JP6685315B2 - プロピレンのエポキシ化のためのチタンゼオライト触媒の再生方法 - Google Patents

プロピレンのエポキシ化のためのチタンゼオライト触媒の再生方法 Download PDF

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JP6685315B2
JP6685315B2 JP2017542404A JP2017542404A JP6685315B2 JP 6685315 B2 JP6685315 B2 JP 6685315B2 JP 2017542404 A JP2017542404 A JP 2017542404A JP 2017542404 A JP2017542404 A JP 2017542404A JP 6685315 B2 JP6685315 B2 JP 6685315B2
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catalyst
reactor
stream
titanium
hydrogen peroxide
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JP2018511459A5 (enExample
JP2018511459A (ja
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リーデル，ドミニク
ヘンリケ テレス，ヨアキム
ヘンリケ テレス，ヨアキム
ウルバンクツィク，ダニエル
ヴェゲルレ，ウルリケ
シュピスケ，ルイーゼ
パルフレスク，アンドレイ−ニコラエ
シュレダー，アレクサンダー
ミュラー，ウルリヒ
ヴァイデンバッハ，マイノルフ
ヴィッツェル，ヴェルナー，ヨット．
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BASF SE
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/90—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/02—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/085—Group IVB- metallosilicates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2017542404A 2015-02-13 2016-02-12 プロピレンのエポキシ化のためのチタンゼオライト触媒の再生方法 Active JP6685315B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201562115658P 2015-02-13 2015-02-13
EP15154998.7 2015-02-13
US62/115,658 2015-02-13
EP15154998 2015-02-13
PCT/EP2016/052983 WO2016128538A1 (en) 2015-02-13 2016-02-12 Process for the regeneration of a titanium zeolite catalyst for propylene epoxidation

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JP2018511459A JP2018511459A (ja) 2018-04-26
JP2018511459A5 JP2018511459A5 (enExample) 2019-03-22
JP6685315B2 true JP6685315B2 (ja) 2020-04-22

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US (1) US10195598B2 (enExample)
EP (1) EP3256252B1 (enExample)
JP (1) JP6685315B2 (enExample)
KR (1) KR102512661B1 (enExample)
CN (2) CN107530693A (enExample)
BR (1) BR112017017269B1 (enExample)
MX (1) MX2017010402A (enExample)
MY (1) MY189272A (enExample)
PL (1) PL3256252T3 (enExample)
SG (1) SG11201706530RA (enExample)
WO (1) WO2016128538A1 (enExample)

