JPH0140339B2 - - Google Patents
Info
- Publication number
- JPH0140339B2 JPH0140339B2 JP56136267A JP13626781A JPH0140339B2 JP H0140339 B2 JPH0140339 B2 JP H0140339B2 JP 56136267 A JP56136267 A JP 56136267A JP 13626781 A JP13626781 A JP 13626781A JP H0140339 B2 JPH0140339 B2 JP H0140339B2
- Authority
- JP
- Japan
- Prior art keywords
- silver halide
- developer
- group
- emulsion
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 claims description 80
- 229910052709 silver Inorganic materials 0.000 claims description 69
- 239000004332 silver Substances 0.000 claims description 69
- 239000000839 emulsion Substances 0.000 claims description 51
- 238000000034 method Methods 0.000 claims description 39
- 239000000463 material Substances 0.000 claims description 25
- 150000001875 compounds Chemical class 0.000 claims description 21
- 238000011161 development Methods 0.000 claims description 20
- 239000010410 layer Substances 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- 150000002460 imidazoles Chemical class 0.000 claims description 7
- 125000005843 halogen group Chemical group 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 3
- 239000002356 single layer Substances 0.000 claims description 3
- 230000035945 sensitivity Effects 0.000 description 26
- 239000000243 solution Substances 0.000 description 25
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 12
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 12
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 12
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 11
- NJYFRQQXXXRJHK-UHFFFAOYSA-N (4-aminophenyl) thiocyanate Chemical class NC1=CC=C(SC#N)C=C1 NJYFRQQXXXRJHK-UHFFFAOYSA-N 0.000 description 10
- LRUDIIUSNGCQKF-UHFFFAOYSA-N 5-methyl-1H-benzotriazole Chemical compound C1=C(C)C=CC2=NNN=C21 LRUDIIUSNGCQKF-UHFFFAOYSA-N 0.000 description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000011591 potassium Substances 0.000 description 9
- 229910052700 potassium Inorganic materials 0.000 description 9
- 239000000975 dye Substances 0.000 description 8
- WSGURAYTCUVDQL-UHFFFAOYSA-N 5-nitro-1h-indazole Chemical compound [O-][N+](=O)C1=CC=C2NN=CC2=C1 WSGURAYTCUVDQL-UHFFFAOYSA-N 0.000 description 7
- 108010010803 Gelatin Proteins 0.000 description 7
- 229920000159 gelatin Polymers 0.000 description 7
- 239000008273 gelatin Substances 0.000 description 7
- 235000019322 gelatine Nutrition 0.000 description 7
- 235000011852 gelatine desserts Nutrition 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 230000001235 sensitizing effect Effects 0.000 description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 239000011630 iodine Substances 0.000 description 4
- 229910052740 iodine Inorganic materials 0.000 description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
- 229920003171 Poly (ethylene oxide) Chemical class 0.000 description 3
- 235000010323 ascorbic acid Nutrition 0.000 description 3
- 229960005070 ascorbic acid Drugs 0.000 description 3
- 239000011668 ascorbic acid Substances 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 239000007771 core particle Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 3
- 229910001961 silver nitrate Inorganic materials 0.000 description 3
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 2
- BAXOFTOLAUCFNW-UHFFFAOYSA-N 1H-indazole Chemical compound C1=CC=C2C=NNC2=C1 BAXOFTOLAUCFNW-UHFFFAOYSA-N 0.000 description 2
- YGBYVNQFNMXDJM-UHFFFAOYSA-N 1h-indazole-5-carbonitrile Chemical compound N#CC1=CC=C2NN=CC2=C1 YGBYVNQFNMXDJM-UHFFFAOYSA-N 0.000 description 2
- JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical class SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 2
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- PZBQVZFITSVHAW-UHFFFAOYSA-N 5-chloro-2h-benzotriazole Chemical compound C1=C(Cl)C=CC2=NNN=C21 PZBQVZFITSVHAW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- QMJDEXCUIQJLGO-UHFFFAOYSA-N [4-(methylamino)phenyl] hydrogen sulfate Chemical compound CNC1=CC=C(OS(O)(=O)=O)C=C1 QMJDEXCUIQJLGO-UHFFFAOYSA-N 0.000 description 2
- HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical compound [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 150000002344 gold compounds Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 2
- 235000019252 potassium sulphite Nutrition 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 description 2
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 2
- JAKYJVJWXKRTSJ-UHFFFAOYSA-N sodium;oxido(oxo)borane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B=O JAKYJVJWXKRTSJ-UHFFFAOYSA-N 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- AXJZCJSXNZZMDU-UHFFFAOYSA-N (5-methyl-1h-imidazol-4-yl)methanol Chemical compound CC=1N=CNC=1CO AXJZCJSXNZZMDU-UHFFFAOYSA-N 0.000 description 1
- LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 1
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical class C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical class C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- YLVACWCCJCZITJ-UHFFFAOYSA-N 1,4-dioxane-2,3-diol Chemical compound OC1OCCOC1O YLVACWCCJCZITJ-UHFFFAOYSA-N 0.000 description 1
- SIQZJFKTROUNPI-UHFFFAOYSA-N 1-(hydroxymethyl)-5,5-dimethylhydantoin Chemical compound CC1(C)N(CO)C(=O)NC1=O SIQZJFKTROUNPI-UHFFFAOYSA-N 0.000 description 1
- FYBFGAFWCBMEDG-UHFFFAOYSA-N 1-[3,5-di(prop-2-enoyl)-1,3,5-triazinan-1-yl]prop-2-en-1-one Chemical compound C=CC(=O)N1CN(C(=O)C=C)CN(C(=O)C=C)C1 FYBFGAFWCBMEDG-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- HAZJTCQWIDBCCE-UHFFFAOYSA-N 1h-triazine-6-thione Chemical class SC1=CC=NN=N1 HAZJTCQWIDBCCE-UHFFFAOYSA-N 0.000 description 1
- YKUDHBLDJYZZQS-UHFFFAOYSA-N 2,6-dichloro-1h-1,3,5-triazin-4-one Chemical compound OC1=NC(Cl)=NC(Cl)=N1 YKUDHBLDJYZZQS-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- PHPYXVIHDRDPDI-UHFFFAOYSA-N 2-bromo-1h-benzimidazole Chemical class C1=CC=C2NC(Br)=NC2=C1 PHPYXVIHDRDPDI-UHFFFAOYSA-N 0.000 description 1
- AYPSHJCKSDNETA-UHFFFAOYSA-N 2-chloro-1h-benzimidazole Chemical class C1=CC=C2NC(Cl)=NC2=C1 AYPSHJCKSDNETA-UHFFFAOYSA-N 0.000 description 1
- SUILEBXRIVKHGT-UHFFFAOYSA-N 2-methyl-1-prop-2-enylimidazole Chemical compound CC1=NC=CN1CC=C SUILEBXRIVKHGT-UHFFFAOYSA-N 0.000 description 1
- KRTDQDCPEZRVGC-UHFFFAOYSA-N 2-nitro-1h-benzimidazole Chemical class C1=CC=C2NC([N+](=O)[O-])=NC2=C1 KRTDQDCPEZRVGC-UHFFFAOYSA-N 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N 2-propanol Substances CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- CBHTTYDJRXOHHL-UHFFFAOYSA-N 2h-triazolo[4,5-c]pyridazine Chemical class N1=NC=CC2=C1N=NN2 CBHTTYDJRXOHHL-UHFFFAOYSA-N 0.000 description 1
- OCVLSHAVSIYKLI-UHFFFAOYSA-N 3h-1,3-thiazole-2-thione Chemical class SC1=NC=CS1 OCVLSHAVSIYKLI-UHFFFAOYSA-N 0.000 description 1
- SJSJAWHHGDPBOC-UHFFFAOYSA-N 4,4-dimethyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)(C)CN1C1=CC=CC=C1 SJSJAWHHGDPBOC-UHFFFAOYSA-N 0.000 description 1
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 description 1
- UTMDJGPRCLQPBT-UHFFFAOYSA-N 4-nitro-1h-1,2,3-benzotriazole Chemical class [O-][N+](=O)C1=CC=CC2=NNN=C12 UTMDJGPRCLQPBT-UHFFFAOYSA-N 0.000 description 1
