JP6041809B2 - 中温作動ナトリウム電池 - Google Patents
中温作動ナトリウム電池 Download PDFInfo
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- JP6041809B2 JP6041809B2 JP2013542120A JP2013542120A JP6041809B2 JP 6041809 B2 JP6041809 B2 JP 6041809B2 JP 2013542120 A JP2013542120 A JP 2013542120A JP 2013542120 A JP2013542120 A JP 2013542120A JP 6041809 B2 JP6041809 B2 JP 6041809B2
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- 239000011734 sodium Substances 0.000 title claims description 62
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title claims description 43
- 229910052708 sodium Inorganic materials 0.000 title claims description 43
- 239000007774 positive electrode material Substances 0.000 claims description 69
- 239000002798 polar solvent Substances 0.000 claims description 65
- 239000007788 liquid Substances 0.000 claims description 39
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 37
- 239000011593 sulfur Substances 0.000 claims description 37
- 229910052717 sulfur Inorganic materials 0.000 claims description 37
- 239000012528 membrane Substances 0.000 claims description 28
- 229910052744 lithium Inorganic materials 0.000 claims description 27
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 26
- 239000007773 negative electrode material Substances 0.000 claims description 21
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 20
- ATHHXGZTWNVVOU-UHFFFAOYSA-N N-methylformamide Chemical compound CNC=O ATHHXGZTWNVVOU-UHFFFAOYSA-N 0.000 claims description 20
- 229910052740 iodine Inorganic materials 0.000 claims description 20
- 239000011630 iodine Substances 0.000 claims description 20
- 150000002500 ions Chemical class 0.000 claims description 20
- 230000005484 gravity Effects 0.000 claims description 18
- 239000011261 inert gas Substances 0.000 claims description 15
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical group CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims description 8
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 8
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 7
- 150000001340 alkali metals Chemical class 0.000 claims description 7
- 239000011149 active material Substances 0.000 claims description 6
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 claims description 5
- OHLUUHNLEMFGTQ-UHFFFAOYSA-N N-methylacetamide Chemical compound CNC(C)=O OHLUUHNLEMFGTQ-UHFFFAOYSA-N 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 5
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 claims description 4
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims description 4
- LZJIBRSVPKKOSI-UHFFFAOYSA-O ethanolammonium nitrate Chemical compound [NH3+]CCO.[O-][N+]([O-])=O LZJIBRSVPKKOSI-UHFFFAOYSA-O 0.000 claims description 4
- RPMPQTVHEJVLCR-UHFFFAOYSA-N pentaaluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3] RPMPQTVHEJVLCR-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 claims description 4
- 239000006182 cathode active material Substances 0.000 claims description 3
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 3
- 239000002585 base Substances 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 239000002241 glass-ceramic Substances 0.000 claims 2
