JP5628829B2 - ひけが少なく優れた表面外観を有する強化ポリアミド組成物およびその物品 - Google Patents
ひけが少なく優れた表面外観を有する強化ポリアミド組成物およびその物品 Download PDFInfo
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- JP5628829B2 JP5628829B2 JP2011542561A JP2011542561A JP5628829B2 JP 5628829 B2 JP5628829 B2 JP 5628829B2 JP 2011542561 A JP2011542561 A JP 2011542561A JP 2011542561 A JP2011542561 A JP 2011542561A JP 5628829 B2 JP5628829 B2 JP 5628829B2
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- resin composition
- polyamide
- semi
- acid
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- 239000000203 mixture Substances 0.000 title claims description 50
- 239000004952 Polyamide Substances 0.000 title description 24
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- 239000011342 resin composition Substances 0.000 claims description 46
- 229920006114 semi-crystalline semi-aromatic polyamide Polymers 0.000 claims description 29
- 239000011521 glass Substances 0.000 claims description 25
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- 239000012744 reinforcing agent Substances 0.000 claims description 12
- DQTKCIVHDDGAFK-UHFFFAOYSA-N 2-(5,6-dihydro-4H-cyclopenta[d][1,3]dithiol-2-ylidene)-1,3-dithiole-4,5-dithiol Chemical compound S1C(S)=C(S)SC1=C1SC(CCC2)=C2S1 DQTKCIVHDDGAFK-UHFFFAOYSA-N 0.000 claims description 7
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- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 4
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- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
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- 229920000642 polymer Polymers 0.000 description 35
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 24
- -1 4-aminocyclohexyl Chemical group 0.000 description 22
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- 229920000098 polyolefin Polymers 0.000 description 17
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- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 16
- 239000003365 glass fiber Substances 0.000 description 10
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- 239000000178 monomer Substances 0.000 description 9
- 239000005977 Ethylene Substances 0.000 description 8
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 150000004985 diamines Chemical class 0.000 description 7
- JCUZDQXWVYNXHD-UHFFFAOYSA-N 2,2,4-trimethylhexane-1,6-diamine Chemical compound NCCC(C)CC(C)(C)CN JCUZDQXWVYNXHD-UHFFFAOYSA-N 0.000 description 6
- 239000004609 Impact Modifier Substances 0.000 description 6
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 6
- 229920000554 ionomer Polymers 0.000 description 6
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- 125000000217 alkyl group Chemical group 0.000 description 5
- 229920006020 amorphous polyamide Polymers 0.000 description 5
- 239000003963 antioxidant agent Substances 0.000 description 5
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
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- 150000008064 anhydrides Chemical group 0.000 description 4
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- 239000012745 toughening agent Substances 0.000 description 4
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
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- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
