PL3256252T3 - Sposób regeneracji katalizatora na bazie zeolitu tytanowego do epoksydowania propylenu - Google Patents

Sposób regeneracji katalizatora na bazie zeolitu tytanowego do epoksydowania propylenu

Info

Publication number
PL3256252T3
PL3256252T3 PL16704206T PL16704206T PL3256252T3 PL 3256252 T3 PL3256252 T3 PL 3256252T3 PL 16704206 T PL16704206 T PL 16704206T PL 16704206 T PL16704206 T PL 16704206T PL 3256252 T3 PL3256252 T3 PL 3256252T3
Authority
PL
Poland
Prior art keywords
eolite
regeneration
titanium
catalyst based
propylene epoxy
Prior art date
Application number
PL16704206T
Other languages
English (en)
Polish (pl)
Inventor
Dominic RIEDEL
Joaquim Henrique Teles
Daniel Urbanczyk
Ulrike Wegerle
Luise Spiske
Andrei-Nicolae PARVULESCU
Alexander SCHRÖDER
Ulrich Müller
Meinolf Weidenbach
Werner WITZL
Original Assignee
Basf Se
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se, Dow Global Technologies Llc filed Critical Basf Se
Publication of PL3256252T3 publication Critical patent/PL3256252T3/pl

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/89Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/90Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/02Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12Treating with free oxygen-containing gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/04Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/6472-50 nm
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/085Group IVB- metallosilicates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
PL16704206T 2015-02-13 2016-02-12 Sposób regeneracji katalizatora na bazie zeolitu tytanowego do epoksydowania propylenu PL3256252T3 (pl)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201562115658P 2015-02-13 2015-02-13
EP15154998 2015-02-13
PCT/EP2016/052983 WO2016128538A1 (en) 2015-02-13 2016-02-12 Process for the regeneration of a titanium zeolite catalyst for propylene epoxidation
EP16704206.8A EP3256252B1 (en) 2015-02-13 2016-02-12 Process for the regeneration of a titanium zeolite catalyst for propylene epoxidation

Publications (1)

Publication Number Publication Date
PL3256252T3 true PL3256252T3 (pl) 2021-10-25

Family

ID=52472215

Family Applications (1)

Application Number Title Priority Date Filing Date
PL16704206T PL3256252T3 (pl) 2015-02-13 2016-02-12 Sposób regeneracji katalizatora na bazie zeolitu tytanowego do epoksydowania propylenu

Country Status (11)

Country Link
US (1) US10195598B2 (enExample)
EP (1) EP3256252B1 (enExample)
JP (1) JP6685315B2 (enExample)
KR (1) KR102512661B1 (enExample)
CN (2) CN107530693A (enExample)
BR (1) BR112017017269B1 (enExample)
MX (1) MX2017010402A (enExample)
MY (1) MY189272A (enExample)
PL (1) PL3256252T3 (enExample)
SG (1) SG11201706530RA (enExample)
WO (1) WO2016128538A1 (enExample)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2821890T3 (es) 2015-05-04 2021-04-28 Basf Se Procedimiento de preparación de melonal
US10308580B2 (en) 2015-07-15 2019-06-04 Basf Se Process for preparing an arylpropene
ES2781329T3 (es) 2015-07-22 2020-09-01 Basf Se Procedimiento para preparar ácido furan-2,5-dicarboxílico
EP3170828A1 (de) 2015-11-23 2017-05-24 Basf Se Verfahren zur herstellung von verbindungen mit 16-oxabicyclo[10.3.1]pentadecengerüst und deren folgeprodukten
ES2765740T3 (es) 2015-11-27 2020-06-10 Basf Se Síntesis ultrarápida de elevado rendimiento-espacio-tiempo de armazones orgánicos-metal
EP3178788A1 (en) 2015-12-08 2017-06-14 Basf Se A tin-containing zeolitic material having a bea framework structure
WO2017097806A1 (en) 2015-12-08 2017-06-15 Basf Se A tin-containing zeolitic material having a bea framework structure
WO2017133995A1 (de) 2016-02-01 2017-08-10 Basf Se Verfahren zur herstellung von c4-c15-lactamen
US10532970B2 (en) 2016-06-29 2020-01-14 Basf Se Process for the preparation of alpha, beta unsaturated aldehydes by oxidation of alcohols in the presence of a liquid phase
WO2018007481A1 (en) 2016-07-08 2018-01-11 Basf Se Process for preparing an organic sulfone
SG11201811020XA (en) 2016-07-20 2019-02-27 Basf Se A process for purifying propylene oxide
MY191861A (en) 2016-07-29 2022-07-18 Basf Corp Process for the preparation of a zeolitic material having a fau-type framework structure and use thereof in the selective catalytic reduction of nox
EP3544730A1 (en) 2016-11-28 2019-10-02 Basf Se Catalyst composite comprising an alkaline earth metal containing cha zeolite and use thereof in a process for the conversion of oxygenates to olefins
BR112019008783A2 (pt) 2016-11-30 2019-07-16 Basf Se processo para a conversão de etano-1,2-diol em etano-1,2-diamina
JP2019536774A (ja) 2016-11-30 2019-12-19 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se Mor骨格構造の銅変性ゼオライトを用いて、モノエタノールアミンをエチレンジアミンに変換する方法
HUE066373T2 (hu) 2016-12-13 2024-07-28 Basf Se Eljárás titántartalmú zeolit elõállítására
BR112020010507A2 (pt) * 2017-12-21 2020-11-10 Basf Se processo para a preparação de aldeídos alfa, beta insaturados
EP3604222A1 (en) * 2018-07-30 2020-02-05 Evonik Operations GmbH Process for the purification of hydrogen cyanide
US20210403333A1 (en) * 2018-11-15 2021-12-30 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Method for preparing hierarchical porous titanosilicate ts-1 molecular sieve
TW202045484A (zh) * 2019-02-08 2020-12-16 德商贏創運營有限公司 有機化合物的氧化
CN110252393A (zh) * 2019-05-21 2019-09-20 江西农业大学 一种用于合成环氧大豆油的钛硅沸石负载镉催化剂、制备方法及应用
CN110075914A (zh) * 2019-05-28 2019-08-02 江苏扬农化工集团有限公司 一种hppo工艺失活钛硅分子筛催化剂器内再生的方法
EP3812375A1 (en) * 2019-10-21 2021-04-28 Evonik Operations GmbH Process for the epoxidation of propene
CN112354557B (zh) * 2020-11-16 2023-03-24 华东师范大学 一种整体式钛沸石催化剂制备方法及其应用
CN112678866B (zh) * 2020-12-24 2023-07-04 中国石油化工股份有限公司 一种烯烃聚合工业废酸渣资源化处理方法
CN112844468A (zh) * 2021-01-19 2021-05-28 中国科学院大连化学物理研究所 一种用于丙烯气相环氧化制环氧丙烷的催化剂及其制备方法
CN117545744A (zh) 2021-06-15 2024-02-09 巴斯夫欧洲公司 用于制备氧化烯烃的方法的停工方法
CN113368895B (zh) * 2021-07-13 2023-09-29 福州大学 一种具有高转化率的丙烯气相环氧化催化剂的制备方法
CN118043136A (zh) * 2021-09-30 2024-05-14 巴斯夫公司 用于脱氢和其他反应的多孔金属氧化物催化剂的预处理
WO2024115737A1 (en) 2022-12-02 2024-06-06 Basf Se Process for regeneration of an epoxidation reactor
CN117504927B (zh) * 2023-11-10 2025-04-29 江西师范大学 一种负载型Ti-MWW分子筛与金属氧化物的复合催化剂及其制备与应用

