JP6731855B2 - 金属有機構造体(mof)黄色蛍光体およびその白色発光素子における応用 - Google Patents
金属有機構造体(mof)黄色蛍光体およびその白色発光素子における応用 Download PDFInfo
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- JP6731855B2 JP6731855B2 JP2016564255A JP2016564255A JP6731855B2 JP 6731855 B2 JP6731855 B2 JP 6731855B2 JP 2016564255 A JP2016564255 A JP 2016564255A JP 2016564255 A JP2016564255 A JP 2016564255A JP 6731855 B2 JP6731855 B2 JP 6731855B2
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title description 14
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- 239000003446 ligand Substances 0.000 claims description 58
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 36
- 229910052725 zinc Inorganic materials 0.000 claims description 27
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 16
- 150000007942 carboxylates Chemical group 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
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- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 8
- 125000003831 tetrazolyl group Chemical group 0.000 claims description 8
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 7
- -1 transition metal cation Chemical class 0.000 claims description 7
- KIOHKYKNIXESSZ-UHFFFAOYSA-N 1,3,5-triazine-2,4,6-tricarboxylic acid Chemical compound OC(=O)C1=NC(C(O)=O)=NC(C(O)=O)=N1 KIOHKYKNIXESSZ-UHFFFAOYSA-N 0.000 claims description 6
- OMEGITYKNVPYCS-UHFFFAOYSA-N 2-aminobenzene-1,3,5-tricarboxylic acid Chemical compound NC1=C(C(O)=O)C=C(C(O)=O)C=C1C(O)=O OMEGITYKNVPYCS-UHFFFAOYSA-N 0.000 claims description 6
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- QMKYBPDZANOJGF-UHFFFAOYSA-K benzene-1,3,5-tricarboxylate(3-) Chemical compound [O-]C(=O)C1=CC(C([O-])=O)=CC(C([O-])=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-K 0.000 claims description 6
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- BJHHREPACLZKDA-UHFFFAOYSA-N 4-(4-phenylphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(C=2C=CC=CC=2)C=C1 BJHHREPACLZKDA-UHFFFAOYSA-N 0.000 claims description 2
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- CMPDXBXNGAEVNY-UHFFFAOYSA-N 5-(4-phenylphenyl)-2h-tetrazole Chemical compound C1=CC=CC=C1C1=CC=C(C2=NNN=N2)C=C1 CMPDXBXNGAEVNY-UHFFFAOYSA-N 0.000 claims 1
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- 238000002796 luminescence method Methods 0.000 description 1
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- 238000001840 matrix-assisted laser desorption--ionisation time-of-flight mass spectrometry Methods 0.000 description 1
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- 238000001144 powder X-ray diffraction data Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
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- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000002216 synchrotron radiation X-ray diffraction Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- JLZUZNKTTIRERF-UHFFFAOYSA-N tetraphenylethylene Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)=C(C=1C=CC=CC=1)C1=CC=CC=C1 JLZUZNKTTIRERF-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
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- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
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- 229910052720 vanadium Inorganic materials 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 229910019901 yttrium aluminum garnet Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
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- C—CHEMISTRY; METALLURGY
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21K—NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
- F21K9/00—Light sources using semiconductor devices as light-generating elements, e.g. using light-emitting diodes [LED] or lasers
- F21K9/60—Optical arrangements integrated in the light source, e.g. for improving the colour rendering index or the light extraction
- F21K9/64—Optical arrangements integrated in the light source, e.g. for improving the colour rendering index or the light extraction using wavelength conversion means distinct or spaced from the light-generating element, e.g. a remote phosphor layer
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
- F21V9/00—Elements for modifying spectral properties, polarisation or intensity of the light emitted, e.g. filters
- F21V9/30—Elements containing photoluminescent material distinct from or spaced from the light source
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