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- 239000000126 substance Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- DCTOHCCUXLBQMS-UHFFFAOYSA-N 1-undecene Chemical compound CCCCCCCCCC=C DCTOHCCUXLBQMS-UHFFFAOYSA-N 0.000 description 2
- PBLZLIFKVPJDCO-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 description 2
- DPQHRXRAZHNGRU-UHFFFAOYSA-N 2,4,4-trimethylhexane-1,6-diamine Chemical compound NCC(C)CC(C)(C)CCN DPQHRXRAZHNGRU-UHFFFAOYSA-N 0.000 description 2
- IGSBHTZEJMPDSZ-UHFFFAOYSA-N 4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine Chemical compound C1CC(N)C(C)CC1CC1CC(C)C(N)CC1 IGSBHTZEJMPDSZ-UHFFFAOYSA-N 0.000 description 2
- BDBZTOMUANOKRT-UHFFFAOYSA-N 4-[2-(4-aminocyclohexyl)propan-2-yl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1C(C)(C)C1CCC(N)CC1 BDBZTOMUANOKRT-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- 239000004953 Aliphatic polyamide Substances 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- XLYMOEINVGRTEX-ARJAWSKDSA-N Ethyl hydrogen fumarate Chemical compound CCOC(=O)\C=C/C(O)=O XLYMOEINVGRTEX-ARJAWSKDSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229920003231 aliphatic polyamide Polymers 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
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- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
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- XLYMOEINVGRTEX-UHFFFAOYSA-N fumaric acid monoethyl ester Natural products CCOC(=O)C=CC(O)=O XLYMOEINVGRTEX-UHFFFAOYSA-N 0.000 description 2
- 125000001841 imino group Chemical group [H]N=* 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
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- 150000003951 lactams Chemical class 0.000 description 2
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
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- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
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- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical class [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- GEQHKFFSPGPGLN-UHFFFAOYSA-N cyclohexane-1,3-diamine Chemical compound NC1CCCC(N)C1 GEQHKFFSPGPGLN-UHFFFAOYSA-N 0.000 description 1
- VKIRRGRTJUUZHS-UHFFFAOYSA-N cyclohexane-1,4-diamine Chemical compound NC1CCC(N)CC1 VKIRRGRTJUUZHS-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- WFMPGHGAHVPFKP-UHFFFAOYSA-N dodecane;methanediamine Chemical compound NCN.CCCCCCCCCCCC WFMPGHGAHVPFKP-UHFFFAOYSA-N 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 210000004709 eyebrow Anatomy 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 150000002696 manganese Chemical class 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000002991 molded plastic Substances 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- ZETYUTMSJWMKNQ-UHFFFAOYSA-N n,n',n'-trimethylhexane-1,6-diamine Chemical compound CNCCCCCCN(C)C ZETYUTMSJWMKNQ-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- AJCDFVKYMIUXCR-UHFFFAOYSA-N oxobarium;oxo(oxoferriooxy)iron Chemical compound [Ba]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O AJCDFVKYMIUXCR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 229920006024 semi-aromatic copolyamide Polymers 0.000 description 1
- 229920006134 semi-aromatic non-crystalline polyamide resin Polymers 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000000326 ultraviolet stabilizing agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31859—Next to an aldehyde or ketone condensation product
