JP5951522B2 - セラミックスペースト及び積層体 - Google Patents
セラミックスペースト及び積層体 Download PDFInfo
- Publication number
- JP5951522B2 JP5951522B2 JP2013031970A JP2013031970A JP5951522B2 JP 5951522 B2 JP5951522 B2 JP 5951522B2 JP 2013031970 A JP2013031970 A JP 2013031970A JP 2013031970 A JP2013031970 A JP 2013031970A JP 5951522 B2 JP5951522 B2 JP 5951522B2
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- ceramic paste
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- 239000000919 ceramic Substances 0.000 title claims description 96
- 239000000654 additive Substances 0.000 claims description 70
- 239000002245 particle Substances 0.000 claims description 47
- 230000000996 additive effect Effects 0.000 claims description 33
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- 239000002253 acid Chemical group 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000012790 adhesive layer Substances 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- 150000002148 esters Chemical group 0.000 claims description 8
- -1 phosphate ester salt Chemical class 0.000 claims description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 150000001412 amines Chemical group 0.000 claims description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 125000001033 ether group Chemical group 0.000 claims description 5
- 125000003916 ethylene diamine group Chemical group 0.000 claims description 5
- 125000002636 imidazolinyl group Chemical group 0.000 claims description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 150000008054 sulfonate salts Chemical class 0.000 claims 1
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- 229910052760 oxygen Inorganic materials 0.000 description 19
- 239000001301 oxygen Substances 0.000 description 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 18
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- UODXCYZDMHPIJE-UHFFFAOYSA-N menthanol Chemical compound CC1CCC(C(C)(C)O)CC1 UODXCYZDMHPIJE-UHFFFAOYSA-N 0.000 description 6
- 239000004014 plasticizer Substances 0.000 description 6
- 150000003863 ammonium salts Chemical class 0.000 description 5
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- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
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- 238000010586 diagram Methods 0.000 description 3
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- 150000004665 fatty acids Chemical class 0.000 description 3
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- 150000003839 salts Chemical class 0.000 description 3
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- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- WOYWLLHHWAMFCB-UHFFFAOYSA-N 2-ethylhexyl acetate Chemical compound CCCCC(CC)COC(C)=O WOYWLLHHWAMFCB-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical group CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- SELZTOJHBRTCNM-UHFFFAOYSA-N acetic acid;phthalic acid Chemical compound CC(O)=O.CC(O)=O.OC(=O)C1=CC=CC=C1C(O)=O SELZTOJHBRTCNM-UHFFFAOYSA-N 0.000 description 2
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- NNRLDGQZIVUQTE-UHFFFAOYSA-N gamma-Terpineol Chemical compound CC(C)=C1CCC(C)(O)CC1 NNRLDGQZIVUQTE-UHFFFAOYSA-N 0.000 description 2
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- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 1
- RUJPNZNXGCHGID-UHFFFAOYSA-N (Z)-beta-Terpineol Natural products CC(=C)C1CCC(C)(O)CC1 RUJPNZNXGCHGID-UHFFFAOYSA-N 0.000 description 1
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- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- CCTFMNIEFHGTDU-UHFFFAOYSA-N 3-methoxypropyl acetate Chemical compound COCCCOC(C)=O CCTFMNIEFHGTDU-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910013641 LiNbO 3 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical group CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 229940088601 alpha-terpineol Drugs 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
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- 239000000314 lubricant Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
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- 238000002360 preparation method Methods 0.000 description 1
