JP6773240B2 - 固体酸化物形燃料電池用電解質材料とその前駆体の製造方法 - Google Patents
固体酸化物形燃料電池用電解質材料とその前駆体の製造方法 Download PDFInfo
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- JP6773240B2 JP6773240B2 JP2019566852A JP2019566852A JP6773240B2 JP 6773240 B2 JP6773240 B2 JP 6773240B2 JP 2019566852 A JP2019566852 A JP 2019566852A JP 2019566852 A JP2019566852 A JP 2019566852A JP 6773240 B2 JP6773240 B2 JP 6773240B2
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- Prior art keywords
- precursor
- electrolyte material
- fuel cell
- starting material
- oxide fuel
- Prior art date
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- 239000002001 electrolyte material Substances 0.000 title claims description 116
- 239000002243 precursor Substances 0.000 title claims description 110
- 239000007787 solid Substances 0.000 title claims description 74
- 239000000446 fuel Substances 0.000 title claims description 50
- 238000004519 manufacturing process Methods 0.000 title claims description 36
- 238000000034 method Methods 0.000 title description 23
- 239000007858 starting material Substances 0.000 claims description 56
- 239000000203 mixture Substances 0.000 claims description 47
- XJUNLJFOHNHSAR-UHFFFAOYSA-J zirconium(4+);dicarbonate Chemical compound [Zr+4].[O-]C([O-])=O.[O-]C([O-])=O XJUNLJFOHNHSAR-UHFFFAOYSA-J 0.000 claims description 29
- 239000002245 particle Substances 0.000 claims description 28
- 238000009826 distribution Methods 0.000 claims description 20
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 17
- 238000010298 pulverizing process Methods 0.000 claims description 16
- 229910052727 yttrium Inorganic materials 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 15
- 238000002441 X-ray diffraction Methods 0.000 claims description 13
- 239000003792 electrolyte Substances 0.000 claims description 12
- 229910052684 Cerium Inorganic materials 0.000 claims description 11
- 229910052726 zirconium Inorganic materials 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 238000005204 segregation Methods 0.000 description 27
- 238000013507 mapping Methods 0.000 description 22
- 229910052788 barium Inorganic materials 0.000 description 16
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 16
- 238000011156 evaluation Methods 0.000 description 16
- 238000010304 firing Methods 0.000 description 14
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 13
- 239000000843 powder Substances 0.000 description 12
- 239000002994 raw material Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- 238000010303 mechanochemical reaction Methods 0.000 description 10
- 229910021523 barium zirconate Inorganic materials 0.000 description 9
- DQBAOWPVHRWLJC-UHFFFAOYSA-N barium(2+);dioxido(oxo)zirconium Chemical compound [Ba+2].[O-][Zr]([O-])=O DQBAOWPVHRWLJC-UHFFFAOYSA-N 0.000 description 9
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 9
- 238000005259 measurement Methods 0.000 description 9
- 229910052712 strontium Inorganic materials 0.000 description 9
- UZLYXNNZYFBAQO-UHFFFAOYSA-N oxygen(2-);ytterbium(3+) Chemical compound [O-2].[O-2].[O-2].[Yb+3].[Yb+3] UZLYXNNZYFBAQO-UHFFFAOYSA-N 0.000 description 8
- 239000002002 slurry Substances 0.000 description 8
- 229910003454 ytterbium oxide Inorganic materials 0.000 description 8
- 229940075624 ytterbium oxide Drugs 0.000 description 8
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 6