- TYMLOMAKGOJONV-UHFFFAOYSA-N 4-nitroaniline Chemical compound NC1=CC=C([N+]([O-])=O)C=C1 TYMLOMAKGOJONV-UHFFFAOYSA-N 0.000 description 1
- BQCIJWPKDPZNHD-UHFFFAOYSA-N 5-bromo-2h-benzotriazole Chemical compound C1=C(Br)C=CC2=NNN=C21 BQCIJWPKDPZNHD-UHFFFAOYSA-N 0.000 description 1
- FVNCILPDWNBPLK-UHFFFAOYSA-N 5-chloro-1h-indazole Chemical compound ClC1=CC=C2NN=CC2=C1 FVNCILPDWNBPLK-UHFFFAOYSA-N 0.000 description 1
- GIQKIFWTIQDQMM-UHFFFAOYSA-N 5h-1,3-oxazole-2-thione Chemical compound S=C1OCC=N1 GIQKIFWTIQDQMM-UHFFFAOYSA-N 0.000 description 1
- ORZRMRUXSPNQQL-UHFFFAOYSA-N 6-nitro-1h-indazole Chemical compound [O-][N+](=O)C1=CC=C2C=NNC2=C1 ORZRMRUXSPNQQL-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 101710134784 Agnoprotein Proteins 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical class OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 229910003803 Gold(III) chloride Inorganic materials 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- SJUCACGNNJFHLB-UHFFFAOYSA-N O=C1N[ClH](=O)NC2=C1NC(=O)N2 Chemical class O=C1N[ClH](=O)NC2=C1NC(=O)N2 SJUCACGNNJFHLB-UHFFFAOYSA-N 0.000 description 1
- QPFYXYFORQJZEC-FOCLMDBBSA-N Phenazopyridine Chemical compound NC1=NC(N)=CC=C1\N=N\C1=CC=CC=C1 QPFYXYFORQJZEC-FOCLMDBBSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N Taurine Natural products NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- 229910052946 acanthite Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001661 cadmium Chemical class 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 150000002012 dioxanes Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- RJHLTVSLYWWTEF-UHFFFAOYSA-K gold trichloride Chemical compound Cl[Au](Cl)Cl RJHLTVSLYWWTEF-UHFFFAOYSA-K 0.000 description 1
- 229940076131 gold trichloride Drugs 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- AKCUHGBLDXXTOM-UHFFFAOYSA-N hydroxy-oxo-phenyl-sulfanylidene-$l^{6}-sulfane Chemical compound SS(=O)(=O)C1=CC=CC=C1 AKCUHGBLDXXTOM-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229940079865 intestinal antiinfectives imidazole derivative Drugs 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 150000002503 iridium Chemical class 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 229950005308 oxymethurea Drugs 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940070891 pyridium Drugs 0.000 description 1
- HBCQSNAFLVXVAY-UHFFFAOYSA-N pyrimidine-2-thiol Chemical class SC1=NC=CC=N1 HBCQSNAFLVXVAY-UHFFFAOYSA-N 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
- 150000003283 rhodium Chemical class 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- 229940056910 silver sulfide Drugs 0.000 description 1
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 125000004964 sulfoalkyl group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003475 thallium Chemical class 0.000 description 1
- JJJPTTANZGDADF-UHFFFAOYSA-N thiadiazole-4-thiol Chemical class SC1=CSN=N1 JJJPTTANZGDADF-UHFFFAOYSA-N 0.000 description 1
- 125000005323 thioketone group Chemical group 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- 229940001496 tribasic sodium phosphate Drugs 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/34—Fog-inhibitors; Stabilisers; Agents inhibiting latent image regression
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/29—Development processes or agents therefor
- G03C5/305—Additives other than developers
Description
æ¬çºæã¯ããã²ã³åéåçæå
ææã®çŸåæ¹æ³
ã«é¢ãããã®ã§ãããç¹ã«é«æ床ã§è¢«èŠåã®é«ã
ããã²ã³åéãã€ã«ã ãã«ããªãçºçãããããš
ãªãè¿ éã«åŠçããæ¹æ³ã«é¢ãããã®ã§ããã éããæãåçç»åã«é¢ããŠãç»åã®å åŠæ¿åºŠ
ãšç»åæ§æããåäœé¢ç©åœã«ééã®æ¯ãäžè¬ã«è¢«
èŠåãšåŒãã§ãç»åãæ§æããéã®å åŠçå¹çã®
è©äŸ¡ã®å°ºåºŠãšããŠãããããã²ã³åéåçæå å±€
ã®è¢«èŠåã¯äžè¬ã«ãããã²ã³åéç²åã®ãµã€ãº
ïŒéåžžçŽåŸåã¯æç®ãããçŽåŸã§ç€ºãããïŒãå°
ããã»ã©å€§ãããç²åãµã€ãºã倧ã«ãªãã»ã©äœäž
ãããäžæ¹ãããã²ã³åéä¹³å€å±€ã®æ床ã¯ãäžè¬
ã«ããã²ã³åéç²åã®ãµã€ãºã倧ããã»ã©é«ããª
ãã®ã§é«æ床ã®åçæå ææã«ã¯ç²åãµã€ãºã®å€§
ããããã²ã³åéä¹³å€ãçšãããããåŸã€ãŠé«æ
床ã®åçæå ææã¯ãäžå®ã®ç»åæ¿åºŠãåŸãã®ã«
åäœé¢ç©åœã倧ãªãééãå¿ èŠãšãããèšãæã
ãã°ãé«ãæ床ãšå¿ èŠãªæ倧ç»åæ¿åºŠã®åæ¹ãåŸ
ãããã«åçæå ææäžã®åäœé¢ç©åœãã«ããå€
ãã®éå¡©ãå«æãããªããã°ãªããªãããããåŸ
æ¥ã®é«æ床åçæå ææã®å®æ ã§ãã€ãã é«æ床ãç¶æãããŸãŸè¢«èŠåãæ¹è¯ããè©Šã¿ã®
ã²ãšã€ãšããŠãé«æ床ç²ç²åããã²ã³åéä¹³å€ã«
çš®ã ã®ããªããŒãæ·»å ããæè¡ãè±åœç¹èš±ç¬¬
1048057å·ãå第1039471å·ãç±³åœç¹èš±ç¬¬3043697
å·ãå第3446618å·åæ现æžã«èšèŒãããŠããã
ãããã¯ãã¥ããã被èŠåãé«ããå¹æã¯è¥å¹²ã
ããå åã§ãªãããããå¡åžèã®åŒ·åºŠã匱ããã
ã®ã§ãã奜ãŸãããªããç¹ã«çŸåšäžè¬çã«äœ¿çšã
ããŠããèªåçŸåæ©ã§ã¯å¡åžèã®åŒ·åºŠã®åŒ±ããã®
ãçšãããšèäžã®ãŒã©ãã³ãäžéšåçŸå液åã¯å®
ç液ã«æº¶ãåºãèªåçŸåæ©ã®æ¬éããŒã©ãŒã«éç
ãããããæå ææã«è»¢åãããŠåçç»åã®æ±æ
ãåŒãèµ·ããšããäžéœåãçããã äžæ¹ãç±³åœç¹èš±ç¬¬2996382å·åã³å第3178282å·
æ现æžã«ã¯è¡šé¢æœååããã²ã³åéç²ç²åãšå éš
ã«ã«ããªæ žãæããããã²ã³åé埮ç²åãåäžå±€
åã¯èšæ¥å±€ã«æ æãããããã²ã³åéåçæå æ
æãçšããŠé«æ床ã§é«ã³ã³ãã©ã¹ããã€é«è¢«èŠå
ã®åçç»åãåŸãããšãèšèŒãããŠããããã®æ¹
æ³ã«ããã°ããŸãè¡šé¢æœååããã²ã³åéç²ç²å
ãçŸåããããã®çŸåã«ããçæç©ããã®è¿åã®
å éšã«ã«ããªæ žãæããããã²ã³åé埮ç²åãæ»
æããŠãã®çŸåãåŒãèµ·ããã®ãšèããããŠã
ããããããã®ããã²ã³åéåçæå ææãéåžž
ã®åŠæ¹ã®çŸå液ã§åŠçãããšçŸåæéãéåžžã«é·
ããªãå®çšçã§ãªãããã®ããåèšåç±³åœç¹èš±æ
现æžäžã«ã¯ããã³ã«ãªãããªç¡«é žå¡©ãªã©ã®ããã²
ã³åé溶å€ãçŸå液äžã«æ·»å ããããšãé瀺ããŠ
ããããšããããã®æ¹æ³ã§ã¯ãåèšåç±³åœç¹èš±æ
现æžã«ãèšèŒãããŠããããã«çŸåæéãççž®ã
ãããšã¯ã§ãããåŸãããç»åã®ç²ç¶æ§ãæªãã
ã«ããªãå€ããªã€ãŠããŸãããã®æ¬ ç¹ã¯ãéåžžã®
ã«ããªé²æ¢å€ïŒäŸãã°ã¡ã«ã«ããããã©ãŸãŒã«
é¡ïŒã§ã¯è§£æ±ºã§ããªãã åŸã€ãŠãæ¬çºæã®ç®çã¯é«æ床ã§é«ã³ã³ãã©ã¹
ããã€é«è¢«èŠåã®åçç»åãç²ç¶æ§åã³ã«ããªã
æªåãããããšãªãè¿ éã«åŸãããšã®ã§ããçŸå
æ¹æ³ãæäŸããããšã«ããã æ¬çºæã®ä»ã®ç®çã¯åäœé¢ç©åœãã®ééã®å°ãª
ãããã²ã³åéåçæå ææãçšããŠé«æ床ã§é«
ã³ã³ãã©ã¹ããã€é«è¢«èŠåã®åçç»åãç²ç¶æ§å
ã³ã«ããªãæªåãããããšãªãè¿ éã«åŸãããšã®
ã§ããçŸåæ¹æ³ãæäŸããããšã«ããã äžèšã®è«žç®çã¯ãè¡šé¢æœååããã²ã³åéä¹³å€
ãšå éšã«ãã¶ãæ žãæããããã²ã³åéä¹³å€ãæ··
åããŠäžå±€ã«ãããåã¯å¥ã ã«éå±€ããŠå¡åžããŠ
æãããã²ã³åéåçæå ææãã次ã®äžè¬åŒ
ïŒïŒãŸãã¯äžè¬åŒïŒïŒã§ç€ºãããååç©ãã
ã³ããã²ã³åé溶å€ãšããŠäžèšäžè¬åŒïŒïŒã®ã€
ãããŸãŒã«èªå°äœãå«æããçŸå液ã§åŠçããã
ãšã«ãã€ãŠéæãããã ïŒåŒäžR1ã¯æ°ŽçŽ ååããããåºãã·ã¢ãåºã
ãŸãã¯ããã²ã³ååãè¡šããR2ã¯æ°ŽçŽ ååãã
ãã²ã³ååããŸãã¯ã¢ã«ãã«åºãè¡šããZ1ãZ4ã¯
åäžã§ãäºãã«ç°ãªã€ãŠããŠããããåã æ°ŽçŽ å
åãã¢ã«ãã«åºãããããã·ã¢ã«ãã«åºãŸãã¯ã¢
ã«ã±ãã«åºãè¡šããïŒ æ¬çºæã®çŸåæ¹æ³ãé©çšããæå ææã«çšãã
è¡šé¢æœååã®ããã²ã³åéä¹³å€ãšã¯ãïŒã1/100
ç§é²å åŸäžèšã«ç€ºãè¡šé¢çŸå(A)ã®æ¹æ³åã³å éšçŸ
å(B)ã®æ¹æ³ã§çŸåããå Žåã«ãè¡šé¢çŸå(A)ã§åŸã
ããæ床ãå éšçŸå(B)ã§åŸãããæ床ãã倧ã«ãª
ãä¹³å€ã奜ãŸããã¯åè ã®æ床ãåŸè ã®ããã®ïŒ
å以äžãšãªãä¹³å€ã§ãããããã§æ床ã¯æ¬¡ã®ãã
ã«å®çŸ©ãããã ïŒ100ïŒEh ã¯æ床ãEhã¯æ倧æ¿åºŠïŒDmaxïŒãšæå°æ¿
床ïŒDminïŒã®äžåºŠäžéã®æ¿åºŠ1/2ïŒDmaxïŒ
DminïŒãåŸãã«èŠããé²å éã瀺ãã ãè¡šé¢çŸå(A)ã äžèšåŠæ¹ã®çŸå液äžã§ã塩床20âã«ãããŠ10å
éçŸåããã âã¡ãã«âïœâã¢ããããšããŒã«ïŒããç¡«é ž
å¡©ïŒ 2.5ïœ ã¢ã¹ã³ã«ãã³é ž 10ïœ ã¡ã¿ç¡Œé žãããªãŠã ã»åæ°Žå¡© 35ïœ èåã«ãª ïŒïœ æ°Žãå ããŠ ïŒ ãå éšçŸå(B)ã èµ€è¡å¡©ïŒïœïŒãšããšããµããã³0.0126ïœïŒ
ãå«ãæŒçœæ¶²äžã§çŽ20âã§10åéåŠçãã次ãã§
10åéæ°ŽæŽåŸãäžèšåŠæ¹ã®çŸå液äžã§ã20âã«ã
ããŠ10åéçŸåããã âã¡ãã«âïœâã¢ããããšããŒã«ïŒããç¡«é ž
å¡©ïŒ 2.5ïœ ã¢ã¹ã³ã«ãã³é ž 10ïœ ã¡ã¿ã»ãé žãããªãŠã åæ°Žå¡© 35ïœ èåã«ãª ïŒïœ ããªç¡«é žãœãŒã ïŒïœ æ°Žãå ããŠ ïŒ è¡šé¢æœååã®ããã²ã³åéãšããŠã¯æ²åéãå«
ããã®ã奜ãŸãããå ·äœçã«ã¯å¡©æ²åéãæ²èå
éãå¡©æ²åéãçšããããšãã§ãããããã§æ²å
éã®å«éã¯0.1ã30ã¢ã«ïŒ ãç¹ã«0.5ã10ã¢ã«ïŒ ã®
ç¯å²ã§ããããšã奜ãŸãããå¹³åç²åãµã€ãºã¯å
éšã«ã«ããªæ žãæããããã²ã³åéä¹³å€ããã倧
ããããšã奜ãŸãããç¹ã«0.6ÎŒïœä»¥äžã§ããããš
ã奜ãŸãããç²åãµã€ãºååžã¯çããŠãåºããŠã
ãããã§ããããä¹³å€äžã®ããã²ã³åéç²åã¯ç«
