JP6100979B2 - ポリトリメチレンテレフタレート組成物、ポリエステル繊維およびそれらの製造方法 - Google Patents
ポリトリメチレンテレフタレート組成物、ポリエステル繊維およびそれらの製造方法 Download PDFInfo
- Publication number
- JP6100979B2 JP6100979B2 JP2016540723A JP2016540723A JP6100979B2 JP 6100979 B2 JP6100979 B2 JP 6100979B2 JP 2016540723 A JP2016540723 A JP 2016540723A JP 2016540723 A JP2016540723 A JP 2016540723A JP 6100979 B2 JP6100979 B2 JP 6100979B2
- Authority
- JP
- Japan
- Prior art keywords
- polytrimethylene terephthalate
- acid
- terephthalate composition
- fiber
- polyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- -1 Polytrimethylene terephthalate Polymers 0.000 title claims description 153
- 229920002215 polytrimethylene terephthalate Polymers 0.000 title claims description 124
- 239000000203 mixture Substances 0.000 title claims description 105
- 239000000835 fiber Substances 0.000 title claims description 98
- 229920000728 polyester Polymers 0.000 title claims description 71
- 238000004519 manufacturing process Methods 0.000 title claims description 33
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 159
- 239000002245 particle Substances 0.000 claims description 82
- 239000004408 titanium dioxide Substances 0.000 claims description 73
- 238000002425 crystallisation Methods 0.000 claims description 32
- 230000008025 crystallization Effects 0.000 claims description 32
- 238000002844 melting Methods 0.000 claims description 27
- 230000008018 melting Effects 0.000 claims description 27
- 238000009826 distribution Methods 0.000 claims description 26
- 239000002131 composite material Substances 0.000 claims description 17
- 229910052698 phosphorus Inorganic materials 0.000 claims description 15
- 239000011574 phosphorus Substances 0.000 claims description 15
- 238000005259 measurement Methods 0.000 claims description 14
- 238000002074 melt spinning Methods 0.000 claims description 14
- NMYFVWYGKGVPIW-UHFFFAOYSA-N 3,7-dioxabicyclo[7.2.2]trideca-1(11),9,12-triene-2,8-dione Chemical group O=C1OCCCOC(=O)C2=CC=C1C=C2 NMYFVWYGKGVPIW-UHFFFAOYSA-N 0.000 claims description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 description 68
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 42
- 230000008569 process Effects 0.000 description 28
- 239000002002 slurry Substances 0.000 description 25
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 19
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 18
- 239000011324 bead Substances 0.000 description 17
- 229920000642 polymer Polymers 0.000 description 16
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 15
- 238000006116 polymerization reaction Methods 0.000 description 15
- 238000010298 pulverizing process Methods 0.000 description 15
- 238000009987 spinning Methods 0.000 description 14
- 238000004804 winding Methods 0.000 description 13
- 150000003609 titanium compounds Chemical class 0.000 description 12
- 239000002253 acid Substances 0.000 description 9
- 238000007380 fibre production Methods 0.000 description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 8
- 238000005809 transesterification reaction Methods 0.000 description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- 238000005886 esterification reaction Methods 0.000 description 6
- 238000006068 polycondensation reaction Methods 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 238000000227 grinding Methods 0.000 description 5
- 239000002685 polymerization catalyst Substances 0.000 description 5
- 230000000379 polymerizing effect Effects 0.000 description 5
- 238000001238 wet grinding Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 150000003503 terephthalic acid derivatives Chemical class 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 3
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 2
- OGBVRMYSNSKIEF-UHFFFAOYSA-N Benzylphosphonic acid Chemical compound OP(O)(=O)CC1=CC=CC=C1 OGBVRMYSNSKIEF-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- QCNWZROVPSVEJA-UHFFFAOYSA-N Heptadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCC(O)=O QCNWZROVPSVEJA-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- BTZVDPWKGXMQFW-UHFFFAOYSA-N Pentadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCC(O)=O BTZVDPWKGXMQFW-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 239000006059 cover glass Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- DGXRZJSPDXZJFG-UHFFFAOYSA-N docosanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCCCCCC(O)=O DGXRZJSPDXZJFG-UHFFFAOYSA-N 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- QQHJDPROMQRDLA-UHFFFAOYSA-N hexadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCC(O)=O QQHJDPROMQRDLA-UHFFFAOYSA-N 0.000 description 2
