JP5798186B2 - 強化電解質膜 - Google Patents
強化電解質膜 Download PDFInfo
- Publication number
- JP5798186B2 JP5798186B2 JP2013512079A JP2013512079A JP5798186B2 JP 5798186 B2 JP5798186 B2 JP 5798186B2 JP 2013512079 A JP2013512079 A JP 2013512079A JP 2013512079 A JP2013512079 A JP 2013512079A JP 5798186 B2 JP5798186 B2 JP 5798186B2
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- electrolyte membrane
- polymer
- proton conducting
- nanofiber mat
- conducting polymer
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1041—Polymer electrolyte composites, mixtures or blends
- H01M8/1053—Polymer electrolyte composites, mixtures or blends consisting of layers of polymers with at least one layer being ionically conductive
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1041—Polymer electrolyte composites, mixtures or blends
- H01M8/1046—Mixtures of at least one polymer and at least one additive
- H01M8/1051—Non-ion-conducting additives, e.g. stabilisers, SiO2 or ZrO2
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
- H01M8/106—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the chemical composition of the porous support
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
- H01M8/1062—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the physical properties of the porous support, e.g. its porosity or thickness
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1067—Polymeric electrolyte materials characterised by their physical properties, e.g. porosity, ionic conductivity or thickness
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
- H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/16—Homopolymers or copolymers of vinylidene fluoride
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0088—Composites
- H01M2300/0094—Composites in the form of layered products, e.g. coatings
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Electrochemistry (AREA)
- Composite Materials (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Fuel Cell (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Reinforced Plastic Materials (AREA)
- Conductive Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US34808610P | 2010-05-25 | 2010-05-25 | |
| US61/348,086 | 2010-05-25 | ||
| PCT/US2011/036935 WO2011149732A2 (en) | 2010-05-25 | 2011-05-18 | Reinforced electrolyte membrane |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013531867A JP2013531867A (ja) | 2013-08-08 |
| JP2013531867A5 JP2013531867A5 (enExample) | 2014-07-03 |
| JP5798186B2 true JP5798186B2 (ja) | 2015-10-21 |
Family
ID=44626644
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013512079A Active JP5798186B2 (ja) | 2010-05-25 | 2011-05-18 | 強化電解質膜 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US9893373B2 (enExample) |
| EP (2) | EP2577787B1 (enExample) |
| JP (1) | JP5798186B2 (enExample) |
| CN (1) | CN103004001B (enExample) |
| WO (1) | WO2011149732A2 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018155598A1 (ja) | 2017-02-23 | 2018-08-30 | 旭化成株式会社 | 組成物、複合膜、膜電極接合体 |
| WO2018186386A1 (ja) | 2017-04-03 | 2018-10-11 | 旭化成株式会社 | 複合高分子電解質膜 |
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8628871B2 (en) * | 2005-10-28 | 2014-01-14 | 3M Innovative Properties Company | High durability fuel cell components with cerium salt additives |
| KR20130114187A (ko) | 2011-01-19 | 2013-10-16 | 클리어엣지 파워 코포레이션 | Pem 적용을 위한 양자 전도성 멤브레인을 보강하기 위한 다공성 나노-섬유 매트 |
| JP5867828B2 (ja) * | 2011-04-28 | 2016-02-24 | 日本バイリーン株式会社 | 複合膜およびその製造方法 |
| CN103857831B (zh) | 2011-10-10 | 2016-08-17 | 3M创新有限公司 | 催化剂电极及其制备和使用方法 |