æ¹äœãå «é¢äœã®ãããªèŠåçïŒregularïŒãªçµæ¶
圢ãæãããã®ã§ãããããŸãçç¶ãæ¿ç¶ãªã©ã®
ãããªå€åçïŒirrlgularïŒãªçµæ¶åœ¢ãæãããã®
ã§ãæãã¯ãããã®çµæ¶åœ¢ã®è€å圢ãæãããã®
ã§ããããçš®ã ã®çµæ¶åœ¢ã®ç²åã®æ··åããæã€ãŠ
ãããã æ¬çºæã«çšããããåçä¹³å€ã¯P.Glafkidesè
Chimie et Physiqne PhotographiqueïŒPaul
Montel瀟åã1967幎ïŒãG.F.Duffinè
Photographic Emulsion ChemistryïŒThe Focal
Pressåã1966幎ïŒãV.L.Zelikman et alè
Making and Coating Photographic Emulsion
ïŒThe Focal Pressåã1964幎ïŒãªã©ã«èšèŒãã
ãæ¹æ³ãçšããŠèª¿è£œããããšãã§ãããããªã
ã¡ãé žæ§æ³ãäžæ§æ³ãã¢ã³ã¢ãã¢æ³çã®ãããã§
ãããããŸãå¯æº¶æ§éå¡©ãšå¯æº¶æ§ããã²ã³å¡©ãå
å¿ããã圢åŒãšããŠã¯çåŽæ··åæ³ãåææ··åæ³ã
ãããã®çµåããªã©ã®ããããçšããŠãããã ç²åãéã€ãªã³éå°ã®äžã«ãããŠåœ¢æãããæ¹
æ³ïŒããããéæ··åæ³ïŒãçšããããšãã§ããã
åææ··åæ³ã®äžã€ã®åœ¢åŒãšããŠããã²ã³åéã®ç
æããã液çžäžã®pAgãäžå®ã«ä¿ã€æ¹æ³ãããªã
ã¡ããããã³ã³ãããŒã«ãã»ããã«ãžãšããæ³ã
çšããããšãã§ããã ãã®æ¹æ³ã«ãããšãçµæ¶åœ¢ãèŠåçã§ç²åãµã€
ãºãåäžã«è¿ãããã²ã³åéä¹³å€ãããããã å¥ã ã«åœ¢æããïŒçš®ä»¥äžã®ããã²ã³åéä¹³å€ã
æ··åããŠçšããŠãããã ããã²ã³åéç²å圢æãŸãã¯ç©ççæã®éçšã«
ãããŠãã«ãããŠã å¡©ãäºéå¡©ãéå¡©ãã¿ãªãŠã
å¡©ãã€ãªãžãŠã å¡©ãŸãã¯ãã®é¯å¡©ãããžãŠã å¡©ãŸ
ãã¯ãã®é¯å¡©ãéå¡©ãŸãã¯éé¯å¡©ãªã©ãå ±åãã
ãŠãããã æ¬çºæã®çŸåæ¹æ³ãé©çšããæå ææã«çšãã
å éšã«ã«ããªæ žãæããããã²ã³åéä¹³å€ãšããŠ
ã¯ãééæç®ã§ïŒïœïŒm2ã«ãªãããã«éææ¯æäœ
äžã«å¡åžããè©Šéšçãé²å ããã«ïŒ€â19ïŒã€ãŒã¹
ããã³ã»ã³ããã¯ç€Ÿæå®çŸå液ïŒã§35âãïŒåé
çŸåãããšã0.5以äžã®ééã«ããªæ¿åºŠïŒæ¯æäœ
èªäœã®æ¿åºŠã¯é€ãïŒãäžããåäžã®è©Šéšçãé²å
ããã«ïŒ€â19ã«æ²åã«ãªãŠã ã0.5ïœïŒå ãã
çŸå液ã§35âãïŒåéçŸåãããšã1.0以äžã®é
éã«ããªæ¿åºŠïŒæ¯æäœèªäœã®æ¿åºŠã¯é€ãïŒãäžã
ãä¹³å€ãçšããããã å éšã«ã«ããªæ žãæããããã²ã³åéä¹³å€ã¯å ¬
ç¥ã®çš®ã ã®ææ³ã§èª¿è£œããããšãã§ãããã«ãã
ãæ¹æ³ãšããŠã¯å ãç·ãç §å°ããæ¹æ³ãéå
å€ãéååç©è¥ããã¯å«ç¡«é»ååç©ãªã©ã§ååŠç
ã«ã«ããªæ žãäœãæ¹æ³åã³ä¹³å€ã®è£œé ãäœpAgã
é«PHã®æ¡ä»¶ã§è¡ããªã©ã®æ¹æ³ããããå éšã®ã¿ã«
ã«ããªæ žãäœãã«ã¯äžèšã®æ¹æ³ã§ããã²ã³åéç²
åã®å éšåã³è¡šé¢ãå ±ã«ã«ããããåŸãè¡šé¢ã®ã«
ããªæ žãèµ€è¡å¡©æº¶æ¶²ã§æŒçœããææ³ãããããã
ã奜ãŸããã®ã¯ãŸãäœpAgãé«PHã«ããæ¹æ³åã¯
ååŠçã«ãããæ¹æ³ã§ãã€ãŠã«ããªæ žãæããã³
ã¢ä¹³å€ã調補ãã次ãã§ãã®ã³ã¢ä¹³å€ã®åšå²ã«ã·
ãšã«ä¹³å€ããã¶ããææ³ã§ããããã®ã³ã¢âã·ãš
ã«ä¹³å€ã®èª¿è£œæ³ã¯å ¬ç¥ã§ãããå®æœã«åœã€ãŠã¯äŸ
ãã°ç±³åœç¹èš±ç¬¬3206313å·æ现æžã®èšèŒãåç §ã§
ããã å éšã«ã«ããªæ žãæããããã²ã³åéä¹³å€ã¯è¡š
é¢æœååããã²ã³åéä¹³å€ãããå°ããå¹³åç²å
ãµã€ãºãæãããã®ã§ã0.5ÎŒïœä»¥äžã®å¹³åç²åãµ
ã€ãºãæã€ãã®ã奜ãŸãããç¹ã«0.4ÎŒïœä»¥äžã®å¹³
åç²åãµã€ãºãæã€ãã®ãè¯ãçµæãäžããã äžè¿°ããïŒçš®ã®ããã²ã³åéä¹³å€ã¯æ··åããŠäž
å±€ã«å¡åžããããåã¯åã ã®ä¹³å€ãå¥å±€ãšããŠé
ããŠå¡åžãããã²ã³åéåçæå ææãšãããè¡š
é¢æœååã®ããã²ã³åéä¹³å€ãšå éšã«ãã¶ãæ žã
æããããã²ã³åéä¹³å€ã®äœ¿çšæ¯çã¯ãäžå±€ã«ã
ããšããå¥å±€ã«ãããšãããééæ¯ïŒéæç®ïŒã§
10ïŒïŒãïŒïŒ10ããã奜ãŸããã¯ïŒïŒïŒãïŒïŒïŒ
ã§ãããå¡åžééã¯ä»»æã§ããããæ¬çºæã«ãã€
ãŠã¯ïŒïœïŒm2ãïŒïœïŒm2ãšãã極ããŠå°ãªãéã§
æºè¶³ãã被èŠåãæ床çã®åçç¹æ§ãåŸãããšã
ã§ããã æ¬çºæã®çŸåæ¹æ³ã«çšããçŸå液ã¯äžè¬åŒ
ïŒïŒã§è¡šãããã€ãããŸãŒã«èªå°äœãããã²ã³
åé溶å€ãšããŠå«æããæŽã«äžè¬åŒïŒïŒãŸãã¯
ïŒïŒã§ç€ºãããååç©ã®ïŒçš®ãšãå«æããããš
ãç¹åŸŽãšãããã®ã§ããããã®ç¹ãé€ããŠã¯äžè¬
çãªããã²ã³åéåççŸå液ãšåäžã®çµæã®çŸå
液ãããªãã¡ïŒâããšãã«âïŒâãã©ãŸãªãã³å
ã³ãã®èªå°äœãâã¡ãã«âïœâã¢ããããšããŒ
ã«ããã€ããããã³çã®çŸåäž»è¬ãäžã€ä»¥äžå«ã
ã 氎溶液ãçšãããããä»ã«äºç¡«é žãããªãŠã ã
ã¢ã¹ã³ã«ãã³é žã®åŠãé žåé²æ¢å€ãç¡«é žãããªãŠ
ã ã®åŠãå¡©é¡ãããŠé žãããŠç ãæ°Žé žåãããªãŠ
ã ãçé žãããªãŠã ã第äžãªã³é žãããªãŠã ã®åŠ
ãPH調ç¯å€ãç·©è¡å€ãèåãããªãŠã ãæ²åãã
ãªãŠã ã®åŠãçŸåæå¶å€ããã«ããªã³ãã°ã«ã¿ãŒ
ã«ã¢ã«ãããã®åŠãã¢ã«ããã系硬èå€ãããªãš
ãã¬ã³ã°ãªã³ãŒã«ãããã·ã¬ã³ã°ãªã³ãŒã«ã®åŠã
ææ©æº¶å€ãªã©ã®å ¬ç¥ã®çŸå液添å å€ãå ããããš
ãã§ããã çŸå液ã®PHã«ç¹ã«å¶éã¯ãªãã9.0ã11.5ã®ç¯
å²ã奜ãŸããã æ¬çºæã§ã¯äžèšã®äžè¬åŒïŒïŒã§è¡šãããã€ã
ããŸãŒã«èªå°äœãçŸåé床ãå¢å ãããçå¹ãæ
ããŠããã®ã§ããã²ã³åé溶å€ãšããŠäœ¿çšããã åŒäžZ1ãZ4ã¯åäžã§ãäºãã«ç°ãªã€ãŠããŠãã
ããåã æ°ŽçŽ ååãã¢ã«ãã«åºãããããã·ã¢ã«
ãã«åºåã¯ã¢ã«ã±ãã«åºãè¡šããã Z1ãZ4ã®ã¢ã«ãã«åºãããããã·ã¢ã«ãã«åºå
ã³ã¢ã«ã±ãã«åºãšããŠã¯åã ççŽ æ°ïŒãŸã§ã®ãã®
ã奜ãŸãããäŸãã°ã¡ãã«åºããšãã«åºãããã
ã«åºãïœâãããã«åºãããã«åºãã¢ãã«åºãã€
ãœã¢ãã«åºãããããã·ã¡ãã«åºãããããã·ãš
ãã«åºãããããã·ãããã«åºãããã«åºãã¢ãª
ã«åºãªã©ãæããããšãã§ããã 以äžã«ãã®å ·äœäŸãåæããã ã€ãããŸãŒã« ïŒâã¡ãã«ã€ãããŸãŒã« ïŒã»ïŒâãžã¡ãã«ã€ãããŸãŒã« ïŒâãšãã«âïŒâã¡ãã«ã€ãããŸãŒã« ïŒâã¢ãã«ã€ãããŸãŒã« ïŒâã€ãœã¢ãã«âïŒâã¡ãã«ã€ãããŸãŒã« ïŒã»ïŒâãžã¡ãã«ã€ãããŸãŒã« ïŒâãšãã«ã€ãããŸãŒã« ïŒâãšãã«ã€ãããŸãŒã« ïŒã»ïŒã»ïŒâããªã¡ãã«ã€ãããŸãŒã« ïŒâããããã·ã¡ãã«âïŒâã¡ãã«âïŒâã¡ã
ã«ã€ãããŸãŒã« ïŒâïŒïŒâããããã·ãšãã«ïŒâïŒâã¡ãã«ã€
ãããŸãŒã« ïŒâã¢ãªã«âïŒâã¡ãã«ã€ãããŸãŒã« ïŒâããã«âïŒâã¡ãã«ã€ãããŸãŒã« ããã²ã³åé溶å€ã®æ·»å éã¯çšããååç©ã®çš®
é¡ã«åãããŠé©å®æ°æãããã¹ãæ§è³ªã®ãã®ã§ã
ããäžè¬çã«ã¯çŸå液ïŒããã0.01ïœïŒã10
ïœïŒã§ããããã奜ããã¯0.05ïœïŒãïŒïœïŒ
ã§ããã æ¬çºæã§çšããäžè¬åŒïŒïŒãŸãã¯ïŒïŒã§ç€º
ãããååç©ã¯ãäžèšã®ããã²ã³åé溶å€ãç¹ã«
ããã³å¡©ãããªç¡«é žå¡©ããã³ïŒçŽã¢ã³ã¢ããŠã å¡©
ã«ããç²ç¶æ§ããã³ã«ããªã®æªåãèããæå¶ã
ãããŸãäžèšäžè¬åŒã®ã€ãããŸãŒã«èªå°äœã¯ç²ç¶
æ§ãã«ããªãæªåãããã«çŸåé床ãéããåå
ç©ã§ããããæ¬çºæã®äžè¬åŒïŒïŒãŸãã¯ïŒïŒ
ã§ç€ºãããååç©ã䜵çšããããšã«ãããäžå±€è¯
奜ãªç²ç¶æ§ããã³äœãã«ããªãéæããããšãã§
ããã åŒäžR1ã¯æ°ŽçŽ ååããããåºãã·ã¢ãåºããŸ
ãã¯ããã²ã³ååïŒå¡©çŽ ãèçŽ ãæ²çŽ ïŒãè¡šã
ããR2ã¯æ°ŽçŽ ååãããã²ã³ååïŒå¡©çŽ ãèçŽ ã
æ²çŽ ïŒããŸãã¯ã¢ã«ãã«åºïŒå¥œãŸããã¯äœçŽã¢ã«
ãã«åºãç¹ã«ã¡ãã«åºããããã¯ãšãã«åºïŒãè¡š
ããã äžè¬åŒïŒïŒã§è¡šãããååç©ã®å ·äœäŸãšããŠ
ã¯ã€ã³ããŸãŒã«ãïŒâãããã€ã³ããŸãŒã«ãïŒâ
ãããã€ã³ããŸãŒã«ãïŒâã·ã¢ãã€ã³ããŸãŒã«ã
ïŒâã¯ããã€ã³ããŸãŒã«çãããäžè¬åŒïŒïŒã§
瀺ãããååç©ã®å ·äœäŸãšããŠã¯ãã³ãããªã¢ãŸ
ãŒã«ãïŒâã¡ãã«ãã³ãããªã¢ãŸãŒã«ãïŒâã¯ã
ããã³ãããªã¢ãŸãŒã«ãïŒâããã ãã³ãããªã¢
ãŸãŒã«çãããããããã®äžã§ãïŒâãããã€ã³
ããŸãŒã«åã¯ïŒâã¡ãã«ãã³ãããªã¢ãŸãŒã«ãæ
ã奜ãŸããã ãããååç©ã®æ·»å éã¯ååç©ã®çš®é¡ã«åãã
ãŠå€æŽã§ããããäžè¬ã«çŸå液ïŒåœã0.01ã
10.0ïœïŒã§ããããã奜ãŸããã¯0.02ã5.0ïœïŒ
ã§ããã äžèšã®çŸå液ã§åŠçããéã®çŸåæéãçŸåæž©
床ã¯çšããæå ææã«äŸåãããçŸåæéã¯10ç§
ãïŒåã奜ãŸãããçŸå枩床ã¯20âã45âã®ç¯å²
ã奜ãŸãããå®çãæ°ŽæŽã«ã€ããŠã¯ããã²ã³åé
æå ææãéåžžåŠçããæ¹æ³ããã®ãŸãŸçšããã
ãã æ¬çºæã®çŸåæ¹æ³ã«ããã°ãäžè¬åŒïŒïŒã§è¡š
ãããããã²ã³åé溶å€ãšäžè¬åŒïŒïŒãŸãã¯
ïŒïŒã§ç€ºãããååç©ãå«ãçŸå液ã§åè¿°ãã
æ¬çºæã®ããã²ã³åéåçæå ææãåŠçããã®
ã§ç²ç¶æ§ãæãããšãªãçãçŸåæéã§é«æ床ã®
ãããã«ããªã®å°ãåçç»åãåŸãããšãã§ã
ãã 以äžã«å®æœäŸãæ²ãæ¬çºæãæŽã«è©³çŽ°ã«èª¬æã
ãã å®æœäŸ ïŒ 80ïœã®èåã«ãªãšïŒïœã®æ²åã«ãªãš10ïœã®ãŒã©
ãã³æ°Žæº¶æ¶²ïŒïŒïŒã60âã«ä¿ã¡ãç¡é žé氎溶液
ïŒ100ïœïŒïŒã30åéãããŠæ·»å ããããšã«ãã€
ãŠå¹³åç²åãµã€ãºïŒã»4ÎŒïœã®æ²èåéä¹³å€ãäœ
ããéåžžã®æ¹æ³ã§è±å¡©åŸïŒÃ10-5ã¢ã«ïŒã¢ã«Ag+
ã®ããªç¡«é žãããªãŠã ãšïŒÃ10-5ã¢ã«ïŒã¢ã«Ag+
ã®å¡©åéé žãæ·»å 60âã§75åéååŠçæãããã
ã®ããã«ããŠäœæããä¹³å€ã¯è¡šé¢æœååã§ããä¹³
å€ãšããã 50âã«ä¿ã€ããŒã©ãã³æ°Žæº¶æ¶²ã«èåã«ãªãšæ²å
ã«ãªã®æ··å氎溶液ãšç¡é žé氎溶液ãåæã«50åé
æ·»å ã0.25ÎŒïœã®ïŒã¢ã«ïŒ ã®ãšãŒããå«ãæ²èå
éã³ã¢ç²åãäœè£œããããã«AgNO3ãæ·»å ã
pAgã5.0ã«ãNaOHãå ãPH9.5ã«ãïŒÃ10-5ã¢
ã«ïŒã¢ã«Ag+ã®å¡©åéé žãå ã50â60åéçæã
ãããšã«ãã€ãŠã³ã¢ç²åã®è¡šé¢ããã¶ããããã
ãã«èåã«ãªãšæ²åã«ãªã®æ··å氎溶液ãšç¡é žéæ°Ž
溶液ãåæã«30åéãããŠæ·»å ããããšã«ãã€ãŠ
åã¿0.05ÎŒïœã®ã·ãšã«ä»ããè¡ãªãïŒã·ãšã«ã®ãš
ãŒãã¯ïŒã¢ã«ïŒ ïŒãç²åå šäœã®ãµã€ãºã0.3ÎŒïœ
ïŒç²åå šäœã®ãšãŒãã¯ïŒã¢ã«ïŒ ïŒã®å éšãã¶ãä¹³
å€ã調補ããããã®ããã«ããŠäœæããå éšã«ã
ã¶ãæ žãæããããã²ã³åéç²åãä¹³å€ãšã
ãã ä¹³å€ã®ã¿ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãæ¯æ
äœäžã«ééãšããŠ3.6ïœïŒm2å¡åžãããã®ããã€
ã«ã è©ŠæïŒãšãããäžæ¹ä¹³å€ãšä¹³å€ãééã§
50ïŒ ã¥ã€ã®å²åã§æ··åãæ¯æäœäžã«ééãšããŠ
3.6ïœïŒm2å¡åžãããã®ããã€ã«ã è©ŠæïŒãšããã
åè©Šæã¯1/10ç§ã§å æ¥äžã§é²å ãã次ã®çŸå液ã
çšããŠ35âã§çŸåãããã çŸå液  ïŒâããšãã«âïŒâãã©ãŸãªãã³ 0.5ïœ ãã€ããããã³ 20.0ïœ ãšãã¬ã³ãžã¢ãã³åé ¢é žäºãããªãŠã 2.0ïœ äºç¡«é žã«ãªãŠã 60.0ïœ ããŠé ž 4.0ïœ çé žã«ãªãŠã 20.0ïœ èåãããªãŠã 5.0ïœ ãžãšãã¬ã³ã°ãªã³ãŒã« 30.0ïœ æ°Žãå ã㊠ïŒãšããã NaOHã§PHïŒ10.0ã«ããã çŸå液  çŸå液ã«ããã³ã«ãªãŠã 0.025ã¢ã«ïŒæ·»å
ãããã®ã çŸå液  çŸå液ã«ããã³ã«ãªãŠã 0.025ã¢ã«ïŒåã³
ïŒâãããã€ã³ããŸãŒã«80mgïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ããã³ã«ãªãŠã 0.025ã¢ã«ïŒåã³