- 239000010405 anode material Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 description 32
- 239000002184 metal Substances 0.000 description 32
- 239000002904 solvent Substances 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 13
- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 description 11
- 238000003411 electrode reaction Methods 0.000 description 9
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000000919 ceramic Substances 0.000 description 8
- 230000007246 mechanism Effects 0.000 description 6
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229920001021 polysulfide Polymers 0.000 description 4
- 239000005077 polysulfide Substances 0.000 description 4
- 150000008117 polysulfides Polymers 0.000 description 4
- 238000006467 substitution reaction Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- 229910001413 alkali metal ion Inorganic materials 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000002608 ionic liquid Substances 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 235000009518 sodium iodide Nutrition 0.000 description 3
- 229910001415 sodium ion Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910014103 Na-S Inorganic materials 0.000 description 2
- 229910014147 Na—S Inorganic materials 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- GFZPUGCMGGUPHH-UHFFFAOYSA-N [I].[Na] Chemical class [I].[Na] GFZPUGCMGGUPHH-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001768 cations Chemical group 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000006112 glass ceramic composition Substances 0.000 description 2
- 229940006487 lithium cation Drugs 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- HYHCSLBZRBJJCH-UHFFFAOYSA-N sodium polysulfide Chemical compound [Na+].S HYHCSLBZRBJJCH-UHFFFAOYSA-N 0.000 description 2
- ZIQRIAYNHAKDDU-UHFFFAOYSA-N sodium;hydroiodide Chemical compound [Na].I ZIQRIAYNHAKDDU-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 239000002227 LISICON Substances 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- 229910003003 Li-S Inorganic materials 0.000 description 1
- 229910009496 Li1.5Al0.5Ge1.5 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- -1 alkali metal salt Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000005354 aluminosilicate glass Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/3909—Sodium-sulfur cells
- H01M10/3954—Sodium-sulfur cells containing additives or special arrangement in the sulfur compartment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/399—Cells with molten salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Description
2Na+3S→Na2S3
Na++1/2I2+e−→NaI
2Na++1/8S8+2e−→Na2S 又は
2Na++3/8S8+2e−→Na2S3
(硫黄の場合、種々の価数のポリスルフィドも正極において形成されるであろう)
NaI→Na++1/2I2+e−
Na2S→2Na++1/8S8+2e− 又は
Na2S3→2Na++3/8S8+2e−
(硫黄の場合、種々の価数のポリスルフィドも正極において還元されるであろう)
正極反応:
1/2I2+e−→I−
(正極活物質13としてヨウ素を使用した場合)
1/8S8+2e−→S−2 又は
Sy+2e−→Sy −2 1<y<30 又は
1/8S8+Sy −2+2e−→S(y+1) −2 1<y<30
(正極活物質13として硫黄を使用した場合、しかしながらある種のポリスルフィドもまた正極に形成される)
負極反応:
Na→Na++e−
正極反応
I→1/2I2+e−
(正極活物質13としてヨウ素を使用した場合)
S→1/8S8+2e− 又は
Sy −2→Sy+2e− 1<y<30 又は
S(y+1) −2→1/8S8+Sy −2+2e− 1<y<30
(正極活物質13として硫黄を使用した場合)
負極反応
Na++e−→Na
正極反応:
2Na++1/8S8+e→Na2S