- JJOJFIHJIRWASH-UHFFFAOYSA-N icosanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCCCC(O)=O JJOJFIHJIRWASH-UHFFFAOYSA-N 0.000 description 2
- 239000010954 inorganic particle Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VAWFFNJAPKXVPH-UHFFFAOYSA-N naphthalene-1,6-dicarboxylic acid Chemical compound OC(=O)C1=CC=CC2=CC(C(=O)O)=CC=C21 VAWFFNJAPKXVPH-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- BNJOQKFENDDGSC-UHFFFAOYSA-N octadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCC(O)=O BNJOQKFENDDGSC-UHFFFAOYSA-N 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 238000003908 quality control method Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- HQHCYKULIHKCEB-UHFFFAOYSA-N tetradecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCC(O)=O HQHCYKULIHKCEB-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- KQTIIICEAUMSDG-UHFFFAOYSA-N tricarballylic acid Chemical compound OC(=O)CC(C(O)=O)CC(O)=O KQTIIICEAUMSDG-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 2
- LWBHHRRTOZQPDM-UHFFFAOYSA-N undecanedioic acid Chemical compound OC(=O)CCCCCCCCCC(O)=O LWBHHRRTOZQPDM-UHFFFAOYSA-N 0.000 description 2
- BQFILCFZXYPAHF-UHFFFAOYSA-N (2,3,4,5,6-pentamethylphenyl)phosphonic acid Chemical compound CC1=C(C(=C(C(=C1P(O)(O)=O)C)C)C)C BQFILCFZXYPAHF-UHFFFAOYSA-N 0.000 description 1
- QNBCUVCNPWVFAX-UHFFFAOYSA-N (2,3,4,5-tetramethylphenyl)phosphonic acid Chemical compound CC=1C(=C(C(=C(C=1)P(O)(O)=O)C)C)C QNBCUVCNPWVFAX-UHFFFAOYSA-N 0.000 description 1
- CBEOMQYXZXNBHV-UHFFFAOYSA-N (2,3,4-triethylphenyl)phosphonic acid Chemical compound C(C)C1=C(C(=C(C=C1)P(O)(O)=O)CC)CC CBEOMQYXZXNBHV-UHFFFAOYSA-N 0.000 description 1
- OPVUJWKXVPOPDB-UHFFFAOYSA-N (2,3,4-trimethylphenyl)phosphonic acid Chemical compound CC1=C(C(=C(C=C1)P(O)(O)=O)C)C OPVUJWKXVPOPDB-UHFFFAOYSA-N 0.000 description 1
- NLVTWUFDUAPGOY-UHFFFAOYSA-N (2,3-diethyl-4,5-dimethylphenyl)phosphonic acid Chemical compound CCc1c(C)c(C)cc(c1CC)P(O)(O)=O NLVTWUFDUAPGOY-UHFFFAOYSA-N 0.000 description 1
- AQECRAAXCIMSJW-UHFFFAOYSA-N (2,3-diethyl-4-methylphenyl)phosphonic acid Chemical compound CCC1=C(C)C=CC(P(O)(O)=O)=C1CC AQECRAAXCIMSJW-UHFFFAOYSA-N 0.000 description 1
- QASAMEAWBNDEGR-UHFFFAOYSA-N (2,3-diethylphenyl)phosphonic acid Chemical compound CCC1=CC=CC(P(O)(O)=O)=C1CC QASAMEAWBNDEGR-UHFFFAOYSA-N 0.000 description 1
- CQPQUNGCTIETKF-UHFFFAOYSA-N (2,3-dimethylnaphthalen-1-yl)phosphonic acid Chemical compound C1=CC=C2C(P(O)(O)=O)=C(C)C(C)=CC2=C1 CQPQUNGCTIETKF-UHFFFAOYSA-N 0.000 description 1
- AOYVABWPDDHCDE-UHFFFAOYSA-N (2,3-dimethylphenyl)phosphonic acid Chemical compound CC1=CC=CC(P(O)(O)=O)=C1C AOYVABWPDDHCDE-UHFFFAOYSA-N 0.000 description 1
- CLAZGYXLHCGILH-UHFFFAOYSA-N (2,3-dipropylphenyl)phosphonic acid Chemical compound CCCC1=CC=CC(P(O)(O)=O)=C1CCC CLAZGYXLHCGILH-UHFFFAOYSA-N 0.000 description 1
- VCPZLNDUMGNUOJ-UHFFFAOYSA-N (2-butyl-3-ethylphenyl)phosphonic acid Chemical compound CCCCc1c(CC)cccc1P(O)(O)=O VCPZLNDUMGNUOJ-UHFFFAOYSA-N 0.000 description 1
- VLJVUWYHQVIDLJ-UHFFFAOYSA-N (2-butyl-3-methylphenyl)phosphonic acid Chemical compound CCCCc1c(C)cccc1P(O)(O)=O VLJVUWYHQVIDLJ-UHFFFAOYSA-N 0.000 description 1
- RJRRZABNCURWAM-UHFFFAOYSA-N (2-butylphenyl)phosphonic acid Chemical compound CCCCC1=CC=CC=C1P(O)(O)=O RJRRZABNCURWAM-UHFFFAOYSA-N 0.000 description 1
- JSHKFYUWWHFTNY-UHFFFAOYSA-N (2-ethylnaphthalen-1-yl)phosphonic acid Chemical compound CCc1ccc2ccccc2c1P(O)(O)=O JSHKFYUWWHFTNY-UHFFFAOYSA-N 0.000 description 1
- NEPSVFXUMQQTNC-UHFFFAOYSA-N (2-methylnaphthalen-1-yl)phosphonic acid Chemical compound C1=CC=CC2=C(P(O)(O)=O)C(C)=CC=C21 NEPSVFXUMQQTNC-UHFFFAOYSA-N 0.000 description 1
- YXTSJMYYIRPSDF-UHFFFAOYSA-N (2-methylphenyl)phosphonic acid Chemical compound CC1=CC=CC=C1P(O)(O)=O YXTSJMYYIRPSDF-UHFFFAOYSA-N 0.000 description 1
- RKACEGCEMGWDFM-UHFFFAOYSA-N (2-pentylphenyl)phosphonic acid Chemical compound CCCCCc1ccccc1P(O)(O)=O RKACEGCEMGWDFM-UHFFFAOYSA-N 0.000 description 1
- GDKNDQBTIVRVAV-UHFFFAOYSA-N (2-propylphenyl)phosphonic acid Chemical compound CCCC1=CC=CC=C1P(O)(O)=O GDKNDQBTIVRVAV-UHFFFAOYSA-N 0.000 description 1
- TVZLESVOQJEDEF-UHFFFAOYSA-N (3,4-dimethyl-2-propylphenyl)phosphonic acid Chemical compound CCCc1c(C)c(C)ccc1P(O)(O)=O TVZLESVOQJEDEF-UHFFFAOYSA-N 0.000 description 1
- PRPYSKMDGDVUSS-UHFFFAOYSA-N (3-ethyl-2-propylphenyl)phosphonic acid Chemical compound CCCc1c(CC)cccc1P(O)(O)=O PRPYSKMDGDVUSS-UHFFFAOYSA-N 0.000 description 1
