JP6085456B2 - リチウムイオン二次電池用電解液及びリチウムイオン二次電池 - Google Patents
リチウムイオン二次電池用電解液及びリチウムイオン二次電池 Download PDFInfo
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- JP6085456B2 JP6085456B2 JP2012265727A JP2012265727A JP6085456B2 JP 6085456 B2 JP6085456 B2 JP 6085456B2 JP 2012265727 A JP2012265727 A JP 2012265727A JP 2012265727 A JP2012265727 A JP 2012265727A JP 6085456 B2 JP6085456 B2 JP 6085456B2
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- Prior art keywords
- ether
- lithium ion
- ion secondary
- lithium
- secondary battery
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- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims description 71
- 229910001416 lithium ion Inorganic materials 0.000 title claims description 71
- 239000003792 electrolyte Substances 0.000 title claims description 12
- 150000002642 lithium compounds Chemical class 0.000 claims description 63
- 239000008151 electrolyte solution Substances 0.000 claims description 60
- 150000002170 ethers Chemical class 0.000 claims description 29
- -1 dicarboxylic acid anion Chemical class 0.000 claims description 26
- 239000002904 solvent Substances 0.000 claims description 20
- 229910003002 lithium salt Inorganic materials 0.000 claims description 19
- 159000000002 lithium salts Chemical class 0.000 claims description 19
- 150000001450 anions Chemical class 0.000 claims description 18
- 239000000126 substance Substances 0.000 claims description 16
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 11
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 11
- 125000004429 atom Chemical group 0.000 claims description 11
- 229910052796 boron Inorganic materials 0.000 claims description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims description 11
- 239000011574 phosphorus Substances 0.000 claims description 11
- 229910015015 LiAsF 6 Inorganic materials 0.000 claims description 6
- 229910013063 LiBF 4 Inorganic materials 0.000 claims description 6
- 229910013684 LiClO 4 Inorganic materials 0.000 claims description 6
- 229910012513 LiSbF 6 Inorganic materials 0.000 claims description 6
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- LGGCGWDMDWEQLN-UHFFFAOYSA-N 1,1,1,2,2,4,4-heptafluoro-4-(1,1,3,3,4,4,4-heptafluorobutoxy)butane Chemical compound FC(F)(F)C(F)(F)CC(F)(F)OC(F)(F)CC(F)(F)C(F)(F)F LGGCGWDMDWEQLN-UHFFFAOYSA-N 0.000 claims description 4
- RPSFZSRVLPIAMN-UHFFFAOYSA-N 1,1,1,2,2-pentafluoro-3-(1,1,2,2-tetrafluoroethoxy)propane Chemical compound FC(F)C(F)(F)OCC(F)(F)C(F)(F)F RPSFZSRVLPIAMN-UHFFFAOYSA-N 0.000 claims description 4
- ZYAMKYAPIQPWQR-UHFFFAOYSA-N 1,1,1,2,2-pentafluoro-3-methoxypropane Chemical compound COCC(F)(F)C(F)(F)F ZYAMKYAPIQPWQR-UHFFFAOYSA-N 0.000 claims description 4
- YQQHEHMVPLLOKE-UHFFFAOYSA-N 1,1,2,2-tetrafluoro-1-methoxyethane Chemical compound COC(F)(F)C(F)F YQQHEHMVPLLOKE-UHFFFAOYSA-N 0.000 claims description 4
- CIVGBESMFDRXNF-UHFFFAOYSA-N 1-(1,1,2,2-tetrafluoroethoxy)butane Chemical compound CCCCOC(F)(F)C(F)F CIVGBESMFDRXNF-UHFFFAOYSA-N 0.000 claims description 4
- DEYAWNMYIUDQER-UHFFFAOYSA-N 1-(1,1,2,2-tetrafluoroethoxy)propane Chemical compound CCCOC(F)(F)C(F)F DEYAWNMYIUDQER-UHFFFAOYSA-N 0.000 claims description 4
- MCWPMXPNJVZOTP-UHFFFAOYSA-N 2,3-dihydro-1,4-benzodioxin-5-ylboronic acid Chemical group O1CCOC2=C1C=CC=C2B(O)O MCWPMXPNJVZOTP-UHFFFAOYSA-N 0.000 claims description 4
