ·äœçã«äœãèšèŒããª
ãã ãŸããæ¬åºé¡äººã®åºé¡ã«ä¿ãç¹éæ58â214343
å·å ¬å ±ã«ã¯ã(A)ãããžãŠã ããã³ïŒãŸãã¯éã®ç¡«
é žå¡©ãš(B)ç¡«é žããªãŠã ããã³ïŒãŸãã¯äºé žåãã¿
ã³ãšãããªãããã«ã ç¶è±ç¡è§Šåªãæ圢ããã«ã
ããã80ééïŒ ä»¥äžãç²åŸ100Ό以äžã®(A)ãš(B)ãš
ãããªãç²ç¶æ··åç©ã«æ°Žãå ããŠç²åç¶ç©ã«ãã
該ç²åç¶ç©ãæŒåºæ圢æ©ã§ããã«ã ç¶ã«æ圢ãã
ããšãç¹åŸŽãšããããã«ã ç¶è±ç¡è§Šåªã®æ圢æ³ã
èšèŒãããŠãããè©²å ¬å ±ã«èšèŒã®æ圢æ³ã«ãã
ãšãæ圢æã«ç¡¬åçŸè±¡ã®èãããããžãŠã ãéãª
ã©ã®ç¡«é žå¡©ãå«æããç²åç¶ç©ã®ç¡¬åçŸè±¡ãé²æ¢
ã§ãã硬åçŸè±¡ã«èµ·å ããæ圢æã®ãã©ãã«ã解
決ã§ãããšããç¹é·ãæããŠããããŸãè©²å ¬å ±ã«
ã¯ç²åç¶ç©ã調補ããéãçé žã«ã«ã·ãŠã ããã³
ããã€ããã°ã©ãã¢ã€ããã·ãªã«ãŸã«ãã¢ã«ãã
ãŸã«ãåçš®ç²åé±ç©ã®ãããªç¡æ©ç©è³ªãæ·»å ããŠ
ããããšã®èšèŒã¯ãããããããç¡æ©ç©è³ªãæ·»å
ããŠããã«ã ç¶ã«æ圢ããå ·äœçããã³è±ç¡è©Šéš
äŸã«ã€ããŠã¯äœãèšèŒããªãã ãçºæã解決ããããšããåé¡ç¹ã ãã¹ããå«æããæã¬ã¹ãäŸãã°ç³çççŒæã¬
ã¹ïŒSOx300ã2000ppm.ãã¹ãïŒã30gïŒïŒ®m3ïŒ
ã®åŠãé«ãã¹ãå«ææã¬ã¹äžã®NOxã觊åªã®å
åšäžã«éå æµåããéã¯ããã¹ãã«ãã觊åªå±€ã®
ç®è©°ãããã¹ãã®å ç©ãªã©ã«èµ·å ããçš®ã ã®ãã©
ãã«ãé²æ¢ããããã«ã觊åªã¯ãã¬ããç¶ã§äœ¿çš
ãããããããã«ã ç¶ã«æ圢ããŠäœ¿çšããæ¹ãæ
å©ã§ãããããã®æ圢ã«å°é£ã䌎ã€ãããæåŸ ã
ãçµæãåŸãããªãããšãå€ããå·¥æ¥çšè§Šåªãšã
ãŠã¯æ圢æ§ïŒçç£æ§ïŒãããã容æã«ããã«ã ç¶
ã«æ圢ã§ããããšã䜿çšæã«ãã¹ãã«ããæ©èã
å°ãªãèæ©èæ§ã®ããããšãèŠæ±ãããã ãŸãåºå®ççŒè£ 眮ãäŸãã°çºé»çšãã€ã©ãŒã§
ã¯ãæé垯æèšãããšé転æ¡ä»¶ã«ãã€ãŠè² è·ã倧
ããå€åããããã«å¿ããŠãã€ã©ãŒåºå£ã®æã¬ã¹
枩床ãå€åããã100ïŒ è² è·ã§ãã€ã©ãŒåºå£ã®æ
ã¬ã¹æž©åºŠã380â以äžã«ãªããã€ã©ãŒãæ°å€ãã
ãããŸãççŒè£ 眮ã®çš®é¡ãè±ç¡è£ 眮ã®ãšãã€ãäœ
眮ã«ãã€ãŠã被åŠçæã¬ã¹ã®æž©åºŠã¯ç°ãªãããè¿
幎ã¯é«æž©ãäŸãã°350ã410âã®é«æž©æ¡ä»¶äžã§ã®æ
ã¬ã¹äžã®NOxé€å»ãèŠæ±ãããããšãå€ãã åŸã€ãŠå·¥æ¥çšè§ŠåªãšããŠã¯ãåèšæ圢æ§ããã³
èæ©èæ§ãšãšãã«ãããã«é«æž©æ¡ä»¶äžã«ãããŠã
é«ãNOxé€å»æŽ»æ§ã瀺ããSO2é žå掻æ§ãäœã
ç¶æããããšãã§ãããã€æž©åºŠãäœäžããå Žåã«
ãå®å®ããNOxé€å»æŽ»æ§ãæãããŸãè±ç¡åŸã®
æã¬ã¹äžã®ã¢ã³ã¢ãã¢æ¿åºŠãäœãããããšãã§ã
ããããªããã«ã ç¶ã®è§Šåªã®éçºã匷ãæãŸããŠ
ããã ãåé¡ç¹ã解決ããããã®æ段ã æ¬çºæã¯ãåèšèŠæ±ãæºè¶³ãããããšãã§ãã
NOxæµåçšè§Šåªã®è£œæ³ãæäŸããããšã«ããã ãŸãæ¬çºæã¯ãNOxãšãšãã«SOxããã³ãã¹
ãå«ææã¬ã¹äžã®NOxããã¢ã³ã¢ãã¢ã®åŠãé
å æ§ç©è³ªã®ååšäžã«éå æµåããéã«äžæ®µãšãã
ããå¹æãçºæ®ããNOxæµåçšè§Šåªã®è£œæ³ãæ
äŸããããšã«ããã æ¬çºæã¯ããããžãŠã ã®åå䟡ãïŒäŸ¡ã®ãããž
ãŠã ååç©ãéå æ§ç©è³ªããã³æº¶åªã®ååšäžã«é
å ããŠãããžãŠã ã®åå䟡ãïŒäŸ¡ããå°ããåå
䟡ã«éå ãããããžãŠã ååç©ã®æº¶æ¶²ãç¡«é žãŸã
ã¯ç¡«é žã®ã¢ã³ã¢ããŠã å¡©ãç¡«é žããªãŠã ããã¿ã³
é žãããã³ç²åé±ç©ãæ··åããŠç²åç¶ç©ã«ãã該
ç²åç¶ç©ãæŒåºæ圢æ©ã§ããã«ã ç¶ã«æ圢ãã
åŸãçŒæããŠè§Šåªã«ããããšãç¹åŸŽãšããNOx
æµåçšè§Šåªã®è£œæ³ã«é¢ããã æ¬çºæã«ãããŠãããžãŠã ã®åå䟡ãïŒäŸ¡ã®ã
ããžãŠã ååç©ãšããŠã¯ãã¡ã¿ãããžã³é žã¢ã³ã¢
ããŠã ãã¡ã¿ãããžã³é žãäºé žåãããžãŠã ãªã©
ãæããããšãã§ãããªãã§ãã¡ã¿ãããžã³é žã¢
ã³ã¢ããŠã ã奜é©ã§ããããŸãéå æ§ç©è³ªãšããŠ
ã¯ïŒäŸ¡ã®ãããžãŠã ååç©ãïŒäŸ¡ããå°ããåå
䟡äžè¬ã«ã¯ïŒäŸ¡ã«éå ããããšãã§ãããã®ã§ã
ãã°ãããäŸãã°ã·ãŠãŠé žãã¯ãšã³é žãé ç³é žãª
ã©ã®ææ©ã«ã«ãã³é žãæããããšãã§ãããªãã§
ãã·ãŠãŠé žã奜é©ã§ããã ãããžãŠã ã®åå䟡ãïŒäŸ¡ã®ãããžãŠã ååç©
ãéå æ§ç©è³ªããã³æº¶åªã®ååšäžã«éå ããŠãã
ãžãŠã ã®åå䟡ãïŒäŸ¡ããå°ããåå䟡ã«éå ã
ããããžãŠã ååç©ã®æº¶æ¶²ã調補ããã«ããã€ãŠ
ã¯ãäŸãã°æ°Žã®åŠã溶åªã«ã¡ã¿ãããžã³é žã¢ã³ã¢
ããŠã ã®åŠãïŒäŸ¡ã®ãããžãŠã ååç©ã溶解ã
ããããã«ã·ãŠãŠé žã®åŠãéå æ§ç©è³ªãå ããŠïŒ
䟡ã®ãããžãŠã ååç©ãéå ããæ¹æ³ã§è¡ã€ãŠ
ãããŸãéå æ§ç©è³ªã溶åªã«æº¶è§£ããã溶液ã«ïŒ
䟡ã®ãããžãŠã ååç©ãå ããŠéå ããæ¹æ³ã§è¡
ã€ãŠãããã溶åªãšããŠã¯ãïŒäŸ¡ã®ãããžãŠã å
åç©ããã³éå æ§ç©è³ªã溶解ãããã®ã§ããã°ã
ãããäžè¬ã«ã¯æ°Žã奜é©ã«äœ¿çšãããã ãŸãæ¬çºæã§äœ¿çšããç¡«é žãŸãã¯ç¡«é žã®ã¢ã³ã¢
ããŠã å¡©ãšããŠã¯ãæ¿ç¡«é žãç¡«é žã¢ã³ã¢ããŠã ã
é žæ§ç¡«é žã¢ã³ã¢ããŠã ãäºç¡«é žã¢ã³ã¢ããŠã ãé
ç¡«é žã¢ã³ã¢ããŠã ãªã©ãæããããšãã§ãããªã
ã§ãç¡«é žã¢ã³ã¢ããŠã ãå®äŸ¡ã§ãããç®çãšãã
觊åªã®åçŸæ§ãããã®ã§å¥œé©ã§ãããç¡«é žãŸãã¯
ç¡«é žã®ã¢ã³ã¢ããŠã å¡©ã¯æ°Žã«äžæº¶æ§ã®ç¡«é žãããž
ã«ã圢æãããããã§å¿ èŠãªãã®ã§ãããããã®
䜿çšéã¯ã䜿çšããïŒäŸ¡ã®ãããžãŠã ååç©ã®ã
ããžãŠã ïŒã°ã©ã ååã«å¯ŸããŠãç¡«é»ãïŒãïŒã°
ã©ã ååã«ãªããããªéã奜é©ã§ãããïŒã°ã©ã
ååããå€ããªãéã§äœ¿çšããŠãå€ã䜿çšããã
ãšã«ããå©ç¹ã¯ç¹ã«ãªãã ç¡«é žããªãŠã ãšããŠã¯ãäžè¬ã«æ¯è¡šé¢ç©10m2ïŒ
ïœä»¥äžã§ãå¹³åç²åŸ0.1ã1.0ÎŒã®æ²éæ§ç¡«é žããª
ãŠã ã奜é©ã«äœ¿çšãããã æ¬çºæã¯ãæ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ããã³ç¡«
é žããªãŠã ãšãšãã«ããã¿ã³é žããã³ç²åé±ç©ã
çµåãããšãæ圢æ§ãæ¹åãããå·¥æ¥çšè§Šåªãšã
ãŠèŠæ±ãããç¹æ§ãæºããããã«ã ç¶è§ŠåªãåŸã
ãããšããçºèŠã«åºããŠããã ãã¿ã³é žãšããŠã¯ããªã«ããã¿ã³é žïŒÎ±âãã¿
ã³é žïŒãã¡ã¿ãã¿ã³é žïŒÎ²âãã¿ã³é žïŒãγâãã¿
ã³é žãªã©ãæããããšãã§ãããããã¯å€ãã®å Ž
åããããã®æ··åç©ãšããŠå ¥æãããããäžè¬ã«
ã¡ã¿ãã¿ã³é žãšåŒã°ããŠããã¡ã¿ãã¿ã³é žãäž»æ
åãšãããã®ã奜é©ã§ããããã¿ã³é žã¯äžè¬ã«æ°Ž
ã¹ã©ãªãšããŠäœ¿çšãããã ãã¿ã³é žã¯ãç¡«é žããªãŠã ãšã¯éã«äžè¬ã«æ¯è¡š
é¢ç©ã100ã300m2ïŒïœãšå€§ãããäžæ¬¡ç²åã®å¹³å
ç²åŸã30ã50â«ãšå°ããã®ã§ã觊åªã®ç©ççæ§
質ãç¹ã«æ¯è¡šé¢ç©çã®æ¹åã«å€§ããå¯äžããŠã
ãã æ¬çºæã¯ãç¡«é žããªãŠã ã䜿çšããéã«è§Šåªã®
æ¯è¡šé¢ç©ãå°ãããªã€ãŠNOxé€å»æŽ»æ§ãäœäžã
ãããSO2é žå掻æ§ãé«ããªã€ããããã®ããã
ã¿ã³é žã®äœ¿çšã«ãã€ãŠãæ¯è¡šé¢ç©ã倧ããããã
ãã«ã¯é©åºŠã«å€§ããªçŽ°åãæãã觊åªã«ããããš
ãã§ãã觊åªæ§èœãäžæ®µãšé«ããããšãå¯èœã§ã