- JTVVIJZOGQWKNB-UHFFFAOYSA-N (3-methyl-2-pentylphenyl)phosphonic acid Chemical compound CCCCCc1c(C)cccc1P(O)(O)=O JTVVIJZOGQWKNB-UHFFFAOYSA-N 0.000 description 1
- HBHBOVLIELOFLI-UHFFFAOYSA-N (3-methyl-2-propylphenyl)phosphonic acid Chemical compound CCCc1c(C)cccc1P(O)(O)=O HBHBOVLIELOFLI-UHFFFAOYSA-N 0.000 description 1
- XHRNRGJBLGSHHE-UHFFFAOYSA-N (4-methylphenyl)phosphinic acid Chemical compound CC1=CC=C(P(O)=O)C=C1 XHRNRGJBLGSHHE-UHFFFAOYSA-N 0.000 description 1
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 1
- FQXGHZNSUOHCLO-UHFFFAOYSA-N 2,2,4,4-tetramethyl-1,3-cyclobutanediol Chemical compound CC1(C)C(O)C(C)(C)C1O FQXGHZNSUOHCLO-UHFFFAOYSA-N 0.000 description 1
- JCTXKRPTIMZBJT-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,3-diol Chemical compound CC(C)C(O)C(C)(C)CO JCTXKRPTIMZBJT-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- JNJHAHZPZILFJI-UHFFFAOYSA-N 2-[2-[4-[4-[2-(2-hydroxyethoxy)ethoxy]phenyl]sulfonylphenoxy]ethoxy]ethanol Chemical compound C1=CC(OCCOCCO)=CC=C1S(=O)(=O)C1=CC=C(OCCOCCO)C=C1 JNJHAHZPZILFJI-UHFFFAOYSA-N 0.000 description 1
- MUHNBZQOTATUGE-UHFFFAOYSA-N 2-[4-[2-[4-(2-hydroxyethoxy)cyclohexyl]propan-2-yl]cyclohexyl]oxyethanol Chemical compound C1CC(OCCO)CCC1C(C)(C)C1CCC(OCCO)CC1 MUHNBZQOTATUGE-UHFFFAOYSA-N 0.000 description 1
- UTNSTOOXQPHXJQ-UHFFFAOYSA-N 2-[4-[4-(2-hydroxyethoxy)phenyl]sulfonylphenoxy]ethanol Chemical compound C1=CC(OCCO)=CC=C1S(=O)(=O)C1=CC=C(OCCO)C=C1 UTNSTOOXQPHXJQ-UHFFFAOYSA-N 0.000 description 1
- DSKYSDCYIODJPC-UHFFFAOYSA-N 2-butyl-2-ethylpropane-1,3-diol Chemical compound CCCCC(CC)(CO)CO DSKYSDCYIODJPC-UHFFFAOYSA-N 0.000 description 1
- FQRURIYVPWZATA-UHFFFAOYSA-N 2-butyl-3,4-dimethylphenol Chemical compound CCCCC1=C(C)C(C)=CC=C1O FQRURIYVPWZATA-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- IZXRSZNHUSJWIQ-UHFFFAOYSA-N 2-methylpropan-2-ol;titanium Chemical compound [Ti].CC(C)(C)O.CC(C)(C)O.CC(C)(C)O.CC(C)(C)O IZXRSZNHUSJWIQ-UHFFFAOYSA-N 0.000 description 1
- UOBYKYZJUGYBDK-UHFFFAOYSA-N 2-naphthoic acid Chemical compound C1=CC=CC2=CC(C(=O)O)=CC=C21 UOBYKYZJUGYBDK-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- WTKQQTGCQAFYOL-UHFFFAOYSA-N 3,4-dihydro-2h-naphthalene-1,1-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)(C(O)=O)CCCC2=C1 WTKQQTGCQAFYOL-UHFFFAOYSA-N 0.000 description 1
- NFEOIEVKEGDOBP-UHFFFAOYSA-N 3-[4-[2-[4-(3-hydroxypropoxy)cyclohexyl]propan-2-yl]cyclohexyl]oxypropan-1-ol Chemical compound OCCCOC1CCC(CC1)C(C)(C)C1CCC(CC1)OCCCO NFEOIEVKEGDOBP-UHFFFAOYSA-N 0.000 description 1
- CPHURRLSZSRQFS-UHFFFAOYSA-N 3-[4-[2-[4-(3-hydroxypropoxy)phenyl]propan-2-yl]phenoxy]propan-1-ol Chemical compound C=1C=C(OCCCO)C=CC=1C(C)(C)C1=CC=C(OCCCO)C=C1 CPHURRLSZSRQFS-UHFFFAOYSA-N 0.000 description 1
- MXQPSOVXNVQFDU-UHFFFAOYSA-N 3-[4-[4-(3-hydroxypropoxy)cyclohexyl]sulfonylcyclohexyl]oxypropan-1-ol Chemical compound OCCCOC1CCC(CC1)S(=O)(=O)C1CCC(CC1)OCCCO MXQPSOVXNVQFDU-UHFFFAOYSA-N 0.000 description 1
- AGPNMMUNVRCMQZ-UHFFFAOYSA-N 3-[4-[4-(3-hydroxypropoxy)phenyl]sulfonylphenoxy]propan-1-ol Chemical compound C1=CC(OCCCO)=CC=C1S(=O)(=O)C1=CC=C(OCCCO)C=C1 AGPNMMUNVRCMQZ-UHFFFAOYSA-N 0.000 description 1
- OHMSWSFFCKZMGL-UHFFFAOYSA-N 3-methylbutylphosphonic acid Chemical compound CC(C)CCP(O)(O)=O OHMSWSFFCKZMGL-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- WVDRSXGPQWNUBN-UHFFFAOYSA-N 4-(4-carboxyphenoxy)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1OC1=CC=C(C(O)=O)C=C1 WVDRSXGPQWNUBN-UHFFFAOYSA-N 0.000 description 1
- NEQFBGHQPUXOFH-UHFFFAOYSA-N 4-(4-carboxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C=C1 NEQFBGHQPUXOFH-UHFFFAOYSA-N 0.000 description 1
- WPSWDCBWMRJJED-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]phenol;oxirane Chemical class C1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 WPSWDCBWMRJJED-UHFFFAOYSA-N 0.000 description 1
- LZINOQJQXIEBNN-UHFFFAOYSA-N 4-hydroxybutyl dihydrogen phosphate Chemical compound OCCCCOP(O)(O)=O LZINOQJQXIEBNN-UHFFFAOYSA-N 0.000 description 1
- QYCPNUMTVZBTMM-UHFFFAOYSA-N 6-formamido-2-[(2-methylpropan-2-yl)oxycarbonylamino]hexanoic acid Chemical compound CC(C)(C)OC(=O)NC(C(O)=O)CCCCNC=O QYCPNUMTVZBTMM-UHFFFAOYSA-N 0.000 description 1
- UUAGPGQUHZVJBQ-UHFFFAOYSA-N Bisphenol A bis(2-hydroxyethyl)ether Chemical compound C=1C=C(OCCO)C=CC=1C(C)(C)C1=CC=C(OCCO)C=C1 UUAGPGQUHZVJBQ-UHFFFAOYSA-N 0.000 description 1
- BCEVJJYVOWNDFP-UHFFFAOYSA-N C1(CCCC2CCCCC12)(C(=O)O)C(=O)O.C1(C(CCC2CCCCC12)C(=O)O)C(=O)O Chemical compound C1(CCCC2CCCCC12)(C(=O)O)C(=O)O.C1(C(CCC2CCCCC12)C(=O)O)C(=O)O BCEVJJYVOWNDFP-UHFFFAOYSA-N 0.000 description 1