- Y10T428/3187—Amide-aldehyde
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyamides (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US20357208P | 2008-12-23 | 2008-12-23 | |
| US61/203,572 | 2008-12-23 | ||
| PCT/US2009/069142 WO2010075351A2 (en) | 2008-12-23 | 2009-12-22 | Low sink marks and excellent surface appearance reinforced polyamide compositions |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012513499A JP2012513499A (ja) | 2012-06-14 |
| JP2012513499A5 JP2012513499A5 (enExample) | 2013-02-14 |
| JP5628829B2 true JP5628829B2 (ja) | 2014-11-19 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011542561A Expired - Fee Related JP5628829B2 (ja) | 2008-12-23 | 2009-12-22 | ひけが少なく優れた表面外観を有する強化ポリアミド組成物およびその物品 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8476354B2 (enExample) |
| EP (1) | EP2367884B1 (enExample) |
| JP (1) | JP5628829B2 (enExample) |
| CN (1) | CN102264839B (enExample) |
| WO (1) | WO2010075351A2 (enExample) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010003920A1 (de) * | 2010-04-13 | 2011-10-13 | Evonik Degussa Gmbh | Flexibles Rohr mit höherer Temperaturbeständigkeit |
| BR112013010473A2 (pt) * | 2010-10-29 | 2016-08-02 | Du Pont | estrutura composta, processo de elaboração, processo de acordo e filme |
| KR101466278B1 (ko) | 2010-12-21 | 2014-11-27 | 제일모직 주식회사 | 폴리아미드 수지 조성물 및 이를 이용한 성형품 |
| JP5669623B2 (ja) * | 2011-02-28 | 2015-02-12 | 旭化成ケミカルズ株式会社 | ポリアミド樹脂組成物及び成形品 |
| CN102153857B (zh) * | 2011-03-16 | 2014-03-26 | 金发科技股份有限公司 | 一种高填充良表面的增强聚酰胺组合物 |
| US20130022786A1 (en) | 2011-07-21 | 2013-01-24 | E I Du Pont De Nemours And Company | Device housings having excellent surface appearance |
| CN102719071B (zh) * | 2012-07-02 | 2014-12-10 | 上海锦湖日丽塑料有限公司 | 一种耐翘曲变形的玻纤增强聚碳酸酯树脂及其制备方法 |
| WO2014032252A1 (zh) * | 2012-08-30 | 2014-03-06 | 海能达通信股份有限公司 | 一种电子设备壳体以及电子设备 |
| US20140182875A1 (en) * | 2012-12-28 | 2014-07-03 | Mark Sprenger | Case for an electronic device |
| FR3018280B1 (fr) * | 2014-03-04 | 2017-05-26 | Arkema France | Composition transparente a base de polyamide chargee de verre |
| EP3157987B1 (en) * | 2014-06-20 | 2018-05-16 | Rhodia Operations | Polyamide molding compositions, molded parts obtained therefrom, and use thereof |
| EP3006507B1 (de) * | 2014-10-10 | 2018-12-19 | Ems-Patent Ag | Verstärkte polyamidformmassen sowie daraus hergestellte spritzgussteile |
| JP6787133B2 (ja) * | 2014-10-27 | 2020-11-18 | 宇部興産株式会社 | ポリアミド組成物およびそれからなる成形品 |
| CN104592752A (zh) * | 2014-12-10 | 2015-05-06 | 苏州博利迈新材料科技有限公司 | 高强度尼龙612复合材料及其制备方法、用途 |
| KR101823204B1 (ko) * | 2015-08-24 | 2018-03-09 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
| EP3222649B1 (de) * | 2016-03-23 | 2018-04-18 | Ems-Patent Ag | Hochtemperaturbeständige polyamidformmassen und deren verwendungen insbesondere im automobilbereich |
| CN106398202A (zh) * | 2016-08-31 | 2017-02-15 | 合肥会通新材料有限公司 | 一种聚酰胺工程塑料及其制备方法 |
| EP3444114B1 (de) * | 2017-08-18 | 2023-10-25 | Ems-Chemie Ag | Verstärkte polyamid-formmassen mit geringem haze und formkörper daraus |
| KR101940418B1 (ko) | 2017-10-30 | 2019-01-18 | 롯데첨단소재(주) | 폴리아미드 수지 조성물 및 이를 포함하는 성형품 |
| KR102171421B1 (ko) | 2017-12-31 | 2020-10-29 | 롯데첨단소재(주) | 폴리아미드 수지 조성물 및 이를 포함하는 성형품 |