ãã ç²åé±ç©ãšããŠã¯ãã¢ã³ã¢ãªããã€ãç³»é±ç©ã
ã«ãªãªãã€ãç³»é±ç©ãããŒãããŠã©ã€ãç³»é±ç©ãª
ã©ãæããããšãã§ãããç²åé±ç©ã¯å°éã®æ°Žã
ãããšå¯å¡æ§ãçŸãããç²åé±ç©ã®äœ¿çšã«ãã€ãŠ
ããã«ã ç¶ã«æ圢ããéã®æ圢æ§ãé¡èã«æ¹åã
ããããªãããšãç²åé±ç©ã䜿çšããŠç²åç¶ç©ã«
ããŠãç²åç¶ç©ã«ããéãã¿ã³é žã䜿çšããªãã€
ãããç¡«é žããªãŠã ã䜿çšããªãã€ãããããšã
æ圢æ§ã¯æªãã ãŸãç²åé±ç©ã®ãªãã§ãã¢ã³ã¢ãªããã€ãç³»é±
ç©ã¯ãæ°Žååžçèœã倧ããæ圢æ§åäžå¹æãé«
ããããã«è§Šåªã®èæ©èæ§ãåäžãããå¹æãã
ããã¢ã³ã¢ãªããã€ãç³»é±ç©ãšããŠã¯ãé žæ§çœ
åã掻æ§çœåããã³ããã€ããªã©ãæããããšã
ã§ããç¹ã«é žæ§çœåã¯ãæ圢æ§ããã³èæ©èæ§ã«
ãããŠæè¯ã®çµæãåŸãããã®ã§å¥œé©ã§ããã ãŸãæ¬çºæã«ãããŠç²åé±ç©ãšããŠã¯ãã«ãªãŠ
ã ããããªãŠã ãªã©ã®ã¢ã«ã«ãªéå±å«æéã®å°ãª
ããã®ã奜ãŸããã¯ã¢ã«ã«ãªéå±å«æé
ïŒNa2OïŒK2Oæç®ïŒãïŒïŒ 以äžã®ãã®ã奜é©ã«
䜿çšããããã¢ã«ã«ãªéå±å«æéãå€ããšãã¢ã«
ã«ãªéå±ã®äºç¡«é žå¡©ãç¡«é žå¡©ãªã©ãçæããŠ
NOxé€å»æŽ»æ§ã®äœäžãèæ©èæ§ã®äœäžãªã©ã®æª
圱é¿ãããã ãŸãç²åé±ç©ã¯ããã®ç²åŸãïŒã60ÎŒã®ç¯å²ã«
ååžããŠãããã®ã奜é©ã«äœ¿çšãããããã®ç¯å²
å€ã®ãã®ãå«ãŸããŠããŠãå·®æ¯ããªãã æ¬çºæã«ãããŠããããžãŠã ã®åå䟡ãïŒäŸ¡ã
ãå°ããåå䟡ã«éå ãããããžãŠã ååç©ã®æº¶
液ãç¡«é žããªãŠã ããã¿ã³é žãããã³ç²åé±ç©ã®
æ··åå²åã¯ãæçµçã«åŸããã觊åªã®æ¯è¡šé¢ç©ã
15ã85m2ïŒïœã奜ãŸããã¯20ã80m2ïŒïœã«ãªãã
ããªå²åã§æ··åããããããæ®éæ··åå²åã¯ãã
ããžãŠã ååç©ã®æº¶æ¶²ãæ°Žã«äžæº¶æ§ã®ç¡«é žãããž
ã«ïŒÎ²âVOSO4ïŒæç®ã§0.5ã35ééïŒ ã奜ãŸã
ãã¯ïŒã10ééïŒ ãç¡«é žããªãŠã ã25ã95éé
ïŒ ã奜ãŸããã¯35ã70ééïŒ ããã¿ã³é žãäºé žå
ãã¿ã³ïŒTiO2ïŒæç®ã§ïŒã65ééïŒ ä»¥äžã奜ãŸ
ããã¯20ã50ééïŒ ãç²åé±ç©ã35ééïŒ ä»¥äžã
奜ãŸããã¯ïŒã25ééïŒ ã®ç¯å²ããéžæãããã
觊åªã®æ¯è¡šé¢ç©ã倧ãããªããšSO2é žå掻æ§ãå°
ãããªãåŸåãããããããŸã倧ãããããšèæ©
èæ§ãæªããªãããŸãæ¯è¡šé¢ç©ãå°ãããªããš
NOxé€å»æŽ»æ§ãæªããªãã æ¬çºæã«ãããŠç²åç¶ç©ã®èª¿è£œã«ããããå¿ èŠ
ã«å¿ããŠé«çŽãã©ãã€ã³ãå€ç³é¡ãå€äŸ¡ã¢ã«ã³ãŒ
ã«ããªã°ãã³ã¹ã«ãã³é žå¡©ã®åŠãæ圢å©å€ãã¬ã©
ã¹ç¹ç¶ãççŽ ç¹ç¶ã®åŠãç¡æ©è³ªç¹ç¶ãæ·»å ããã
ãšãã§ããã æ¬çºæã«ãããŠããããžãŠã ã®åå䟡ãïŒäŸ¡ã
ãå°ããåå䟡ã«éå ãããããžãŠã ååç©ã®æº¶
液ãç¡«é žãŸãã¯ç¡«é žã®ã¢ã³ã¢ããŠã å¡©ãç¡«é žããª
ãŠã ããã¿ã³é žãããã³ç²åé±ç©ã®æ··åæ¹æ³ãšã
ãŠã¯ãäžè¬ã«ãããžãŠã ååç©ã®æº¶æ¶²ã«ç¡«é žãŸã
ã¯ç¡«é žã®ã¢ã³ã¢ããŠã å¡©ããã¿ã³é žããã³ç¡«é žã
ãªãŠã ãæ··åããåŸã也ç¥ããŠç²ç¶æ··åç©ãšãã
ããã«ç²åé±ç©ãæ··åããæ··åç©ã«æ°Žãå ããŠç²
åç¶ç©ã«ããæ¹æ³ãæ¡çšãããããæ··åé åºãæ
äœã¯ãã以å€ã®æ¹æ³ã§æ··åããŠãããã æ°Žã®éã¯ãæŒåºæ圢æ©ã§ããã«ã ç¶ã«æ圢ã§ã
ãçšåºŠã®éãäžè¬ã«ã¯æ··åç©ã«å¯ŸããŠïŒã35éé
ïŒ ã奜ãŸããã¯ïŒã30ééïŒ ã«ãªãããã«ããã®
ãé©åœã§ãããåŸãããç²åç¶ç©ã¯ãã®ç¡¬åºŠãïŒ
ã20KgïŒcm2ã奜ãŸããã¯ïŒã15KgïŒcm2ã®ç¯å²ã«ãª
ãããã«ããã®ãæãŸãããæ°Žã®éãå€ããã
ããå°ãªãããããããšåŸãããç²åç¶ç©ã硬ã
ããããæãããããããŠæ圢æ§ãæªããªãããŸ
ãç²åç¶ç©ã®èª¿è£œã¯ãäŸãã°ããŒããŒã®ãããªåŸ
æ¥å ¬ç¥ã®æ··ç·Žæ©ãçšããŠè¡ãã®ãé©åœã§ãããã
ãã§ãç²åç¶ç©ã®ç¡¬åºŠã¯å±±äžåŒåå£ç¡¬åºŠèšã«ãã
枬å®ã æ¬çºæã«ãããŠç²åç¶ç©ãããã«ã ç¶ã«æ圢ã
ãã«ããã€ãŠã¯ãããèªäœå ¬ç¥ã®æŒåºæ圢æ©ãäŸ
ãã°ãã¹ãã³ã¿ã€ãããªãŒã¬ãŒã¿ã€ããªã©ãé©å®
䜿çšãããæŒåºæ圢æ©åºå£ã«ãšãã€ããéåãã
ããããšã«ãã€ãŠãå€è§çç¶ãåçç¶ãã åçç¶
ãªã©ã®ããã«ã ç¶ã«æ圢ããããšãã§ããããã
ã«ã ç¶ã«æ圢ãããæ圢ç©ã¯ãããã䜿çšæ¡ä»¶ã«
å¿ããŠé©åœãªé·ããäŸãã°10ã100cmã«åæãã
å¿ èŠã«å¿ããŠä¹Ÿç¥ããåŸãçŒæããã ããã«ã ç¶æ圢ç©ã®çŒæã¯ã200ã450âã奜ãŸ
ããã¯350ã450âã®æž©åºŠã§è¡ãã®ãé©åœã§ããã
çŒææéã¯äžè¬ã«ã¯ïŒã24æéã奜ãŸããã¯ïŒã
16æéçšåºŠãé©åœã§ããããŸãçŒæé°å²æ°ã¯ç¹ã«
å¶éããããäŸãã°äºç¡«é žã¬ã¹ãã¢ã³ã¢ãã¢ãæ°Ž
èžæ°ãçªçŽ ãé žçŽ ãªã©ããããå«ãé°å²æ°ã§ãã
ããã空æ°ã®åŠãé žçŽ å«æã¬ã¹é°å²æ°ãçµæžçã§
ãããããŸã奜é©ã§ãããã çŒæããããšã«ãã€ãŠåæãšããŠäœ¿çšãããã
ãžãŠã ååç©ã¯ãæ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ïŒÎ²
âVOSO4ïŒã«ãªãã®ã§ã觊åªäžã®ãããžãŠã å
åç©ãšããŠã¯æ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ä»¥å€ã«ä»
ã®ãããžãŠã ååç©ã¯ã»ãšãã©å«ãŸããŠããªã
ããå°éïŒå šãããžãŠã ååç©ã®ïŒééïŒ ä»¥äžçš
床ïŒã§ããã°ä»ã®ãããžãŠã ååç©ãå«ãŸããŠã
ãŠãå·®æ¯ããªãããªãæ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«
ããèªäœã¯ãèµ€å€ç·åžåã¹ãã¯ãã«ã«ãããšãæ°Ž
溶æ§ç¡«é žãããžã«ïŒÎ±âVOSO4ïŒã«ã¯èŠãããª
ã940-1cmããã³510-1cmã«ç¹åŸŽçãªåžåããŒã¯ã
æããŠãããASTM19â1400ã«ãããžãŠã ïŒIVïŒ
ãªããµã€ããµã«ããšã€ããVanadiumïŒIVïŒ
OxideSalfateããšããŠèšèŒãããŠããã觊åªäž
ã®ç¡«é žãããžã«æ¿åºŠãïŒééïŒ ä»¥äžã®å Žåã«ã¯ã
940cm-1ããã³510cm-1ã®èµ€å€ç·åžåã¹ãã¯ãã«ã¯
é¡èã§ã¯ãªãããESCAãçšããŠåæãããšãã
ããžãŠã ã®åå䟡ã¯ïŒäŸ¡ã§ããããŸã觊åªãæ°Žã«
ã€ããŠããããžãŠã ã®æº¶åºããªãããšãããæ°Žã«
äžæº¶æ§ã®ç¡«é žãããžã«ãšèªããããã ãŸãåæãšããŠäœ¿çšãããã¿ã³é žã¯ã觊åªäžã§
ã©ã®ãããªãã¿ã³ååç©ã«ãªã€ãŠãããç·åæ
ã¹ãã¯ãã«ãªã©ã§ã¯ååæããã§ã¯ãªããããã¿
ã³é žãšäºé žåãã¿ã³ãå«ãè€éãªãã¿ã³ååç©ã«
ãªã€ãŠããã®ã§ã¯ãªãããšæšå®ãããã ãå®æœäŸã åäŸã«ãããŠãNOxé€å»æŽ»æ§ã®è©Šéšã¯ããã
ã«ã ç¶ã®è§Šåªãã¹ãã³ã¬ã¹è£œåå¿ç®¡ã«å å¡«ããå
å¿ç®¡ã«ãNO300ppmãNH3300ppmã
SO2800ppmãH2O10ïŒ ãO23ïŒ ããã³æ®ãN2ã
ããªãã¢ãã«ã¬ã¹ïŒNH3ïŒNOïŒïŒïŒã¢ã«æ¯ïŒ
ãã空éé床5000hr-1ã®æµéã§æµãã350âã380
âããã³400âã«ä¿æãã24æéåŸãåå¿ç®¡å ¥å£
ããã³åºå£ã«ãããã¬ã¹äžã®NOxå«æéãååŠ
çºå åŒNOxåæèšã§æž¬å®ãã次åŒã«åŸã€ãŠNOx
é€å»çïŒïŒ ïŒãæ±ããæ¹æ³ã§è¡ã€ãã NOxé€å»çïŒïŒ ïŒïŒX1âX2ïŒX1Ã100 X1ïŒåå¿ç®¡å ¥å£ã«ãããã¬ã¹äžã®NOxæ¿åºŠ X2ïŒåå¿ç®¡åºå£ã«ãããã¬ã¹äžã®NOxæ¿åºŠ ãŸãSO2ã®é žå掻æ§ã®è©Šéšã¯ãåèšã¢ãã«ã¬ã¹