- ODGHZTUDIMAKNX-UHFFFAOYSA-N CCCCCCP(O)=O Chemical compound CCCCCCP(O)=O ODGHZTUDIMAKNX-UHFFFAOYSA-N 0.000 description 1
- MTWVYGIIHVUGNL-UHFFFAOYSA-N CCCCP(O)=O Chemical compound CCCCP(O)=O MTWVYGIIHVUGNL-UHFFFAOYSA-N 0.000 description 1
- RCZPHVPIOWNERS-UHFFFAOYSA-N CCCO[Ti] Chemical compound CCCO[Ti] RCZPHVPIOWNERS-UHFFFAOYSA-N 0.000 description 1
- DGLXNOJGOHKWTN-UHFFFAOYSA-N CCCP(O)=O Chemical compound CCCP(O)=O DGLXNOJGOHKWTN-UHFFFAOYSA-N 0.000 description 1
- ACBPPDYBJZVCTL-UHFFFAOYSA-N CCP(O)=O Chemical compound CCP(O)=O ACBPPDYBJZVCTL-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- IFAWYXIHOVRGHQ-UHFFFAOYSA-N Nonadecandioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCCC(O)=O IFAWYXIHOVRGHQ-UHFFFAOYSA-N 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- QLZHNIAADXEJJP-UHFFFAOYSA-N Phenylphosphonic acid Chemical compound OP(O)(=O)C1=CC=CC=C1 QLZHNIAADXEJJP-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- XDODWINGEHBYRT-UHFFFAOYSA-N [2-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCCCC1CO XDODWINGEHBYRT-UHFFFAOYSA-N 0.000 description 1
- LUSFFPXRDZKBMF-UHFFFAOYSA-N [3-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCCC(CO)C1 LUSFFPXRDZKBMF-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- INNSZZHSFSFSGS-UHFFFAOYSA-N acetic acid;titanium Chemical compound [Ti].CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O INNSZZHSFSFSGS-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- LBVBDLCCWCJXFA-UHFFFAOYSA-N adamantane-1,2-dicarboxylic acid Chemical compound C1C(C2)CC3CC1C(C(=O)O)C2(C(O)=O)C3 LBVBDLCCWCJXFA-UHFFFAOYSA-N 0.000 description 1
- RVIZJROSQMQZCG-UHFFFAOYSA-N adamantane-1,2-diol Chemical compound C1C(C2)CC3CC1C(O)C2(O)C3 RVIZJROSQMQZCG-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000005011 alkyl ether group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000005129 aryl carbonyl group Chemical group 0.000 description 1
- 150000007860 aryl ester derivatives Chemical class 0.000 description 1
- 125000005013 aryl ether group Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- KYQRDNYMKKJUTH-UHFFFAOYSA-N bicyclo[2.2.1]heptane-3,4-dicarboxylic acid Chemical compound C1CC2(C(O)=O)C(C(=O)O)CC1C2 KYQRDNYMKKJUTH-UHFFFAOYSA-N 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229940043430 calcium compound Drugs 0.000 description 1
- 150000001674 calcium compounds Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- UQFFSTQNDQYSAT-UHFFFAOYSA-N cyclobut-2-ene-1,1-dicarboxylic acid Chemical compound OC(=O)C1(C(O)=O)CC=C1 UQFFSTQNDQYSAT-UHFFFAOYSA-N 0.000 description 1
- PDXRQENMIVHKPI-UHFFFAOYSA-N cyclohexane-1,1-diol Chemical compound OC1(O)CCCCC1 PDXRQENMIVHKPI-UHFFFAOYSA-N 0.000 description 1
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
- PFURGBBHAOXLIO-UHFFFAOYSA-N cyclohexane-1,2-diol Chemical compound OC1CCCCC1O PFURGBBHAOXLIO-UHFFFAOYSA-N 0.000 description 1
- XBZSBBLNHFMTEB-UHFFFAOYSA-N cyclohexane-1,3-dicarboxylic acid Chemical compound OC(=O)C1CCCC(C(O)=O)C1 XBZSBBLNHFMTEB-UHFFFAOYSA-N 0.000 description 1
- RLMGYIOTPQVQJR-UHFFFAOYSA-N cyclohexane-1,3-diol Chemical compound OC1CCCC(O)C1 RLMGYIOTPQVQJR-UHFFFAOYSA-N 0.000 description 1
- VKONPUDBRVKQLM-UHFFFAOYSA-N cyclohexane-1,4-diol Chemical compound OC1CCC(O)CC1 VKONPUDBRVKQLM-UHFFFAOYSA-N 0.000 description 1
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 1
- DZQISOJKASMITI-UHFFFAOYSA-N decyl-dioxido-oxo-$l^{5}-phosphane;hydron Chemical compound CCCCCCCCCCP(O)(O)=O DZQISOJKASMITI-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- KSHDLNQYVGBYHZ-UHFFFAOYSA-N dibutylphosphinic acid Chemical compound CCCCP(O)(=O)CCCC KSHDLNQYVGBYHZ-UHFFFAOYSA-N 0.000 description 1
- KTLIMPGQZDZPSB-UHFFFAOYSA-N diethylphosphinic acid Chemical compound CCP(O)(=O)CC KTLIMPGQZDZPSB-UHFFFAOYSA-N 0.000 description 1
- NGKCHGKFHQDOPZ-UHFFFAOYSA-N dihexylphosphinic acid Chemical compound CCCCCCP(O)(=O)CCCCCC NGKCHGKFHQDOPZ-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- GOJNABIZVJCYFL-UHFFFAOYSA-N dimethylphosphinic acid Chemical compound CP(C)(O)=O GOJNABIZVJCYFL-UHFFFAOYSA-N 0.000 description 1
- QOWUATSFMAQUCQ-UHFFFAOYSA-N dinaphthalen-2-ylphosphinic acid Chemical compound C1=C(C=CC2=CC=CC=C12)P(O)(=O)C1=CC2=CC=CC=C2C=C1 QOWUATSFMAQUCQ-UHFFFAOYSA-N 0.000 description 1
- BEQVQKJCLJBTKZ-UHFFFAOYSA-N diphenylphosphinic acid Chemical compound C=1C=CC=CC=1P(=O)(O)C1=CC=CC=C1 BEQVQKJCLJBTKZ-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- WMDPJKZHARKRQI-UHFFFAOYSA-N dipropylphosphinic acid Chemical compound CCCP(O)(=O)CCC WMDPJKZHARKRQI-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- GHLKSLMMWAKNBM-UHFFFAOYSA-N dodecane-1,12-diol Chemical compound OCCCCCCCCCCCCO GHLKSLMMWAKNBM-UHFFFAOYSA-N 0.000 description 1