| KR20140126734A (ko) * | 2012-03-29 | 2014-10-31 | 코오롱인더스트리 주식회사 | 고분자 전해질막, 이의 제조 방법 및 이를 포함하는 막-전극 어셈블리 |
| JP6155469B2 (ja) * | 2012-07-02 | 2017-07-05 | パナソニックIpマネジメント株式会社 | 固体高分子型燃料電池用の膜電極接合体とその製造方法および固体高分子型燃料電池 |
| CN103015036B (zh) * | 2012-12-27 | 2015-05-06 | 东南大学 | 一种马赛克型纳米膜 |
| KR101995527B1 (ko) * | 2012-12-28 | 2019-07-02 | 코오롱인더스트리 주식회사 | 연료전지용 강화복합막 및 이를 포함하는 연료전지용 막-전극 어셈블리 |
| US9371423B2 (en) | 2013-07-09 | 2016-06-21 | General Electric Company | Methods and apparatus for crosslinking a silicon carbide fiber precursor polymer |
| US20160181643A1 (en) * | 2013-08-06 | 2016-06-23 | Audi Ag | Method for fabricating electrolyte membrane using in-situ cross-linking |
| US10333176B2 (en) * | 2013-08-12 | 2019-06-25 | The University Of Akron | Polymer electrolyte membranes for rechargeable batteries |
| KR102098639B1 (ko) * | 2013-09-30 | 2020-04-08 | 코오롱인더스트리 주식회사 | 고분자 전해질막, 이의 제조 방법 및 이를 포함하는 막-전극 어셈블리 |
| KR101833600B1 (ko) | 2013-10-25 | 2018-02-28 | 파나소닉 아이피 매니지먼트 가부시키가이샤 | 연료 전지용의 전해질막 및 그 제조 방법, 및 막전극 접합체 및 연료 전지 |
| KR101541967B1 (ko) * | 2013-11-22 | 2015-08-05 | 경희대학교 산학협력단 | 폴리비닐리덴 플루오라이드 및 부분술폰화 폴리아릴렌계 고분자의 혼합용액을 전기방사하여 제조되는 압전센서 및 나노발전 기능을 갖는 새로운 나노섬유 웹 |
| WO2015083546A1 (ja) * | 2013-12-03 | 2015-06-11 | 日本バルカー工業株式会社 | 電気化学素子用複合膜 |
| WO2015088579A1 (en) | 2013-12-09 | 2015-06-18 | General Electric Company | Polymeric-metal composite electrode-based electrochemical device for generating oxidants |
| KR101485119B1 (ko) * | 2014-02-12 | 2015-01-22 | 광주과학기술원 | 전기방사를 이용한 개선된 폴리에테르설폰 나노섬유 멤브레인의 제조방법 |
| KR20150097024A (ko) * | 2014-02-17 | 2015-08-26 | 삼성에스디아이 주식회사 | 고분자 전해질막, 이를 포함하는 막전극 접합체 및 연료전지 |
| US9425461B2 (en) * | 2014-04-17 | 2016-08-23 | Los Alamos National Security, Llc | Rejuvenation of automotive fuel cells |
| US20160161433A1 (en) * | 2014-05-16 | 2016-06-09 | Massachusetts Institute Of Technology | Electrospun Polymer Fibers for Gas Sensing |
| EP3162387B1 (en) * | 2014-06-27 | 2021-06-09 | St1 Co., Ltd. | Nano-fiber mat, method for manufacturing same, and use thereof as cell culture mat or guided bone regeneration shielding membrane |
| GB201413794D0 (en) * | 2014-08-04 | 2014-09-17 | Johnson Matthey Fuel Cells Ltd And Universit� De Montpellier Ii And Ct Nat De La Rech Scient | Membrane |
| CN107112561A (zh) * | 2014-12-24 | 2017-08-29 | 3M创新有限公司 | 电化学装置中的多孔粘合剂网络 |
| CN104681834A (zh) * | 2015-02-05 | 2015-06-03 | 成都新柯力化工科技有限公司 | 一种角蛋白燃料电池质子交换膜及制备方法 |
| JP6483511B2 (ja) * | 2015-04-14 | 2019-03-13 | 日本バイリーン株式会社 | ポリエーテルスルホン系繊維集合体及びその製造方法 |
| KR102619769B1 (ko) | 2015-05-26 | 2024-01-02 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 산소 발생 촉매 전극을 갖는 전극막 조립체, 이의 제조 방법 및 사용 방법 |
| CN105514466B (zh) * | 2016-01-13 | 2018-03-09 | 山东星火科学技术研究院 | 一种负载多元催化剂的甲醇燃料电池质子交换膜的制备方法 |
| CA3013441C (en) * | 2016-02-18 | 2022-09-20 | Toray Industries, Inc. | Composite polymer electrolyte membrane, and membrane electrode assembly and solid polymer fuel cell using same |
| JP6792952B2 (ja) * | 2016-03-31 | 2020-12-02 | 旭化成株式会社 | 多孔質膜及び固体高分子型燃料電池用電解質膜 |
| KR101956169B1 (ko) | 2016-05-24 | 2019-03-08 | 한양대학교 산학협력단 | 자기-가습성 이온교환 복합막 및 그 제조방법 |
| JP2019525387A (ja) * | 2016-06-17 | 2019-09-05 | スリーエム イノベイティブ プロパティズ カンパニー | イオン交換膜及びその製造方法、膜電極接合体、並びにレドックスフロー電池 |
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| JP6327759B2 (ja) * | 2016-10-28 | 2018-05-23 | 公立大学法人首都大学東京 | 高分子電解質膜及び燃料電池 |
| KR102563567B1 (ko) * | 2016-12-28 | 2023-08-03 | 현대자동차주식회사 | 연료전지용 고분자 전해질막 및 그 제조방법 |
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| WO2019025897A1 (en) | 2017-07-31 | 2019-02-07 | 3M Innovative Properties Company | MEMBRANE |