ãåèšãšåæ§ã«ããŠç©ºéé床5000hr-1ã®æµéã§æµ
ãã350âããã³380âã«ä¿æãã72æéåŸãåå¿
ç®¡å ¥å£ããã³åºå£ã«ãããã¬ã¹äžã®SO2ããã³
SO3æ¿åºŠãåæã枬å®ãã次åŒã«ããSO2é žåç
ïŒïŒ ïŒãæ±ããæ¹æ³ã§è¡ã€ãã SO2é žåçïŒïŒºïŒïŒ¹Ã100 ïŒåå¿ç®¡å ¥å£ã«ãããã¬ã¹äžã®SO2æ¿åºŠ ïŒåå¿ç®¡åºå£ã«ãããã¬ã¹äžã®SO3æ¿åºŠ ãŸãèæ©èæ§ã®è©Šéšã¯ãç³ççããã€ã©ãŒã®æ
ã¬ã¹ïŒãã¹ãå«æé12gïŒïŒ®m3ïŒNOxå«æé
320ppmãSOxå«æé280ppmã枩床350âïŒãã
ãã¯ãŒã§æå§ããã¬ã¹ç·é床15.5mïŒsecã®æã¬
ã¹ãé·ãïŒé«ãïŒ100mmã®ããã«ã ç¶ã®è§Šåªã®äž
æ¹ããäžæ¹ã«16æ¥éå¹ãã€ããåŸã觊åªããšãã
ããŠè§Šåªã秀éããééæžå°éããæ©èçïŒéé
ïŒ ïŒãæ±ããæ¹æ³ã§è¡ã€ãã å®æœäŸ ïŒ ã¡ã¿ãããžã³é žã¢ã³ã¢ããŠã 0.43Kgã15ã®æ°Ž
ã«å ããŠçŽ70âã«å æž©ããæ¹æäžã«ã·ãŠãŠé ž0.7
KgãåŸã ã«å ããŠãããžãŠã ãéå ãããã®ãã
ãžãŠã ååç©ã®æº¶æ¶²ã«ãç¡«é žã¢ã³ã¢ããŠã 0.73Kg
ãå ãã次ãã§æ²éæ§ç¡«é žããªãŠã ç²æ«13.7Kgã
ãã³ã¡ã¿ãã¿ã³é žã®æ°Žã¹ã©ãªãäºé žåãã¿ã³æç®
ã§11.2Kgãå ããŠããŒã¹ãç¶ã«ããåŸããã©ã 也
ç¥æ©ã§150âã§ä¹Ÿç¥ããŠç²ç¶æ··åç©ãåŸãã 次ãã§ãç²ç¶æ··åç©ã«ãç²ç¶ã®é žæ§çœåïŒã¢ã«
ã«ãªéå±å«æéïŒNa2Oããã³K2OãšããŠ0.9éé
ïŒ ïŒ4.5Kgãã°ãªã»ãªã³1.2Kgãå€ç³é¡0.06Kgãã
ã³æ°Ž8.4Kgãå ããæ··ç·ŽããŠç²åç¶ç©ã«ããåŸã
ãã¹ãã³ã¿ã€ãã®æŒåºæ圢æ©ãçšããŠãäžèŸºã70
mmã®æ£æ¹åœ¢ã§ãã®äžã瞊ïŒç®ã暪ïŒç®ãèå1.5
mmã®æ Œåç¶ã«ä»åãããŠããããã«ã ç¶ã®æ圢ç©
ïŒé·ã700mmïŒã«æ圢ãã100âã§ä¹Ÿç¥ãã空æ°é°
å²æ°äžã«400âã§ïŒæéçŒæããŠããã«ã ç¶è§Šåª
ãåŸããåŸããã觊åªã®çµæã¯ãç¡«é žããªãŠã
45.7ééïŒ ãæ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ïŒéé
ïŒ ããã¿ã³ååç©ïŒTiO2æç®ïŒ37.8ééïŒ ãã
ã³é žæ§çœå15ééïŒ ãããªãããªããæ圢åã®ç²
åç¶ç©ã®ç¡¬åçŸè±¡ã¯èªããããªãã€ãããŸãæ圢
æ§ãéåžžã«ããã觊åªã¯ããå²ãããã³ã€ã®ãªã
ãã®ã§ãã€ãã觊åªã®æ¯è¡šé¢ç©ã¯64m2ïŒïœã§ãã€
ããNOxé€å»çãSO2é žåçããã³æ©èçã®è©Š
éšçµæã¯ã第ïŒè¡šã«ç€ºãã å®æœäŸ ïŒ å®æœäŸïŒã®é žæ§çœåã«ãããŠãã³ããã€ãç²æ«
ã䜿çšããã»ãã¯ãå®æœäŸïŒãšåæ§ã«ããŠããã«
ã ç¶è§Šåªã補é ãããå®æœäŸïŒãšåæ§ã«ç²åç¶ç©
ã®ç¡¬åçŸè±¡ã¯èªããããããŸãæ圢æ§ãããã觊
åªã®ããå²ãããã³ã€ã¯èªããããªãã€ãã觊åª
ã®æ¯è¡šé¢ç©ã¯62m2ïŒïœã§ãã€ãã觊åªæ§èœã®è©Šéš
çµæã¯ã第ïŒè¡šã«ç€ºãã å®æœäŸ ïŒ å®æœäŸïŒã®é žæ§çœåã®ãããã«ã«ãªãªãã€ãç³»
ç²åé±ç©ã®ã«ãªãªã³ç²æ«ã䜿çšããã»ãã¯ãå®æœ
äŸïŒãšåæ§ã«ããŠããã«ã ç¶è§Šåªã補é ãããæ
圢åã®ç²åç¶ç©ã®ç¡¬åçŸè±¡ã¯èªããããã觊åªã®
ããå²ãããã³ã€ã¯èªããããªãã€ãã觊åªã®æ¯
è¡šé¢ç©ã¯62m2ïŒïœã§ãã€ãã觊åªæ§èœã®è©Šéšçµæ
ã¯ã第ïŒè¡šã«ç€ºãã æ¯èŒäŸ ïŒ å®æœäŸïŒã®ã¡ã¿ãã¿ã³é žã䜿çšãããå®æœäŸïŒ
ãšåæ§ã®æäœã§ãæ²éæ§ç¡«é žããªãŠã ã73.4éé
ïŒ ãæ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ã11.6ééïŒ ãã
ã³é žæ§çœå15ééïŒ ãããªãçµæã®ããã«ã ç¶è§Š
åªã補é ãã觊åªæ§èœè©Šéšãè¡ã€ããæ圢åã®ç²
åç¶ç©ã¯è¥å¹²ç¡¬åçŸè±¡ãèªããããããŸãæ圢æ§
ããããªãã€ãã觊åªã®æ¯è¡šé¢ç©ã¯7.9m2ïŒïœã§
ãã€ãã觊åªæ§èœã®è©Šéšçµæã¯ã第ïŒè¡šã«ç€ºãã æ¯èŒäŸ ïŒ ã¡ã¿ãããžã³é žã¢ã³ã¢ããŠã 0.43Kgãã·ãŠãŠé ž
0.7Kgãç¡«é žã¢ã³ã¢ããŠã 0.73Kgãæ²éæ§ç¡«é žã
ãªãŠã 13.7Kgããã³äºé žåãã¿ã³ïŒã¢ãã¿ãŒãŒ
åïŒç²æ«11.2Kgã70âã«å æž©ããæ°Ž30ã«å ãã
æ¹æããåŸã150âã§åŽé§ä¹Ÿç¥ããåŸãå®æœäŸïŒ
ãšåæ§ã«ããŠé žæ§çœåãã°ãªã»ãªã³ãå€ç³é¡ãã
ã³æ°Žãå ããŠããã«ã ç¶è§Šåªã補é ããã觊åªã¯
ç¡«é žããªãŠã 45.7ééïŒ ãæ°Žã«äžæº¶æ§ã®ç¡«é žãã
ãžã«ïŒééïŒ ãäºé žåãã¿ã³37.3ééïŒ ããã³é ž
æ§çœå15ééïŒ ã®çµæãããªãã觊åªã®æ¯è¡šé¢ç©
ã¯8.4m2ïŒïœã§ãã€ãã觊åªæ§èœã®è©Šéšçµæã¯ã
第ïŒè¡šã«ç€ºãã æ¯èŒäŸ ïŒ å®æœäŸïŒã®ç¡«é žããªãŠã ã䜿çšãããã¡ã¿ãã¿
ã³é žã®äœ¿çšéãå¢ãããå®æœäŸïŒãšåæ§ã®æäœ
ã§ããã¿ã³ååç©ïŒTiO2æç®ïŒ83ééïŒ ãæ°Žã«
äžæº¶æ§ã®ç¡«é žãããžã«ïŒééïŒ ãé žæ§çœå15éé
ïŒ ãããªãçµæã®ããã«ã ç¶è§Šåªã補é ãããæ
圢åã®ç²åç¶ç©ã®ç¡¬åçŸè±¡ã¯èªããããªãã€ã
ããæ圢æ§ãæªãããŸãèæ©èæ§è©Šéšãè¡ã€ããš
ãããæ©èç28.5ïŒ ã§ãã€ãã®ã§ãNOxé€å»çã
SO2é žåçãªã©ã®è©Šéšã¯è¡ããªãã€ãã 觊åªã®æ¯è¡šé¢ç©ã¯92m2ïŒïœã§ãã€ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã®é žæ§çœåã䜿çšããªãã€ãã»ãã¯ã
å®æœäŸïŒãšåæ§ã®æäœã§ããã«ã ç¶è§Šåªã®è£œé ã
è©Šã¿ãããæ圢æ§ãæªããåäžã«æŒåºãããšãã§
ããã觊åªåŽé¢ã«ããå²ããçãããŸã圢ç¶ãã
ã³ã€ã§ãã€ãã®ã§ã觊åªæ§èœè©Šéšã¯è¡ããªãã€
ãã
VOSO4ïŒãç¡«é žããªãŠã ããã¿ã³ååç©ããã³ç²
åé±ç©ãå«æããããã«ã ç¶ã®çªçŽ é žåç©æµåçš
觊åªã®è£œæ³ã«é¢ãããã æŽã«è©³ããã¯ãæ¬çºæã¯ãçªçŽ é žåç©ãå«æã
ãæã¬ã¹ç¹ã«çªçŽ é žåç©ãšãšãã«ç¡«é»é žåç©ãã
ã³ãã¹ãå«ææã¬ã¹äžã®çªçŽ é žåç©ãéå æµåã
ãã®ã«é©ããçªçŽ é žåç©æµåçšè§Šåªã®è£œæ³ã«é¢ã
ãã ãåŸæ¥ã®æè¡ã ãã€ã©ãŒãçºé»æã補éæãªã©ãã¯ãããåçš®
å·¥å Žã®åºå®ççŒè£ 眮ããæåºãããäžé žåçªçŽ
ïŒNOïŒãäºé žåçªçŽ ïŒNO2ïŒãªã©ã®çªçŽ é žåç©
ïŒNOxïŒãããã«ã¯NOxãšãšãã«äºé žåç¡«é»
ïŒSO2ïŒãäžé žåç¡«é»ïŒSO3ïŒãªã©ã®ç¡«é»é žåç©
ïŒSOxïŒããã¹ããå«æããæã¬ã¹äžã®NOxãã
次åŒã«ç€ºãããã«ã¢ã³ã¢ãã¢ã®åŠãéå æ§ç©è³ªã®
ååšäžã«éå ããŠæµåããæ¹æ³ããã³ãã®éã«äœ¿
çšããçªçŽ é žåç©éå æµåçšè§Šåªã«ã€ããŠã¯ãã
ã§ã«å€æ°ç¥ãããŠããã 4NOïŒ4NH3ïŒO2â6H2OïŒ4N2 6NOïŒ4NH3â5N2ïŒ6H2O 6NO2ïŒ8NH3â7N2ïŒ12H2O 代衚çãªçªçŽ é žåç©æµåçšè§ŠåªãšããŠã¯ãéã
é ããããžãŠã ãªã©ã®é žåç©ã掻æ§æåãšããã
ãããã¢ã«ããïŒãã¿ãã¢ãªã©ã®æ äœã«æ æãã
ããã®ãããããããã®è§Šåªã§ãV2O5âTio2觊
åªã¯ãäœæž©ïŒ300âååŸïŒã§ãé«æŽ»æ§ã§èSOxæ§
ã倧ããããããã觊åªã§ããããSO2ãSO3ã«
é žåãã掻æ§ã倧ãããããSO3ãå€éã«è§Šåªäž
ã§çæãããããæ·»å ããéå æ§ç©è³ªã®ã¢ã³ã¢ã
ã¢ãšçµåããŠè§Šåªè¡šé¢ã«èç©ããããç±äº€æåšã
ç éãªã©ã«é žæ§ç¡«é žã¢ã³ã¢ããŠã ã®ãããªç¡«é»å