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19723751A1 (de) 1997-06-06 1998-12-10 Basf Ag Formkörper und Verfahren zu dessen Herstellung
US6114551A (en) 1999-10-04 2000-09-05 Mobil Oil Corporation Olefin epoxidation catalysts
DE10044798A1 (de) * 2000-09-11 2002-04-04 Basf Ag Verfahren zur Regenerierung eines Zeolith-Katalysators
DE50115570D1 (de) 2001-01-08 2010-09-09 Evonik Degussa Gmbh Verfahren zur Epoxidierung von Olefinen
DE10320635A1 (de) 2003-05-08 2004-11-18 Basf Ag Verfahren zur Herstellung von Propylenoxid
EP1489074A1 (en) 2003-06-18 2004-12-22 Degussa AG Process for the epoxidation of propene
US20050277542A1 (en) * 2004-06-14 2005-12-15 Kaminsky Mark P Catalyst regeneration process
KR101166932B1 (ko) 2005-07-27 2012-07-19 에스케이이노베이션 주식회사 티타늄 함유 분자체 촉매의 재생방법
JP2009233656A (ja) * 2008-03-05 2009-10-15 Sumitomo Chemical Co Ltd チタノシリケート触媒の再生方法
CN101480623B (zh) * 2009-02-24 2011-06-08 江苏扬农化工集团有限公司 一种钛硅分子筛催化剂的再生方法
WO2011115234A1 (en) * 2010-03-18 2011-09-22 Sumitomo Chemical Company, Limited Method for regenerating titanosilicate catalysts
RU2740556C2 (ru) 2012-02-07 2021-01-15 Басф Се МИКРОПОРОШОК И ФОРМОВАННОЕ ИЗДЕЛИЕ, СОДЕРЖАЩЕЕ ЦЕОЛИТНЫЙ МАТЕРИАЛ, СОДЕРЖАЩИЙ Ti И Zn
CN104014365B (zh) * 2013-02-28 2016-08-24 中国石油化工股份有限公司 一种钛硅分子筛的再生方法
MY182811A (en) * 2013-07-24 2021-02-05 Basf Se Regeneration of a titanium containing zeolite

Also Published As

Publication number Publication date
MX2017010402A (es) 2018-05-28
WO2016128538A1 (en) 2016-08-18
KR20170117509A (ko) 2017-10-23
MY189272A (en) 2022-01-31
SG11201706530RA (en) 2017-09-28
CN107530693A (zh) 2018-01-02
CN119456024A (zh) 2025-02-18
KR102512661B1 (ko) 2023-03-21
EP3256252B1 (en) 2021-04-07
BR112017017269B1 (pt) 2022-05-24
JP2018511459A (ja) 2018-04-26
BR112017017269A2 (pt) 2018-04-17
US20180036723A1 (en) 2018-02-08
EP3256252A1 (en) 2017-12-20
US10195598B2 (en) 2019-02-05
JP6685315B2 (ja) 2020-04-22

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