ïŒâã¡ãã«ãã³ãããªã¢ãŸãŒã«70mgïŒæ·»å ãã
ãã®ã çŸå液  çŸå液ã«ããã³ã«ãªãŠã 0.025ã¢ã«ïŒåã³
ïŒâãããã€ã³ããŸãŒã«40mgïŒåã³ïŒâã¡ãã«
ãã³ãããªã¢ãŸãŒã«35mgïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ããã³ã«ãªãŠã 0.025ã¢ã«ïŒåã³
ïŒâããšãã«ã»ïŒã¡ã«ã«ããããã©ãŸãŒã«90mgïŒ
æ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.025ã¢
ã«ïŒããã³ïŒâãããã€ã³ããŸãŒã«80mgïŒã
æ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.025ã¢
ã«ïŒåã³ïŒâã¡ãã«ãã³ãããªã¢ãŸãŒã«70mgïŒ
ãæ·»å ãããã®ã
ã«é¢ãããã®ã§ãããç¹ã«é«æ床ã§è¢«èŠåã®é«ã
ããã²ã³åéãã€ã«ã ãã«ããªãçºçãããããš
ãªãè¿ éã«åŠçããæ¹æ³ã«é¢ãããã®ã§ããã éããæãåçç»åã«é¢ããŠãç»åã®å åŠæ¿åºŠ
ãšç»åæ§æããåäœé¢ç©åœã«ééã®æ¯ãäžè¬ã«è¢«
èŠåãšåŒãã§ãç»åãæ§æããéã®å åŠçå¹çã®
è©äŸ¡ã®å°ºåºŠãšããŠãããããã²ã³åéåçæå å±€
ã®è¢«èŠåã¯äžè¬ã«ãããã²ã³åéç²åã®ãµã€ãº
ïŒéåžžçŽåŸåã¯æç®ãããçŽåŸã§ç€ºãããïŒãå°
ããã»ã©å€§ãããç²åãµã€ãºã倧ã«ãªãã»ã©äœäž
ãããäžæ¹ãããã²ã³åéä¹³å€å±€ã®æ床ã¯ãäžè¬
ã«ããã²ã³åéç²åã®ãµã€ãºã倧ããã»ã©é«ããª
ãã®ã§é«æ床ã®åçæå ææã«ã¯ç²åãµã€ãºã®å€§
ããããã²ã³åéä¹³å€ãçšãããããåŸã€ãŠé«æ
床ã®åçæå ææã¯ãäžå®ã®ç»åæ¿åºŠãåŸãã®ã«
åäœé¢ç©åœã倧ãªãééãå¿ èŠãšãããèšãæã
ãã°ãé«ãæ床ãšå¿ èŠãªæ倧ç»åæ¿åºŠã®åæ¹ãåŸ
ãããã«åçæå ææäžã®åäœé¢ç©åœãã«ããå€
ãã®éå¡©ãå«æãããªããã°ãªããªãããããåŸ
æ¥ã®é«æ床åçæå ææã®å®æ ã§ãã€ãã é«æ床ãç¶æãããŸãŸè¢«èŠåãæ¹è¯ããè©Šã¿ã®
ã²ãšã€ãšããŠãé«æ床ç²ç²åããã²ã³åéä¹³å€ã«
çš®ã ã®ããªããŒãæ·»å ããæè¡ãè±åœç¹èš±ç¬¬
1048057å·ãå第1039471å·ãç±³åœç¹èš±ç¬¬3043697
å·ãå第3446618å·åæ现æžã«èšèŒãããŠããã
ãããã¯ãã¥ããã被èŠåãé«ããå¹æã¯è¥å¹²ã
ããå åã§ãªãããããå¡åžèã®åŒ·åºŠã匱ããã
ã®ã§ãã奜ãŸãããªããç¹ã«çŸåšäžè¬çã«äœ¿çšã
ããŠããèªåçŸåæ©ã§ã¯å¡åžèã®åŒ·åºŠã®åŒ±ããã®
ãçšãããšèäžã®ãŒã©ãã³ãäžéšåçŸå液åã¯å®
ç液ã«æº¶ãåºãèªåçŸåæ©ã®æ¬éããŒã©ãŒã«éç
ãããããæå ææã«è»¢åãããŠåçç»åã®æ±æ
ãåŒãèµ·ããšããäžéœåãçããã äžæ¹ãç±³åœç¹èš±ç¬¬2996382å·åã³å第3178282å·
æ现æžã«ã¯è¡šé¢æœååããã²ã³åéç²ç²åãšå éš
ã«ã«ããªæ žãæããããã²ã³åé埮ç²åãåäžå±€
åã¯èšæ¥å±€ã«æ æãããããã²ã³åéåçæå æ
æãçšããŠé«æ床ã§é«ã³ã³ãã©ã¹ããã€é«è¢«èŠå
ã®åçç»åãåŸãããšãèšèŒãããŠããããã®æ¹
æ³ã«ããã°ããŸãè¡šé¢æœååããã²ã³åéç²ç²å
ãçŸåããããã®çŸåã«ããçæç©ããã®è¿åã®
å éšã«ã«ããªæ žãæããããã²ã³åé埮ç²åãæ»
æããŠãã®çŸåãåŒãèµ·ããã®ãšèããããŠã
ããããããã®ããã²ã³åéåçæå ææãéåžž
ã®åŠæ¹ã®çŸå液ã§åŠçãããšçŸåæéãéåžžã«é·
ããªãå®çšçã§ãªãããã®ããåèšåç±³åœç¹èš±æ
现æžäžã«ã¯ããã³ã«ãªãããªç¡«é žå¡©ãªã©ã®ããã²
ã³åé溶å€ãçŸå液äžã«æ·»å ããããšãé瀺ããŠ
ããããšããããã®æ¹æ³ã§ã¯ãåèšåç±³åœç¹èš±æ
现æžã«ãèšèŒãããŠããããã«çŸåæéãççž®ã
ãããšã¯ã§ãããåŸãããç»åã®ç²ç¶æ§ãæªãã
ã«ããªãå€ããªã€ãŠããŸãããã®æ¬ ç¹ã¯ãéåžžã®
ã«ããªé²æ¢å€ïŒäŸãã°ã¡ã«ã«ããããã©ãŸãŒã«
é¡ïŒã§ã¯è§£æ±ºã§ããªãã åŸã€ãŠãæ¬çºæã®ç®çã¯é«æ床ã§é«ã³ã³ãã©ã¹
ããã€é«è¢«èŠåã®åçç»åãç²ç¶æ§åã³ã«ããªã
æªåãããããšãªãè¿ éã«åŸãããšã®ã§ããçŸå
æ¹æ³ãæäŸããããšã«ããã æ¬çºæã®ä»ã®ç®çã¯åäœé¢ç©åœãã®ééã®å°ãª
ãããã²ã³åéåçæå ææãçšããŠé«æ床ã§é«
ã³ã³ãã©ã¹ããã€é«è¢«èŠåã®åçç»åãç²ç¶æ§å
ã³ã«ããªãæªåãããããšãªãè¿ éã«åŸãããšã®
ã§ããçŸåæ¹æ³ãæäŸããããšã«ããã äžèšã®è«žç®çã¯ãè¡šé¢æœååããã²ã³åéä¹³å€
ãšå éšã«ãã¶ãæ žãæããããã²ã³åéä¹³å€ãæ··
åããŠäžå±€ã«ãããåã¯å¥ã ã«éå±€ããŠå¡åžããŠ
æãããã²ã³åéåçæå ææãã次ã®äžè¬åŒ
ïŒïŒãŸãã¯äžè¬åŒïŒïŒã§ç€ºãããååç©ãã
ã³ããã²ã³åé溶å€ãšããŠäžèšäžè¬åŒïŒïŒã®ã€
ãããŸãŒã«èªå°äœãå«æããçŸå液ã§åŠçããã
ãšã«ãã€ãŠéæãããã ïŒåŒäžR1ã¯æ°ŽçŽ ååããããåºãã·ã¢ãåºã
ãŸãã¯ããã²ã³ååãè¡šããR2ã¯æ°ŽçŽ ååãã
ãã²ã³ååããŸãã¯ã¢ã«ãã«åºãè¡šããZ1ãZ4ã¯
åäžã§ãäºãã«ç°ãªã€ãŠããŠããããåã æ°ŽçŽ å
åãã¢ã«ãã«åºãããããã·ã¢ã«ãã«åºãŸãã¯ã¢
ã«ã±ãã«åºãè¡šããïŒ æ¬çºæã®çŸåæ¹æ³ãé©çšããæå ææã«çšãã
è¡šé¢æœååã®ããã²ã³åéä¹³å€ãšã¯ãïŒã1/100
ç§é²å åŸäžèšã«ç€ºãè¡šé¢çŸå(A)ã®æ¹æ³åã³å éšçŸ
å(B)ã®æ¹æ³ã§çŸåããå Žåã«ãè¡šé¢çŸå(A)ã§åŸã
ããæ床ãå éšçŸå(B)ã§åŸãããæ床ãã倧ã«ãª
ãä¹³å€ã奜ãŸããã¯åè ã®æ床ãåŸè ã®ããã®ïŒ
å以äžãšãªãä¹³å€ã§ãããããã§æ床ã¯æ¬¡ã®ãã
ã«å®çŸ©ãããã ïŒ100ïŒEh ã¯æ床ãEhã¯æ倧æ¿åºŠïŒDmaxïŒãšæå°æ¿
床ïŒDminïŒã®äžåºŠäžéã®æ¿åºŠ1/2ïŒDmaxïŒ
DminïŒãåŸãã«èŠããé²å éã瀺ãã ãè¡šé¢çŸå(A)ã äžèšåŠæ¹ã®çŸå液äžã§ã塩床20âã«ãããŠ10å
éçŸåããã âã¡ãã«âïœâã¢ããããšããŒã«ïŒããç¡«é ž
å¡©ïŒ 2.5ïœ ã¢ã¹ã³ã«ãã³é ž 10ïœ ã¡ã¿ç¡Œé žãããªãŠã ã»åæ°Žå¡© 35ïœ èåã«ãª ïŒïœ æ°Žãå ããŠ ïŒ ãå éšçŸå(B)ã èµ€è¡å¡©ïŒïœïŒãšããšããµããã³0.0126ïœïŒ
ãå«ãæŒçœæ¶²äžã§çŽ20âã§10åéåŠçãã次ãã§
10åéæ°ŽæŽåŸãäžèšåŠæ¹ã®çŸå液äžã§ã20âã«ã
ããŠ10åéçŸåããã âã¡ãã«âïœâã¢ããããšããŒã«ïŒããç¡«é ž
å¡©ïŒ 2.5ïœ ã¢ã¹ã³ã«ãã³é ž 10ïœ ã¡ã¿ã»ãé žãããªãŠã åæ°Žå¡© 35ïœ èåã«ãª ïŒïœ ããªç¡«é žãœãŒã ïŒïœ æ°Žãå ããŠ ïŒ è¡šé¢æœååã®ããã²ã³åéãšããŠã¯æ²åéãå«
ããã®ã奜ãŸãããå ·äœçã«ã¯å¡©æ²åéãæ²èå
éãå¡©æ²åéãçšããããšãã§ãããããã§æ²å
éã®å«éã¯0.1ã30ã¢ã«ïŒ ãç¹ã«0.5ã10ã¢ã«ïŒ ã®
ç¯å²ã§ããããšã奜ãŸãããå¹³åç²åãµã€ãºã¯å
éšã«ã«ããªæ žãæããããã²ã³åéä¹³å€ããã倧
ããããšã奜ãŸãããç¹ã«0.6ÎŒïœä»¥äžã§ããããš
ã奜ãŸãããç²åãµã€ãºååžã¯çããŠãåºããŠã
ãããã§ããããä¹³å€äžã®ããã²ã³åéç²åã¯ç«
æ¹äœãå «é¢äœã®ãããªèŠåçïŒregularïŒãªçµæ¶
圢ãæãããã®ã§ãããããŸãçç¶ãæ¿ç¶ãªã©ã®
ãããªå€åçïŒirrlgularïŒãªçµæ¶åœ¢ãæãããã®
ã§ãæãã¯ãããã®çµæ¶åœ¢ã®è€å圢ãæãããã®
ã§ããããçš®ã ã®çµæ¶åœ¢ã®ç²åã®æ··åããæã€ãŠ
ãããã æ¬çºæã«çšããããåçä¹³å€ã¯P.Glafkidesè
Chimie et Physiqne PhotographiqueïŒPaul
Montel瀟åã1967幎ïŒãG.F.Duffinè
Photographic Emulsion ChemistryïŒThe Focal
Pressåã1966幎ïŒãV.L.Zelikman et alè
Making and Coating Photographic Emulsion
ïŒThe Focal Pressåã1964幎ïŒãªã©ã«èšèŒãã
ãæ¹æ³ãçšããŠèª¿è£œããããšãã§ãããããªã
ã¡ãé žæ§æ³ãäžæ§æ³ãã¢ã³ã¢ãã¢æ³çã®ãããã§
ãããããŸãå¯æº¶æ§éå¡©ãšå¯æº¶æ§ããã²ã³å¡©ãå
å¿ããã圢åŒãšããŠã¯çåŽæ··åæ³ãåææ··åæ³ã
ãããã®çµåããªã©ã®ããããçšããŠãããã ç²åãéã€ãªã³éå°ã®äžã«ãããŠåœ¢æãããæ¹
æ³ïŒããããéæ··åæ³ïŒãçšããããšãã§ããã
åææ··åæ³ã®äžã€ã®åœ¢åŒãšããŠããã²ã³åéã®ç
æããã液çžäžã®pAgãäžå®ã«ä¿ã€æ¹æ³ãããªã
ã¡ããããã³ã³ãããŒã«ãã»ããã«ãžãšããæ³ã
çšããããšãã§ããã ãã®æ¹æ³ã«ãããšãçµæ¶åœ¢ãèŠåçã§ç²åãµã€
ãºãåäžã«è¿ãããã²ã³åéä¹³å€ãããããã å¥ã ã«åœ¢æããïŒçš®ä»¥äžã®ããã²ã³åéä¹³å€ã
æ··åããŠçšããŠãããã ããã²ã³åéç²å圢æãŸãã¯ç©ççæã®éçšã«
ãããŠãã«ãããŠã å¡©ãäºéå¡©ãéå¡©ãã¿ãªãŠã
å¡©ãã€ãªãžãŠã å¡©ãŸãã¯ãã®é¯å¡©ãããžãŠã å¡©ãŸ
ãã¯ãã®é¯å¡©ãéå¡©ãŸãã¯éé¯å¡©ãªã©ãå ±åãã
ãŠãããã æ¬çºæã®çŸåæ¹æ³ãé©çšããæå ææã«çšãã
å éšã«ã«ããªæ žãæããããã²ã³åéä¹³å€ãšããŠ
ã¯ãééæç®ã§ïŒïœïŒm2ã«ãªãããã«éææ¯æäœ
äžã«å¡åžããè©Šéšçãé²å ããã«ïŒ€â19ïŒã€ãŒã¹
ããã³ã»ã³ããã¯ç€Ÿæå®çŸå液ïŒã§35âãïŒåé
çŸåãããšã0.5以äžã®ééã«ããªæ¿åºŠïŒæ¯æäœ
èªäœã®æ¿åºŠã¯é€ãïŒãäžããåäžã®è©Šéšçãé²å
ããã«ïŒ€â19ã«æ²åã«ãªãŠã ã0.5ïœïŒå ãã
çŸå液ã§35âãïŒåéçŸåãããšã1.0以äžã®é
éã«ããªæ¿åºŠïŒæ¯æäœèªäœã®æ¿åºŠã¯é€ãïŒãäžã
ãä¹³å€ãçšããããã å éšã«ã«ããªæ žãæããããã²ã³åéä¹³å€ã¯å ¬
ç¥ã®çš®ã ã®ææ³ã§èª¿è£œããããšãã§ãããã«ãã
ãæ¹æ³ãšããŠã¯å ãç·ãç §å°ããæ¹æ³ãéå
å€ãéååç©è¥ããã¯å«ç¡«é»ååç©ãªã©ã§ååŠç
ã«ã«ããªæ žãäœãæ¹æ³åã³ä¹³å€ã®è£œé ãäœpAgã
é«PHã®æ¡ä»¶ã§è¡ããªã©ã®æ¹æ³ããããå éšã®ã¿ã«
ã«ããªæ žãäœãã«ã¯äžèšã®æ¹æ³ã§ããã²ã³åéç²
åã®å éšåã³è¡šé¢ãå ±ã«ã«ããããåŸãè¡šé¢ã®ã«
ããªæ žãèµ€è¡å¡©æº¶æ¶²ã§æŒçœããææ³ãããããã
ã奜ãŸããã®ã¯ãŸãäœpAgãé«PHã«ããæ¹æ³åã¯
ååŠçã«ãããæ¹æ³ã§ãã€ãŠã«ããªæ žãæããã³
ã¢ä¹³å€ã調補ãã次ãã§ãã®ã³ã¢ä¹³å€ã®åšå²ã«ã·
ãšã«ä¹³å€ããã¶ããææ³ã§ããããã®ã³ã¢âã·ãš
ã«ä¹³å€ã®èª¿è£œæ³ã¯å ¬ç¥ã§ãããå®æœã«åœã€ãŠã¯äŸ
ãã°ç±³åœç¹èš±ç¬¬3206313å·æ现æžã®èšèŒãåç §ã§
ããã å éšã«ã«ããªæ žãæããããã²ã³åéä¹³å€ã¯è¡š
é¢æœååããã²ã³åéä¹³å€ãããå°ããå¹³åç²å
ãµã€ãºãæãããã®ã§ã0.5ÎŒïœä»¥äžã®å¹³åç²åãµ
ã€ãºãæã€ãã®ã奜ãŸãããç¹ã«0.4ÎŒïœä»¥äžã®å¹³
åç²åãµã€ãºãæã€ãã®ãè¯ãçµæãäžããã äžè¿°ããïŒçš®ã®ããã²ã³åéä¹³å€ã¯æ··åããŠäž
å±€ã«å¡åžããããåã¯åã ã®ä¹³å€ãå¥å±€ãšããŠé
ããŠå¡åžãããã²ã³åéåçæå ææãšãããè¡š
é¢æœååã®ããã²ã³åéä¹³å€ãšå éšã«ãã¶ãæ žã
æããããã²ã³åéä¹³å€ã®äœ¿çšæ¯çã¯ãäžå±€ã«ã
ããšããå¥å±€ã«ãããšãããééæ¯ïŒéæç®ïŒã§
10ïŒïŒãïŒïŒ10ããã奜ãŸããã¯ïŒïŒïŒãïŒïŒïŒ
ã§ãããå¡åžééã¯ä»»æã§ããããæ¬çºæã«ãã€
ãŠã¯ïŒïœïŒm2ãïŒïœïŒm2ãšãã極ããŠå°ãªãéã§
æºè¶³ãã被èŠåãæ床çã®åçç¹æ§ãåŸãããšã
ã§ããã æ¬çºæã®çŸåæ¹æ³ã«çšããçŸå液ã¯äžè¬åŒ
ïŒïŒã§è¡šãããã€ãããŸãŒã«èªå°äœãããã²ã³
åé溶å€ãšããŠå«æããæŽã«äžè¬åŒïŒïŒãŸãã¯
ïŒïŒã§ç€ºãããååç©ã®ïŒçš®ãšãå«æããããš
ãç¹åŸŽãšãããã®ã§ããããã®ç¹ãé€ããŠã¯äžè¬
çãªããã²ã³åéåççŸå液ãšåäžã®çµæã®çŸå
液ãããªãã¡ïŒâããšãã«âïŒâãã©ãŸãªãã³å
ã³ãã®èªå°äœãâã¡ãã«âïœâã¢ããããšããŒ
ã«ããã€ããããã³çã®çŸåäž»è¬ãäžã€ä»¥äžå«ã
ã 氎溶液ãçšãããããä»ã«äºç¡«é žãããªãŠã ã