åç©ãä»çå ç©ãããããŠã觊åªã®å£åãè£ çœ®ã®
è èãªã©ãã¯ãããçš®ã ã®é転äžã®ãã©ãã«ãåŒ
ãããããšããæ¬ ç¹ãããã ãŸãæ äœããã³ïŒãŸãã¯æŽ»æ§æåãšããŠéå±ç¡«
é žå¡©ã䜿çšããçªçŽ é žåç©æµåçšè§Šåªã«ã€ããŠã
ãã§ã«å€æ°ç¥ãããŠããããããã®è§Šåªã¯ãè
SOxæ§ããã³å¯¿åœã®ç¹ã§æ¯èŒçãããã觊åªã§ã
ãããæã¬ã¹äžã®ãã¹ããªã©ã®ä»çã«ããæ±æã
ãã觊åªãæ°ŽæŽã«ããåçããããšããå Žåãé
転äžã«æ°Žã觊åªã«ããã€ããããå Žåãªã©æŽ»æ§æ
åã溶åºãããã觊åªã厩å£ãããããŠããŸãã»
ãã«äœæž©ïŒ300âååŸïŒã§ã®æŽ»æ§ãäœããšããé£
ç¹ãããã ãŸãç¹éæ51â103869å·å ¬å ±ã®ç¹èš±è«æ±ã®ç¯å²
ã«ã¯ãéåžžã«å€ãã®éå±ç¡«é žå¡©è§Šåªã«ã€ããŠã®èš
èŒããããããã®å ¬å ±ã«èšèŒã®è§Šåªã¯ããã®ç¬¬ïŒ
ããŒãžãå·Šæ¬ã第20è¡ãåããŒãžãå³æ¬ã第ïŒè¡
ã®è§Šåªèª¿è£œæã«çŒæããå¿ èŠã¯ãªãã掻æ§æåã
æ°ŽæŽã«ãã€ãŠå®¹æã«åé¢ã§ãããšã®èšèŒãããæ
ããã§ããããã«ã觊åªã®èæ°Žæ§ã«ãããŠå€§ããª
é£ç¹ããããæ°ŽæŽã«ãã€ãŠè§Šåªãåçããããšã
ããšã觊åªã厩å£ãããã掻æ§æåã溶åºããŠã
ãŸã€ããããã æ¬åºé¡äººã®åºé¡ã«ä¿ãç¹å ¬æ56â32020å·å ¬å ±
ïŒè¥¿ãã€ãå ¬éç¹èš±å ¬å ±ç¬¬2842147å·ïŒã«ã¯ãç¡«é ž
ããªãŠã ãšæ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ãšãããªã
觊åªãèšèŒãããŠãããè©²å ¬å ±ã«èšèŒã®è§Šåªã¯ã
èæ°Žæ§ããã³èSOxæ§ã«ããããSO2ãSO3ã«é ž
åãã掻æ§ïŒSO2é žå掻æ§ïŒãäœããæ¯èŒçäœæž©
ã§NOxé€å»æŽ»æ§ãé«ããšããç¹é·ãæããŠããã
ãŸããç¹éæ59â59249å·å ¬å ±ã«ã¯ããããžãŠã
ã®åå䟡ãïŒäŸ¡ã®ãããžãŠã ååç©ã«æ°Žã®ååšäž
ã§éå æ§ç©è³ªãå ããŠãããžãŠã ã®åå䟡ãïŒäŸ¡
ããå°ããåå䟡ã«éå ãããããžãŠã ååç©ã®
溶液ãç¡«é žãŸãã¯ç¡«é žã®ã¢ã³ã¢ããŠã å¡©ãç¡«é žã
ãªãŠã ãããã³æ°Žé žåãã¿ã³ãæ··åããåŸãçŒæ
ããããšãç¹åŸŽãšãããã¿ã³ååç©ãç¡«é žããªãŠ
ã ããã³æ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ãããªãçªçŽ
é žåç©éå æµåçšè§Šåªã®è£œæ³ãèšèŒãããŠããã
è©²å ¬å ±ã«èšèŒã®æ¹æ³ã«ãã觊åªã¯ãNH3ïŒNO
ïŒã¢ã«æ¯ïŒãïŒä»¥äžã«ããŠ300ã340âã§æã¬ã¹ã
åŠçããå Žåã®NOxé€å»æŽ»æ§ãé«ããè±ç¡åŸã®
æã¬ã¹äžã«æ®çããã¢ã³ã¢ãã¢ãå°ãªããSO2é ž
å掻æ§ãäœããšããç¹é·ãæããŠããã ç¹å ¬æ56â32020å·å ¬å ±ãç¹éæ59â59249å·å ¬
å ±ãªã©ã«èšèŒã®æ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ãå«æ
ãã觊åªã¯ãåèšãããããªããããç¹é·ãæã
ãŠãããããããã®å ¬å ±ã«ã¯ã觊åªãããã«ã ç¶
ã«æ圢ããæ¹æ³ããã³ããã«ã ç¶ã«æ圢ãã觊åª
ã®è±ç¡è©ŠéšäŸã«ã€ããŠã¯å ·äœçã«äœãèšèŒããª
ãã ãŸããæ¬åºé¡äººã®åºé¡ã«ä¿ãç¹éæ58â214343
å·å ¬å ±ã«ã¯ã(A)ãããžãŠã ããã³ïŒãŸãã¯éã®ç¡«
é žå¡©ãš(B)ç¡«é žããªãŠã ããã³ïŒãŸãã¯äºé žåãã¿
ã³ãšãããªãããã«ã ç¶è±ç¡è§Šåªãæ圢ããã«ã
ããã80ééïŒ ä»¥äžãç²åŸ100Ό以äžã®(A)ãš(B)ãš
ãããªãç²ç¶æ··åç©ã«æ°Žãå ããŠç²åç¶ç©ã«ãã
該ç²åç¶ç©ãæŒåºæ圢æ©ã§ããã«ã ç¶ã«æ圢ãã
ããšãç¹åŸŽãšããããã«ã ç¶è±ç¡è§Šåªã®æ圢æ³ã
èšèŒãããŠãããè©²å ¬å ±ã«èšèŒã®æ圢æ³ã«ãã
ãšãæ圢æã«ç¡¬åçŸè±¡ã®èãããããžãŠã ãéãª
ã©ã®ç¡«é žå¡©ãå«æããç²åç¶ç©ã®ç¡¬åçŸè±¡ãé²æ¢
ã§ãã硬åçŸè±¡ã«èµ·å ããæ圢æã®ãã©ãã«ã解
決ã§ãããšããç¹é·ãæããŠããããŸãè©²å ¬å ±ã«
ã¯ç²åç¶ç©ã調補ããéãçé žã«ã«ã·ãŠã ããã³
ããã€ããã°ã©ãã¢ã€ããã·ãªã«ãŸã«ãã¢ã«ãã
ãŸã«ãåçš®ç²åé±ç©ã®ãããªç¡æ©ç©è³ªãæ·»å ããŠ
ããããšã®èšèŒã¯ãããããããç¡æ©ç©è³ªãæ·»å
ããŠããã«ã ç¶ã«æ圢ããå ·äœçããã³è±ç¡è©Šéš
äŸã«ã€ããŠã¯äœãèšèŒããªãã ãçºæã解決ããããšããåé¡ç¹ã ãã¹ããå«æããæã¬ã¹ãäŸãã°ç³çççŒæã¬
ã¹ïŒSOx300ã2000ppm.ãã¹ãïŒã30gïŒïŒ®m3ïŒ
ã®åŠãé«ãã¹ãå«ææã¬ã¹äžã®NOxã觊åªã®å
åšäžã«éå æµåããéã¯ããã¹ãã«ãã觊åªå±€ã®
ç®è©°ãããã¹ãã®å ç©ãªã©ã«èµ·å ããçš®ã ã®ãã©
ãã«ãé²æ¢ããããã«ã觊åªã¯ãã¬ããç¶ã§äœ¿çš
ãããããããã«ã ç¶ã«æ圢ããŠäœ¿çšããæ¹ãæ
å©ã§ãããããã®æ圢ã«å°é£ã䌎ã€ãããæåŸ ã
ãçµæãåŸãããªãããšãå€ããå·¥æ¥çšè§Šåªãšã
ãŠã¯æ圢æ§ïŒçç£æ§ïŒãããã容æã«ããã«ã ç¶
ã«æ圢ã§ããããšã䜿çšæã«ãã¹ãã«ããæ©èã
å°ãªãèæ©èæ§ã®ããããšãèŠæ±ãããã ãŸãåºå®ççŒè£ 眮ãäŸãã°çºé»çšãã€ã©ãŒã§
ã¯ãæé垯æèšãããšé転æ¡ä»¶ã«ãã€ãŠè² è·ã倧
ããå€åããããã«å¿ããŠãã€ã©ãŒåºå£ã®æã¬ã¹
枩床ãå€åããã100ïŒ è² è·ã§ãã€ã©ãŒåºå£ã®æ
ã¬ã¹æž©åºŠã380â以äžã«ãªããã€ã©ãŒãæ°å€ãã
ãããŸãççŒè£ 眮ã®çš®é¡ãè±ç¡è£ 眮ã®ãšãã€ãäœ
眮ã«ãã€ãŠã被åŠçæã¬ã¹ã®æž©åºŠã¯ç°ãªãããè¿
幎ã¯é«æž©ãäŸãã°350ã410âã®é«æž©æ¡ä»¶äžã§ã®æ
ã¬ã¹äžã®NOxé€å»ãèŠæ±ãããããšãå€ãã åŸã€ãŠå·¥æ¥çšè§ŠåªãšããŠã¯ãåèšæ圢æ§ããã³
èæ©èæ§ãšãšãã«ãããã«é«æž©æ¡ä»¶äžã«ãããŠã
é«ãNOxé€å»æŽ»æ§ã瀺ããSO2é žå掻æ§ãäœã
ç¶æããããšãã§ãããã€æž©åºŠãäœäžããå Žåã«
ãå®å®ããNOxé€å»æŽ»æ§ãæãããŸãè±ç¡åŸã®
æã¬ã¹äžã®ã¢ã³ã¢ãã¢æ¿åºŠãäœãããããšãã§ã
ããããªããã«ã ç¶ã®è§Šåªã®éçºã匷ãæãŸããŠ
ããã ãåé¡ç¹ã解決ããããã®æ段ã æ¬çºæã¯ãåèšèŠæ±ãæºè¶³ãããããšãã§ãã
NOxæµåçšè§Šåªã®è£œæ³ãæäŸããããšã«ããã ãŸãæ¬çºæã¯ãNOxãšãšãã«SOxããã³ãã¹
ãå«ææã¬ã¹äžã®NOxããã¢ã³ã¢ãã¢ã®åŠãé
å æ§ç©è³ªã®ååšäžã«éå æµåããéã«äžæ®µãšãã
ããå¹æãçºæ®ããNOxæµåçšè§Šåªã®è£œæ³ãæ
äŸããããšã«ããã æ¬çºæã¯ããããžãŠã ã®åå䟡ãïŒäŸ¡ã®ãããž
ãŠã ååç©ãéå æ§ç©è³ªããã³æº¶åªã®ååšäžã«é
å ããŠãããžãŠã ã®åå䟡ãïŒäŸ¡ããå°ããåå
䟡ã«éå ãããããžãŠã ååç©ã®æº¶æ¶²ãç¡«é žãŸã
ã¯ç¡«é žã®ã¢ã³ã¢ããŠã å¡©ãç¡«é žããªãŠã ããã¿ã³
é žãããã³ç²åé±ç©ãæ··åããŠç²åç¶ç©ã«ãã該
ç²åç¶ç©ãæŒåºæ圢æ©ã§ããã«ã ç¶ã«æ圢ãã
åŸãçŒæããŠè§Šåªã«ããããšãç¹åŸŽãšããNOx
æµåçšè§Šåªã®è£œæ³ã«é¢ããã æ¬çºæã«ãããŠãããžãŠã ã®åå䟡ãïŒäŸ¡ã®ã
ããžãŠã ååç©ãšããŠã¯ãã¡ã¿ãããžã³é žã¢ã³ã¢
ããŠã ãã¡ã¿ãããžã³é žãäºé žåãããžãŠã ãªã©
ãæããããšãã§ãããªãã§ãã¡ã¿ãããžã³é žã¢
ã³ã¢ããŠã ã奜é©ã§ããããŸãéå æ§ç©è³ªãšããŠ
ã¯ïŒäŸ¡ã®ãããžãŠã ååç©ãïŒäŸ¡ããå°ããåå
䟡äžè¬ã«ã¯ïŒäŸ¡ã«éå ããããšãã§ãããã®ã§ã
ãã°ãããäŸãã°ã·ãŠãŠé žãã¯ãšã³é žãé ç³é žãª
ã©ã®ææ©ã«ã«ãã³é žãæããããšãã§ãããªãã§
ãã·ãŠãŠé žã奜é©ã§ããã ãããžãŠã ã®åå䟡ãïŒäŸ¡ã®ãããžãŠã ååç©