- SVMUEEINWGBIPD-UHFFFAOYSA-N dodecylphosphonic acid Chemical compound CCCCCCCCCCCCP(O)(O)=O SVMUEEINWGBIPD-UHFFFAOYSA-N 0.000 description 1
- 229920006240 drawn fiber Polymers 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- AEDZKIACDBYJLQ-UHFFFAOYSA-N ethane-1,2-diol;hydrate Chemical compound O.OCCO AEDZKIACDBYJLQ-UHFFFAOYSA-N 0.000 description 1
- XGZNHFPFJRZBBT-UHFFFAOYSA-N ethanol;titanium Chemical compound [Ti].CCO.CCO.CCO.CCO XGZNHFPFJRZBBT-UHFFFAOYSA-N 0.000 description 1
- MWQBWSPPTQGZII-UHFFFAOYSA-N ethoxy(phenyl)phosphinic acid Chemical compound CCOP(O)(=O)C1=CC=CC=C1 MWQBWSPPTQGZII-UHFFFAOYSA-N 0.000 description 1
- GATNOFPXSDHULC-UHFFFAOYSA-N ethylphosphonic acid Chemical compound CCP(O)(O)=O GATNOFPXSDHULC-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000010035 extrusion spinning Methods 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- UHSVYKSYPSBAKN-UHFFFAOYSA-N heptan-1-olate titanium(4+) Chemical compound CCCCCCCO[Ti](OCCCCCCC)(OCCCCCCC)OCCCCCCC UHSVYKSYPSBAKN-UHFFFAOYSA-N 0.000 description 1
- SXCBDZAEHILGLM-UHFFFAOYSA-N heptane-1,7-diol Chemical compound OCCCCCCCO SXCBDZAEHILGLM-UHFFFAOYSA-N 0.000 description 1
- VAJFLSRDMGNZJY-UHFFFAOYSA-N heptylphosphonic acid Chemical compound CCCCCCCP(O)(O)=O VAJFLSRDMGNZJY-UHFFFAOYSA-N 0.000 description 1
- GJBXIPOYHVMPQJ-UHFFFAOYSA-N hexadecane-1,16-diol Chemical compound OCCCCCCCCCCCCCCCCO GJBXIPOYHVMPQJ-UHFFFAOYSA-N 0.000 description 1
- KOARADCEQDEFIO-UHFFFAOYSA-N hexan-1-olate;titanium(4+) Chemical compound CCCCCCO[Ti](OCCCCCC)(OCCCCCC)OCCCCCC KOARADCEQDEFIO-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- UEKWYRXXACHNAS-UHFFFAOYSA-N hexoxy(phenyl)phosphinic acid Chemical compound CCCCCCOP(O)(=O)C1=CC=CC=C1 UEKWYRXXACHNAS-UHFFFAOYSA-N 0.000 description 1
- GJWAEWLHSDGBGG-UHFFFAOYSA-N hexylphosphonic acid Chemical compound CCCCCCP(O)(O)=O GJWAEWLHSDGBGG-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000002697 manganese compounds Chemical class 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- ZEIWWVGGEOHESL-UHFFFAOYSA-N methanol;titanium Chemical compound [Ti].OC.OC.OC.OC ZEIWWVGGEOHESL-UHFFFAOYSA-N 0.000 description 1
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- BCDIWLCKOCHCIH-UHFFFAOYSA-N methylphosphinic acid Chemical compound CP(O)=O BCDIWLCKOCHCIH-UHFFFAOYSA-N 0.000 description 1
- YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 description 1
- AQWKTFYCLNFHLF-UHFFFAOYSA-N naphthalen-1-ylphosphinic acid Chemical compound OP(=O)c1cccc2ccccc12 AQWKTFYCLNFHLF-UHFFFAOYSA-N 0.000 description 1
- YOOYVODKUBZAPO-UHFFFAOYSA-N naphthalen-1-ylphosphonic acid Chemical compound C1=CC=C2C(P(O)(=O)O)=CC=CC2=C1 YOOYVODKUBZAPO-UHFFFAOYSA-N 0.000 description 1
- SCCNWOCAQYWVCD-UHFFFAOYSA-N naphthalen-2-ylphosphinic acid Chemical compound OP(=O)c1ccc2ccccc2c1 SCCNWOCAQYWVCD-UHFFFAOYSA-N 0.000 description 1
- ABMFBCRYHDZLRD-UHFFFAOYSA-N naphthalene-1,4-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=C(C(O)=O)C2=C1 ABMFBCRYHDZLRD-UHFFFAOYSA-N 0.000 description 1
- DFFZOPXDTCDZDP-UHFFFAOYSA-N naphthalene-1,5-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1C(O)=O DFFZOPXDTCDZDP-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- WPUMVKJOWWJPRK-UHFFFAOYSA-N naphthalene-2,7-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=CC2=CC(C(=O)O)=CC=C21 WPUMVKJOWWJPRK-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- OLGGYSFJQGDOFX-UHFFFAOYSA-N nonylphosphonic acid Chemical compound CCCCCCCCCP(O)(O)=O OLGGYSFJQGDOFX-UHFFFAOYSA-N 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- NJGCRMAPOWGWMW-UHFFFAOYSA-N octylphosphonic acid Chemical compound CCCCCCCCP(O)(O)=O NJGCRMAPOWGWMW-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002903 organophosphorus compounds Chemical group 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- ZBPYFGWSQQFVCJ-UHFFFAOYSA-N pentadecane-1,15-diol Chemical compound OCCCCCCCCCCCCCCCO ZBPYFGWSQQFVCJ-UHFFFAOYSA-N 0.000 description 1
- WEMICRSBTLTNGT-UHFFFAOYSA-N pentan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCC[O-].CCCCC[O-].CCCCC[O-].CCCCC[O-] WEMICRSBTLTNGT-UHFFFAOYSA-N 0.000 description 1
- CKVICYBZYGZLLP-UHFFFAOYSA-N pentylphosphonic acid Chemical compound CCCCCP(O)(O)=O CKVICYBZYGZLLP-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- MLCHBQKMVKNBOV-UHFFFAOYSA-N phenylphosphinic acid Chemical compound OP(=O)C1=CC=CC=C1 MLCHBQKMVKNBOV-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- XRVCFZPJAHWYTB-UHFFFAOYSA-N prenderol Chemical compound CCC(CC)(CO)CO XRVCFZPJAHWYTB-UHFFFAOYSA-N 0.000 description 1