ã¢ã¹ã³ã«ãã³é žã®åŠãé žåé²æ¢å€ãç¡«é žãããªãŠ
ã ã®åŠãå¡©é¡ãããŠé žãããŠç ãæ°Žé žåãããªãŠ
ã ãçé žãããªãŠã ã第äžãªã³é žãããªãŠã ã®åŠ
ãPH調ç¯å€ãç·©è¡å€ãèåãããªãŠã ãæ²åãã
ãªãŠã ã®åŠãçŸåæå¶å€ããã«ããªã³ãã°ã«ã¿ãŒ
ã«ã¢ã«ãããã®åŠãã¢ã«ããã系硬èå€ãããªãš
ãã¬ã³ã°ãªã³ãŒã«ãããã·ã¬ã³ã°ãªã³ãŒã«ã®åŠã
ææ©æº¶å€ãªã©ã®å ¬ç¥ã®çŸå液添å å€ãå ããããš
ãã§ããã çŸå液ã®PHã«ç¹ã«å¶éã¯ãªãã9.0ã11.5ã®ç¯
å²ã奜ãŸããã æ¬çºæã§ã¯äžèšã®äžè¬åŒïŒïŒã§è¡šãããã€ã
ããŸãŒã«èªå°äœãçŸåé床ãå¢å ãããçå¹ãæ
ããŠããã®ã§ããã²ã³åé溶å€ãšããŠäœ¿çšããã åŒäžZ1ãZ4ã¯åäžã§ãäºãã«ç°ãªã€ãŠããŠãã
ããåã æ°ŽçŽ ååãã¢ã«ãã«åºãããããã·ã¢ã«
ãã«åºåã¯ã¢ã«ã±ãã«åºãè¡šããã Z1ãZ4ã®ã¢ã«ãã«åºãããããã·ã¢ã«ãã«åºå
ã³ã¢ã«ã±ãã«åºãšããŠã¯åã ççŽ æ°ïŒãŸã§ã®ãã®
ã奜ãŸãããäŸãã°ã¡ãã«åºããšãã«åºãããã
ã«åºãïœâãããã«åºãããã«åºãã¢ãã«åºãã€
ãœã¢ãã«åºãããããã·ã¡ãã«åºãããããã·ãš
ãã«åºãããããã·ãããã«åºãããã«åºãã¢ãª
ã«åºãªã©ãæããããšãã§ããã 以äžã«ãã®å ·äœäŸãåæããã ã€ãããŸãŒã« ïŒâã¡ãã«ã€ãããŸãŒã« ïŒã»ïŒâãžã¡ãã«ã€ãããŸãŒã« ïŒâãšãã«âïŒâã¡ãã«ã€ãããŸãŒã« ïŒâã¢ãã«ã€ãããŸãŒã« ïŒâã€ãœã¢ãã«âïŒâã¡ãã«ã€ãããŸãŒã« ïŒã»ïŒâãžã¡ãã«ã€ãããŸãŒã« ïŒâãšãã«ã€ãããŸãŒã« ïŒâãšãã«ã€ãããŸãŒã« ïŒã»ïŒã»ïŒâããªã¡ãã«ã€ãããŸãŒã« ïŒâããããã·ã¡ãã«âïŒâã¡ãã«âïŒâã¡ã
ã«ã€ãããŸãŒã« ïŒâïŒïŒâããããã·ãšãã«ïŒâïŒâã¡ãã«ã€
ãããŸãŒã« ïŒâã¢ãªã«âïŒâã¡ãã«ã€ãããŸãŒã« ïŒâããã«âïŒâã¡ãã«ã€ãããŸãŒã« ããã²ã³åé溶å€ã®æ·»å éã¯çšããååç©ã®çš®
é¡ã«åãããŠé©å®æ°æãããã¹ãæ§è³ªã®ãã®ã§ã
ããäžè¬çã«ã¯çŸå液ïŒããã0.01ïœïŒã10
ïœïŒã§ããããã奜ããã¯0.05ïœïŒãïŒïœïŒ
ã§ããã æ¬çºæã§çšããäžè¬åŒïŒïŒãŸãã¯ïŒïŒã§ç€º
ãããååç©ã¯ãäžèšã®ããã²ã³åé溶å€ãç¹ã«
ããã³å¡©ãããªç¡«é žå¡©ããã³ïŒçŽã¢ã³ã¢ããŠã å¡©
ã«ããç²ç¶æ§ããã³ã«ããªã®æªåãèããæå¶ã
ãããŸãäžèšäžè¬åŒã®ã€ãããŸãŒã«èªå°äœã¯ç²ç¶
æ§ãã«ããªãæªåãããã«çŸåé床ãéããåå
ç©ã§ããããæ¬çºæã®äžè¬åŒïŒïŒãŸãã¯ïŒïŒ
ã§ç€ºãããååç©ã䜵çšããããšã«ãããäžå±€è¯
奜ãªç²ç¶æ§ããã³äœãã«ããªãéæããããšãã§
ããã åŒäžR1ã¯æ°ŽçŽ ååããããåºãã·ã¢ãåºããŸ
ãã¯ããã²ã³ååïŒå¡©çŽ ãèçŽ ãæ²çŽ ïŒãè¡šã
ããR2ã¯æ°ŽçŽ ååãããã²ã³ååïŒå¡©çŽ ãèçŽ ã
æ²çŽ ïŒããŸãã¯ã¢ã«ãã«åºïŒå¥œãŸããã¯äœçŽã¢ã«
ãã«åºãç¹ã«ã¡ãã«åºããããã¯ãšãã«åºïŒãè¡š
ããã äžè¬åŒïŒïŒã§è¡šãããååç©ã®å ·äœäŸãšããŠ
ã¯ã€ã³ããŸãŒã«ãïŒâãããã€ã³ããŸãŒã«ãïŒâ
ãããã€ã³ããŸãŒã«ãïŒâã·ã¢ãã€ã³ããŸãŒã«ã
ïŒâã¯ããã€ã³ããŸãŒã«çãããäžè¬åŒïŒïŒã§
瀺ãããååç©ã®å ·äœäŸãšããŠã¯ãã³ãããªã¢ãŸ
ãŒã«ãïŒâã¡ãã«ãã³ãããªã¢ãŸãŒã«ãïŒâã¯ã
ããã³ãããªã¢ãŸãŒã«ãïŒâããã ãã³ãããªã¢
ãŸãŒã«çãããããããã®äžã§ãïŒâãããã€ã³
ããŸãŒã«åã¯ïŒâã¡ãã«ãã³ãããªã¢ãŸãŒã«ãæ
ã奜ãŸããã ãããååç©ã®æ·»å éã¯ååç©ã®çš®é¡ã«åãã
ãŠå€æŽã§ããããäžè¬ã«çŸå液ïŒåœã0.01ã
10.0ïœïŒã§ããããã奜ãŸããã¯0.02ã5.0ïœïŒ
ã§ããã äžèšã®çŸå液ã§åŠçããéã®çŸåæéãçŸåæž©
床ã¯çšããæå ææã«äŸåãããçŸåæéã¯10ç§
ãïŒåã奜ãŸãããçŸå枩床ã¯20âã45âã®ç¯å²
ã奜ãŸãããå®çãæ°ŽæŽã«ã€ããŠã¯ããã²ã³åé
æå ææãéåžžåŠçããæ¹æ³ããã®ãŸãŸçšããã
ãã æ¬çºæã®çŸåæ¹æ³ã«ããã°ãäžè¬åŒïŒïŒã§è¡š
ãããããã²ã³åé溶å€ãšäžè¬åŒïŒïŒãŸãã¯
ïŒïŒã§ç€ºãããååç©ãå«ãçŸå液ã§åè¿°ãã
æ¬çºæã®ããã²ã³åéåçæå ææãåŠçããã®
ã§ç²ç¶æ§ãæãããšãªãçãçŸåæéã§é«æ床ã®
ãããã«ããªã®å°ãåçç»åãåŸãããšãã§ã
ãã 以äžã«å®æœäŸãæ²ãæ¬çºæãæŽã«è©³çŽ°ã«èª¬æã
ãã å®æœäŸ ïŒ 80ïœã®èåã«ãªãšïŒïœã®æ²åã«ãªãš10ïœã®ãŒã©
ãã³æ°Žæº¶æ¶²ïŒïŒïŒã60âã«ä¿ã¡ãç¡é žé氎溶液
ïŒ100ïœïŒïŒã30åéãããŠæ·»å ããããšã«ãã€
ãŠå¹³åç²åãµã€ãºïŒã»4ÎŒïœã®æ²èåéä¹³å€ãäœ
ããéåžžã®æ¹æ³ã§è±å¡©åŸïŒÃ10-5ã¢ã«ïŒã¢ã«Ag+
ã®ããªç¡«é žãããªãŠã ãšïŒÃ10-5ã¢ã«ïŒã¢ã«Ag+
ã®å¡©åéé žãæ·»å 60âã§75åéååŠçæãããã
ã®ããã«ããŠäœæããä¹³å€ã¯è¡šé¢æœååã§ããä¹³
å€ãšããã 50âã«ä¿ã€ããŒã©ãã³æ°Žæº¶æ¶²ã«èåã«ãªãšæ²å
ã«ãªã®æ··å氎溶液ãšç¡é žé氎溶液ãåæã«50åé
æ·»å ã0.25ÎŒïœã®ïŒã¢ã«ïŒ ã®ãšãŒããå«ãæ²èå
éã³ã¢ç²åãäœè£œããããã«AgNO3ãæ·»å ã
pAgã5.0ã«ãNaOHãå ãPH9.5ã«ãïŒÃ10-5ã¢
ã«ïŒã¢ã«Ag+ã®å¡©åéé žãå ã50â60åéçæã
ãããšã«ãã€ãŠã³ã¢ç²åã®è¡šé¢ããã¶ããããã
ãã«èåã«ãªãšæ²åã«ãªã®æ··å氎溶液ãšç¡é žéæ°Ž
溶液ãåæã«30åéãããŠæ·»å ããããšã«ãã€ãŠ
åã¿0.05ÎŒïœã®ã·ãšã«ä»ããè¡ãªãïŒã·ãšã«ã®ãš
ãŒãã¯ïŒã¢ã«ïŒ ïŒãç²åå šäœã®ãµã€ãºã0.3ÎŒïœ
ïŒç²åå šäœã®ãšãŒãã¯ïŒã¢ã«ïŒ ïŒã®å éšãã¶ãä¹³
å€ã調補ããããã®ããã«ããŠäœæããå éšã«ã
ã¶ãæ žãæããããã²ã³åéç²åãä¹³å€ãšã
ãã ä¹³å€ã®ã¿ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãæ¯æ
äœäžã«ééãšããŠ3.6ïœïŒm2å¡åžãããã®ããã€
ã«ã è©ŠæïŒãšãããäžæ¹ä¹³å€ãšä¹³å€ãééã§
50ïŒ ã¥ã€ã®å²åã§æ··åãæ¯æäœäžã«ééãšããŠ
3.6ïœïŒm2å¡åžãããã®ããã€ã«ã è©ŠæïŒãšããã
åè©Šæã¯1/10ç§ã§å æ¥äžã§é²å ãã次ã®çŸå液ã
çšããŠ35âã§çŸåãããã çŸå液  ïŒâããšãã«âïŒâãã©ãŸãªãã³ 0.5ïœ ãã€ããããã³ 20.0ïœ ãšãã¬ã³ãžã¢ãã³åé ¢é žäºãããªãŠã 2.0ïœ äºç¡«é žã«ãªãŠã 60.0ïœ ããŠé ž 4.0ïœ çé žã«ãªãŠã 20.0ïœ èåãããªãŠã 5.0ïœ ãžãšãã¬ã³ã°ãªã³ãŒã« 30.0ïœ æ°Žãå ã㊠ïŒãšããã NaOHã§PHïŒ10.0ã«ããã çŸå液  çŸå液ã«ããã³ã«ãªãŠã 0.025ã¢ã«ïŒæ·»å
ãããã®ã çŸå液  çŸå液ã«ããã³ã«ãªãŠã 0.025ã¢ã«ïŒåã³
ïŒâãããã€ã³ããŸãŒã«80mgïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ããã³ã«ãªãŠã 0.025ã¢ã«ïŒåã³
ïŒâã¡ãã«ãã³ãããªã¢ãŸãŒã«70mgïŒæ·»å ãã
ãã®ã çŸå液  çŸå液ã«ããã³ã«ãªãŠã 0.025ã¢ã«ïŒåã³
ïŒâãããã€ã³ããŸãŒã«40mgïŒåã³ïŒâã¡ãã«
ãã³ãããªã¢ãŸãŒã«35mgïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ããã³ã«ãªãŠã 0.025ã¢ã«ïŒåã³
ïŒâããšãã«ã»ïŒã¡ã«ã«ããããã©ãŸãŒã«90mgïŒ
æ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.025ã¢
ã«ïŒããã³ïŒâãããã€ã³ããŸãŒã«80mgïŒã
æ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.025ã¢
ã«ïŒåã³ïŒâã¡ãã«ãã³ãããªã¢ãŸãŒã«70mgïŒ
ãæ·»å ãããã®ã
ãè¡šã
ãè¡šã
è¡šã®äžã§ãã¶ãå€ã¯å¯èŠå
ã®æ£å
æ¿åºŠã§æž¬å®ã
ããã®ã§ãããæ床ã¯ãã¶ãå€ãã©ã¹1.0ã®æ¿åºŠ
ãäžããçžå¯Ÿé²å éã®éæ°ã§ãããã€ã«ã è©ŠæïŒ
ãçŸå液ã§35â25ç§çŸåããŠåŸããããã®ãçž
察æ床100ãšããŠè¡šç€ºãããæ倧æ¿åºŠãšã¯é²å é
ãå€ããšããã§ã®å åŠæ¿åºŠã瀺ããç²ç¶ã¯åŸãã
ããã€ã«ã ãèŠèŠçã«è©äŸ¡ãããã®ã§ããïŒã¯è¯
ããïŒã¯èš±å®¹ã§ããã¬ãã«ïŒïŒã¯ç²ç¶æ§ãæªãã
ïŒã¯éåžžã«æªãã¬ãã«ã§ããããšã瀺ãã 第ïŒè¡šããæãããªããã«ãã€ã«ã è©ŠæïŒã¯æ
倧æ¿åºŠïŒïŒïŒããåŸãããªããäžæ¹ãã€ã«ã è©Šæ
ïŒãéåžžã®çŸå液ã§çŸååŠçããŠããã€ã«ã è©Š
æïŒã®å Žåããã¯æ倧æ¿åºŠãé«ããããé«ãæ床
ãåŸããç¹ã«çŸåæéãé·ããããšæ床ãå¢å€§ã
ããããã¯ç±³åœç¹èš±ç¬¬2996382å·ã«èšèŒãããŠã
ããšããã®ãã®ãšåå 容ã®çµæã§ãããããã«å
æ现æžã«èšèŒãããŠããããã²ã³åéã®æº¶å€ãšã
ãŠããã³ã«ãªãŠã ãçšããçŸå液ã§ã¯æ床ã¯å¢
倧ããããã¶ããèããå¢å€§ããŠç²ç¶æ§ãæªåã
ããäžæ¹ãããã³ã«ãªãŠã ãšæ¬çºæã®äžè¬åŒ
ïŒïŒåã¯ïŒïŒã§ç€ºãããååç©ã䜵çšããŠã
ãçŸå液ïŒïŒ€ïŒïŒ¥ã¯æ床ã¯å¢å€§ãããŸãŸã§ãã¶
ããå°ãç²ç¶æ§ã®æªåããªããããããæ¬çºæã®
äžè¬åŒïŒïŒã®ã€ãããŸãŒã«èªå°äœãããã²ã³å
é溶å€ãšããŠçšããããã«äžè¬åŒïŒïŒãŸãã¯äž
è¬åŒïŒïŒã®ååç©ã䜵çšããçŸå液ïŒïŒ¹ã«æ¯
ã¹æ床äžæã®å¹æãå°ãããæ¬çºæã®çŸå液ïŒ
ã¯æŽã«é«ãæ床ãäžããç¹ã§ããããŠãããäž
è¬åŒïŒïŒåã¯ïŒïŒã§è¡šããããååç©ã¯ãã
ã²ã³åéã®ã«ããªé²æ¢å€ãšããŠç¥ãããŠãããã
ãã®ãã¶ãé²æ¢å¹æã¯ãã€ã«ã è©ŠæïŒã®ããã«ä¹³
å€ãšä¹³å€ãæ··åãããã€ã«ã è©Šæã§ç¹ã«ãã¶
ãé²æ¢å¹æã倧ãããªãããšã第ïŒè¡šããæãã
ã§ãããæ¯èŒã®ããã«äœµèšãããã¶ãé²æ¢å€ãšã
ãŠç¥ãããŠããïŒâããšãã«âïŒâã¡ã«ã«ããã
ãã©ãŸãŒã«ãçšããçŸå液ã®å Žåã¯ãã€ã«ã è©Š
æïŒã§ã®ãã¶ãé²æ¢å¹æã¯äžå åã§ããäžè¬åŒ
ïŒïŒåã¯ïŒïŒã§ç€ºãããååç©ã®å Žåãç¹ã«
æå¹ã§ããããšã¯æããã§ããã å®æœäŸ ïŒ å®æœäŸïŒã®ãã€ã«ã è©ŠæïŒã以äžã«ç€ºãåçŸå
液ãçšããŠ35â25ç§ïŒ50ç§ïŒ75ç§ã§çŸååŠçãã
次ãã§å®çãæ°ŽæŽã也ç¥ããã çŸå液  ïŒïŒïŒãžã¡ãã«ïŒããšãã«ïŒã»ãã©ãŸãªãã³
0.6ïœ ãã€ããããã³ 25.0ïœ ãšãã¬ã³ãžã¢ãã³åé ¢é žäºãããªãŠã 2.0ïœ äºç¡«é žã«ãªãŠã 55.0ïœ ããŠé ž 2.0ïœ çé žãããªãŠã 25.0ïœ èåã«ãªãŠã 4.0ïœ æ°Žãå ã㊠ïŒãšãã KOHã§PHïŒ10.2ã«ããã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«ã0.04ã¢
ã«ïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«ã0.02ã¢
ã«ïŒåã³ïŒâãããã€ã³ããŸãŒã«40mgïŒæ·»å
ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«ã0.02ã¢
ã«ïŒåã³ïŒâã¡ãã«ãã³ãããªã¢ãŸãŒã«35mgïŒ
æ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.02ã¢ã«ïŒ
åã³ïŒâãããã€ã³ããŸãŒã«20mgïŒåã³ïŒâ
ã¡ãã«ãã³ãããªã¢ãŸãŒã«20mgïŒæ·»å ããã
ã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.02ã¢ã«ïŒ
åã³ïŒâããšãã«âïŒâã¡ã«ã«ããããã©ãŸãŒ
ã«45mgïŒæ·»å ãããã®ã çŸå液 ïŒ çŸå液ã«ïŒâããããã·ã¡ãã«âïŒâã¡ãã«
ã€ãããŸãŒã«0.02ã¢ã«ïŒåã³ïŒâã¡ãã«ãã³ã
ããªã¢ãŸãŒã«35mgïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¢ãªã«âïŒâã¡ãã«ã€ãããŸãŒ
ã«0.02ã¢ã«ïŒåã³ïŒâãããã€ã³ããŸãŒã«40
mgïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ããã³ã«ãªãŠã ã¢ã«ïŒãæ·»å ãã
ãã®ã çŸå液  çŸå液ã«ããã³ã«ãªãŠã ã¢ã«ïŒåã³ïŒâã¡