ãéå æ§ç©è³ªããã³æº¶åªã®ååšäžã«éå ããŠãã
ãžãŠã ã®åå䟡ãïŒäŸ¡ããå°ããåå䟡ã«éå ã
ããããžãŠã ååç©ã®æº¶æ¶²ã調補ããã«ããã€ãŠ
ã¯ãäŸãã°æ°Žã®åŠã溶åªã«ã¡ã¿ãããžã³é žã¢ã³ã¢
ããŠã ã®åŠãïŒäŸ¡ã®ãããžãŠã ååç©ã溶解ã
ããããã«ã·ãŠãŠé žã®åŠãéå æ§ç©è³ªãå ããŠïŒ
䟡ã®ãããžãŠã ååç©ãéå ããæ¹æ³ã§è¡ã€ãŠ
ãããŸãéå æ§ç©è³ªã溶åªã«æº¶è§£ããã溶液ã«ïŒ
䟡ã®ãããžãŠã ååç©ãå ããŠéå ããæ¹æ³ã§è¡
ã€ãŠãããã溶åªãšããŠã¯ãïŒäŸ¡ã®ãããžãŠã å
åç©ããã³éå æ§ç©è³ªã溶解ãããã®ã§ããã°ã
ãããäžè¬ã«ã¯æ°Žã奜é©ã«äœ¿çšãããã ãŸãæ¬çºæã§äœ¿çšããç¡«é žãŸãã¯ç¡«é žã®ã¢ã³ã¢
ããŠã å¡©ãšããŠã¯ãæ¿ç¡«é žãç¡«é žã¢ã³ã¢ããŠã ã
é žæ§ç¡«é žã¢ã³ã¢ããŠã ãäºç¡«é žã¢ã³ã¢ããŠã ãé
ç¡«é žã¢ã³ã¢ããŠã ãªã©ãæããããšãã§ãããªã
ã§ãç¡«é žã¢ã³ã¢ããŠã ãå®äŸ¡ã§ãããç®çãšãã
觊åªã®åçŸæ§ãããã®ã§å¥œé©ã§ãããç¡«é žãŸãã¯
ç¡«é žã®ã¢ã³ã¢ããŠã å¡©ã¯æ°Žã«äžæº¶æ§ã®ç¡«é žãããž
ã«ã圢æãããããã§å¿ èŠãªãã®ã§ãããããã®
䜿çšéã¯ã䜿çšããïŒäŸ¡ã®ãããžãŠã ååç©ã®ã
ããžãŠã ïŒã°ã©ã ååã«å¯ŸããŠãç¡«é»ãïŒãïŒã°
ã©ã ååã«ãªããããªéã奜é©ã§ãããïŒã°ã©ã
ååããå€ããªãéã§äœ¿çšããŠãå€ã䜿çšããã
ãšã«ããå©ç¹ã¯ç¹ã«ãªãã ç¡«é žããªãŠã ãšããŠã¯ãäžè¬ã«æ¯è¡šé¢ç©10m2ïŒ
ïœä»¥äžã§ãå¹³åç²åŸ0.1ã1.0ÎŒã®æ²éæ§ç¡«é žããª
ãŠã ã奜é©ã«äœ¿çšãããã æ¬çºæã¯ãæ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ããã³ç¡«
é žããªãŠã ãšãšãã«ããã¿ã³é žããã³ç²åé±ç©ã
çµåãããšãæ圢æ§ãæ¹åãããå·¥æ¥çšè§Šåªãšã
ãŠèŠæ±ãããç¹æ§ãæºããããã«ã ç¶è§ŠåªãåŸã
ãããšããçºèŠã«åºããŠããã ãã¿ã³é žãšããŠã¯ããªã«ããã¿ã³é žïŒÎ±âãã¿
ã³é žïŒãã¡ã¿ãã¿ã³é žïŒÎ²âãã¿ã³é žïŒãγâãã¿
ã³é žãªã©ãæããããšãã§ãããããã¯å€ãã®å Ž
åããããã®æ··åç©ãšããŠå ¥æãããããäžè¬ã«
ã¡ã¿ãã¿ã³é žãšåŒã°ããŠããã¡ã¿ãã¿ã³é žãäž»æ
åãšãããã®ã奜é©ã§ããããã¿ã³é žã¯äžè¬ã«æ°Ž
ã¹ã©ãªãšããŠäœ¿çšãããã ãã¿ã³é žã¯ãç¡«é žããªãŠã ãšã¯éã«äžè¬ã«æ¯è¡š
é¢ç©ã100ã300m2ïŒïœãšå€§ãããäžæ¬¡ç²åã®å¹³å
ç²åŸã30ã50â«ãšå°ããã®ã§ã觊åªã®ç©ççæ§
質ãç¹ã«æ¯è¡šé¢ç©çã®æ¹åã«å€§ããå¯äžããŠã
ãã æ¬çºæã¯ãç¡«é žããªãŠã ã䜿çšããéã«è§Šåªã®
æ¯è¡šé¢ç©ãå°ãããªã€ãŠNOxé€å»æŽ»æ§ãäœäžã
ãããSO2é žå掻æ§ãé«ããªã€ããããã®ããã
ã¿ã³é žã®äœ¿çšã«ãã€ãŠãæ¯è¡šé¢ç©ã倧ããããã
ãã«ã¯é©åºŠã«å€§ããªçŽ°åãæãã觊åªã«ããããš
ãã§ãã觊åªæ§èœãäžæ®µãšé«ããããšãå¯èœã§ã
ãã ç²åé±ç©ãšããŠã¯ãã¢ã³ã¢ãªããã€ãç³»é±ç©ã
ã«ãªãªãã€ãç³»é±ç©ãããŒãããŠã©ã€ãç³»é±ç©ãª
ã©ãæããããšãã§ãããç²åé±ç©ã¯å°éã®æ°Žã
ãããšå¯å¡æ§ãçŸãããç²åé±ç©ã®äœ¿çšã«ãã€ãŠ
ããã«ã ç¶ã«æ圢ããéã®æ圢æ§ãé¡èã«æ¹åã
ããããªãããšãç²åé±ç©ã䜿çšããŠç²åç¶ç©ã«
ããŠãç²åç¶ç©ã«ããéãã¿ã³é žã䜿çšããªãã€
ãããç¡«é žããªãŠã ã䜿çšããªãã€ãããããšã
æ圢æ§ã¯æªãã ãŸãç²åé±ç©ã®ãªãã§ãã¢ã³ã¢ãªããã€ãç³»é±
ç©ã¯ãæ°Žååžçèœã倧ããæ圢æ§åäžå¹æãé«
ããããã«è§Šåªã®èæ©èæ§ãåäžãããå¹æãã
ããã¢ã³ã¢ãªããã€ãç³»é±ç©ãšããŠã¯ãé žæ§çœ
åã掻æ§çœåããã³ããã€ããªã©ãæããããšã
ã§ããç¹ã«é žæ§çœåã¯ãæ圢æ§ããã³èæ©èæ§ã«
ãããŠæè¯ã®çµæãåŸãããã®ã§å¥œé©ã§ããã ãŸãæ¬çºæã«ãããŠç²åé±ç©ãšããŠã¯ãã«ãªãŠ
ã ããããªãŠã ãªã©ã®ã¢ã«ã«ãªéå±å«æéã®å°ãª
ããã®ã奜ãŸããã¯ã¢ã«ã«ãªéå±å«æé
ïŒNa2OïŒK2Oæç®ïŒãïŒïŒ 以äžã®ãã®ã奜é©ã«
䜿çšããããã¢ã«ã«ãªéå±å«æéãå€ããšãã¢ã«
ã«ãªéå±ã®äºç¡«é žå¡©ãç¡«é žå¡©ãªã©ãçæããŠ
NOxé€å»æŽ»æ§ã®äœäžãèæ©èæ§ã®äœäžãªã©ã®æª
圱é¿ãããã ãŸãç²åé±ç©ã¯ããã®ç²åŸãïŒã60ÎŒã®ç¯å²ã«
ååžããŠãããã®ã奜é©ã«äœ¿çšãããããã®ç¯å²
å€ã®ãã®ãå«ãŸããŠããŠãå·®æ¯ããªãã æ¬çºæã«ãããŠããããžãŠã ã®åå䟡ãïŒäŸ¡ã
ãå°ããåå䟡ã«éå ãããããžãŠã ååç©ã®æº¶
液ãç¡«é žããªãŠã ããã¿ã³é žãããã³ç²åé±ç©ã®
æ··åå²åã¯ãæçµçã«åŸããã觊åªã®æ¯è¡šé¢ç©ã
15ã85m2ïŒïœã奜ãŸããã¯20ã80m2ïŒïœã«ãªãã
ããªå²åã§æ··åããããããæ®éæ··åå²åã¯ãã
ããžãŠã ååç©ã®æº¶æ¶²ãæ°Žã«äžæº¶æ§ã®ç¡«é žãããž
ã«ïŒÎ²âVOSO4ïŒæç®ã§0.5ã35ééïŒ ã奜ãŸã
ãã¯ïŒã10ééïŒ ãç¡«é žããªãŠã ã25ã95éé
ïŒ ã奜ãŸããã¯35ã70ééïŒ ããã¿ã³é žãäºé žå
ãã¿ã³ïŒTiO2ïŒæç®ã§ïŒã65ééïŒ ä»¥äžã奜ãŸ
ããã¯20ã50ééïŒ ãç²åé±ç©ã35ééïŒ ä»¥äžã
奜ãŸããã¯ïŒã25ééïŒ ã®ç¯å²ããéžæãããã
觊åªã®æ¯è¡šé¢ç©ã倧ãããªããšSO2é žå掻æ§ãå°
ãããªãåŸåãããããããŸã倧ãããããšèæ©
èæ§ãæªããªãããŸãæ¯è¡šé¢ç©ãå°ãããªããš
NOxé€å»æŽ»æ§ãæªããªãã æ¬çºæã«ãããŠç²åç¶ç©ã®èª¿è£œã«ããããå¿ èŠ
ã«å¿ããŠé«çŽãã©ãã€ã³ãå€ç³é¡ãå€äŸ¡ã¢ã«ã³ãŒ
ã«ããªã°ãã³ã¹ã«ãã³é žå¡©ã®åŠãæ圢å©å€ãã¬ã©
ã¹ç¹ç¶ãççŽ ç¹ç¶ã®åŠãç¡æ©è³ªç¹ç¶ãæ·»å ããã
ãšãã§ããã æ¬çºæã«ãããŠããããžãŠã ã®åå䟡ãïŒäŸ¡ã
ãå°ããåå䟡ã«éå ãããããžãŠã ååç©ã®æº¶
液ãç¡«é žãŸãã¯ç¡«é žã®ã¢ã³ã¢ããŠã å¡©ãç¡«é žããª
ãŠã ããã¿ã³é žãããã³ç²åé±ç©ã®æ··åæ¹æ³ãšã
ãŠã¯ãäžè¬ã«ãããžãŠã ååç©ã®æº¶æ¶²ã«ç¡«é žãŸã
ã¯ç¡«é žã®ã¢ã³ã¢ããŠã å¡©ããã¿ã³é žããã³ç¡«é žã
ãªãŠã ãæ··åããåŸã也ç¥ããŠç²ç¶æ··åç©ãšãã
ããã«ç²åé±ç©ãæ··åããæ··åç©ã«æ°Žãå ããŠç²
åç¶ç©ã«ããæ¹æ³ãæ¡çšãããããæ··åé åºãæ
äœã¯ãã以å€ã®æ¹æ³ã§æ··åããŠãããã æ°Žã®éã¯ãæŒåºæ圢æ©ã§ããã«ã ç¶ã«æ圢ã§ã
ãçšåºŠã®éãäžè¬ã«ã¯æ··åç©ã«å¯ŸããŠïŒã35éé
ïŒ ã奜ãŸããã¯ïŒã30ééïŒ ã«ãªãããã«ããã®
ãé©åœã§ãããåŸãããç²åç¶ç©ã¯ãã®ç¡¬åºŠãïŒ
ã20KgïŒcm2ã奜ãŸããã¯ïŒã15KgïŒcm2ã®ç¯å²ã«ãª
ãããã«ããã®ãæãŸãããæ°Žã®éãå€ããã
ããå°ãªãããããããšåŸãããç²åç¶ç©ã硬ã
ããããæãããããããŠæ圢æ§ãæªããªãããŸ
ãç²åç¶ç©ã®èª¿è£œã¯ãäŸãã°ããŒããŒã®ãããªåŸ
æ¥å ¬ç¥ã®æ··ç·Žæ©ãçšããŠè¡ãã®ãé©åœã§ãããã
ãã§ãç²åç¶ç©ã®ç¡¬åºŠã¯å±±äžåŒåå£ç¡¬åºŠèšã«ãã
枬å®ã æ¬çºæã«ãããŠç²åç¶ç©ãããã«ã ç¶ã«æ圢ã
ãã«ããã€ãŠã¯ãããèªäœå ¬ç¥ã®æŒåºæ圢æ©ãäŸ
ãã°ãã¹ãã³ã¿ã€ãããªãŒã¬ãŒã¿ã€ããªã©ãé©å®
䜿çšãããæŒåºæ圢æ©åºå£ã«ãšãã€ããéåãã
ããããšã«ãã€ãŠãå€è§çç¶ãåçç¶ãã åçç¶
ãªã©ã®ããã«ã ç¶ã«æ圢ããããšãã§ããããã