- ZASBKNPRLPFSCA-UHFFFAOYSA-N 2-(difluoromethoxy)-1,1,1-trifluoroethane Chemical compound FC(F)OCC(F)(F)F ZASBKNPRLPFSCA-UHFFFAOYSA-N 0.000 claims description 4
- OBAYXRZHJPDDHB-UHFFFAOYSA-N 2-methyl-1-(1,1,2,2-tetrafluoroethoxy)propane Chemical compound CC(C)COC(F)(F)C(F)F OBAYXRZHJPDDHB-UHFFFAOYSA-N 0.000 claims description 4
- CIMLAZSOXWBTDB-UHFFFAOYSA-N 3-methyl-1-(1,1,2,2-tetrafluoroethoxy)butane Chemical compound CC(C)CCOC(F)(F)C(F)F CIMLAZSOXWBTDB-UHFFFAOYSA-N 0.000 claims description 4
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Images
Classifications
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- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
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- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
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- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
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- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
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JP2012265727A JP6085456B2 (ja) | 2012-12-04 | 2012-12-04 | リチウムイオン二次電池用電解液及びリチウムイオン二次電池 |
KR1020130085656A KR20140071870A (ko) | 2012-12-04 | 2013-07-19 | 리튬 이차 전지용 전해액 및 이를 포함하는 리튬 이차 전지 |
US14/083,256 US9478828B2 (en) | 2012-12-04 | 2013-11-18 | Electrolyte for rechargeable lithium battery and rechargeable lithium battery including the same |
KR1020130150224A KR101854718B1 (ko) | 2012-12-04 | 2013-12-04 | 리튬 이차 전지용 전해액 및 이를 포함하는 리튬 이차 전지 |
CN201310645969.XA CN103855428B (zh) | 2012-12-04 | 2013-12-04 | 用于可再充电锂电池的电解质和包括其的可再充电锂电池 |
EP13195585.8A EP2741362B1 (en) | 2012-12-04 | 2013-12-04 | Electrolyte for rechargeable lithium battery and rechargeable lithium battery including the same |
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JP2012265727A JP6085456B2 (ja) | 2012-12-04 | 2012-12-04 | リチウムイオン二次電池用電解液及びリチウムイオン二次電池 |
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US10811727B2 (en) | 2017-12-07 | 2020-10-20 | Enevate Corporation | Silicon-based energy storage devices with ether containing electrolyte additives |
US10957898B2 (en) | 2018-12-21 | 2021-03-23 | Enevate Corporation | Silicon-based energy storage devices with anhydride containing electrolyte additives |
US11456484B2 (en) | 2017-12-07 | 2022-09-27 | Enevate Corporation | Silicon-based energy storage devices with linear carbonate containing electrolyte additives |
US11075408B2 (en) | 2017-12-07 | 2021-07-27 | Enevate Corporation | Silicon-based energy storage devices with fluorinated polymer containing electrolyte additives |
WO2015025882A1 (ja) * | 2013-08-21 | 2015-02-26 | 積水化学工業株式会社 | 電解液、及びリチウムイオン二次電池 |
TWI580097B (zh) * | 2014-09-26 | 2017-04-21 | Lg化學股份有限公司 | 非水性液態電解質及含彼之鋰二次電池 |
JP6669506B2 (ja) * | 2015-01-26 | 2020-03-18 | 株式会社日本触媒 | 非水電解液及びこれを備えたリチウムイオン二次電池 |
JP6676280B2 (ja) * | 2015-03-03 | 2020-04-08 | 株式会社豊田中央研究所 | リチウムイオン二次電池及びその使用方法 |
CA2994808C (en) * | 2015-08-04 | 2023-12-05 | E.I. Du Pont De Nemours And Company | Nonaqueous electrolyte compositions comprising lithium oxalato phosphates |
JP6975525B2 (ja) * | 2015-10-02 | 2021-12-01 | 株式会社日本触媒 | リチウムイオン二次電池 |
KR102555496B1 (ko) | 2015-11-12 | 2023-07-12 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 양극 활물질, 이를 포함하는 양극 및 리튬 이차 전지 |
WO2017179681A1 (ja) * | 2016-04-15 | 2017-10-19 | 国立大学法人東京大学 | リチウムイオン二次電池 |
JP7233359B2 (ja) * | 2016-08-19 | 2023-03-06 | ソルヴェイ(ソシエテ アノニム) | シリルオキサレートを含有する非水性電解質組成物 |