| US11577496B2 (en) | 2017-12-31 | 2023-02-14 | Lotte Chemical Corporation | Polyamide resin composition and molded article comprising the same |
| KR102198388B1 (ko) | 2018-05-31 | 2021-01-05 | 롯데첨단소재(주) | 폴리아미드 수지 조성물 및 이를 포함하는 성형품 |
| MX2021012287A (es) * | 2019-04-10 | 2022-01-04 | Du Pont | Composiciones de poliamida. |
| WO2020258266A1 (en) * | 2019-06-28 | 2020-12-30 | Arkema France | Use of a reinforced thermoplastic composition |
| EP4118133A1 (en) * | 2020-03-13 | 2023-01-18 | INVISTA Textiles (U.K.) Limited | Thermoplastic resins for network applications |
| CN115298264B (zh) * | 2020-04-09 | 2025-08-05 | 巴斯夫欧洲公司 | 光学元件用聚酰胺组合物 |
| TWI784445B (zh) * | 2021-01-27 | 2022-11-21 | 英商英威達紡織（英國）有限公司 | 包含用於網路應用之熱塑性樹脂的殼體物件、天線系統及通信方法 |
| WO2023037193A1 (en) * | 2021-09-08 | 2023-03-16 | Inv Nylon Polymers Americas, Llc | Articles for use with 5g radio waves |
| EP4413083A4 (en) * | 2021-10-07 | 2025-06-11 | Solvay Specialty Polymers USA, LLC | Electrostatic dissipative polyamide composition and article comprising it |
| GB202115260D0 (en) * | 2021-10-22 | 2021-12-08 | Invista Textiles Uk Ltd | Process for consecutive batch production of polyamide |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61174141A (ja) | 1985-01-25 | 1986-08-05 | Nitto Boseki Co Ltd | ガラス繊維及びその製造方法 |
| EP0196194B1 (en) | 1985-03-23 | 1989-12-27 | Nitto Boseki Co., Ltd. | Glass fiber strand and method of producing the same |
| JPH0689250B2 (ja) * | 1988-11-22 | 1994-11-09 | 豊田合成株式会社 | 強化ナイロン樹脂組成物 |
| JPH10130494A (ja) * | 1996-10-29 | 1998-05-19 | Unitika Ltd | ポリアミド樹脂組成物、これを用いてなる車両用鏡体保持部品及び電気機器筐体部品 |
| AU2002211884A1 (en) * | 2000-10-10 | 2002-04-22 | E.I. Du Pont De Nemours And Company | Translucent polyamide blends |
| JP4240996B2 (ja) * | 2002-10-24 | 2009-03-18 | 宇部興産株式会社 | エンジン冷却水系部品用ポリアミド樹脂組成物及びそれからなる部品 |
| JP4876377B2 (ja) * | 2004-08-05 | 2012-02-15 | 日東紡績株式会社 | 扁平ガラス繊維含有ペレットの製造方法 |
| JP5281735B2 (ja) * | 2006-02-28 | 2013-09-04 | ユニチカ株式会社 | 光反射成形品用ポリアミド樹脂組成物 |
| JP2007315483A (ja) * | 2006-05-25 | 2007-12-06 | Nsk Ltd | スライドドア用転がり軸受 |
| US8859665B2 (en) | 2006-12-05 | 2014-10-14 | E I Du Pont De Nemours And Company | Polyamide housings for portable electronic devices |
| ATE427341T1 (de) | 2006-12-28 | 2009-04-15 | Ems Chemie Ag | Mit flachen glasfasern verstarkte polyamidformmassen sowie daraus hergestellte spritzgussteile |
| JP4946498B2 (ja) * | 2007-02-20 | 2012-06-06 | 日本精工株式会社 | 樹脂製プーリ |
| JP5279415B2 (ja) * | 2007-09-03 | 2013-09-04 | ユニチカ株式会社 | 樹脂組成物およびそれを用いた成形体 |
| JP2008274301A (ja) * | 2008-08-07 | 2008-11-13 | Ube Ind Ltd | エンジン冷却水系部品用ポリアミド樹脂組成物及びそれからなる部品 |
-
2009
- 2009-12-17 US US12/640,086 patent/US8476354B2/en not_active Expired - Fee Related
- 2009-12-22 WO PCT/US2009/069142 patent/WO2010075351A2/en not_active Ceased
- 2009-12-22 EP EP09775076.4A patent/EP2367884B1/en not_active Not-in-force
- 2009-12-22 JP JP2011542561A patent/JP5628829B2/ja not_active Expired - Fee Related
- 2009-12-22 CN CN200980152329.7A patent/CN102264839B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP2367884B1 (en) | 2018-09-26 |
| US20100160008A1 (en) | 2010-06-24 |
| WO2010075351A2 (en) | 2010-07-01 |
| CN102264839B (zh) | 2014-05-07 |
| CN102264839A (zh) | 2011-11-30 |
| US8476354B2 (en) | 2013-07-02 |
| WO2010075351A3 (en) | 2010-08-19 |
| JP2012513499A (ja) | 2012-06-14 |
| EP2367884A2 (en) | 2011-09-28 |
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