- F21V9/00—Elements for modifying spectral properties, polarisation or intensity of the light emitted, e.g. filters
- F21V9/40—Elements for modifying spectral properties, polarisation or intensity of the light emitted, e.g. filters with provision for controlling spectral properties, e.g. colour, or intensity
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- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/18—Metal complexes
- C09K2211/183—Metal complexes of the refractory metals, i.e. Ti, V, Cr, Zr, Nb, Mo, Hf, Ta or W
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- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/18—Metal complexes
- C09K2211/188—Metal complexes of other metals not provided for in one of the previous groups
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21Y—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES F21K, F21L, F21S and F21V, RELATING TO THE FORM OR THE KIND OF THE LIGHT SOURCES OR OF THE COLOUR OF THE LIGHT EMITTED
- F21Y2115/00—Light-generating elements of semiconductor light sources
- F21Y2115/10—Light-emitting diodes [LED]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B20/00—Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
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- Optics & Photonics (AREA)
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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PCT/US2015/027583 WO2015164784A1 (en) | 2014-04-25 | 2015-04-24 | Metal organic framework (mof) yellow phosphors and their applications in white light emitting devices |
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JP (1) | JP6731855B2 (zh) |
CN (1) | CN106459095B (zh) |
WO (1) | WO2015164784A1 (zh) |
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CN105541885A (zh) * | 2016-01-26 | 2016-05-04 | 南阳师范学院 | 一种具有发光功能的烟酸衍生物配体钐金属配合物及其制备方法 |
CN105968377B (zh) * | 2016-06-17 | 2019-04-05 | 江苏科技大学 | 一种发光金属有机框架化合物及其制备方法和应用 |
CN107188801B (zh) * | 2017-05-15 | 2020-05-05 | 天津大学 | 基于四苯基乙烯离子络合物的二价铜离子荧光探针及制备方法及用途 |
WO2019091389A1 (en) * | 2017-11-07 | 2019-05-16 | The Hong Kong University Of Science And Technology | Fluorescent probes for silver ion detection |
US11567023B2 (en) * | 2018-03-22 | 2023-01-31 | Kabushiki Kaisha Toshiba | Molecular detection apparatus and molecular detection method |
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WO2020043087A1 (en) * | 2018-08-27 | 2020-03-05 | The Hong Kong University Of Science And Technology | Method of detecting human serum albumin in biological fluids |
CN109400898B (zh) * | 2018-10-25 | 2021-05-18 | 陕西科技大学 | 一种锰配位聚合物及其制备方法和应用 |
CN109294564B (zh) * | 2018-11-30 | 2021-06-01 | 东南大学 | 一种wled荧光粉的制备方法和制得的荧光粉及其应用 |
CN109633144B (zh) * | 2018-12-28 | 2020-07-14 | 南昌大学 | 一种以聚集诱导发光荧光微球为信标载体制备的荧光免疫层析试纸条 |
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CN110669037B (zh) * | 2019-10-15 | 2023-03-28 | 西北师范大学 | 一种锌金属有机框架配合物在荧光识别铅离子中的应用 |
CN110790941B (zh) * | 2019-11-14 | 2021-08-27 | 重庆师范大学 | 含内消螺旋链的锌-有机配位聚合物及其制法与应用 |
US11387250B2 (en) | 2019-12-20 | 2022-07-12 | Sandisk Technologies Llc | Three-dimensional memory device containing metal-organic framework inter-word line insulating layers |
US11296028B2 (en) | 2019-12-20 | 2022-04-05 | Sandisk Technologies Llc | Semiconductor device containing metal-organic framework inter-line insulator structures and methods of manufacturing the same |
US11493180B2 (en) | 2020-07-08 | 2022-11-08 | Abdullah Alrasheed | Cleansing lamp utilizing metal-organic framework |
US11430736B2 (en) | 2020-08-24 | 2022-08-30 | Sandisk Technologies Llc | Semiconductor device including having metal organic framework interlayer dielectric layer between metal lines and methods of forming the same |
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CN114752072B (zh) * | 2022-05-30 | 2023-07-18 | 山西大学 | Zn金属-有机骨架材料和白光荧光粉材料及其制备方法 |
CN115785467B (zh) * | 2022-11-28 | 2023-08-29 | 重庆师范大学 | 三重互穿的双核Zn2-MOF材料及其制法与在制备橙黄光LED器件中的应用 |
CN116120581B (zh) * | 2023-02-01 | 2024-06-04 | 重庆师范大学 | 稠杂环基mof材料及其制法与在红光led器件制备中的应用 |
CN116120577B (zh) * | 2023-02-01 | 2024-05-28 | 重庆师范大学 | 双核基多孔转光材料及其制法与在制备暖黄光led器件中的应用 |
CN116120582A (zh) * | 2023-02-10 | 2023-05-16 | 山东瑞捷新材料有限公司 | 一种钛-稀土基金属有机框架材料及其制备方法和应用 |
CN117106117B (zh) * | 2023-10-25 | 2024-02-13 | 传化智联股份有限公司 | 含有Nd和Al元素的ZnPF-1催化剂及其制备和在制备聚丁二烯中的应用 |
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US7985868B1 (en) * | 2006-11-01 | 2011-07-26 | Sandia Corporation | Hybrid metal organic scintillator materials system and particle detector |
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