| JP6999411B2 (ja) * | 2017-12-26 | 2022-01-18 | 旭化成株式会社 | 複合高分子電解質膜 |
| US12034180B1 (en) * | 2018-01-09 | 2024-07-09 | Oceanit Laboratories, Inc. | Multi layered nanostructured materials for ionic and electronic transport in chemical and electrochemical devices |
| CA3091102A1 (en) * | 2018-03-29 | 2019-10-03 | Toray Industries, Inc. | Composite electrolyte membrane |
| JP7265367B2 (ja) * | 2019-02-05 | 2023-04-26 | 旭化成株式会社 | 高分子電解質膜 |
| CN110534779B (zh) * | 2019-08-21 | 2021-02-02 | 清华大学 | 一种非氟聚合物增强型膜电极及其制备方法 |
| JP7607414B2 (ja) | 2020-07-09 | 2024-12-27 | 旭化成株式会社 | 高分子電解質膜、及び固体高分子形燃料電池 |
| DE102020215405A1 (de) | 2020-12-07 | 2022-06-09 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren zur Herstellung einer Membran-Elektroden-Anordnung (MEA), Membran-Elektroden-Anordnung (MEA) sowie Brennstoffzelle |
| US12341227B2 (en) | 2021-06-04 | 2025-06-24 | 3M Innovative Properties Company | Perfluorosulfonyl monomers suitable for fluoropolymers and fuel cell membrane articles |
| WO2022256669A1 (en) | 2021-06-04 | 2022-12-08 | 3M Innovative Properties Company | Fluorinated ionomers, polymer electrolyte membranes, fuel cells, and methods |
| CN113948719B (zh) * | 2021-08-30 | 2023-03-03 | 东风汽车集团股份有限公司 | 一种透气性高的气体扩散层及其制备方法 |
| US12249721B2 (en) | 2022-01-31 | 2025-03-11 | Hydrogenics Corporation | Additive application of microporous layer onto gas diffusion layer |
| GB2624228A (en) | 2022-11-11 | 2024-05-15 | Johnson Matthey Hydrogen Technologies Ltd | Reinforced ion-conducting membrane |
| FR3157685A1 (fr) * | 2023-12-21 | 2025-06-27 | Compagnie Generale Des Etablissements Michelin | Membrane conductrice d’ions et son procédé de préparation par électrofilage d’un polyéthersulfone. |
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| CA2300934C (en) | 1997-08-29 | 2008-08-26 | Foster-Miller, Inc. | Composite solid polymer electrolyte membranes |
| US6090895A (en) | 1998-05-22 | 2000-07-18 | 3M Innovative Properties Co., | Crosslinked ion conductive membranes |
| KR20020063020A (ko) | 2001-01-26 | 2002-08-01 | 한국과학기술연구원 | 미세 섬유상 고분자웹의 제조 방법 |
| US6727386B2 (en) | 2001-10-25 | 2004-04-27 | 3M Innovative Properties Company | Aromatic imide and aromatic methylidynetrissulfonyl compounds and method of making |
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-
2011
- 2011-05-18 WO PCT/US2011/036935 patent/WO2011149732A2/en not_active Ceased
- 2011-05-18 CN CN201180035481.4A patent/CN103004001B/zh active Active
- 2011-05-18 EP EP11721958.4A patent/EP2577787B1/en active Active
- 2011-05-18 JP JP2013512079A patent/JP5798186B2/ja active Active
- 2011-05-18 US US13/699,210 patent/US9893373B2/en active Active
- 2011-05-18 EP EP16191228.2A patent/EP3147982A1/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018155598A1 (ja) | 2017-02-23 | 2018-08-30 | 旭化成株式会社 | 組成物、複合膜、膜電極接合体 |
| WO2018186386A1 (ja) | 2017-04-03 | 2018-10-11 | 旭化成株式会社 | 複合高分子電解質膜 |
| US11705569B2 (en) | 2017-04-03 | 2023-07-18 | Asahi Kasei Kabushiki Kaisha | Composite polymer electrolyte membrane |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2011149732A2 (en) | 2011-12-01 |
| CN103004001A (zh) | 2013-03-27 |
| US20130101918A1 (en) | 2013-04-25 |
| EP3147982A1 (en) | 2017-03-29 |
| EP2577787B1 (en) | 2016-10-05 |
| CN103004001B (zh) | 2016-02-17 |
| JP2013531867A (ja) | 2013-08-08 |
| EP2577787A2 (en) | 2013-04-10 |
| US9893373B2 (en) | 2018-02-13 |
| WO2011149732A3 (en) | 2012-03-01 |
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