(正極活物質13として硫黄を使用した場合、しかしながらある種のポリスルフィドもまた正極に形成される)
負極反応:
Na→Na++e−
正極反応:
Na2S→2Na++1/8S8+2e
負極反応:
Na++e−→Na
Claims (19)
- 負極材を収納する負極室と、正極室と、正極室中に存在する極性溶媒と、正極室中に存在する正極活物質と、負極室と正極室とを分離するイオン導電性セパレーターと、正極集電体とから成る再充電可能ガルバーニ電池であって、負極材は液体アルカリ金属から成り、正極活物質は、その比重が極性溶媒の比重よりも大きい非ガス物質から成り、正極集電体は、正極活物質および極性溶媒の界面位置が変化しても正極活物質および極性溶媒の界面を電気的に接続する構成を有し、ガルバーニ電池の充放電時に、正極室中の液体をガルバーニ電池から排出でき、再度ガルバーニ電池に流入できる構成をガルバーニ電池が有することを特徴とする再充電可能ガルバーニ電池。
- 負極材がナトリウム又はリチウムから成る請求項1記載の再充電可能ガルバーニ電池。
- 正極活物質が硫黄またはヨウ素の少なくとも1つから成る請求項2に記載の再充電可能ガルバーニ電池。
- 負極材がリチウムから成り、正極活物質が硫黄から成り、ガルバーニ電池の温度が185℃〜250℃に維持される請求項3に記載の再充電可能ガルバーニ電池。
- 負極材がナトリウムから成り、ガルバーニ電池の温度が100℃〜200℃に維持される請求項3に記載の再充電可能ガルバーニ電池。
- ガルバーニ電池の温度が100℃〜185℃に維持される請求項5に記載の再充電可能ガルバーニ電池。
- ガルバーニ電池の温度が110℃〜170℃に維持される請求項5に記載の再充電可能ガルバーニ電池。
- イオン導電性膜が、NaSICON、ナトリウムβアルミナ、ナトリウムβ’アルミナ、ナトリウムβ”アルミナ、LiSICON及びガラスセラミックの少なくとも1つから成る請求項3に記載の再充電可能ガルバーニ電池。
- 極性溶媒が、アセトアミド、メチルアセトアミド、ジメチルアセトアミド、N−メチルホルムアミド(NMF)、ホルムアミド、ジメチルホルムアミド、テトラグリム、ジグリ
ム、ジメチルエーテル、硝酸エタノールアンモニウム、イミダゾリウムハロゲノアルミネート塩、及びこれらの組合せから選択される1つ以上から成る請求項3に記載の再充電可能ガルバーニ電池。 - ガルバーニ電池の充放電時に、極性溶媒をガルバーニ電池より排出でき、再度ガルバーニ電池に流入できる構成をガルバーニ電池が有する請求項3に記載の再充電可能ガルバーニ電池。
- 負極室内の上部空間に不活性ガスを存在させることが出来、ガルバーニ電池の充放電時に不活性ガスをガルバーニ電池から排出でき、再度ガルバーニ電池に流入できる構成をガルバーニ電池が有する請求項10に記載の再充電可能ガルバーニ電池。
- イオン導電性膜が平面状またはチューブ状である請求項1に記載の再充電可能ガルバーニ電池。
- 正極集電体が、正極室の基部から上部に向けて伸びている1つ以上のフィンから成る請求項1に記載の再充電可能ガルバーニ電池。
- 電池が完全に充電された状態または完全に放電した状態において、界面がフィンの高さを超えないようにフィンの高さが設計されている請求項13に記載の再充電可能ガルバーニ電池。
- フィンに1つ以上の穴が設けられている請求項14に記載の再充電可能ガルバーニ電池。
- 負極材から成る負極室と、正極室と、正極室内に存在する極性溶媒と、正極室内に存在する正極活物質と、負極室と極性溶媒とを分離するイオン導電性セパレーターと、正極集電体とから成るガルバーニ電池が1つ以上から成る電池であって、電池は100℃〜250℃で作動し、負極は液体のナトリウム又はリチウムから成り、正極活物質は液体の硫黄またはヨウ素から成り、正極活物質の比重は極性溶媒の比重より大きく、正極集電体は、正極活物質および極性溶媒の界面位置が変化しても正極活物質および極性溶媒の界面を電気的に接続する構成を有し、ガルバーニ電池の充放電時に、正極室中の液体をガルバーニ電池から排出でき、再度ガルバーニ電池に流入できる構成をガルバーニ電池が有することを特徴とする電池。
- 極性溶媒が、アセトアミド、メチルアセトアミド、ジメチルアセトアミド、N−メチルホルムアミド(NMF)、ホルムアミド、ジメチルホルムアミド、テトラグリム、ジグリム、ジメチルエーテル、硝酸エタノールアンモニウム、イミダゾリウムハロゲノアルミネート塩、及びこれらの組合せから選択される1つ以上から成り、イオン導電性膜が、NaSICON、ナトリウムβアルミナ、ナトリウムβ’アルミナ、ナトリウムβ”アルミナ、LiSICON及びガラスセラミックの少なくとも1つから成り、イオン導電性膜が平面状またはチューブ状である請求項16に記載の電池。
- 負極材がナトリウムから成り、ガルバーニ電池の温度が100℃〜200℃に維持される請求項17に記載の電池。
- 負極室と、正極室と、正極室内に存在する正極集電体と、正極室から負極室を分離するイオン導電性膜とから成る電池を得る工程と;負極室内に負極材を配置する工程と;正極室内に正極活物質を配置する工程と;正極室内に極性溶媒を配置する工程と;正極活物質および極性溶媒の界面位置が変化しても正極活物質および極性溶媒の界面を電気的に接続することを確実にする工程と、ガルバーニ電池の充放電時に、正極室中の液体をガルバーニ電池から排出でき、再度ガルバーニ電池に流入できる構成を付与する工程とから成るガルバーニ電池の組立方法であって、負極材は液体アルカリ金属から成り、正極活物質は硫黄またはヨウ素から成り、正極活物質が正極室内の極性溶媒よりも下に位置するように正極活物質の比重は極性溶媒の比重よりも大きいことを特徴とするガルバーニ電池の組立方法。
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- 2011-11-30 KR KR1020137016600A patent/KR101940337B1/ko active IP Right Grant
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KR102220665B1 (ko) * | 2018-06-12 | 2021-02-25 | 김민웅 | 수동식 칼 연마장치 |
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KR20130129993A (ko) | 2013-11-29 |
EP2647080A2 (en) | 2013-10-09 |
JP2013545246A (ja) | 2013-12-19 |
US20120141856A1 (en) | 2012-06-07 |
EP2647080B8 (en) | 2019-05-22 |
WO2012075079A2 (en) | 2012-06-07 |
WO2012075079A3 (en) | 2012-09-20 |
US10170798B2 (en) | 2019-01-01 |
EP2647080B1 (en) | 2018-08-29 |
KR101940337B1 (ko) | 2019-01-18 |
EP2647080A4 (en) | 2015-04-22 |
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