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ES2821890T3 (es) 2015-05-04 2021-04-28 Basf Se Procedimiento de preparación de melonal
US10308580B2 (en) 2015-07-15 2019-06-04 Basf Se Process for preparing an arylpropene
ES2781329T3 (es) 2015-07-22 2020-09-01 Basf Se Procedimiento para preparar ácido furan-2,5-dicarboxílico
EP3170828A1 (de) 2015-11-23 2017-05-24 Basf Se Verfahren zur herstellung von verbindungen mit 16-oxabicyclo[10.3.1]pentadecengerüst und deren folgeprodukten
ES2765740T3 (es) 2015-11-27 2020-06-10 Basf Se Síntesis ultrarápida de elevado rendimiento-espacio-tiempo de armazones orgánicos-metal
EP3178788A1 (en) 2015-12-08 2017-06-14 Basf Se A tin-containing zeolitic material having a bea framework structure
WO2017097806A1 (en) 2015-12-08 2017-06-15 Basf Se A tin-containing zeolitic material having a bea framework structure
WO2017133995A1 (de) 2016-02-01 2017-08-10 Basf Se Verfahren zur herstellung von c4-c15-lactamen
US10532970B2 (en) 2016-06-29 2020-01-14 Basf Se Process for the preparation of alpha, beta unsaturated aldehydes by oxidation of alcohols in the presence of a liquid phase
WO2018007481A1 (en) 2016-07-08 2018-01-11 Basf Se Process for preparing an organic sulfone
SG11201811020XA (en) 2016-07-20 2019-02-27 Basf Se A process for purifying propylene oxide
MY191861A (en) 2016-07-29 2022-07-18 Basf Corp Process for the preparation of a zeolitic material having a fau-type framework structure and use thereof in the selective catalytic reduction of nox
EP3544730A1 (en) 2016-11-28 2019-10-02 Basf Se Catalyst composite comprising an alkaline earth metal containing cha zeolite and use thereof in a process for the conversion of oxygenates to olefins
BR112019008783A2 (pt) 2016-11-30 2019-07-16 Basf Se processo para a conversão de etano-1,2-diol em etano-1,2-diamina
JP2019536774A (ja) 2016-11-30 2019-12-19 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Ｍｏｒ骨格構造の銅変性ゼオライトを用いて、モノエタノールアミンをエチレンジアミンに変換する方法
HUE066373T2 (hu) 2016-12-13 2024-07-28 Basf Se Eljárás titántartalmú zeolit elõállítására
BR112020010507A2 (pt) * 2017-12-21 2020-11-10 Basf Se processo para a preparação de aldeídos alfa, beta insaturados
EP3604222A1 (en) * 2018-07-30 2020-02-05 Evonik Operations GmbH Process for the purification of hydrogen cyanide
US20210403333A1 (en) * 2018-11-15 2021-12-30 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Method for preparing hierarchical porous titanosilicate ts-1 molecular sieve
TW202045484A (zh) * 2019-02-08 2020-12-16 德商贏創運營有限公司 有機化合物的氧化
CN110252393A (zh) * 2019-05-21 2019-09-20 江西农业大学 一种用于合成环氧大豆油的钛硅沸石负载镉催化剂、制备方法及应用
CN110075914A (zh) * 2019-05-28 2019-08-02 江苏扬农化工集团有限公司 一种hppo工艺失活钛硅分子筛催化剂器内再生的方法
EP3812375A1 (en) * 2019-10-21 2021-04-28 Evonik Operations GmbH Process for the epoxidation of propene
CN112354557B (zh) * 2020-11-16 2023-03-24 华东师范大学 一种整体式钛沸石催化剂制备方法及其应用
CN112678866B (zh) * 2020-12-24 2023-07-04 中国石油化工股份有限公司 一种烯烃聚合工业废酸渣资源化处理方法
CN112844468A (zh) * 2021-01-19 2021-05-28 中国科学院大连化学物理研究所 一种用于丙烯气相环氧化制环氧丙烷的催化剂及其制备方法
CN117545744A (zh) 2021-06-15 2024-02-09 巴斯夫欧洲公司 用于制备氧化烯烃的方法的停工方法
CN113368895B (zh) * 2021-07-13 2023-09-29 福州大学 一种具有高转化率的丙烯气相环氧化催化剂的制备方法
CN118043136A (zh) * 2021-09-30 2024-05-14 巴斯夫公司 用于脱氢和其他反应的多孔金属氧化物催化剂的预处理
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CN117504927B (zh) * 2023-11-10 2025-04-29 江西师范大学 一种负载型Ti-MWW分子筛与金属氧化物的复合催化剂及其制备与应用

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PL3256252T3 (pl) 2021-10-25
MX2017010402A (es) 2018-05-28
WO2016128538A1 (en) 2016-08-18
KR20170117509A (ko) 2017-10-23
MY189272A (en) 2022-01-31
SG11201706530RA (en) 2017-09-28
CN107530693A (zh) 2018-01-02
CN119456024A (zh) 2025-02-18
KR102512661B1 (ko) 2023-03-21
EP3256252B1 (en) 2021-04-07
BR112017017269B1 (pt) 2022-05-24
JP2018511459A (ja) 2018-04-26
BR112017017269A2 (pt) 2018-04-17
US20180036723A1 (en) 2018-02-08
EP3256252A1 (en) 2017-12-20
US10195598B2 (en) 2019-02-05

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