CN107530693A - 用于丙烯环氧化的钛沸石催化剂的再生方法 - Google Patents

用于丙烯环氧化的钛沸石催化剂的再生方法 Download PDF

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Publication number
CN107530693A
CN107530693A CN201680020837.XA CN201680020837A CN107530693A CN 107530693 A CN107530693 A CN 107530693A CN 201680020837 A CN201680020837 A CN 201680020837A CN 107530693 A CN107530693 A CN 107530693A
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CN
China
Prior art keywords
catalyst
reactor
stream
hydrogen peroxide
titanium
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Pending
Application number
CN201680020837.XA
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English (en)
Chinese (zh)
Inventor
D·里德尔
J·H·泰勒斯
D·乌尔班奇克
U·韦格利
L·斯皮斯基
A-N·帕乌莱斯库
A·施罗德
U·穆勒
M·韦登巴赫
W·J·维特兹
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BASF SE
Dow Global Technologies LLC
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BASF SE
Dow Global Technologies LLC
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Priority to CN202311377139.3A priority Critical patent/CN119456024A/zh
Publication of CN107530693A publication Critical patent/CN107530693A/zh
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/89Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/90Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/02Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12Treating with free oxygen-containing gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/04Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/6472-50 nm
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/085Group IVB- metallosilicates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201680020837.XA 2015-02-13 2016-02-12 用于丙烯环氧化的钛沸石催化剂的再生方法 Pending CN107530693A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202311377139.3A CN119456024A (zh) 2015-02-13 2016-02-12 用于丙烯环氧化的钛沸石催化剂的再生方法

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201562115658P 2015-02-13 2015-02-13
EP15154998.7 2015-02-13
US62/115,658 2015-02-13
EP15154998 2015-02-13
PCT/EP2016/052983 WO2016128538A1 (en) 2015-02-13 2016-02-12 Process for the regeneration of a titanium zeolite catalyst for propylene epoxidation

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CN202311377139.3A Pending CN119456024A (zh) 2015-02-13 2016-02-12 用于丙烯环氧化的钛沸石催化剂的再生方法

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US (1) US10195598B2 (enExample)
EP (1) EP3256252B1 (enExample)
JP (1) JP6685315B2 (enExample)
KR (1) KR102512661B1 (enExample)
CN (2) CN107530693A (enExample)
BR (1) BR112017017269B1 (enExample)
MX (1) MX2017010402A (enExample)
MY (1) MY189272A (enExample)
PL (1) PL3256252T3 (enExample)
SG (1) SG11201706530RA (enExample)
WO (1) WO2016128538A1 (enExample)

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CN110252393A (zh) * 2019-05-21 2019-09-20 江西农业大学 一种用于合成环氧大豆油的钛硅沸石负载镉催化剂、制备方法及应用
CN112678866A (zh) * 2020-12-24 2021-04-20 中国石油化工股份有限公司 一种烯烃聚合工业废酸渣资源化处理方法
CN113396012A (zh) * 2019-02-08 2021-09-14 赢创运营有限公司 有机化合物的氧化
RU2769979C1 (ru) * 2018-11-15 2022-04-12 Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайэнс Способ получения иерархического пористого титанатносиликатного молекулярного сита ts-1