ãã«ãã³ãããªã¢ãŸãŒã«35mgïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.02ã¢ã«ïŒ
åã³ã€ã³ããŸãŒã«mgïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.02ã¢ã«ïŒ
åã³ïŒâã·ã¢ãã€ã³ããŸãŒã«mgïŒæ·»å ããã
ã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.02ã¢ã«ïŒ
åã³ïŒâã¯ããã€ã³ããŸãŒã«mgïŒæ·»å ããã
ã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.02ã¢ã«ïŒ
åã³ãã³ãããªã¢ãŸãŒã«mgïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.02ã¢ã«ïŒ
åã³ïŒâã¯ãããã³ãããªã¢ãŸãŒã«mgïŒæ·»å
ãããã®ã
ããã®ã§ãããæ床ã¯ãã¶ãå€ãã©ã¹1.0ã®æ¿åºŠ
ãäžããçžå¯Ÿé²å éã®éæ°ã§ãããã€ã«ã è©ŠæïŒ
ãçŸå液ã§35â25ç§çŸåããŠåŸããããã®ãçž
察æ床100ãšããŠè¡šç€ºãããæ倧æ¿åºŠãšã¯é²å é
ãå€ããšããã§ã®å åŠæ¿åºŠã瀺ããç²ç¶ã¯åŸãã
ããã€ã«ã ãèŠèŠçã«è©äŸ¡ãããã®ã§ããïŒã¯è¯
ããïŒã¯èš±å®¹ã§ããã¬ãã«ïŒïŒã¯ç²ç¶æ§ãæªãã
ïŒã¯éåžžã«æªãã¬ãã«ã§ããããšã瀺ãã 第ïŒè¡šããæãããªããã«ãã€ã«ã è©ŠæïŒã¯æ
倧æ¿åºŠïŒïŒïŒããåŸãããªããäžæ¹ãã€ã«ã è©Šæ
ïŒãéåžžã®çŸå液ã§çŸååŠçããŠããã€ã«ã è©Š
æïŒã®å Žåããã¯æ倧æ¿åºŠãé«ããããé«ãæ床
ãåŸããç¹ã«çŸåæéãé·ããããšæ床ãå¢å€§ã
ããããã¯ç±³åœç¹èš±ç¬¬2996382å·ã«èšèŒãããŠã
ããšããã®ãã®ãšåå 容ã®çµæã§ãããããã«å
æ现æžã«èšèŒãããŠããããã²ã³åéã®æº¶å€ãšã
ãŠããã³ã«ãªãŠã ãçšããçŸå液ã§ã¯æ床ã¯å¢
倧ããããã¶ããèããå¢å€§ããŠç²ç¶æ§ãæªåã
ããäžæ¹ãããã³ã«ãªãŠã ãšæ¬çºæã®äžè¬åŒ
ïŒïŒåã¯ïŒïŒã§ç€ºãããååç©ã䜵çšããŠã
ãçŸå液ïŒïŒ€ïŒïŒ¥ã¯æ床ã¯å¢å€§ãããŸãŸã§ãã¶
ããå°ãç²ç¶æ§ã®æªåããªããããããæ¬çºæã®
äžè¬åŒïŒïŒã®ã€ãããŸãŒã«èªå°äœãããã²ã³å
é溶å€ãšããŠçšããããã«äžè¬åŒïŒïŒãŸãã¯äž
è¬åŒïŒïŒã®ååç©ã䜵çšããçŸå液ïŒïŒ¹ã«æ¯
ã¹æ床äžæã®å¹æãå°ãããæ¬çºæã®çŸå液ïŒ
ã¯æŽã«é«ãæ床ãäžããç¹ã§ããããŠãããäž
è¬åŒïŒïŒåã¯ïŒïŒã§è¡šããããååç©ã¯ãã
ã²ã³åéã®ã«ããªé²æ¢å€ãšããŠç¥ãããŠãããã
ãã®ãã¶ãé²æ¢å¹æã¯ãã€ã«ã è©ŠæïŒã®ããã«ä¹³
å€ãšä¹³å€ãæ··åãããã€ã«ã è©Šæã§ç¹ã«ãã¶
ãé²æ¢å¹æã倧ãããªãããšã第ïŒè¡šããæãã
ã§ãããæ¯èŒã®ããã«äœµèšãããã¶ãé²æ¢å€ãšã
ãŠç¥ãããŠããïŒâããšãã«âïŒâã¡ã«ã«ããã
ãã©ãŸãŒã«ãçšããçŸå液ã®å Žåã¯ãã€ã«ã è©Š
æïŒã§ã®ãã¶ãé²æ¢å¹æã¯äžå åã§ããäžè¬åŒ
ïŒïŒåã¯ïŒïŒã§ç€ºãããååç©ã®å Žåãç¹ã«
æå¹ã§ããããšã¯æããã§ããã å®æœäŸ ïŒ å®æœäŸïŒã®ãã€ã«ã è©ŠæïŒã以äžã«ç€ºãåçŸå
液ãçšããŠ35â25ç§ïŒ50ç§ïŒ75ç§ã§çŸååŠçãã
次ãã§å®çãæ°ŽæŽã也ç¥ããã çŸå液  ïŒïŒïŒãžã¡ãã«ïŒããšãã«ïŒã»ãã©ãŸãªãã³
0.6ïœ ãã€ããããã³ 25.0ïœ ãšãã¬ã³ãžã¢ãã³åé ¢é žäºãããªãŠã 2.0ïœ äºç¡«é žã«ãªãŠã 55.0ïœ ããŠé ž 2.0ïœ çé žãããªãŠã 25.0ïœ èåã«ãªãŠã 4.0ïœ æ°Žãå ã㊠ïŒãšãã KOHã§PHïŒ10.2ã«ããã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«ã0.04ã¢
ã«ïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«ã0.02ã¢
ã«ïŒåã³ïŒâãããã€ã³ããŸãŒã«40mgïŒæ·»å
ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«ã0.02ã¢
ã«ïŒåã³ïŒâã¡ãã«ãã³ãããªã¢ãŸãŒã«35mgïŒ
æ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.02ã¢ã«ïŒ
åã³ïŒâãããã€ã³ããŸãŒã«20mgïŒåã³ïŒâ
ã¡ãã«ãã³ãããªã¢ãŸãŒã«20mgïŒæ·»å ããã
ã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.02ã¢ã«ïŒ
åã³ïŒâããšãã«âïŒâã¡ã«ã«ããããã©ãŸãŒ
ã«45mgïŒæ·»å ãããã®ã çŸå液 ïŒ çŸå液ã«ïŒâããããã·ã¡ãã«âïŒâã¡ãã«
ã€ãããŸãŒã«0.02ã¢ã«ïŒåã³ïŒâã¡ãã«ãã³ã
ããªã¢ãŸãŒã«35mgïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¢ãªã«âïŒâã¡ãã«ã€ãããŸãŒ
ã«0.02ã¢ã«ïŒåã³ïŒâãããã€ã³ããŸãŒã«40
mgïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ããã³ã«ãªãŠã ã¢ã«ïŒãæ·»å ãã
ãã®ã çŸå液  çŸå液ã«ããã³ã«ãªãŠã ã¢ã«ïŒåã³ïŒâã¡
ãã«ãã³ãããªã¢ãŸãŒã«35mgïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.02ã¢ã«ïŒ
åã³ã€ã³ããŸãŒã«mgïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.02ã¢ã«ïŒ
åã³ïŒâã·ã¢ãã€ã³ããŸãŒã«mgïŒæ·»å ããã
ã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.02ã¢ã«ïŒ
åã³ïŒâã¯ããã€ã³ããŸãŒã«mgïŒæ·»å ããã
ã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.02ã¢ã«ïŒ
åã³ãã³ãããªã¢ãŸãŒã«mgïŒæ·»å ãããã®ã çŸå液  çŸå液ã«ïŒâã¡ãã«ã€ãããŸãŒã«0.02ã¢ã«ïŒ
åã³ïŒâã¯ãããã³ãããªã¢ãŸãŒã«mgïŒæ·»å
ãããã®ã
ãè¡šã
ãè¡šã
ãè¡šã
ãã®ç¬¬ïŒè¡šã§ç€ºããã¶ãïŒæ床ïŒæ倧æ¿åºŠïŒç²
ç¶ã¯ç¬¬ïŒè¡šã®å Žåãšåãæå³ã§ãããæ¯èŒå®éšã«
çšããçŸå液ã¯çŸå液ã«èŒã¹ãŠé«ãæ床ãšé«
ãæ倧æ¿åºŠãåŸããããããããã¶ãå€ãå¢å
ããç²ç¶æ§ãè¥å¹²æªåããã ãããæ¬çºæã®ããã«äžè¬åŒïŒïŒåã¯ïŒïŒ
ã§ç€ºãããååç©ã䜵çšããçŸå液ïŒïŒªïŒïŒ«ïŒ
ïŒïŒïŒ®ïŒïŒ±ïŒïŒ²ïŒïŒ³ïŒïŒŽïŒïŒµã®å Žåã¯æ床ãšæ倧
æ¿åºŠãç¶æããªãããã¶ããèããæžå°ãããŠå¹
æçã§ãããæ¯èŒã®ããã«ãã¶ãé²æ¢å€ãšããŠç¥
ãããŠããïŒâããšãã«âïŒâã¡ã«ã«ããããã©
ãŸãŒã«ãçšããçŸå液ã®å Žåã¯ãã€ã«ã è©ŠæïŒ
ã§ã®ãã¶ãé²æ¢å¹æã¯äžå åã§ããæ¬çºæã®äžè¬
åŒïŒïŒïŒïŒã®ååç©ã®å Žåãç¹ã«æå¹ã§ãã
ããšã¯æããã§ããã ãŸããæ¬çºæã®ã€ãããŸãŒã«èªå°äœä»¥å€ã®ãã
ã²ã³åé溶å€ãçšããçŸå液ïŒïŒ°ã¯ãã¶ããé«
ããæ床ãäœãããã€ç²ç¶æ§ãæ¬çºæã®çŸå液ã
ãæªãã€ãã æ¬çºæã®çŸåæ¹æ³ãé©çšããæå ææã«çšãã
è¡šé¢æœååããã²ã³åéä¹³å€ã¯åžžæ³ã«ãã€ãŠååŠ
å¢æãããããšãã§ãããååŠå¢æå€ã«ã¯ããšã
ã°ãç±³åœç¹èš±2399083å·ãå2540085å·ãå
2597856å·ãå2597915å·ã«ç€ºããããããªå¡©åé
é žå¡©ãäžå¡©åéãªã©éååç©ãç±³åœç¹èš±2448060
å·ãå2540086å·ãå2566245å·ãå2566263å·ã
å2598079å·ã«ç€ºããããããªçœéããã©ãžãŠã ã
ã€ãªãžãŠã ãããžãŠã ãã«ãããŠã ã®ãããªè²Žé
å±ã®å¡©é¡ãç±³åœç¹èš±1574944å·ãå2410689å·ãå
3189458å·ãå3501313å·ãçã«èšèŒãããŠããã
ããªéå¡©ãšåå¿ããŠç¡«åéã圢æããã€ãªãŠåå
ç©ãç±³åœç¹èš±2487850å·ãå2518698å·ãå
2521925å·ãå2521926å·ãå2694637å·ãå
2983610å·ãå3201254å·ã«èšèŒãããŠãããããª
第äžã¹ãºå¡©ãã¢ãã³é¡ããã®ä»ã®éå æ§ç©è³ªãªã©
ããããããã äžæ¹å éšãã¶ãæ žãæããããã²ã³åéä¹³å€ã¯
è¡šé¢æœååä¹³å€ãšåæ§ãªæ¹æ³ãçšããŠååŠå¢æã
ãŠããããååŠå¢æããªãæ¹ã奜ãŸããã æ¬çºæã§çšããååçä¹³å€ã«äœ¿çšãã芪氎æ§ã³
ãã€ãã«ã¯äŸãã°ããŒã©ãã³ãã³ãã€ãç¶ã¢ã«ã
ãã³ãã«ãŒã€ã³ãã«ã«ããã·ã¡ãã«ã»ã«ããŒãºã
ããããã·ãšãã«ã»ã«ããŒãºçã®ã»ã«ããŒãºèªå°
äœãå¯å€©ãã¢ã«ã®ã³é žãœãŒãã柱ç²èªå°äœãªã©ã®
ç³èªå°äœãåæ芪氎æ§ã³ãã€ããäŸãã°ãããªã
ãã«ã¢ã«ã³ãŒã«ãããªïŒ®âããã«ãããªãã³ãã
ãªã¢ã¯ãªã«é žå ±éåäœãããªã¢ã¯ãªã«ã¢ãããŸã
ã¯ãããã®èªå°äœãéšåå æ°Žå解ç©çããããã
ããå¿ èŠã«å¿ããŠããããã®ã³ãã€ãã®äºã€ä»¥äž
ã®çžæº¶æ§æ··åç©ã䜿çšããããã®äžã§æãäžè¬ç
ã«çšããããã®ã¯ãŒã©ãã³ã§ãããŒã©ãã³ã¯äžéš
ãŸãã¯å šéšãåæé«ååç©è³ªã§çœ®ããããããšã
ã§ããã»ãããããããŒã©ãã³èªå°äœã䜿çšããŠ
ãããã æ¬çºæã«çšããããåçä¹³å€ã¯ãã¡ãã³è²çŽ é¡
ãã®ä»ã«ãã€ãŠåå å¢æãããŠããããããã®å¢
æè²çŽ ã¯åç¬ã«çšããŠããããããããã®çµåã
ãçšããŠããããå¢æè²çŽ ã®çµåãã¯ç¹ã«åŒ·è²å¢
æã®ç®çã§ãã°ãã°çšãããããå¢æè²çŽ ãšãšã
ã«ãããèªèº«åå å¢æäœçšããããªãè²çŽ ããã
ã¯å¯èŠå ãå®è³ªçã«åžåããªãç©è³ªã§ãã€ãŠã匷
è²å¢æã瀺ãç©è³ªãä¹³å€äžã«å«ãã§ãããã æçšãªå¢æè²çŽ ã匷è²å¢æã瀺ãè²çŽ ã®çµåã
åã³åŒ·è²å¢æã瀺ãç©è³ªã¯ãªãµãŒãã»ãã¹ã¯ããŒ
ãžã€ïŒResearch DisclosureïŒ176å·»17643ïŒ1978
幎12æçºè¡ïŒç¬¬23é ã®ïŒªé ã«èšèŒãããŠããã æ¬çºæã«çšããããåçä¹³å€ã«ã¯ãæå ææã®
補é å·¥çšãä¿åäžãããã¯åçåŠçäžã®ã«ããªã
é²æ¢ããããã¯åçæ§èœãå®å®åãããç®çã§ã
çš®ã ã®ååç©ãå«æãããããšãã§ãããããªã
ã¡ã¢ãŸãŒã«é¡ããšãã°ãã³ãŸãã¢ãŸãªãŠã å¡©ãã
ãããã³ãºã€ãããŸãŒã«é¡ãã¯ãããã³ãºã€ãã
ãŸãŒã«é¡ãããã¢ãã³ãºã€ãããŸãŒã«é¡ãã¡ã«ã«
ãããã¢ãŸãŒã«é¡ãã¡ã«ã«ãããã³ãŸãã¢ãŸãŒã«
é¡ãã¡ã«ã«ãããã³ãºã€ãããŸãŒã«é¡ãã¡ã«ã«ã
ããã¢ãžã¢ãŸãŒã«é¡ãããããã³ãŸããªã¢ãŸãŒã«
é¡ãã¡ã«ã«ããããã©ãŸãŒã«é¡ïŒç¹ã«ïŒâããšã
ã«âïŒâã¡ã«ã«ããããã©ãŸãŒã«ïŒãªã©ïŒã¡ã«ã«
ããããªããžã³é¡ïŒã¡ã«ã«ããããªã¢ãžã³é¡ïŒã
ãšãã°ãªããµãŸãªã³ããªã³ã®ãããªããªã±ãåå
ç©ïŒã¢ã¶ã€ã³ãã³é¡ãããšãã°ããªã¢ã¶ã€ã³ãã³
é¡ãããã©ã¢ã¶ã€ã³ãã³é¡ïŒç¹ã«ïŒâããããã·
眮æïŒïŒïŒïŒïŒ3aïŒïŒïŒããã©ã¶ã€ã³ãã³é¡ïŒã
ãã³ã¿ã¢ã¶ã€ã³ãã³é¡ãªã©ïŒãã³ãŒã³ããªã¹ã«ã
ãªã³é žããã³ãŒã³ã¹ã«ãã€ã³é žããã³ãŒã³ã¹ã«ã
ãªã³é žã¢ããçã®ãããªã«ããªé²æ¢å€ãŸãã¯å®å®
å€ãšããŠç¥ãããå€ãã®ååç©ãå ããããšãã§
ããã æ¬çºæã«çšããããåçä¹³å€ã«ã¯ç¡æ©ãŸãã¯æ
æ©ã®ç¡¬èå€ãå«æããŠãããäŸãã°ã¯ãã å¡©ïŒã¯
ãã æã°ããé ¢é žã¯ãã ãªã©ïŒãã¢ã«ãããé¡
ïŒãã«ã ã¢ã«ããããã°ãªãªããµãŒã«ãã°ã«ã¿ãŒ
ã«ã¢ã«ããããªã©ïŒãâã¡ãããŒã«ååç©ïŒãž
ã¡ãããŒã«å°¿çŽ ãã¡ãããŒã«ãžã¡ãã«ããã³ãã€
ã³ãªã©ïŒããžãªããµã³èªå°äœïŒïŒïŒïŒâãžããã
ãã·ãžãªããµã³ãªã©ïŒã掻æ§ããã«ååç©ïŒïŒïŒ
ïŒïŒïŒâããªã¢ã¯ãªãã€ã«âãããµãããââ
ããªã¢ãžã³ãïŒïŒïŒâããã«ã¹ã«ããã«âïŒâã
ããããŒã«ãªã©ïŒã掻æ§ããã²ã³ååç©ïŒïŒïŒïŒ
âãžã¯ãã«âïŒâããããã·âïœâããªã¢ãžã³ãª
ã©ïŒãã ã³ããã²ã³é žé¡ïŒã ã³ã¯ãã«é žãã ã³ã
ãšããã·ã¯ãã«é žãªã©ïŒããªã©ãåç¬ãŸãã¯çµå
ãããŠçšããããšãã§ããã æ¬çºæã«çšããããåçä¹³å€ã«ã¯å¡åžå©å€ã垯
é»é²æ¢ãã¹ããªæ§æ¹è¯ãä¹³ååæ£ãæ¥çé²æ¢ãã
ã³åçç¹æ§æ¹è¯ïŒããšãã°çŸåä¿é²ã硬調åãå¢
æïŒãªã©çš®ã ã®ç®çã§çš®ã ã®çé¢æŽ»æ§å€ãå«ãã§