ã«ã ç¶ã«æ圢ãããæ圢ç©ã¯ãããã䜿çšæ¡ä»¶ã«
å¿ããŠé©åœãªé·ããäŸãã°10ã100cmã«åæãã
å¿ èŠã«å¿ããŠä¹Ÿç¥ããåŸãçŒæããã ããã«ã ç¶æ圢ç©ã®çŒæã¯ã200ã450âã奜ãŸ
ããã¯350ã450âã®æž©åºŠã§è¡ãã®ãé©åœã§ããã
çŒææéã¯äžè¬ã«ã¯ïŒã24æéã奜ãŸããã¯ïŒã
16æéçšåºŠãé©åœã§ããããŸãçŒæé°å²æ°ã¯ç¹ã«
å¶éããããäŸãã°äºç¡«é žã¬ã¹ãã¢ã³ã¢ãã¢ãæ°Ž
èžæ°ãçªçŽ ãé žçŽ ãªã©ããããå«ãé°å²æ°ã§ãã
ããã空æ°ã®åŠãé žçŽ å«æã¬ã¹é°å²æ°ãçµæžçã§
ãããããŸã奜é©ã§ãããã çŒæããããšã«ãã€ãŠåæãšããŠäœ¿çšãããã
ãžãŠã ååç©ã¯ãæ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ïŒÎ²
âVOSO4ïŒã«ãªãã®ã§ã觊åªäžã®ãããžãŠã å
åç©ãšããŠã¯æ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ä»¥å€ã«ä»
ã®ãããžãŠã ååç©ã¯ã»ãšãã©å«ãŸããŠããªã
ããå°éïŒå šãããžãŠã ååç©ã®ïŒééïŒ ä»¥äžçš
床ïŒã§ããã°ä»ã®ãããžãŠã ååç©ãå«ãŸããŠã
ãŠãå·®æ¯ããªãããªãæ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«
ããèªäœã¯ãèµ€å€ç·åžåã¹ãã¯ãã«ã«ãããšãæ°Ž
溶æ§ç¡«é žãããžã«ïŒÎ±âVOSO4ïŒã«ã¯èŠãããª
ã940-1cmããã³510-1cmã«ç¹åŸŽçãªåžåããŒã¯ã
æããŠãããASTM19â1400ã«ãããžãŠã ïŒIVïŒ
ãªããµã€ããµã«ããšã€ããVanadiumïŒIVïŒ
OxideSalfateããšããŠèšèŒãããŠããã觊åªäž
ã®ç¡«é žãããžã«æ¿åºŠãïŒééïŒ ä»¥äžã®å Žåã«ã¯ã
940cm-1ããã³510cm-1ã®èµ€å€ç·åžåã¹ãã¯ãã«ã¯
é¡èã§ã¯ãªãããESCAãçšããŠåæãããšãã
ããžãŠã ã®åå䟡ã¯ïŒäŸ¡ã§ããããŸã觊åªãæ°Žã«
ã€ããŠããããžãŠã ã®æº¶åºããªãããšãããæ°Žã«
äžæº¶æ§ã®ç¡«é žãããžã«ãšèªããããã ãŸãåæãšããŠäœ¿çšãããã¿ã³é žã¯ã觊åªäžã§
ã©ã®ãããªãã¿ã³ååç©ã«ãªã€ãŠãããç·åæ
ã¹ãã¯ãã«ãªã©ã§ã¯ååæããã§ã¯ãªããããã¿
ã³é žãšäºé žåãã¿ã³ãå«ãè€éãªãã¿ã³ååç©ã«
ãªã€ãŠããã®ã§ã¯ãªãããšæšå®ãããã ãå®æœäŸã åäŸã«ãããŠãNOxé€å»æŽ»æ§ã®è©Šéšã¯ããã
ã«ã ç¶ã®è§Šåªãã¹ãã³ã¬ã¹è£œåå¿ç®¡ã«å å¡«ããå
å¿ç®¡ã«ãNO300ppmãNH3300ppmã
SO2800ppmãH2O10ïŒ ãO23ïŒ ããã³æ®ãN2ã
ããªãã¢ãã«ã¬ã¹ïŒNH3ïŒNOïŒïŒïŒã¢ã«æ¯ïŒ
ãã空éé床5000hr-1ã®æµéã§æµãã350âã380
âããã³400âã«ä¿æãã24æéåŸãåå¿ç®¡å ¥å£
ããã³åºå£ã«ãããã¬ã¹äžã®NOxå«æéãååŠ
çºå åŒNOxåæèšã§æž¬å®ãã次åŒã«åŸã€ãŠNOx
é€å»çïŒïŒ ïŒãæ±ããæ¹æ³ã§è¡ã€ãã NOxé€å»çïŒïŒ ïŒïŒX1âX2ïŒX1Ã100 X1ïŒåå¿ç®¡å ¥å£ã«ãããã¬ã¹äžã®NOxæ¿åºŠ X2ïŒåå¿ç®¡åºå£ã«ãããã¬ã¹äžã®NOxæ¿åºŠ ãŸãSO2ã®é žå掻æ§ã®è©Šéšã¯ãåèšã¢ãã«ã¬ã¹
ãåèšãšåæ§ã«ããŠç©ºéé床5000hr-1ã®æµéã§æµ
ãã350âããã³380âã«ä¿æãã72æéåŸãåå¿
ç®¡å ¥å£ããã³åºå£ã«ãããã¬ã¹äžã®SO2ããã³
SO3æ¿åºŠãåæã枬å®ãã次åŒã«ããSO2é žåç
ïŒïŒ ïŒãæ±ããæ¹æ³ã§è¡ã€ãã SO2é žåçïŒïŒºïŒïŒ¹Ã100 ïŒåå¿ç®¡å ¥å£ã«ãããã¬ã¹äžã®SO2æ¿åºŠ ïŒåå¿ç®¡åºå£ã«ãããã¬ã¹äžã®SO3æ¿åºŠ ãŸãèæ©èæ§ã®è©Šéšã¯ãç³ççããã€ã©ãŒã®æ
ã¬ã¹ïŒãã¹ãå«æé12gïŒïŒ®m3ïŒNOxå«æé
320ppmãSOxå«æé280ppmã枩床350âïŒãã
ãã¯ãŒã§æå§ããã¬ã¹ç·é床15.5mïŒsecã®æã¬
ã¹ãé·ãïŒé«ãïŒ100mmã®ããã«ã ç¶ã®è§Šåªã®äž
æ¹ããäžæ¹ã«16æ¥éå¹ãã€ããåŸã觊åªããšãã
ããŠè§Šåªã秀éããééæžå°éããæ©èçïŒéé
ïŒ ïŒãæ±ããæ¹æ³ã§è¡ã€ãã å®æœäŸ ïŒ ã¡ã¿ãããžã³é žã¢ã³ã¢ããŠã 0.43Kgã15ã®æ°Ž
ã«å ããŠçŽ70âã«å æž©ããæ¹æäžã«ã·ãŠãŠé ž0.7
KgãåŸã ã«å ããŠãããžãŠã ãéå ãããã®ãã
ãžãŠã ååç©ã®æº¶æ¶²ã«ãç¡«é žã¢ã³ã¢ããŠã 0.73Kg
ãå ãã次ãã§æ²éæ§ç¡«é žããªãŠã ç²æ«13.7Kgã
ãã³ã¡ã¿ãã¿ã³é žã®æ°Žã¹ã©ãªãäºé žåãã¿ã³æç®
ã§11.2Kgãå ããŠããŒã¹ãç¶ã«ããåŸããã©ã 也
ç¥æ©ã§150âã§ä¹Ÿç¥ããŠç²ç¶æ··åç©ãåŸãã 次ãã§ãç²ç¶æ··åç©ã«ãç²ç¶ã®é žæ§çœåïŒã¢ã«
ã«ãªéå±å«æéïŒNa2Oããã³K2OãšããŠ0.9éé
ïŒ ïŒ4.5Kgãã°ãªã»ãªã³1.2Kgãå€ç³é¡0.06Kgãã
ã³æ°Ž8.4Kgãå ããæ··ç·ŽããŠç²åç¶ç©ã«ããåŸã
ãã¹ãã³ã¿ã€ãã®æŒåºæ圢æ©ãçšããŠãäžèŸºã70
mmã®æ£æ¹åœ¢ã§ãã®äžã瞊ïŒç®ã暪ïŒç®ãèå1.5
mmã®æ Œåç¶ã«ä»åãããŠããããã«ã ç¶ã®æ圢ç©
ïŒé·ã700mmïŒã«æ圢ãã100âã§ä¹Ÿç¥ãã空æ°é°
å²æ°äžã«400âã§ïŒæéçŒæããŠããã«ã ç¶è§Šåª
ãåŸããåŸããã觊åªã®çµæã¯ãç¡«é žããªãŠã
45.7ééïŒ ãæ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ïŒéé
ïŒ ããã¿ã³ååç©ïŒTiO2æç®ïŒ37.8ééïŒ ãã
ã³é žæ§çœå15ééïŒ ãããªãããªããæ圢åã®ç²
åç¶ç©ã®ç¡¬åçŸè±¡ã¯èªããããªãã€ãããŸãæ圢
æ§ãéåžžã«ããã觊åªã¯ããå²ãããã³ã€ã®ãªã
ãã®ã§ãã€ãã觊åªã®æ¯è¡šé¢ç©ã¯64m2ïŒïœã§ãã€
ããNOxé€å»çãSO2é žåçããã³æ©èçã®è©Š
éšçµæã¯ã第ïŒè¡šã«ç€ºãã å®æœäŸ ïŒ å®æœäŸïŒã®é žæ§çœåã«ãããŠãã³ããã€ãç²æ«
ã䜿çšããã»ãã¯ãå®æœäŸïŒãšåæ§ã«ããŠããã«
ã ç¶è§Šåªã補é ãããå®æœäŸïŒãšåæ§ã«ç²åç¶ç©
ã®ç¡¬åçŸè±¡ã¯èªããããããŸãæ圢æ§ãããã觊
åªã®ããå²ãããã³ã€ã¯èªããããªãã€ãã觊åª
ã®æ¯è¡šé¢ç©ã¯62m2ïŒïœã§ãã€ãã觊åªæ§èœã®è©Šéš
çµæã¯ã第ïŒè¡šã«ç€ºãã å®æœäŸ ïŒ å®æœäŸïŒã®é žæ§çœåã®ãããã«ã«ãªãªãã€ãç³»
ç²åé±ç©ã®ã«ãªãªã³ç²æ«ã䜿çšããã»ãã¯ãå®æœ
äŸïŒãšåæ§ã«ããŠããã«ã ç¶è§Šåªã補é ãããæ
圢åã®ç²åç¶ç©ã®ç¡¬åçŸè±¡ã¯èªããããã觊åªã®
ããå²ãããã³ã€ã¯èªããããªãã€ãã觊åªã®æ¯
è¡šé¢ç©ã¯62m2ïŒïœã§ãã€ãã觊åªæ§èœã®è©Šéšçµæ
ã¯ã第ïŒè¡šã«ç€ºãã æ¯èŒäŸ ïŒ å®æœäŸïŒã®ã¡ã¿ãã¿ã³é žã䜿çšãããå®æœäŸïŒ
ãšåæ§ã®æäœã§ãæ²éæ§ç¡«é žããªãŠã ã73.4éé
ïŒ ãæ°Žã«äžæº¶æ§ã®ç¡«é žãããžã«ã11.6ééïŒ ãã
ã³é žæ§çœå15ééïŒ ãããªãçµæã®ããã«ã ç¶è§Š
åªã補é ãã觊åªæ§èœè©Šéšãè¡ã€ããæ圢åã®ç²
åç¶ç©ã¯è¥å¹²ç¡¬åçŸè±¡ãèªããããããŸãæ圢æ§
ããããªãã€ãã觊åªã®æ¯è¡šé¢ç©ã¯7.9m2ïŒïœã§
ãã€ãã觊åªæ§èœã®è©Šéšçµæã¯ã第ïŒè¡šã«ç€ºãã æ¯èŒäŸ ïŒ ã¡ã¿ãããžã³é žã¢ã³ã¢ããŠã 0.43Kgãã·ãŠãŠé ž
0.7Kgãç¡«é žã¢ã³ã¢ããŠã 0.73Kgãæ²éæ§ç¡«é žã
ãªãŠã 13.7Kgããã³äºé žåãã¿ã³ïŒã¢ãã¿ãŒãŒ
åïŒç²æ«11.2Kgã70âã«å æž©ããæ°Ž30ã«å ãã
æ¹æããåŸã150âã§åŽé§ä¹Ÿç¥ããåŸãå®æœäŸïŒ
ãšåæ§ã«ããŠé žæ§çœåãã°ãªã»ãªã³ãå€ç³é¡ãã
ã³æ°Žãå ããŠããã«ã ç¶è§Šåªã補é ããã觊åªã¯