JP6778396B2 (ja) * | 2017-05-09 | 2020-11-04 | トヨタ自動車株式会社 | 非水電解質二次電池 |
US11329321B2 (en) | 2017-05-29 | 2022-05-10 | Nec Corporation | Lithium ion secondary battery |
WO2019113528A1 (en) * | 2017-12-07 | 2019-06-13 | Enevate Corporation | Silicon-based energy storage devices with carboxylic ether, carboxylic acid based salt, or acrylate electrolyte containing electrolyte additives |
WO2019113532A1 (en) | 2017-12-07 | 2019-06-13 | Enevate Corporation | Silicon-based energy storage devices with fluorinated cyclic compound containing electrolyte additives |
WO2019180945A1 (ja) * | 2018-03-23 | 2019-09-26 | 富山薬品工業株式会社 | 蓄電デバイス用電解質及び非水電解液 |
JP7155719B2 (ja) * | 2018-07-31 | 2022-10-19 | 株式会社Gsユアサ | 非水電解質蓄電素子及び非水電解質蓄電素子の製造方法 |
US11165099B2 (en) | 2018-12-21 | 2021-11-02 | Enevate Corporation | Silicon-based energy storage devices with cyclic organosilicon containing electrolyte additives |
WO2020190076A1 (ko) * | 2019-03-21 | 2020-09-24 | 주식회사 엘지화학 | 리튬 이차전지용 비수전해액 및 이를 포함하는 리튬 이차전지 |
JP7243461B2 (ja) * | 2019-05-31 | 2023-03-22 | 株式会社豊田自動織機 | 電解液及びリチウムイオン二次電池 |
US11398641B2 (en) | 2019-06-05 | 2022-07-26 | Enevate Corporation | Silicon-based energy storage devices with silicon containing electrolyte additives |
EP3982444A4 (en) * | 2019-06-05 | 2023-11-29 | Daikin Industries, Ltd. | ELECTROLYTIC SOLUTION, SECONDARY BATTERY AND MODULE |
US20220209230A1 (en) | 2019-07-22 | 2022-06-30 | Lg Energy Solution, Ltd. | Lithium Secondary Battery |
WO2022054343A1 (ja) * | 2020-09-14 | 2022-03-17 | TeraWatt Technology株式会社 | リチウム2次電池 |
KR20230093305A (ko) * | 2020-10-23 | 2023-06-27 | 유미코아 | 특정 액체 전해질을 갖는 전기화학 셀 |
WO2023059080A1 (ko) * | 2021-10-06 | 2023-04-13 | 솔브레인 주식회사 | 전해액 및 이를 포함하는 이차전지 |
EP4415099A1 (en) * | 2021-10-06 | 2024-08-14 | Soulbrain Co., Ltd. | Electrolyte and secondary battery comprising same |
CN114447426B (zh) * | 2021-12-22 | 2024-08-16 | 清华大学 | 锂硫电池电解液、其制备方法及锂硫电池 |
WO2024184682A1 (en) * | 2023-03-08 | 2024-09-12 | Ses Holdings Pte. Ltd. | Electrolytes containing sulfonamide-type cyclic salts, and energy-storage cells and batteries made therewith |
CN116903660A (zh) * | 2023-06-01 | 2023-10-20 | 福建德尔科技股份有限公司 | 二氟双草酸磷酸锂的自动化安全制备方法 |
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EP1879252A4 (en) * | 2005-04-19 | 2010-06-23 | Panasonic Corp | WATER-FREE ELECTROLYTE SOLUTION, ELECTROCHEMICAL ENERGY STORAGE DEVICE THEREFOR AND SECONDARY BATTERY WITH A WATER-FREE ELECTROLYTE |
JP2008077915A (ja) * | 2006-09-20 | 2008-04-03 | Sanyo Electric Co Ltd | リフロー対応リチウム二次電池 |
CA2686890C (en) * | 2007-05-11 | 2015-10-20 | National Research Council Of Canada | Plastic crystal electrolyte with a broad potential window |
KR101159001B1 (ko) * | 2007-09-12 | 2012-06-21 | 다이킨 고교 가부시키가이샤 | 전해액 |
JP2009187880A (ja) * | 2008-02-08 | 2009-08-20 | Panasonic Corp | 非水電解液二次電池 |
JP5253905B2 (ja) * | 2008-06-30 | 2013-07-31 | パナソニック株式会社 | 非水電解液および非水電解液二次電池 |
JP2010123287A (ja) * | 2008-11-17 | 2010-06-03 | Panasonic Corp | 非水電解液および非水電解液二次電池 |
US9263731B2 (en) * | 2010-11-12 | 2016-02-16 | A123 Systems Llc | High performance lithium or lithium ion cell |
US9123973B2 (en) * | 2010-12-22 | 2015-09-01 | Samsung Sdi Co., Ltd. | Electrolyte for lithium secondary battery and lithium secondary battery comprising the same |
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2012
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