ãããã ããšãã°ãµããã³ïŒã¹ããã€ãç³»ïŒãã¢ã«ãã¬
ã³ãªããµã€ãèªå°äœïŒäŸãã°ããªãšãã¬ã³ã°ãªã³
ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ïŒããªãããã¬ã³
ã°ãªã³ãŒã«çž®åç©ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ãšãŒãã«é¡ãŸãã¯ããªãšãã¬ã³ã°ãªã³ãŒã«ã¢
ã«ãã«ã¢ãªãŒã«ãšãŒãã«é¡ãããªãšãã¬ã³ã°ãªã³
ãŒã«ãšã¹ãã«é¡ãããªãšãã¬ã³ã°ãªã³ãŒã«ãœã«ã
ã¿ã³ãšã¹ãã«é¡ãããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ã¢ãã³ãŸãã¯ã¢ããé¡ãã·ãªã³ãŒã³ã®ããªãš
ãã¬ã³ãªããµã€ãä»å ç©é¡ïŒãã°ãªã·ããŒã«èªå°
äœïŒããšãã°ã¢ã«ã±ãã«ã³ãã¯é žããªã°ãªã»ãª
ããã¢ã«ãã«ããšããŒã«ããªã°ãªã»ãªãïŒãå€äŸ¡
ã¢ã«ã³ãŒã«ã®èèªé žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«ãš
ã¹ãã«é¡ãªã©ã®éã€ãªã³æ§çé¢æŽ»æ§å€ïŒã¢ã«ãã«
ã«ã«ãã³é žå¡©ãã¢ã«ãã«åºã¹ã«ããªã³é žå¡©ãã¢ã«
ãã«ãã³ãŒã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ããã¿ã¬
ã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ãã¢
ã«ãã«ãªã³é žãšã¹ãã«é¡ãâã¢ã·ã«ââã¢ã«
ãã«ã¿ãŠãªã³é¡ãã¹ã«ãã³ãã¯é žãšã¹ãã«é¡ãã¹
ã«ãã¢ã«ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšã
ã«ãšãŒãã«é¡ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãªã³
é žãšã¹ãã«é¡ãªã©ã®ãããªãã«ã«ããã·åºãã¹ã«
ãåºããã¹ãåºãç¡«é žãšã¹ãã«åºãçé žãšã¹ãã«
åºçã®é žæ§åºãå«ãã¢ããªã³çé¢æŽ»æ§å€ïŒã¢ãã
é žé¡ãã¢ããã¢ã«ãã«ã¹ã«ãã³é žé¡ãã¢ããã¢ã«
ãã«ç¡«é žãŸãã¯çé žãšã¹ãã«é¡ãã¢ã«ãã«ãã¿ã€
ã³é¡ãã¢ãã³ãªãã·ãé¡ãªã©ã®äž¡æ§çé¢æŽ»æ§å€ïŒ
ã¢ã«ãã«ã¢ãã³å¡©é¡ãèèªæãããã¯è³éŠæ第ïŒ
çŽã¢ã³ã¢ããŠã å¡©é¡ãããªãžãŠã ãã€ãããŸãªãŠ
ã ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãããã³
èèªæãŸãã¯è€çŽ ç°ãå«ããã¹ãããŠã ãŸãã¯ã¹
ã«ãããŠã å¡©é¡ãªã©ã®ã«ããªã³çé¢æŽ»æ§å€ãçšã
ãããšãã§ããã ãŸãåçæå ææã®åž¯é»é²æ¢ã®ããã«ã¯ãäŸã
ã°ç±³åœç¹èš±ç¬¬2882157å·ãå2972535å·ãå
3062785å·ãå3262807å·ãå3514291å·ãå
3615531å·ãå3753716å·ãå3938999å·ãå
3988158å·ãå4118231å·ãå4126467å·ãå
4200465å·ãè±åœç¹èš±ç¬¬1235075å·ãå1155977å·ã
å1461438å·ãå1352975å·ãå1484868å·ãå
1535685å·çã«èšèŒãããŠãããããªããªããŒé¡
ããäŸãã°ç±³åœç¹èš±ç¬¬4070189å·ãå4147550å·ç
ã«èšãããŠãããããªã©ããã¯ã¹é¡ãŸãã¯ç±³åœç¹
蚱第3062700å·ãå3245833å·ãå3525621å·ã«èš
èŒãããŠãããããªé žåäºéãåå°äœãã³ãã€ã
ã·ãªã«çãæ§æå±€ã®äžã«å«æãããããšãæå¹ã§
ããã æ¬çºæã®çŸåæ¹æ³ãé©çšããåçæå ææã¯å
è¿°ã®åçä¹³å€å±€åã³ãã®ä»ã®å±€ãåçæå ææã«
éåžžçšãããããã©ã¹ããã¯ãã€ã«ã ãçŽãåžãª
ã©ã®å¯ææ§æ¯æäœãŸãã¯ã¬ã©ã¹ãé¶åšãéå±ãªã©
ã®åæ§ã®æ¯æäœã«å¡åžãããã®ã§ãããå¯ææ§æ¯
æäœãšããŠæçšãªãã®ã¯ãç¡é žã»ã«ããŒã¹ãé ¢é ž
ã»ã«ããŒã¹ãé ¢é žé ªé žã»ã«ããŒã¹ãããªã¹ãã¬
ã³ãããªå¡©åããã«ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒ
ããããªã«ãŒãããŒãçã®ååæãŸãã¯åæé«å
åããæããã€ã«ã ããã©ã€ã¿å±€ãŸãã¯Î±âãªã¬
ãã€ã³ããªããŒïŒäŸãã°ããªãšãã¬ã³ãããªãã
ãã¬ã³ããšãã¬ã³ïŒããã³å ±éåäœïŒçãå¡åžãŸ
ãã¯ã©ãããŒãããçŽçã§ãããæ¯æäœã¯ææã
é¡æãçšããŠçè²ãããŠããŠããããé®å ã®ç®ç
ã§é»è²ã«ããŠãããããããã®æ¯æäœã®è¡šé¢ã¯äž
è¬ã«ãåçä¹³å€å±€çãšã®æ¥çãããããããã«äž
éåŠçããããæ¯æäœè¡šé¢ã¯äžå¡åŠçã«åãŸãã¯
åŸã«ãã³ããæŸé»ã玫å€ç·ç §å°ãç«çåŠççãæœ
ããŠãããã ãã®ä»ãæ¬çºæã«çšããåçæå ææã«ã¯çš®ã
ã®å ¬ç¥ã®çŽ æãæ·»å å€ãçšããŠãããããã«ã€ã
ãŠã¯Research DisclosureèªèšèŒNo.17643ãåè
ã«ããããšãã§ããã
ç¶ã¯ç¬¬ïŒè¡šã®å Žåãšåãæå³ã§ãããæ¯èŒå®éšã«
çšããçŸå液ã¯çŸå液ã«èŒã¹ãŠé«ãæ床ãšé«
ãæ倧æ¿åºŠãåŸããããããããã¶ãå€ãå¢å
ããç²ç¶æ§ãè¥å¹²æªåããã ãããæ¬çºæã®ããã«äžè¬åŒïŒïŒåã¯ïŒïŒ
ã§ç€ºãããååç©ã䜵çšããçŸå液ïŒïŒªïŒïŒ«ïŒ
ïŒïŒïŒ®ïŒïŒ±ïŒïŒ²ïŒïŒ³ïŒïŒŽïŒïŒµã®å Žåã¯æ床ãšæ倧
æ¿åºŠãç¶æããªãããã¶ããèããæžå°ãããŠå¹
æçã§ãããæ¯èŒã®ããã«ãã¶ãé²æ¢å€ãšããŠç¥
ãããŠããïŒâããšãã«âïŒâã¡ã«ã«ããããã©
ãŸãŒã«ãçšããçŸå液ã®å Žåã¯ãã€ã«ã è©ŠæïŒ
ã§ã®ãã¶ãé²æ¢å¹æã¯äžå åã§ããæ¬çºæã®äžè¬
åŒïŒïŒïŒïŒã®ååç©ã®å Žåãç¹ã«æå¹ã§ãã
ããšã¯æããã§ããã ãŸããæ¬çºæã®ã€ãããŸãŒã«èªå°äœä»¥å€ã®ãã
ã²ã³åé溶å€ãçšããçŸå液ïŒïŒ°ã¯ãã¶ããé«
ããæ床ãäœãããã€ç²ç¶æ§ãæ¬çºæã®çŸå液ã
ãæªãã€ãã æ¬çºæã®çŸåæ¹æ³ãé©çšããæå ææã«çšãã
è¡šé¢æœååããã²ã³åéä¹³å€ã¯åžžæ³ã«ãã€ãŠååŠ
å¢æãããããšãã§ãããååŠå¢æå€ã«ã¯ããšã
ã°ãç±³åœç¹èš±2399083å·ãå2540085å·ãå
2597856å·ãå2597915å·ã«ç€ºããããããªå¡©åé
é žå¡©ãäžå¡©åéãªã©éååç©ãç±³åœç¹èš±2448060
å·ãå2540086å·ãå2566245å·ãå2566263å·ã
å2598079å·ã«ç€ºããããããªçœéããã©ãžãŠã ã
ã€ãªãžãŠã ãããžãŠã ãã«ãããŠã ã®ãããªè²Žé
å±ã®å¡©é¡ãç±³åœç¹èš±1574944å·ãå2410689å·ãå
3189458å·ãå3501313å·ãçã«èšèŒãããŠããã
ããªéå¡©ãšåå¿ããŠç¡«åéã圢æããã€ãªãŠåå
ç©ãç±³åœç¹èš±2487850å·ãå2518698å·ãå
2521925å·ãå2521926å·ãå2694637å·ãå
2983610å·ãå3201254å·ã«èšèŒãããŠãããããª
第äžã¹ãºå¡©ãã¢ãã³é¡ããã®ä»ã®éå æ§ç©è³ªãªã©
ããããããã äžæ¹å éšãã¶ãæ žãæããããã²ã³åéä¹³å€ã¯
è¡šé¢æœååä¹³å€ãšåæ§ãªæ¹æ³ãçšããŠååŠå¢æã
ãŠããããååŠå¢æããªãæ¹ã奜ãŸããã æ¬çºæã§çšããååçä¹³å€ã«äœ¿çšãã芪氎æ§ã³
ãã€ãã«ã¯äŸãã°ããŒã©ãã³ãã³ãã€ãç¶ã¢ã«ã
ãã³ãã«ãŒã€ã³ãã«ã«ããã·ã¡ãã«ã»ã«ããŒãºã
ããããã·ãšãã«ã»ã«ããŒãºçã®ã»ã«ããŒãºèªå°
äœãå¯å€©ãã¢ã«ã®ã³é žãœãŒãã柱ç²èªå°äœãªã©ã®
ç³èªå°äœãåæ芪氎æ§ã³ãã€ããäŸãã°ãããªã
ãã«ã¢ã«ã³ãŒã«ãããªïŒ®âããã«ãããªãã³ãã
ãªã¢ã¯ãªã«é žå ±éåäœãããªã¢ã¯ãªã«ã¢ãããŸã
ã¯ãããã®èªå°äœãéšåå æ°Žå解ç©çããããã
ããå¿ èŠã«å¿ããŠããããã®ã³ãã€ãã®äºã€ä»¥äž
ã®çžæº¶æ§æ··åç©ã䜿çšããããã®äžã§æãäžè¬ç
ã«çšããããã®ã¯ãŒã©ãã³ã§ãããŒã©ãã³ã¯äžéš
ãŸãã¯å šéšãåæé«ååç©è³ªã§çœ®ããããããšã
ã§ããã»ãããããããŒã©ãã³èªå°äœã䜿çšããŠ
ãããã æ¬çºæã«çšããããåçä¹³å€ã¯ãã¡ãã³è²çŽ é¡
ãã®ä»ã«ãã€ãŠåå å¢æãããŠããããããã®å¢
æè²çŽ ã¯åç¬ã«çšããŠããããããããã®çµåã
ãçšããŠããããå¢æè²çŽ ã®çµåãã¯ç¹ã«åŒ·è²å¢
æã®ç®çã§ãã°ãã°çšãããããå¢æè²çŽ ãšãšã
ã«ãããèªèº«åå å¢æäœçšããããªãè²çŽ ããã
ã¯å¯èŠå ãå®è³ªçã«åžåããªãç©è³ªã§ãã€ãŠã匷
è²å¢æã瀺ãç©è³ªãä¹³å€äžã«å«ãã§ãããã æçšãªå¢æè²çŽ ã匷è²å¢æã瀺ãè²çŽ ã®çµåã
åã³åŒ·è²å¢æã瀺ãç©è³ªã¯ãªãµãŒãã»ãã¹ã¯ããŒ
ãžã€ïŒResearch DisclosureïŒ176å·»17643ïŒ1978
幎12æçºè¡ïŒç¬¬23é ã®ïŒªé ã«èšèŒãããŠããã æ¬çºæã«çšããããåçä¹³å€ã«ã¯ãæå ææã®
補é å·¥çšãä¿åäžãããã¯åçåŠçäžã®ã«ããªã
é²æ¢ããããã¯åçæ§èœãå®å®åãããç®çã§ã
çš®ã ã®ååç©ãå«æãããããšãã§ãããããªã
ã¡ã¢ãŸãŒã«é¡ããšãã°ãã³ãŸãã¢ãŸãªãŠã å¡©ãã
ãããã³ãºã€ãããŸãŒã«é¡ãã¯ãããã³ãºã€ãã
ãŸãŒã«é¡ãããã¢ãã³ãºã€ãããŸãŒã«é¡ãã¡ã«ã«
ãããã¢ãŸãŒã«é¡ãã¡ã«ã«ãããã³ãŸãã¢ãŸãŒã«
é¡ãã¡ã«ã«ãããã³ãºã€ãããŸãŒã«é¡ãã¡ã«ã«ã
ããã¢ãžã¢ãŸãŒã«é¡ãããããã³ãŸããªã¢ãŸãŒã«
é¡ãã¡ã«ã«ããããã©ãŸãŒã«é¡ïŒç¹ã«ïŒâããšã
ã«âïŒâã¡ã«ã«ããããã©ãŸãŒã«ïŒãªã©ïŒã¡ã«ã«
ããããªããžã³é¡ïŒã¡ã«ã«ããããªã¢ãžã³é¡ïŒã
ãšãã°ãªããµãŸãªã³ããªã³ã®ãããªããªã±ãåå
ç©ïŒã¢ã¶ã€ã³ãã³é¡ãããšãã°ããªã¢ã¶ã€ã³ãã³
é¡ãããã©ã¢ã¶ã€ã³ãã³é¡ïŒç¹ã«ïŒâããããã·
眮æïŒïŒïŒïŒïŒ3aïŒïŒïŒããã©ã¶ã€ã³ãã³é¡ïŒã
ãã³ã¿ã¢ã¶ã€ã³ãã³é¡ãªã©ïŒãã³ãŒã³ããªã¹ã«ã
ãªã³é žããã³ãŒã³ã¹ã«ãã€ã³é žããã³ãŒã³ã¹ã«ã
ãªã³é žã¢ããçã®ãããªã«ããªé²æ¢å€ãŸãã¯å®å®
å€ãšããŠç¥ãããå€ãã®ååç©ãå ããããšãã§
ããã æ¬çºæã«çšããããåçä¹³å€ã«ã¯ç¡æ©ãŸãã¯æ
æ©ã®ç¡¬èå€ãå«æããŠãããäŸãã°ã¯ãã å¡©ïŒã¯
ãã æã°ããé ¢é žã¯ãã ãªã©ïŒãã¢ã«ãããé¡
ïŒãã«ã ã¢ã«ããããã°ãªãªããµãŒã«ãã°ã«ã¿ãŒ
ã«ã¢ã«ããããªã©ïŒãâã¡ãããŒã«ååç©ïŒãž
ã¡ãããŒã«å°¿çŽ ãã¡ãããŒã«ãžã¡ãã«ããã³ãã€
ã³ãªã©ïŒããžãªããµã³èªå°äœïŒïŒïŒïŒâãžããã
ãã·ãžãªããµã³ãªã©ïŒã掻æ§ããã«ååç©ïŒïŒïŒ
ïŒïŒïŒâããªã¢ã¯ãªãã€ã«âãããµãããââ
ããªã¢ãžã³ãïŒïŒïŒâããã«ã¹ã«ããã«âïŒâã
ããããŒã«ãªã©ïŒã掻æ§ããã²ã³ååç©ïŒïŒïŒïŒ
âãžã¯ãã«âïŒâããããã·âïœâããªã¢ãžã³ãª
ã©ïŒãã ã³ããã²ã³é žé¡ïŒã ã³ã¯ãã«é žãã ã³ã
ãšããã·ã¯ãã«é žãªã©ïŒããªã©ãåç¬ãŸãã¯çµå
ãããŠçšããããšãã§ããã æ¬çºæã«çšããããåçä¹³å€ã«ã¯å¡åžå©å€ã垯
é»é²æ¢ãã¹ããªæ§æ¹è¯ãä¹³ååæ£ãæ¥çé²æ¢ãã
ã³åçç¹æ§æ¹è¯ïŒããšãã°çŸåä¿é²ã硬調åãå¢
æïŒãªã©çš®ã ã®ç®çã§çš®ã ã®çé¢æŽ»æ§å€ãå«ãã§
ãããã ããšãã°ãµããã³ïŒã¹ããã€ãç³»ïŒãã¢ã«ãã¬
ã³ãªããµã€ãèªå°äœïŒäŸãã°ããªãšãã¬ã³ã°ãªã³
ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ïŒããªãããã¬ã³
ã°ãªã³ãŒã«çž®åç©ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ãšãŒãã«é¡ãŸãã¯ããªãšãã¬ã³ã°ãªã³ãŒã«ã¢
ã«ãã«ã¢ãªãŒã«ãšãŒãã«é¡ãããªãšãã¬ã³ã°ãªã³
ãŒã«ãšã¹ãã«é¡ãããªãšãã¬ã³ã°ãªã³ãŒã«ãœã«ã
ã¿ã³ãšã¹ãã«é¡ãããªã¢ã«ãã¬ã³ã°ãªã³ãŒã«ã¢ã«
ãã«ã¢ãã³ãŸãã¯ã¢ããé¡ãã·ãªã³ãŒã³ã®ããªãš
ãã¬ã³ãªããµã€ãä»å ç©é¡ïŒãã°ãªã·ããŒã«èªå°
äœïŒããšãã°ã¢ã«ã±ãã«ã³ãã¯é žããªã°ãªã»ãª
ããã¢ã«ãã«ããšããŒã«ããªã°ãªã»ãªãïŒãå€äŸ¡
ã¢ã«ã³ãŒã«ã®èèªé žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«ãš
ã¹ãã«é¡ãªã©ã®éã€ãªã³æ§çé¢æŽ»æ§å€ïŒã¢ã«ãã«
ã«ã«ãã³é žå¡©ãã¢ã«ãã«åºã¹ã«ããªã³é žå¡©ãã¢ã«