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- 229910002076 stabilized zirconia Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- QJVXKWHHAMZTBY-GCPOEHJPSA-N syringin Chemical compound COC1=CC(\C=C\CO)=CC(OC)=C1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 QJVXKWHHAMZTBY-GCPOEHJPSA-N 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B18/00—Layered products essentially comprising ceramics, e.g. refractory products
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- C04B35/453—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zinc, tin, or bismuth oxides or solid solutions thereof with other oxides, e.g. zincates, stannates or bismuthates
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Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
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| JP2013031970A JP5951522B2 (ja) | 2012-03-28 | 2013-02-21 | セラミックスペースト及び積層体 |
| US13/849,680 US9187374B2 (en) | 2012-03-28 | 2013-03-25 | Ceramics paste and laminated body |
| EP13160979.4A EP2664599B1 (de) | 2012-03-28 | 2013-03-26 | Keramische paste und laminatkörper |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| JP2012073050 | 2012-03-28 | ||
| JP2012073050 | 2012-03-28 | ||
| JP2013031970A JP5951522B2 (ja) | 2012-03-28 | 2013-02-21 | セラミックスペースト及び積層体 |
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| JP2013227192A JP2013227192A (ja) | 2013-11-07 |
| JP5951522B2 true JP5951522B2 (ja) | 2016-07-13 |
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| EP (1) | EP2664599B1 (de) |
| JP (1) | JP5951522B2 (de) |
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| JP5788926B2 (ja) * | 2013-05-13 | 2015-10-07 | 日本碍子株式会社 | 炭化水素ガスセンサ |
| JP6324760B2 (ja) * | 2014-03-05 | 2018-05-16 | 日本碍子株式会社 | ガスセンサ |
| JP6295906B2 (ja) * | 2014-09-29 | 2018-03-20 | 株式会社デンソー | 積層型ガスセンサ素子およびその製造方法 |
| WO2016136905A1 (ja) * | 2015-02-27 | 2016-09-01 | 国立研究開発法人物質・材料研究機構 | 母材と粒状材料を混合した受容体層を被覆したセンサ |
| US9850588B2 (en) | 2015-09-09 | 2017-12-26 | Rohm And Haas Electronic Materials Llc | Bismuth electroplating baths and methods of electroplating bismuth on a substrate |
| DE112019000051T5 (de) * | 2018-03-29 | 2020-01-23 | Ngk Insulators, Ltd. | Gassensorelement |
| JP7319214B2 (ja) * | 2019-09-18 | 2023-08-01 | 日本特殊陶業株式会社 | センサ素子、ガスセンサ及びセンサ素子の製造方法 |
| US11940405B2 (en) * | 2019-09-18 | 2024-03-26 | Niterra Co., Ltd. | Sensor element, gas sensor, and method for manufacturing sensor element |
| CN111517778B (zh) * | 2020-05-20 | 2021-07-20 | 华南理工大学 | 一种低温烧结氧化锌压敏陶瓷及其制备方法 |
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| JP2002321980A (ja) * | 2001-04-23 | 2002-11-08 | Tdk Corp | セラミック塗料、セラミックグリーンシートの製造方法およびセラミック電子部品の製造方法 |
| JP2002321981A (ja) | 2001-04-23 | 2002-11-08 | Sanyo Chem Ind Ltd | セラミック材料用分散剤 |
| JP4152841B2 (ja) * | 2003-09-12 | 2008-09-17 | Ｔｄｋ株式会社 | セラミックスラリーの製造方法、グリーンシートおよび積層セラミック部品 |
| JP2005247660A (ja) * | 2004-03-05 | 2005-09-15 | Jsr Corp | 誘電体膜形成用組成物、誘電体膜形成用組成物の製造方法ならびに誘電体膜および誘電体膜を含むキャパシタ |
| US7695580B2 (en) | 2006-01-17 | 2010-04-13 | Air Products And Chemicals, Inc. | Method of forming a ceramic to ceramic joint |
| JP4262743B2 (ja) | 2006-12-28 | 2009-05-13 | 日本碍子株式会社 | ＮＯｘ分解電極及びＮＯｘセンサの製造方法 |
| JP5005564B2 (ja) * | 2008-01-28 | 2012-08-22 | 日本碍子株式会社 | 積層体の形成方法、センサ素子の作製方法、およびセンサ素子 |
| EP2415731B1 (de) * | 2009-03-31 | 2015-02-25 | Sekisui Chemical Co., Ltd. | Verfahren zur herstellung einer schlammzusammensetzung |
| JP5412390B2 (ja) * | 2009-09-11 | 2014-02-12 | 株式会社日本触媒 | 固体酸化物形燃料電池用スカンジア安定化ジルコニアシートの製造方法および固体酸化物形燃料電池用スカンジア安定化ジルコニアシート |
| JP5666941B2 (ja) * | 2010-02-26 | 2015-02-12 | 花王株式会社 | 塩基性セラミックス含有スラリー組成物 |
| CN105175590B (zh) * | 2010-08-19 | 2017-10-03 | 株式会社可乐丽 | 聚乙烯醇缩醛树脂 |
| JP5885622B2 (ja) | 2011-09-07 | 2016-03-15 | 花王株式会社 | 塩基性セラミックス含有スラリー組成物 |
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Also Published As
| Publication number | Publication date |
|---|---|
| US20130260983A1 (en) | 2013-10-03 |
| EP2664599A1 (de) | 2013-11-20 |
| JP2013227192A (ja) | 2013-11-07 |
| EP2664599B1 (de) | 2019-11-20 |
| US9187374B2 (en) | 2015-11-17 |
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