- 229950006800 prenderol Drugs 0.000 description 1
- NSETWVJZUWGCKE-UHFFFAOYSA-N propylphosphonic acid Chemical compound CCCP(O)(O)=O NSETWVJZUWGCKE-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 125000003003 spiro group Chemical group 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- LCZVKKUAUWQDPX-UHFFFAOYSA-N tert-butyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]ethyl]amino]acetate Chemical compound CC(=O)OC1=CC=CC=C1CN(CC(=O)OC(C)(C)C)CCN(CC(=O)OC(C)(C)C)CC1=CC=CC=C1OC(C)=O LCZVKKUAUWQDPX-UHFFFAOYSA-N 0.000 description 1
- OGDSVONAYZTTDA-UHFFFAOYSA-N tert-butylphosphonic acid Chemical compound CC(C)(C)P(O)(O)=O OGDSVONAYZTTDA-UHFFFAOYSA-N 0.000 description 1
- XLKZJJVNBQCVIX-UHFFFAOYSA-N tetradecane-1,14-diol Chemical compound OCCCCCCCCCCCCCCO XLKZJJVNBQCVIX-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- DPNUIZVZBWBCPB-UHFFFAOYSA-J titanium(4+);tetraphenoxide Chemical compound [Ti+4].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 DPNUIZVZBWBCPB-UHFFFAOYSA-J 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- ZFZDWMXUMXACHS-IACGZSPGSA-N tricyclo[5.2.1.02,6]decane-4,8-dimethanol Chemical compound C([C@H]1C2)C(CO)[C@H]2C2C1CC(CO)C2 ZFZDWMXUMXACHS-IACGZSPGSA-N 0.000 description 1
- DXNCZXXFRKPEPY-UHFFFAOYSA-N tridecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCC(O)=O DXNCZXXFRKPEPY-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- SFENPMLASUEABX-UHFFFAOYSA-N trihexyl phosphate Chemical compound CCCCCCOP(=O)(OCCCCCC)OCCCCCC SFENPMLASUEABX-UHFFFAOYSA-N 0.000 description 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- QJAVUVZBMMXBRO-UHFFFAOYSA-N tripentyl phosphate Chemical compound CCCCCOP(=O)(OCCCCC)OCCCCC QJAVUVZBMMXBRO-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- RXPQRKFMDQNODS-UHFFFAOYSA-N tripropyl phosphate Chemical compound CCCOP(=O)(OCCC)OCCC RXPQRKFMDQNODS-UHFFFAOYSA-N 0.000 description 1
- MGEISCKTUGVOHN-UHFFFAOYSA-N tris(2-hydroxyethyl) phosphate Chemical compound OCCOP(=O)(OCCO)OCCO MGEISCKTUGVOHN-UHFFFAOYSA-N 0.000 description 1
- XCBZQRLQLSKCLQ-UHFFFAOYSA-N tris(2-hydroxypropyl) phosphate Chemical compound CC(O)COP(=O)(OCC(C)O)OCC(C)O XCBZQRLQLSKCLQ-UHFFFAOYSA-N 0.000 description 1
- RAHOVDYZPHFOSY-UHFFFAOYSA-N tris(3-hydroxypropyl) phosphate Chemical compound OCCCOP(=O)(OCCCO)OCCCO RAHOVDYZPHFOSY-UHFFFAOYSA-N 0.000 description 1
- XSMIOONHPKRREI-UHFFFAOYSA-N undecane-1,11-diol Chemical compound OCCCCCCCCCCCO XSMIOONHPKRREI-UHFFFAOYSA-N 0.000 description 1
- GKIQHTGBORJXKZ-UHFFFAOYSA-N undecylphosphonic acid Chemical compound CCCCCCCCCCCP(O)(O)=O GKIQHTGBORJXKZ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 208000016261 weight loss Diseases 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/205—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase
- C08J3/2053—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the additives only being premixed with a liquid phase
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D1/00—Treatment of filament-forming or like material
- D01D1/02—Preparation of spinning solutions
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/04—Pigments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K2003/026—Phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Multicomponent Fibers (AREA)
Description
(a)固有粘度が0.50〜1.60dL/gの範囲にあること。
(b)レーザー回折/散乱式粒子径分布測定装置による粒度分布測定における、粒径1.0μmを超える粒子の重量分布が5.0重量%以下である二酸化チタンを0.05〜3.0重量%含有すること。
(c)示差走査熱量計を用いて、融点以上に加熱したポリトリメチレンテレフタレート組成物を10℃/分の速度で降温した際に示される結晶化発熱ピークトップ温度が165℃以上であること。
(d)示差走査熱量計を用いて、融点以上に加熱したポリトリメチレンテレフタレート組成物を10℃/分の速度で降温した際に示される結晶化発熱ピークの半値幅が20℃以下であること、
である。
本発明に用いるポリエステルは、トリメチレンテレフタレートを主たる繰り返し単位とするポリエステルである。ここで主たる繰り返し単位とは、ポリエステルを構成する全繰り返し単位中、85モル%以上、好ましくは90モル%以上、より好ましくは95モル%以上がトリメチレンテレフタレートからなるポリエステルであることを表す。このポリエステルは、トリメチレンテレフタレート単位を構成する成分以外の第3成分を共重合した、共重合ポリトリメチレンテレフタレートであってもよい。
さらに具体的に第3成分として好ましく用いられる成分について述べる。
(a)固有粘度が0.50〜1.60dL/gの範囲にあること。
(b)レーザー回折/散乱式粒子径分布測定装置による粒度分布測定における、粒径1.0μmを超える粒子の重量分布が5.0重量%以下である二酸化チタンを0.05〜3.0重量%含有すること。
(c)示差走査熱量計を用いて、融点以上に加熱したポリトリメチレンテレフタレート組成物を10℃/分の速度で降温した際に表れる結晶化発熱ピークトップ温度が165℃以上であること。
(d)示差走査熱量計を用いて、融点以上に加熱したポリトリメチレンテレフタレート組成物を10℃/分の速度で降温した際に表れる結晶化発熱ピークの半値幅が20℃以下であること。
ポリエステルポリマーの固有粘度は、ウベローデ粘度計を用い、オルトクロロフェノール溶液中、35℃において測定した粘度の値から求めた。
ポリトリメチレンテレフタレート組成物の結晶化発熱ピーク温度、半値幅は、TA Instruments社製示差走査熱量計 DSC Q20を用いて、サンプル10mgを窒素雰囲気下20℃/分の速度で30℃から280℃まで昇温し、280℃到達後2分間保持し、その後10℃/分の速度で50℃まで降温した。降温の過程で表示される降温結晶化温度のピークトップ温度とピーク半値幅を求めた。また昇温時の吸熱ピークトップ温度を測定することにより、ポリトリメチレンテレフタレート組成物の融点を測定することができ、評価している組成物がポリトリメチレンテレフタレート組成物であることを示す指標となりうる。