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 6
- 239000011324 bead Substances 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 5
- 238000010532 solid phase synthesis reaction Methods 0.000 description 5
- 229910000018 strontium carbonate Inorganic materials 0.000 description 5
- 239000013078 crystal Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 229910000420 cerium oxide Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 3
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- -1 temperature Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- JCDQGOSXWGXOQQ-UHFFFAOYSA-H ytterbium(3+);tricarbonate Chemical compound [Yb+3].[Yb+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O JCDQGOSXWGXOQQ-UHFFFAOYSA-H 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- 229910003026 (La,Sr)(Co,Fe)O3 Inorganic materials 0.000 description 1
- FFQALBCXGPYQGT-UHFFFAOYSA-N 2,4-difluoro-5-(trifluoromethyl)aniline Chemical compound NC1=CC(C(F)(F)F)=C(F)C=C1F FFQALBCXGPYQGT-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010021143 Hypoxia Diseases 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- UNJPQTDTZAKTFK-UHFFFAOYSA-K cerium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Ce+3] UNJPQTDTZAKTFK-UHFFFAOYSA-K 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 1
- QVOIJBIQBYRBCF-UHFFFAOYSA-H yttrium(3+);tricarbonate Chemical compound [Y+3].[Y+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O QVOIJBIQBYRBCF-UHFFFAOYSA-H 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/006—Compounds containing, besides zirconium, two or more other elements, with the exception of oxygen or hydrogen
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
- H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
- H01M8/1253—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides the electrolyte containing zirconium oxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/30—Three-dimensional structures
- C01P2002/34—Three-dimensional structures perovskite-type (ABO3)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
- H01M2300/0071—Oxides
- H01M2300/0074—Ion conductive at high temperature
- H01M2300/0077—Ion conductive at high temperature based on zirconium oxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Energy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Fuel Cell (AREA)
- Conductive Materials (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2020116068A JP6927376B2 (ja) | 2018-08-30 | 2020-07-06 | 固体酸化物形燃料電池用電解質材料とその前駆体の製造方法 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2018161058 | 2018-08-30 | ||
| JP2018161058 | 2018-08-30 | ||
| PCT/JP2019/033818 WO2020045540A1 (ja) | 2018-08-30 | 2019-08-28 | 固体酸化物形燃料電池用電解質材料とその前駆体の製造方法 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020116068A Division JP6927376B2 (ja) | 2018-08-30 | 2020-07-06 | 固体酸化物形燃料電池用電解質材料とその前駆体の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPWO2020045540A1 JPWO2020045540A1 (ja) | 2020-09-03 |
| JP6773240B2 true JP6773240B2 (ja) | 2020-10-21 |
Family
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Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019566852A Active JP6773240B2 (ja) | 2018-08-30 | 2019-08-28 | 固体酸化物形燃料電池用電解質材料とその前駆体の製造方法 |
| JP2020116068A Active JP6927376B2 (ja) | 2018-08-30 | 2020-07-06 | 固体酸化物形燃料電池用電解質材料とその前駆体の製造方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020116068A Active JP6927376B2 (ja) | 2018-08-30 | 2020-07-06 | 固体酸化物形燃料電池用電解質材料とその前駆体の製造方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US11962051B2 (zh) |
| JP (2) | JP6773240B2 (zh) |
| CN (1) | CN112585791A (zh) |
| TW (1) | TWI813749B (zh) |
| WO (1) | WO2020045540A1 (zh) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2021140817A1 (zh) * | 2020-01-07 | 2021-07-15 | ||
| CN114395772B (zh) * | 2021-12-14 | 2023-06-09 | 深圳大学 | 一种降低能耗共电解烷烃与二氧化碳制备增殖化学品的方法及电解池反应器 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5244753A (en) | 1990-05-29 | 1993-09-14 | Matsushita Electric Industrial Co., Ltd. | Solid electrolyte fuel cell and method for manufacture of same |
| JPH0543240A (ja) * | 1991-08-09 | 1993-02-23 | Teika Corp | ジルコニウム含有ペロブスカイト化合物微粉体の製造方法 |
| CN101014538B (zh) * | 2004-08-13 | 2012-07-04 | 堺化学工业株式会社 | 钙钛矿化合物粉末的制备方法 |
| US20060133988A1 (en) * | 2004-12-21 | 2006-06-22 | Showa Denko K.K. | Titanium-containing perovskite composite oxide particle, production process thereof and capacitor |
| JP2006265003A (ja) | 2005-03-22 | 2006-10-05 | Nippon Chem Ind Co Ltd | 誘電体セラミック形成用組成物および誘電体セラミック材料 |
| JP4952880B2 (ja) * | 2005-11-15 | 2012-06-13 | 戸田工業株式会社 | プロトン伝導性ペロブスカイト微粒子の製造法、及び該粒子粉末 |
| JP2009035447A (ja) | 2007-08-01 | 2009-02-19 | Central Res Inst Of Electric Power Ind | セラミックス粉体及びその焼結体とそれを利用した固体酸化物型燃料電池用空気極 |
| JP2009231075A (ja) * | 2008-03-24 | 2009-10-08 | Toyota Central R&D Labs Inc | ペロブスカイト型複合酸化物薄膜 |
| JP2011190149A (ja) | 2010-03-15 | 2011-09-29 | Sumitomo Osaka Cement Co Ltd | 複合セラミックス粉体およびその製造方法並びに固体酸化物形燃料電池 |
| JP5146492B2 (ja) * | 2010-06-14 | 2013-02-20 | Ｔｄｋ株式会社 | 誘電体磁器組成物およびその製造方法 |
| JP2012072037A (ja) * | 2010-09-29 | 2012-04-12 | Tdk Corp | 誘電体磁器組成物およびその製造方法ならびにセラミック電子部品 |
| JP5936897B2 (ja) | 2012-03-28 | 2016-06-22 | 住友電気工業株式会社 | 固体電解質、固体電解質の製造方法、固体電解質積層体及び固体電解質積層体の製造方法及び燃料電池 |
| JP5676038B2 (ja) * | 2013-07-11 | 2015-02-25 | 日本特殊陶業株式会社 | 固体酸化物形燃料電池セル、その製造方法、燃料電池セルスタック、及び固体酸化物形燃料電池。 |
| JP6161467B2 (ja) | 2013-08-23 | 2017-07-12 | Ａｇｃセイミケミカル株式会社 | 固体酸化物型燃料電池用複合酸化物粉末及びその製造方法 |
| US9896771B2 (en) * | 2014-02-07 | 2018-02-20 | Panasonic Intellectual Property Management Co., Ltd. | Dehydrogenation device |
| US20160003767A1 (en) | 2014-07-01 | 2016-01-07 | Panasonic Intellectual Property Management Co., Ltd. | Proton-conducting oxide |
| EP3220464B1 (en) | 2014-11-13 | 2018-11-28 | Sumitomo Electric Industries, Ltd. | Cell structure, method for manufacturing the same, and fuel cell |
| EP3279987B1 (en) * | 2015-03-30 | 2019-11-27 | Sumitomo Electric Industries, Ltd. | Proton conductor, fuel-cell solid-electrolyte layer, cell structure, and fuel cell provided with same |
| JP6783042B2 (ja) * | 2015-08-17 | 2020-11-11 | 住友電気工業株式会社 | セル構造体の製造方法 |
| WO2017104806A1 (ja) * | 2015-12-18 | 2017-06-22 | 住友電気工業株式会社 | プロトン伝導体、セル構造体およびこれらの製造方法、燃料電池ならびに水電解装置 |
| US20170288248A1 (en) | 2016-04-04 | 2017-10-05 | Panasonic Corporation | Membrane electrode assembly and solid oxide fuel cell |
| WO2018021484A1 (ja) | 2016-07-27 | 2018-02-01 | 日本碍子株式会社 | 電気化学セル |
| JP6813992B2 (ja) | 2016-08-29 | 2021-01-13 | 株式会社ノリタケカンパニーリミテド | 固体酸化物形燃料電池とこれに用いる電極材料 |
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| TWI813749B (zh) | 2023-09-01 |
| JP2020170718A (ja) | 2020-10-15 |
| JPWO2020045540A1 (ja) | 2020-09-03 |
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