ãã«ãã³ãŒã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ããã¿ã¬
ã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ãã¢
ã«ãã«ãªã³é žãšã¹ãã«é¡ãâã¢ã·ã«ââã¢ã«
ãã«ã¿ãŠãªã³é¡ãã¹ã«ãã³ãã¯é žãšã¹ãã«é¡ãã¹
ã«ãã¢ã«ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšã
ã«ãšãŒãã«é¡ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãªã³
é žãšã¹ãã«é¡ãªã©ã®ãããªãã«ã«ããã·åºãã¹ã«
ãåºããã¹ãåºãç¡«é žãšã¹ãã«åºãçé žãšã¹ãã«
åºçã®é žæ§åºãå«ãã¢ããªã³çé¢æŽ»æ§å€ïŒã¢ãã
é žé¡ãã¢ããã¢ã«ãã«ã¹ã«ãã³é žé¡ãã¢ããã¢ã«
ãã«ç¡«é žãŸãã¯çé žãšã¹ãã«é¡ãã¢ã«ãã«ãã¿ã€
ã³é¡ãã¢ãã³ãªãã·ãé¡ãªã©ã®äž¡æ§çé¢æŽ»æ§å€ïŒ
ã¢ã«ãã«ã¢ãã³å¡©é¡ãèèªæãããã¯è³éŠæ第ïŒ
çŽã¢ã³ã¢ããŠã å¡©é¡ãããªãžãŠã ãã€ãããŸãªãŠ
ã ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãããã³
èèªæãŸãã¯è€çŽ ç°ãå«ããã¹ãããŠã ãŸãã¯ã¹
ã«ãããŠã å¡©é¡ãªã©ã®ã«ããªã³çé¢æŽ»æ§å€ãçšã
ãããšãã§ããã ãŸãåçæå ææã®åž¯é»é²æ¢ã®ããã«ã¯ãäŸã
ã°ç±³åœç¹èš±ç¬¬2882157å·ãå2972535å·ãå
3062785å·ãå3262807å·ãå3514291å·ãå
3615531å·ãå3753716å·ãå3938999å·ãå
3988158å·ãå4118231å·ãå4126467å·ãå
4200465å·ãè±åœç¹èš±ç¬¬1235075å·ãå1155977å·ã
å1461438å·ãå1352975å·ãå1484868å·ãå
1535685å·çã«èšèŒãããŠãããããªããªããŒé¡
ããäŸãã°ç±³åœç¹èš±ç¬¬4070189å·ãå4147550å·ç
ã«èšãããŠãããããªã©ããã¯ã¹é¡ãŸãã¯ç±³åœç¹
蚱第3062700å·ãå3245833å·ãå3525621å·ã«èš
èŒãããŠãããããªé žåäºéãåå°äœãã³ãã€ã
ã·ãªã«çãæ§æå±€ã®äžã«å«æãããããšãæå¹ã§
ããã æ¬çºæã®çŸåæ¹æ³ãé©çšããåçæå ææã¯å
è¿°ã®åçä¹³å€å±€åã³ãã®ä»ã®å±€ãåçæå ææã«
éåžžçšãããããã©ã¹ããã¯ãã€ã«ã ãçŽãåžãª
ã©ã®å¯ææ§æ¯æäœãŸãã¯ã¬ã©ã¹ãé¶åšãéå±ãªã©
ã®åæ§ã®æ¯æäœã«å¡åžãããã®ã§ãããå¯ææ§æ¯
æäœãšããŠæçšãªãã®ã¯ãç¡é žã»ã«ããŒã¹ãé ¢é ž
ã»ã«ããŒã¹ãé ¢é žé ªé žã»ã«ããŒã¹ãããªã¹ãã¬
ã³ãããªå¡©åããã«ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒ
ããããªã«ãŒãããŒãçã®ååæãŸãã¯åæé«å
åããæããã€ã«ã ããã©ã€ã¿å±€ãŸãã¯Î±âãªã¬
ãã€ã³ããªããŒïŒäŸãã°ããªãšãã¬ã³ãããªãã
ãã¬ã³ããšãã¬ã³ïŒããã³å ±éåäœïŒçãå¡åžãŸ
ãã¯ã©ãããŒãããçŽçã§ãããæ¯æäœã¯ææã
é¡æãçšããŠçè²ãããŠããŠããããé®å ã®ç®ç
ã§é»è²ã«ããŠãããããããã®æ¯æäœã®è¡šé¢ã¯äž
è¬ã«ãåçä¹³å€å±€çãšã®æ¥çãããããããã«äž
éåŠçããããæ¯æäœè¡šé¢ã¯äžå¡åŠçã«åãŸãã¯
åŸã«ãã³ããæŸé»ã玫å€ç·ç §å°ãç«çåŠççãæœ
ããŠãããã ãã®ä»ãæ¬çºæã«çšããåçæå ææã«ã¯çš®ã
ã®å ¬ç¥ã®çŽ æãæ·»å å€ãçšããŠãããããã«ã€ã
ãŠã¯Research DisclosureèªèšèŒNo.17643ãåè
ã«ããããšãã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ è¡šé¢æœååããã²ã³åéä¹³å€ãšå éšã«ãã¶ã
æ žãæããããã²ã³åéä¹³å€ãæ··åããŠäžå±€ã«ã
ããåã¯å¥ã ã«éå±€ããŠå¡åžããŠæãããã²ã³å
éåçæå ææãã次ã®äžè¬åŒïŒïŒãŸãã¯äžè¬
åŒïŒïŒã§ç€ºãããååç©ããã³ããã²ã³åé溶
å€ãšããŠäžèšäžè¬åŒïŒïŒã®ã€ãããŸãŒã«èªå°äœ
ãå«æããçŸå液ã§åŠçããããšãç¹åŸŽãšããã
ãã²ã³åéåçæå ææã®çŸåæ¹æ³ã ïŒåŒäžR1ã¯æ°ŽçŽ ååããããåºãã·ã¢ãåºã
ãŸãã¯ããã²ã³ååãè¡šãããR2ã¯æ°ŽçŽ ååã
ããã²ã³ååããŸãã¯ã¢ã«ãã«åºãè¡šãããZ1ã
Z4ã¯åäžã§ãäºãã«ç°ãªã€ãŠããŠããããåã æ°Ž
çŽ ååãã¢ã«ãã«åºãããããã·ã¢ã«ãã«åºãŸã
ã¯ã¢ã«ã±ãã«åºãè¡šããïŒ
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56136267A JPS5837643A (ja) | 1981-08-31 | 1981-08-31 | ããã²ã³åéåçæå ææã®çŸåæ¹æ³ |
US06/413,315 US4435500A (en) | 1981-08-31 | 1982-08-31 | Method for developing silver halide photographic light-sensitive material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56136267A JPS5837643A (ja) | 1981-08-31 | 1981-08-31 | ããã²ã³åéåçæå ææã®çŸåæ¹æ³ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5837643A JPS5837643A (ja) | 1983-03-04 |
JPH0140339B2 true JPH0140339B2 (ja) | 1989-08-28 |
Family
ID=15171188
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56136267A Granted JPS5837643A (ja) | 1981-08-31 | 1981-08-31 | ããã²ã³åéåçæå ææã®çŸåæ¹æ³ |
Country Status (2)
Country | Link |
---|---|
US (1) | US4435500A (ja) |
JP (1) | JPS5837643A (ja) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59121039A (ja) * | 1982-12-27 | 1984-07-12 | Fuji Photo Film Co Ltd | ããã²ã³åéåçæå ææ |
JPH0650377B2 (ja) * | 1984-02-15 | 1994-06-29 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©ãŒå転åçæå ææã®åŠçæ¹æ³ |
IT1177232B (it) * | 1984-11-16 | 1987-08-26 | Minnesota Mining & Mfg | Procedimento per lo sviluppo ad alto contrasto di elementi fotografici e soluzione di sviluppo fotografica acquosa alcalina |
JPH0612434B2 (ja) * | 1985-05-17 | 1994-02-16 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ |
JPS622248A (ja) * | 1985-06-27 | 1987-01-08 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéåçæå ææ |
JP2530145B2 (ja) * | 1986-03-13 | 1996-09-04 | ã³ãã«æ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææåã³ãã®åŠçæ¹æ³ |
JPH0650379B2 (ja) * | 1986-04-28 | 1994-06-29 | ã³ãã«æ ªåŒäŒç€Ÿ | é«æ床ã§ãã¶ããå°ãªãããã²ã³åéã«ã©âåçæå ææ |
US5192647A (en) * | 1986-10-24 | 1993-03-09 | Fuji Photo Film Co., Ltd. | Method for development processing of silver halide photographic |
JP2794449B2 (ja) * | 1988-06-03 | 1998-09-03 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéæå ææã®çŸååŠçæ¹æ³ |
USH1020H (en) | 1989-09-25 | 1992-02-04 | Konica Corporation | Developing solution for light-sensitive silver halide photographic material and method of forming photographic image making use of it |
US5389507A (en) * | 1992-12-31 | 1995-02-14 | Eastman Kodak Company | Reversal elements with internal latent image forming core-shell emulsions |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4913580A (ja) * | 1972-04-04 | 1974-02-06 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE609927A (ja) | 1959-01-12 | |||
US2996382A (en) | 1959-01-12 | 1961-08-15 | Eastman Kodak Co | Photographic elements having improved sensitivity |
US3397987A (en) | 1965-05-24 | 1968-08-20 | Eastman Kodak Co | Photographic emulsion containing mercapto development anti-foggants |
US3607278A (en) | 1968-04-18 | 1971-09-21 | Eastman Kodak Co | Photographic elements containing fogged and unfogged silver halide grains and a slow silver halide emulsion layer |
US3708300A (en) | 1970-11-19 | 1973-01-02 | Eastman Kodak Co | Silver-dye-bleach photographic materials |
-
1981
- 1981-08-31 JP JP56136267A patent/JPS5837643A/ja active Granted
-
1982
- 1982-08-31 US US06/413,315 patent/US4435500A/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4913580A (ja) * | 1972-04-04 | 1974-02-06 |
Also Published As
Publication number | Publication date |
---|---|
JPS5837643A (ja) | 1983-03-04 |
US4435500A (en) | 1984-03-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPH0690447B2 (ja) | ããã²ã³åéåçæå ææ | |
JPH0140339B2 (ja) | ||
JPH0473858B2 (ja) | ||
JPH0564777B2 (ja) | ||
JPH0220091B2 (ja) | ||
JPH0668615B2 (ja) | è¶ ç¡¬èª¿ãã¬ååçæå ææ | |
JPS6329729B2 (ja) | ||
JPH0820688B2 (ja) | è¶ è¿ éåŠçå¯èœãªããã²ã³åéåçæå ææ | |
JPH0619526B2 (ja) | ããã²ã³åéåçæå ææã®çŸååŠçæ¹æ³ | |
JPH0640200B2 (ja) | æŸå°ç·çšããã²ã³åéåçæå ææ | |
JPH0518090B2 (ja) | ||
JPS6172230A (ja) | éå¡©æ¡æ£è»¢åæ³çšæå èŠçŽ | |
US6528227B2 (en) | Film/screen system and image-forming system for use in direct X-ray applications | |
JP2873852B2 (ja) | ããã²ã³åéåçæå ææ | |
JP2709756B2 (ja) | ããã²ã³åéåçæå ææ | |
JP2748059B2 (ja) | ããã²ã³åéåçæå ææçšçŸå液 | |
EP1195641B1 (en) | Film/Screen system and image-forming system for use in direct X-ray applications | |
JPH0466335B2 (ja) | ||
JPH06250324A (ja) | ããã²ã³åéåçæå ææ | |
JPH04358143A (ja) | ããã²ã³åéåçæå ææ | |
JPS62275242A (ja) | çŽæ¥ããžçšããã²ã³åéæå ææ | |
US20020018954A1 (en) | Single-side coated silver halide photographic film material having reduced tendency to curl | |
JPS62189461A (ja) | 垯é»é²æ¢æ§èœãæ¹è¯ãããããã²ã³åéåçæå ææ | |
JPH045373B2 (ja) | ||
JPH0682190B2 (ja) | ããã²ã³åéåçæå ææ |