サンプルを加熱溶融して、円形ディスクを作成し、(株)リガク製蛍光X線装置 ZSX100E型を用いて含有しているチタン元素量とリン元素量を定量した。二酸化チタン量は定量されたチタン元素量から換算して求めた。
ポリマー50mgを2枚のカバーグラス間にはさんで280℃で溶融プレスし、急冷したのち、位相差顕微鏡を用いて観察し、日本レギュレーター(株)製画像解析装置 ルーゼックス500で顕微鏡像内の最大長が5.0μm以上の粒子数をカウントした。
調製された二酸化チタン/トリメチレングリコールスラリーを(株)堀場製作所製レーザー回折/散乱式粒子径分布測定装置 LA−950を用いて、粒度分布を測定した。測定されたデータから粒径1.0μmを超える粒子の重量比率を求めた。
JIS L−1070記載の方法に準拠して測定を行った。
ポリエステル繊維100mを検尺機で巻取り、その重量から繊度(dtex)を求め、マルチフィラメントの単糸数で除した値を単糸繊度とした。
マルチフィラメントパッケージを100本分巻き取り、断糸の発生により3kgパッケージの完巻が出来なかった割合を断糸率として評価した。
マルチフィラメントパッケージを100本分巻き取り、巻き取られた繊維の表面に毛羽があるものを数えて、その割合を毛羽率とした。
ポリトリメチレンテレフタレート組成物中の粗大粒子が含まれている影響を評価するために下記の操作にて、濾過圧上昇率を評価した。小型1軸スクリュータイプ押出機の溶融ポリエステルの出側にポリエステルの定量供給装置を取り付けた紡糸口金中に金網フィルターを装着した。次いで、溶融ポリエステルの温度、溶融ポリエステルの流量が一定となるようにコントロールし、3日間にわたって連続的に溶融紡糸を行った。この時の紡糸口金に備えた圧力計の圧力を記録し、溶融紡糸開始初期の圧力値に対する3日後の圧力値の上昇率を求めた。
得られたポリエステル組成物中のポリエステル部分の繰り返し単位の化学構造は、ポリエステル組成物のサンプルを適切な溶媒に溶解させ、日本電子製JEOLA−600を用いて600MHzの1H−NMRスペクトルを測定し算出した。
得られた繊維サンプルを繊維軸に直交する方向で切断し、その切断面を光学顕微鏡で観察し、複合繊維の横断面の形状を観察した。その断面形状から異形度の評価を行った。
ヘリカル式撹拌翼を有する混合器において、Sachtleben Chemie社製二酸化チタン HOMBITAN LW−S(アナターゼ型、平均粒径0.3μm)を50重量%の濃度となるようにトリメチレングリコールと1時間混合させて二酸化チタンスラリーを調製し、粉砕メディアとして平均粒径0.8mmのガラスビーズを重点させたNETZSCH−Feinmahltechnik社製Agitator Bead Mill LME30に導入して該スラリーの湿式粉砕を2回、装置内でスラリーを循環させて実施し、トリメチレングリコールを添加して二酸化チタンが20重量%の濃度となるように希釈した。この粉砕処理時の処理条件は、処理温度58〜62度、回転数3000〜3100ppm、流量31〜32kg/hであった。その後、スラリー中の二酸化チタンの粒度分布を測定した。得られた結果を表1に示した。
スラリーの湿式粉砕を3回、装置内でスラリーを循環させて実施したこと以外は参考例1と同様に行った。得られた結果を表1に併せて示した。
二酸化チタンとして、チタン工業(株)製KRONOS KA−30(アナターゼ型、平均粒径0.2〜0.4μm)を使用したこと以外は参考例1と同様に行った。得られた結果を表1に併せて示した。
スラリーの湿式粉砕を1回実施したこと以外は参考例1と同様に行った。得られた結果を表1に併せて示した。
粉砕メディアとして平均粒径0.5mmのガラスビーズを使用したこと以外は参考例1と同様に行った。得られた結果を表1に併せて示した。
粉砕メディアとして平均粒径1.5mmのガラスビーズを使用したこと以外は参考例1と同様に行った。得られた結果を表1に併せて示した。
テレフタル酸に対するモル比が2.3となるようにトリメチレングリコールを分散させ、水およびトリメチレングリコール蒸気を留出できる連続式エステル化反応装置に連続的に供給し、徐々に反応させながら、250℃まで昇温して予備重合を行った。その後、得られた反応物に対して、最終的に得られるポリトリメチレンテレフタレートに対して、テトラ−n−ブトキシチタンを0.08重量%、リン酸トリメチルを0.01重量%、参考例1で調製した二酸化チタンスラリーを二酸化チタン量として0.3重量%となるように連続的に添加しながら、連続式重合反応装置に供給した。反応混合物は徐々に昇温しながら減圧して過剰のトリメチレングリコールを除去し、最終的に温度を265℃、圧力を70Pa以下として、固有粘度が0.96dL/gとなる時点で反応装置から押し出し、ストランドカッターによってペレット化した。ペレット化されたポリトリメチレンテレフタレート組成物の固有粘度、結晶化発熱ピーク温度と半値幅、二酸化チタン量とリン元素量、二酸化チタン粗大粒子の数をそれぞれ測定した。得られた結果を表2に示す。
実施例1において、使用した二酸化チタンスラリーを参考例1のものから参考例2〜6で調製したものに変更し、順に実施例2、3、比較例1、2、3とした以外は、実施例1と同様に行った。結果を表2及び表3に併せて示した。
実施例1で得られたポリトリメチレンテレフタレート組成物のペレットおよび固有粘度0.52dL/gのポリエチレンテレフタレートのペレットを、エクストルーダーを用いてポリトリメチレンテレフタレートは265℃、ポリエチレンテレフタレートは285℃でそれぞれ溶融したのち、両ポリマーの温度を270℃として、複合比が50:50となるように、すなわちそれぞれのポリマーの吐出量を10.6g/分とし、図2に示すような繊維横断面形状の異形度が1.4となる形状で吐出口径0.29mm、吐出口数72個の公知の複合紡糸口金を通して紡出した。
実施例4において、使用したポリトリメチレンテレフタレート組成物のペレットを比較例1で調製したものに変更した以外は実施例4と同様に行った。すなわち二酸化チタンスラリーとしては参考例4で調製したものを用いた。結果を表4に併せて示す。
2 本発明のポリトリメチレンテレフタレート組成物以外の樹脂からなる成分
Claims (5)
- ポリトリメチレンテレフタレートが、主たる繰り返し単位をトリメチレンテレフタレート単位とするポリエステルであり、下記(a)〜(d)の各要件を同時に満足する、ポリトリメチレンテレフタレート組成物。
(a)固有粘度が0.50〜1.60dL/gの範囲にあること。
(b)レーザー回折/散乱式粒子径分布測定装置による粒度分布測定における、粒径1.0μmを超える粒子の重量分布が5.0重量%以下である二酸化チタンを0.05〜3.0重量%含有すること。
(c)示差走査熱量計を用いて、融点以上に加熱したポリトリメチレンテレフタレート組成物を10℃/分の速度で降温した際に表れる結晶化発熱ピークトップ温度が165℃以上であること。
(d)示差走査熱量計を用いて、融点以上に加熱したポリトリメチレンテレフタレート組成物を10℃/分の速度で降温した際に表れる結晶化発熱ピークの半値幅が20℃以下であること。 - リン元素量として、3〜100重量ppm含有している請求項1記載のポリトリメチレンテレフタレート組成物。
- 請求項1または2に記載のポリトリメチレンテレフタレート組成物から構成されたポリエステル繊維。
- 請求項1または2に記載のポリトリメチレンテレフタレート組成物が少なくとも1成分を構成しているポリエステル複合繊維。
- 請求項1または2に記載のポリトリメチレンテレフタレート組成物を溶融紡糸することを特徴とするポリエステル繊維の製造方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015007729 | 2015-01-19 | ||
JP2015007729 | 2015-01-19 | ||
PCT/JP2016/050821 WO2016117428A1 (ja) | 2015-01-19 | 2016-01-13 | ポリトリメチレンテレフタレート組成物、ポリエステル繊維およびそれらの製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP6100979B2 true JP6100979B2 (ja) | 2017-03-22 |
JPWO2016117428A1 JPWO2016117428A1 (ja) | 2017-04-27 |
Family
ID=56416975
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016540723A Active JP6100979B2 (ja) | 2015-01-19 | 2016-01-13 | ポリトリメチレンテレフタレート組成物、ポリエステル繊維およびそれらの製造方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US10550241B2 (ja) |
EP (1) | EP3249012B1 (ja) |
JP (1) | JP6100979B2 (ja) |
KR (1) | KR102535438B1 (ja) |
CN (1) | CN107109040B (ja) |
TW (1) | TWI684626B (ja) |
WO (1) | WO2016117428A1 (ja) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102124376B1 (ko) * | 2018-09-28 | 2020-06-19 | 주식회사 휴비스 | 3d 프린터용 필라멘트 |
KR102124375B1 (ko) * | 2018-09-28 | 2020-06-19 | 주식회사 휴비스 | 3d 프린터용 필라멘트 |
KR102419939B1 (ko) * | 2019-12-27 | 2022-07-11 | 도레이첨단소재 주식회사 | 습식부직포 및 이를 포함하는 물품 |