ç¡«é žããªãŠã 45.7ééïŒ ãæ°Žã«äžæº¶æ§ã®ç¡«é žãã
ãžã«ïŒééïŒ ãäºé žåãã¿ã³37.3ééïŒ ããã³é ž
æ§çœå15ééïŒ ã®çµæãããªãã觊åªã®æ¯è¡šé¢ç©
ã¯8.4m2ïŒïœã§ãã€ãã觊åªæ§èœã®è©Šéšçµæã¯ã
第ïŒè¡šã«ç€ºãã æ¯èŒäŸ ïŒ å®æœäŸïŒã®ç¡«é žããªãŠã ã䜿çšãããã¡ã¿ãã¿
ã³é žã®äœ¿çšéãå¢ãããå®æœäŸïŒãšåæ§ã®æäœ
ã§ããã¿ã³ååç©ïŒTiO2æç®ïŒ83ééïŒ ãæ°Žã«
äžæº¶æ§ã®ç¡«é žãããžã«ïŒééïŒ ãé žæ§çœå15éé
ïŒ ãããªãçµæã®ããã«ã ç¶è§Šåªã補é ãããæ
圢åã®ç²åç¶ç©ã®ç¡¬åçŸè±¡ã¯èªããããªãã€ã
ããæ圢æ§ãæªãããŸãèæ©èæ§è©Šéšãè¡ã€ããš
ãããæ©èç28.5ïŒ ã§ãã€ãã®ã§ãNOxé€å»çã
SO2é žåçãªã©ã®è©Šéšã¯è¡ããªãã€ãã 觊åªã®æ¯è¡šé¢ç©ã¯92m2ïŒïœã§ãã€ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã®é žæ§çœåã䜿çšããªãã€ãã»ãã¯ã
å®æœäŸïŒãšåæ§ã®æäœã§ããã«ã ç¶è§Šåªã®è£œé ã
è©Šã¿ãããæ圢æ§ãæªããåäžã«æŒåºãããšãã§
ããã觊åªåŽé¢ã«ããå²ããçãããŸã圢ç¶ãã
ã³ã€ã§ãã€ãã®ã§ã觊åªæ§èœè©Šéšã¯è¡ããªãã€
ãã
ãè¡šã
ãè¡šã
åèäŸ
å®æœäŸïŒãïŒããã³æ¯èŒäŸïŒãïŒã®è§Šåªã䜿çš
ããã¢ãã«ã¬ã¹ãšããŠNH3ã®éã300ppmãã
240ppmã«ãããã¢ãã«ã¬ã¹äžã®NH3ïŒNOïŒ0.8
ïŒã¢ã«æ¯ïŒã«ããŠã380âã«ãããNOxé€å»æŽ»æ§
ã®è©Šéšãè¡ã€ãã
ããã¢ãã«ã¬ã¹ãšããŠNH3ã®éã300ppmãã
240ppmã«ãããã¢ãã«ã¬ã¹äžã®NH3ïŒNOïŒ0.8
ïŒã¢ã«æ¯ïŒã«ããŠã380âã«ãããNOxé€å»æŽ»æ§
ã®è©Šéšãè¡ã€ãã
æ¬çºæã«ãããšã次ã®ãããªå¹æãããã
ããã«ã ç¶ã®è§Šåªã«æ圢ããéã®æ圢æ§ãã
ãã容æã«å·¥æ¥çšè§ŠåªãšããŠèŠæ±ãããè«žç¹æ§ã
æºãããããã«ã ç¶è§ŠåªãåŸãããã ããã«ã ç¶ã«æ圢ããåã®ç²åç¶ç©ã調補ãã
éãç¹ã«ç²ç¶æ··åç©ã®ç²åŸå¶åŸ¡ãããªããŠãç²å
ç¶ç©ã®ç¡¬åçŸè±¡ãçããªãã®ã§ã觊åªè£œé ã«ãã
ãçç£æ§ã®åäžãã¯ããããšãã§ããã ãŸãåèšå®æœäŸãæ¯èŒäŸããã³åèäŸãããæ
ããã§ããããã«ãæ¬çºæã«ãã€ãŠåŸããããã
ã«ã ç¶è§Šåªã¯ãç¹ã«èæ©èæ§ã«ããããé«æž©æ¡ä»¶
äžã«ãããŠãNOxé€å»çãé«ããSO2é žåçã
äœããšããé¡èãªå¹æãããããŸãè±ç¡è£ 眮ãã
æåºãããæã¬ã¹äžã®æ®çNH3ãå°ãªããšãã
ç¹é·ãæããŠããã ããã«å¯ŸããŠãç²åé±ç©ã䜿çšããªãã§ããã«
ã ç¶ã«æ圢ããå Žåã¯æ圢æ§ãæªãïŒæ¯èŒäŸïŒïŒ
ãŸãç²åé±ç©ã䜿çšããŠãç¡«é žããªãŠã ã䜿çšã
ãªããšæ圢æ§ããã³èæ©èæ§ãæªããæ¯è¡šé¢ç©ã
倧ããïŒæ¯èŒäŸïŒïŒããŸãç²åé±ç©ã䜿çšããŠã
ãã¿ã³é žã䜿çšããªãå Žåã¯æ¯è¡šé¢ç©ãå°ããã
NOxé€å»çãSO2é žåçãèæ©èæ§ãæ®çNH3
ãªã©ã®é¢ã§äžååã§ããããŸãæ圢æ§ã«è¥å¹²ã®é£
ç¹ãçããïŒæ¯èŒäŸïŒïŒãããŸãç²åé±ç©ã䜿çšã
ãŠããã¿ã³é žã«ãããŠäºé žåãã¿ã³ã䜿çšããå Ž
åã¯NOxé€å»çããã³èæ©èæ§ãæªããæ®ç
NH3ãå€ãïŒæ¯èŒäŸïŒïŒã
ãã容æã«å·¥æ¥çšè§ŠåªãšããŠèŠæ±ãããè«žç¹æ§ã
æºãããããã«ã ç¶è§ŠåªãåŸãããã ããã«ã ç¶ã«æ圢ããåã®ç²åç¶ç©ã調補ãã
éãç¹ã«ç²ç¶æ··åç©ã®ç²åŸå¶åŸ¡ãããªããŠãç²å
ç¶ç©ã®ç¡¬åçŸè±¡ãçããªãã®ã§ã觊åªè£œé ã«ãã
ãçç£æ§ã®åäžãã¯ããããšãã§ããã ãŸãåèšå®æœäŸãæ¯èŒäŸããã³åèäŸãããæ
ããã§ããããã«ãæ¬çºæã«ãã€ãŠåŸããããã
ã«ã ç¶è§Šåªã¯ãç¹ã«èæ©èæ§ã«ããããé«æž©æ¡ä»¶
äžã«ãããŠãNOxé€å»çãé«ããSO2é žåçã
äœããšããé¡èãªå¹æãããããŸãè±ç¡è£ 眮ãã
æåºãããæã¬ã¹äžã®æ®çNH3ãå°ãªããšãã
ç¹é·ãæããŠããã ããã«å¯ŸããŠãç²åé±ç©ã䜿çšããªãã§ããã«
ã ç¶ã«æ圢ããå Žåã¯æ圢æ§ãæªãïŒæ¯èŒäŸïŒïŒ
ãŸãç²åé±ç©ã䜿çšããŠãç¡«é žããªãŠã ã䜿çšã
ãªããšæ圢æ§ããã³èæ©èæ§ãæªããæ¯è¡šé¢ç©ã
倧ããïŒæ¯èŒäŸïŒïŒããŸãç²åé±ç©ã䜿çšããŠã
ãã¿ã³é žã䜿çšããªãå Žåã¯æ¯è¡šé¢ç©ãå°ããã
NOxé€å»çãSO2é žåçãèæ©èæ§ãæ®çNH3
ãªã©ã®é¢ã§äžååã§ããããŸãæ圢æ§ã«è¥å¹²ã®é£
ç¹ãçããïŒæ¯èŒäŸïŒïŒãããŸãç²åé±ç©ã䜿çšã
ãŠããã¿ã³é žã«ãããŠäºé žåãã¿ã³ã䜿çšããå Ž
åã¯NOxé€å»çããã³èæ©èæ§ãæªããæ®ç
NH3ãå€ãïŒæ¯èŒäŸïŒïŒã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ãããžãŠã ã®åå䟡ãïŒäŸ¡ã®ãããžãŠã åå
ç©ãéå æ§ç©è³ªããã³æº¶åªã®ååšäžã«éå ããŠã
ããžãŠã ã®åå䟡ãïŒäŸ¡ããå°ããåå䟡ã«éå
ãããããžãŠã ååç©ã®æº¶æ¶²ãç¡«é žãŸãã¯ç¡«é žã®
ã¢ã³ã¢ããŠã å¡©ãç¡«é žããªãŠã ããã¿ã³é žããã
ã³ç²åé±ç©ãæ··åããŠç²åç¶ç©ã«ãã該ç²åç¶ç©
ãæŒåºæ圢æ©ã§ããã«ã ç¶ã«æ圢ããåŸãçŒæã
ãŠè§Šåªã«ããããšãç¹åŸŽãšããçªçŽ é žåç©æµåçš
觊åªã®è£œæ³ã ïŒ ç²åé±ç©ããã¢ã³ã¢ãªããã€ãç³»é±ç©ã§ãã
ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çªçŽ é žåç©æµåçšè§Š
åªã®è£œæ³ã ïŒ ã¢ã³ã¢ãªããã€ãç³»é±ç©ããé žæ§çœåã§ãã
ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®çªçŽ é žåç©æµåçšè§Š
åªã®è£œæ³ã ïŒ ïŒäŸ¡ã®ãããžãŠã ååç©ãã¡ã¿ãããžã³é žã¢
ã³ã¢ããŠã ã§ãéå æ§ç©è³ªãã·ãŠãŠé žã§ã溶åªã
æ°Žã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒé èšèŒã®
çªçŽ é žåç©æµåçšè§Šåªã®è£œæ³ã ïŒ è§Šåªããæ¯è¡šé¢ç©15ã85m2ïŒïœã§ããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé åã¯ç¬¬ïŒé èšèŒã®çªçŽ é ž
åç©æµåçšè§Šåªã®è£œæ³ã
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59186570A JPS6164334A (ja) | 1984-09-07 | 1984-09-07 | çªçŽ é žåç©æµåçšè§Šåªã®è£œæ³ |
DE19853531871 DE3531871A1 (de) | 1984-09-07 | 1985-09-06 | Verfahren zur herstellung eines katalysators fuer die reduktive entfernung eines stickoxids |
CN 85107366 CN1009803B (zh) | 1984-09-07 | 1985-09-29 | å¶å€çšäºè¿åæ³è±é€æ°®æ°§åç©çèçªå¬ååçå·¥èº |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59186570A JPS6164334A (ja) | 1984-09-07 | 1984-09-07 | çªçŽ é žåç©æµåçšè§Šåªã®è£œæ³ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6164334A JPS6164334A (ja) | 1986-04-02 |
JPH0242536B2 true JPH0242536B2 (ja) | 1990-09-25 |
Family
ID=16190840
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59186570A Granted JPS6164334A (ja) | 1984-09-07 | 1984-09-07 | çªçŽ é žåç©æµåçšè§Šåªã®è£œæ³ |
Country Status (2)
Country | Link |
---|---|
JP (1) | JPS6164334A (ja) |
DE (1) | DE3531871A1 (ja) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3541705A1 (de) * | 1985-11-26 | 1987-05-27 | Eugen Dipl Chem Dr Phil Dumont | Katalysatormassen aus metallkeramik fuer die reduktion von oxiden des schwefels und stickstoffs in gasstroemen |
GB8619536D0 (en) * | 1986-08-11 | 1986-09-24 | Shell Int Research | Bimetallic catalyst |
US4929586A (en) * | 1988-06-09 | 1990-05-29 | W. R. Grace & Co.-Conn. | Catalysts for selective catalytic reduction DeNOx technology |
US5137855A (en) * | 1988-06-09 | 1992-08-11 | W. R. Grace & Co.-Conn. | Catalysts for selective catalytic reduction denox technology |
DE4116364A1 (de) * | 1991-05-18 | 1992-11-19 | Basf Ag | Metalloxide enthaltender katalysator fuer verfahren zum oxidativen abbau von organischen verbindungen aus abgasen von verbrennungsanlagen |
DE19538799A1 (de) * | 1995-10-18 | 1997-04-24 | Sued Chemie Ag | Wabenförmiger KatalysatortrÀger |
DE19635383A1 (de) * | 1996-08-31 | 1998-03-05 | Katalysatorenwerke Huels Gmbh | DeNOx-Katalysator fÃŒr stark Staub-haltige Abgase |
JP3690070B2 (ja) * | 1996-09-12 | 2005-08-31 | æŸäžé»åšç£æ¥æ ªåŒäŒç€Ÿ | æã¬ã¹æµåçšè§Šåªåã³ãã®è£œé æ¹æ³äžŠã³ã«æã¬ã¹æµåãã£ã«ã¿äžŠã³ã«æã¬ã¹æµåè£ çœ® |
KR100415434B1 (ko) * | 1998-09-25 | 2004-03-24 | íëì€ê³µì 죌ìíì¬ | ì§ìì°í묌ì 거륌ìííìŽíëìê°íë¬ë§ëë²€í ëìŽížìëŽì§ëë°ëëììŽë§€ |
DE19847008A1 (de) | 1998-10-13 | 2000-04-20 | Degussa | Stickoxid-Speicherkatalysator |
EP1145762A1 (en) * | 2000-04-11 | 2001-10-17 | dmc2 Degussa Metals Catalysts Cerdec AG | Process for the preparation of a vanadia SCR-catalyst supported on titania |
DE102008001319A1 (de) * | 2008-04-22 | 2009-10-29 | Evonik Röhm Gmbh | Katalysator zur Umsetzung von CarbonsÀurenitrilen |
DE102014201263A1 (de) | 2014-01-23 | 2015-07-23 | Johnson Matthey Catalysts (Germany) Gmbh | Katalysator |
DE102015205843A1 (de) * | 2015-03-31 | 2016-10-06 | Johnson Matthey Catalysts (Germany) Gmbh | Katalysator insbesondere zur Abgasreinigung |
CN106268775A (zh) * | 2016-07-15 | 2017-01-04 | æµæ±åŸ·åç¯ä¿ç§æè¡ä»œæéå ¬åž | è磚èçªåŒå¬åå |
CN106179320A (zh) * | 2016-07-15 | 2016-12-07 | æµæ±åŸ·åç¯ä¿ç§æè¡ä»œæéå ¬åž | è磚åå¹³æ¿åŒå¬åå |
CN106732544A (zh) * | 2016-12-20 | 2017-05-31 | æµæ±åŸ·åç¯ä¿ç§æè¡ä»œæéå ¬åž | äžç§è±é€äºåè±çå¬åååå ¶å¶å€æ¹æ³ |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5450495A (en) * | 1977-09-30 | 1979-04-20 | Ube Ind Ltd | Nitrogen oxides purification catalyst |
JPS5959249A (ja) * | 1982-09-28 | 1984-04-05 | Ube Ind Ltd | çªçŽ é žåç©éå æµåçšè§Šåªã®è£œæ³ |
-
1984
- 1984-09-07 JP JP59186570A patent/JPS6164334A/ja active Granted
-
1985
- 1985-09-06 DE DE19853531871 patent/DE3531871A1/de active Granted
Also Published As
Publication number | Publication date |
---|---|
DE3531871C2 (ja) | 1989-07-13 |
JPS6164334A (ja) | 1986-04-02 |
DE3531871A1 (de) | 1986-03-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4221768A (en) | Catalyst for purifying exhaust and waste gases | |
JPH0242536B2 (ja) | ||
CA1221953A (en) | Catalyst for purifying nitrogen oxides from exhaust and waste gases | |
JP5936680B2 (ja) | ãããžãŠã ãå«ãã§ããªãããŸãã¯ãããžãŠã ãæžå°ãããïŒ€ïœ ïŒ®ïŒ¯ïœè§Šåªã®ããã®åæãããã³ãã®è£œé æ¹æ³ | |
KR100370460B1 (ko) | ì 첎íëŠì€ìì§ìì°í묌ëë륌ì€ìŽêž°ìíìŽë§€ë³íêž°ë°ê·žì ì¡°ë°©ë² | |
JPH08196B2 (ja) | ççŒæã¬ã¹ã®çªçŽ é žåç©å«æéãæžå°ãããè§Šåª | |
GB2193655A (en) | Catalyst for removing nitrogen oxides from exhaust gases | |
JP2730987B2 (ja) | çªçŽ é žåç©é€å»çšè§Šåªããã³è©²è§ŠåªãçšããçªçŽ é žåç©ã®é€å»æ¹æ³ | |
KR101308496B1 (ko) | íë컎 ìŽë§€ì ì ì¡° ë°©ë² | |
KR101700433B1 (ko) | ííí ì íì ìŽë§€íì ìŽë§€ì© ëë žë³µí© ìŽì°íí°íëì ì ì¡°ë°©ë² | |
JP2013091045A (ja) | æã¬ã¹åŠçæ¹æ³ | |
JPS6211892B2 (ja) | ||
JP6132498B2 (ja) | ãã¿ã³ã»ã±ã€çŽ ã»ã¿ã³ã°ã¹ãã³ã®é žåç©ããããçšããè±ç¡è§Šåªãåœè©²é žåç©ã®èª¿è£œæ¹æ³ããã³è±ç¡æ¹æ³ | |
CA1125730A (en) | Catalyst for reducing nitrogen oxides and process for producing the same | |
JP4798909B2 (ja) | çªçŽ é žåç©é€å»çšè§Šåªããã³ãã®è£œé æ¹æ³ | |
JPS6257382B2 (ja) | ||
KR100641694B1 (ko) | íì§ìŽë§€ ìì¶ì±íì© í°íëì ì ì¡°ë°©ë² | |
JPH0114810B2 (ja) | ||
JP2583912B2 (ja) | çªçŽ é žåç©é€å»çšè§Šåª | |
JP3496964B2 (ja) | æã¬ã¹äžã®çªçŽ é žåç©ã®ã¢ã³ã¢ãã¢éå çšè§Šåªããã³ãã®è£œé æ¹æ³ | |
JPS6312348A (ja) | ã¢ã³ã¢ãã¢ã«ããçªçŽ é žåç©ã®æ¥è§Šéå çšè§Šåª | |
JPS6245340A (ja) | ççŒæã¬ã¹ã®çªçŽ é žåç©å«æéãæžå°ãããè§Šåª | |
JPH0824651A (ja) | ã¢ã³ã¢ãã¢å解çšè§Šåªããã³ãã®è§Šåªãçšããã¢ã³ã¢ãã¢ã®å解æ¹æ³ | |
JP6016572B2 (ja) | æã¬ã¹åŠç觊åªããã³æã¬ã¹åŠçæ¹æ³ | |
JP2825343B2 (ja) | çªçŽ é žåç©é€å»çšè§Šåªã®è£œé æ¹æ³ |