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ES2781329T3 (es) 2015-07-22 2020-09-01 Basf Se Procedimiento para preparar ácido furan-2,5-dicarboxílico
EP3170828A1 (de) 2015-11-23 2017-05-24 Basf Se Verfahren zur herstellung von verbindungen mit 16-oxabicyclo[10.3.1]pentadecengerüst und deren folgeprodukten
ES2765740T3 (es) 2015-11-27 2020-06-10 Basf Se Síntesis ultrarápida de elevado rendimiento-espacio-tiempo de armazones orgánicos-metal
EP3178788A1 (en) 2015-12-08 2017-06-14 Basf Se A tin-containing zeolitic material having a bea framework structure
WO2017097806A1 (en) 2015-12-08 2017-06-15 Basf Se A tin-containing zeolitic material having a bea framework structure
WO2017133995A1 (de) 2016-02-01 2017-08-10 Basf Se Verfahren zur herstellung von c4-c15-lactamen
US10532970B2 (en) 2016-06-29 2020-01-14 Basf Se Process for the preparation of alpha, beta unsaturated aldehydes by oxidation of alcohols in the presence of a liquid phase
WO2018007481A1 (en) 2016-07-08 2018-01-11 Basf Se Process for preparing an organic sulfone
SG11201811020XA (en) 2016-07-20 2019-02-27 Basf Se A process for purifying propylene oxide
MY191861A (en) 2016-07-29 2022-07-18 Basf Corp Process for the preparation of a zeolitic material having a fau-type framework structure and use thereof in the selective catalytic reduction of nox
EP3544730A1 (en) 2016-11-28 2019-10-02 Basf Se Catalyst composite comprising an alkaline earth metal containing cha zeolite and use thereof in a process for the conversion of oxygenates to olefins
BR112019008783A2 (pt) 2016-11-30 2019-07-16 Basf Se processo para a conversão de etano-1,2-diol em etano-1,2-diamina
JP2019536774A (ja) 2016-11-30 2019-12-19 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se Mor骨格構造の銅変性ゼオライトを用いて、モノエタノールアミンをエチレンジアミンに変換する方法
HUE066373T2 (hu) 2016-12-13 2024-07-28 Basf Se Eljárás titántartalmú zeolit elõállítására
BR112020010507A2 (pt) * 2017-12-21 2020-11-10 Basf Se processo para a preparação de aldeídos alfa, beta insaturados
EP3604222A1 (en) * 2018-07-30 2020-02-05 Evonik Operations GmbH Process for the purification of hydrogen cyanide
CN110075914A (zh) * 2019-05-28 2019-08-02 江苏扬农化工集团有限公司 一种hppo工艺失活钛硅分子筛催化剂器内再生的方法
EP3812375A1 (en) * 2019-10-21 2021-04-28 Evonik Operations GmbH Process for the epoxidation of propene
CN112354557B (zh) * 2020-11-16 2023-03-24 华东师范大学 一种整体式钛沸石催化剂制备方法及其应用
CN112844468A (zh) * 2021-01-19 2021-05-28 中国科学院大连化学物理研究所 一种用于丙烯气相环氧化制环氧丙烷的催化剂及其制备方法
CN117545744A (zh) 2021-06-15 2024-02-09 巴斯夫欧洲公司 用于制备氧化烯烃的方法的停工方法
CN113368895B (zh) * 2021-07-13 2023-09-29 福州大学 一种具有高转化率的丙烯气相环氧化催化剂的制备方法
CN118043136A (zh) * 2021-09-30 2024-05-14 巴斯夫公司 用于脱氢和其他反应的多孔金属氧化物催化剂的预处理
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CN117504927B (zh) * 2023-11-10 2025-04-29 江西师范大学 一种负载型Ti-MWW分子筛与金属氧化物的复合催化剂及其制备与应用

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RU2769979C1 (ru) * 2018-11-15 2022-04-12 Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайэнс Способ получения иерархического пористого титанатносиликатного молекулярного сита ts-1
CN113396012A (zh) * 2019-02-08 2021-09-14 赢创运营有限公司 有机化合物的氧化
CN110252393A (zh) * 2019-05-21 2019-09-20 江西农业大学 一种用于合成环氧大豆油的钛硅沸石负载镉催化剂、制备方法及应用
CN112678866A (zh) * 2020-12-24 2021-04-20 中国石油化工股份有限公司 一种烯烃聚合工业废酸渣资源化处理方法
CN112678866B (zh) * 2020-12-24 2023-07-04 中国石油化工股份有限公司 一种烯烃聚合工业废酸渣资源化处理方法

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PL3256252T3 (pl) 2021-10-25
MX2017010402A (es) 2018-05-28
WO2016128538A1 (en) 2016-08-18
KR20170117509A (ko) 2017-10-23
MY189272A (en) 2022-01-31
SG11201706530RA (en) 2017-09-28
CN119456024A (zh) 2025-02-18
KR102512661B1 (ko) 2023-03-21
EP3256252B1 (en) 2021-04-07
BR112017017269B1 (pt) 2022-05-24
JP2018511459A (ja) 2018-04-26
BR112017017269A2 (pt) 2018-04-17
US20180036723A1 (en) 2018-02-08
EP3256252A1 (en) 2017-12-20
US10195598B2 (en) 2019-02-05
JP6685315B2 (ja) 2020-04-22

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