KR102477568B1 (ko) | 2020-06-16 | 2022-12-15 | 서울대학교산학협력단 | 1 mm 이하 크기 생체 시료의 투명화 전처리 방법 및 이를 포함하는 생체 시료의 투명화 방법 |
CN114106415B (zh) * | 2021-08-05 | 2023-06-13 | 浙江恒逸石化研究院有限公司 | 一种聚酯用液态二氧化钛消光剂和应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006022241A (ja) * | 2004-07-09 | 2006-01-26 | Teijin Fibers Ltd | ポリエステル組成物、その製造方法および繊維 |
JP2008248164A (ja) * | 2007-03-30 | 2008-10-16 | Teijin Fibers Ltd | 撥水性ポリエステル組成物及びポリエステル繊維 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05132611A (ja) * | 1991-11-14 | 1993-05-28 | Teijin Ltd | 繊維用ポリエステル組成物 |
ES2210807T3 (es) | 1997-09-03 | 2004-07-01 | Asahi Kasei Kabushiki Kaisha | Compuesto de resina de poliester. |
ID28765A (id) | 1998-10-30 | 2001-06-28 | Asahi Chemical Ind | Komposisi poliester dan serat yang dihasilkannya |
JP2007186629A (ja) | 2006-01-16 | 2007-07-26 | Asahi Kasei Chemicals Corp | ポリトリメチレンテレフタレート樹脂組成物 |
JP2009035572A (ja) | 2007-07-31 | 2009-02-19 | Solotex Corp | 二酸化チタンマスターバッチ、および二酸化チタン含有ポリトリメチレンテレフタレート系ポリエステルの製造方法 |
JP2009091445A (ja) * | 2007-10-09 | 2009-04-30 | Asahi Kasei Fibers Corp | ポリエーテルエステル及びその繊維、加工糸、織編物 |
JP4942667B2 (ja) * | 2008-01-11 | 2012-05-30 | 旭化成せんい株式会社 | ポリエーテルエステル繊維、加工糸、織編物 |
JP4924495B2 (ja) * | 2008-03-14 | 2012-04-25 | 東レ株式会社 | スクリーン紗用モノフィラメント |
JP2009221412A (ja) * | 2008-03-18 | 2009-10-01 | Toray Ind Inc | 改質ポリエステルの製造方法 |
JP5346207B2 (ja) * | 2008-12-05 | 2013-11-20 | 旭化成せんい株式会社 | ポリエーテルエステル及びポリエーテルエステル組成物 |
JP5132611B2 (ja) | 2009-03-10 | 2013-01-30 | キヤノン株式会社 | 現像剤補給容器 |
-
2016
- 2016-01-13 JP JP2016540723A patent/JP6100979B2/ja active Active
- 2016-01-13 EP EP16740035.7A patent/EP3249012B1/en active Active
- 2016-01-13 WO PCT/JP2016/050821 patent/WO2016117428A1/ja active Application Filing
- 2016-01-13 US US15/541,635 patent/US10550241B2/en active Active
- 2016-01-13 CN CN201680006367.1A patent/CN107109040B/zh active Active
- 2016-01-13 KR KR1020177022298A patent/KR102535438B1/ko active IP Right Grant
- 2016-01-19 TW TW105101559A patent/TWI684626B/zh active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006022241A (ja) * | 2004-07-09 | 2006-01-26 | Teijin Fibers Ltd | ポリエステル組成物、その製造方法および繊維 |
JP2008248164A (ja) * | 2007-03-30 | 2008-10-16 | Teijin Fibers Ltd | 撥水性ポリエステル組成物及びポリエステル繊維 |
Also Published As
Publication number | Publication date |
---|---|
JPWO2016117428A1 (ja) | 2017-04-27 |
KR20170105551A (ko) | 2017-09-19 |
US10550241B2 (en) | 2020-02-04 |
US20180265667A1 (en) | 2018-09-20 |
CN107109040B (zh) | 2019-06-28 |
CN107109040A (zh) | 2017-08-29 |
KR102535438B1 (ko) | 2023-05-22 |
TW201631030A (zh) | 2016-09-01 |
EP3249012A1 (en) | 2017-11-29 |
WO2016117428A1 (ja) | 2016-07-28 |
TWI684626B (zh) | 2020-02-11 |
EP3249012A4 (en) | 2018-01-10 |
EP3249012B1 (en) | 2019-08-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6100979B2 (ja) | ポリトリメチレンテレフタレート組成物、ポリエステル繊維およびそれらの製造方法 | |
US6685859B2 (en) | Processes for making poly(trimethylene terephthalate) yarn | |
EP2258891B1 (en) | Polyethylene naphthalate fiber and process for producing the polyethylene naphthalate fiber | |
EP2253747B1 (en) | Polyethylene naphthalate fiber and process for producing the polyethylene naphthalate fiber | |
US4668732A (en) | Polyester composition and process for producing the same | |
US7332561B2 (en) | Polytrimethylene terephthalate composition particles and process for producing same | |
JP7251260B2 (ja) | カチオン可染性ポリエステルおよびその製造方法 | |
JP2004183143A (ja) | ポリエステル繊維及びその製造方法 | |
WO2017022569A1 (ja) | ポリエチレンテレフタレート繊維およびポリエステル樹脂 | |
JP2013064156A (ja) | ポリエステルの製造方法およびそのポリエステルを用いてなるポリエステル繊維 | |
JP6515743B2 (ja) | 難燃性ポリエステル繊維およびその製造方法 | |
JP2015010294A (ja) | メルトブロー不織布製造用ポリエチレンテレフタレート組成物、およびそれからなるメルトブロー不織布 | |
JP2004218160A (ja) | 易フィブリル性ポリエステル繊維 | |
JP2011063895A (ja) | ポリエステル繊維及びそれを用いて得られた仮撚加工糸 | |
JP5245630B2 (ja) | ポリエステルの製造方法およびそのポリエステルを用いてなるポリエステル繊維 | |
JP2004256965A (ja) | 複合仮撚加工糸の製造方法 | |
JP3973575B2 (ja) | 易フィブリル性ポリエステル繊維 | |
JP2007191601A (ja) | マスターバッチ組成物の製造方法 | |
JP2001213952A (ja) | 非アンチモン系ポリエステル重合用触媒 | |
JP2005126869A (ja) | ポリエステル未延伸糸の製造方法 | |
JP2004060063A (ja) | ポリエステル未延伸糸の製造方法 | |
JP2007191600A (ja) | ポリトリメチレンテレフタレート系マスターバッチ組成物およびポリエステル組成物 | |
JP2004277962A (ja) | 混繊糸の製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20161129 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20161216 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20170131 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20170223 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6100979 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313111 |
|
S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |