CN102264839B - 具有浅缩痕和极佳表面外观的增强聚酰胺组合物 - Google Patents
具有浅缩痕和极佳表面外观的增强聚酰胺组合物 Download PDFInfo
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- CN102264839B CN102264839B CN200980152329.7A CN200980152329A CN102264839B CN 102264839 B CN102264839 B CN 102264839B CN 200980152329 A CN200980152329 A CN 200980152329A CN 102264839 B CN102264839 B CN 102264839B
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- 229910021645 metal ion Inorganic materials 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical class C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- AJCDFVKYMIUXCR-UHFFFAOYSA-N oxobarium;oxo(oxoferriooxy)iron Chemical compound [Ba]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O AJCDFVKYMIUXCR-UHFFFAOYSA-N 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical group CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000007715 potassium iodide Nutrition 0.000 description 1
- 229960004839 potassium iodide Drugs 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001012 protector Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229920006024 semi-aromatic copolyamide Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical class NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31859—Next to an aldehyde or ketone condensation product
- Y10T428/3187—Amide-aldehyde
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyamides (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US20357208P | 2008-12-23 | 2008-12-23 | |
| US61/203572 | 2008-12-23 | ||
| PCT/US2009/069142 WO2010075351A2 (en) | 2008-12-23 | 2009-12-22 | Low sink marks and excellent surface appearance reinforced polyamide compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102264839A CN102264839A (zh) | 2011-11-30 |
| CN102264839B true CN102264839B (zh) | 2014-05-07 |
Family
ID=42199780
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200980152329.7A Expired - Fee Related CN102264839B (zh) | 2008-12-23 | 2009-12-22 | 具有浅缩痕和极佳表面外观的增强聚酰胺组合物 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8476354B2 (enExample) |
| EP (1) | EP2367884B1 (enExample) |
| JP (1) | JP5628829B2 (enExample) |
| CN (1) | CN102264839B (enExample) |
| WO (1) | WO2010075351A2 (enExample) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010003920A1 (de) * | 2010-04-13 | 2011-10-13 | Evonik Degussa Gmbh | Flexibles Rohr mit höherer Temperaturbeständigkeit |
| BR112013010473A2 (pt) * | 2010-10-29 | 2016-08-02 | Du Pont | estrutura composta, processo de elaboração, processo de acordo e filme |
| KR101466278B1 (ko) | 2010-12-21 | 2014-11-27 | 제일모직 주식회사 | 폴리아미드 수지 조성물 및 이를 이용한 성형품 |
| JP5669623B2 (ja) * | 2011-02-28 | 2015-02-12 | 旭化成ケミカルズ株式会社 | ポリアミド樹脂組成物及び成形品 |
| CN102153857B (zh) * | 2011-03-16 | 2014-03-26 | 金发科技股份有限公司 | 一种高填充良表面的增强聚酰胺组合物 |
| US20130022786A1 (en) | 2011-07-21 | 2013-01-24 | E I Du Pont De Nemours And Company | Device housings having excellent surface appearance |
| CN102719071B (zh) * | 2012-07-02 | 2014-12-10 | 上海锦湖日丽塑料有限公司 | 一种耐翘曲变形的玻纤增强聚碳酸酯树脂及其制备方法 |
| WO2014032252A1 (zh) * | 2012-08-30 | 2014-03-06 | 海能达通信股份有限公司 | 一种电子设备壳体以及电子设备 |
| US20140182875A1 (en) * | 2012-12-28 | 2014-07-03 | Mark Sprenger | Case for an electronic device |
| FR3018280B1 (fr) * | 2014-03-04 | 2017-05-26 | Arkema France | Composition transparente a base de polyamide chargee de verre |
| EP3157987B1 (en) * | 2014-06-20 | 2018-05-16 | Rhodia Operations | Polyamide molding compositions, molded parts obtained therefrom, and use thereof |
| EP3006507B1 (de) * | 2014-10-10 | 2018-12-19 | Ems-Patent Ag | Verstärkte polyamidformmassen sowie daraus hergestellte spritzgussteile |
| JP6787133B2 (ja) * | 2014-10-27 | 2020-11-18 | 宇部興産株式会社 | ポリアミド組成物およびそれからなる成形品 |
| CN104592752A (zh) * | 2014-12-10 | 2015-05-06 | 苏州博利迈新材料科技有限公司 | 高强度尼龙612复合材料及其制备方法、用途 |
| KR101823204B1 (ko) * | 2015-08-24 | 2018-03-09 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
| EP3222649B1 (de) * | 2016-03-23 | 2018-04-18 | Ems-Patent Ag | Hochtemperaturbeständige polyamidformmassen und deren verwendungen insbesondere im automobilbereich |
| CN106398202A (zh) * | 2016-08-31 | 2017-02-15 | 合肥会通新材料有限公司 | 一种聚酰胺工程塑料及其制备方法 |
| EP3444114B1 (de) * | 2017-08-18 | 2023-10-25 | Ems-Chemie Ag | Verstärkte polyamid-formmassen mit geringem haze und formkörper daraus |
| KR101940418B1 (ko) | 2017-10-30 | 2019-01-18 | 롯데첨단소재(주) | 폴리아미드 수지 조성물 및 이를 포함하는 성형품 |
| KR102171421B1 (ko) | 2017-12-31 | 2020-10-29 | 롯데첨단소재(주) | 폴리아미드 수지 조성물 및 이를 포함하는 성형품 |
| US11577496B2 (en) | 2017-12-31 | 2023-02-14 | Lotte Chemical Corporation | Polyamide resin composition and molded article comprising the same |
| KR102198388B1 (ko) | 2018-05-31 | 2021-01-05 | 롯데첨단소재(주) | 폴리아미드 수지 조성물 및 이를 포함하는 성형품 |
| MX2021012287A (es) * | 2019-04-10 | 2022-01-04 | Du Pont | Composiciones de poliamida. |
| WO2020258266A1 (en) * | 2019-06-28 | 2020-12-30 | Arkema France | Use of a reinforced thermoplastic composition |
| EP4118133A1 (en) * | 2020-03-13 | 2023-01-18 | INVISTA Textiles (U.K.) Limited | Thermoplastic resins for network applications |
| CN115298264B (zh) * | 2020-04-09 | 2025-08-05 | 巴斯夫欧洲公司 | 光学元件用聚酰胺组合物 |
| TWI784445B (zh) * | 2021-01-27 | 2022-11-21 | 英商英威達紡織(英國)有限公司 | 包含用於網路應用之熱塑性樹脂的殼體物件、天線系統及通信方法 |
| WO2023037193A1 (en) * | 2021-09-08 | 2023-03-16 | Inv Nylon Polymers Americas, Llc | Articles for use with 5g radio waves |
| EP4413083A4 (en) * | 2021-10-07 | 2025-06-11 | Solvay Specialty Polymers USA, LLC | Electrostatic dissipative polyamide composition and article comprising it |
| GB202115260D0 (en) * | 2021-10-22 | 2021-12-08 | Invista Textiles Uk Ltd | Process for consecutive batch production of polyamide |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002031053A2 (en) * | 2000-10-10 | 2002-04-18 | E.I. Du Pont De Nemours And Company | Translucent polyamide blends |
| EP1413604A1 (en) * | 2002-10-24 | 2004-04-28 | Ube Industries, Ltd. | Polyamide resin composition for part of engine cooling water system and part comprising the same |
| JP2008202693A (ja) * | 2007-02-20 | 2008-09-04 | Nsk Ltd | 樹脂製プーリ |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61174141A (ja) | 1985-01-25 | 1986-08-05 | Nitto Boseki Co Ltd | ガラス繊維及びその製造方法 |
| EP0196194B1 (en) | 1985-03-23 | 1989-12-27 | Nitto Boseki Co., Ltd. | Glass fiber strand and method of producing the same |
| JPH0689250B2 (ja) * | 1988-11-22 | 1994-11-09 | 豊田合成株式会社 | 強化ナイロン樹脂組成物 |
| JPH10130494A (ja) * | 1996-10-29 | 1998-05-19 | Unitika Ltd | ポリアミド樹脂組成物、これを用いてなる車両用鏡体保持部品及び電気機器筐体部品 |
| JP4876377B2 (ja) * | 2004-08-05 | 2012-02-15 | 日東紡績株式会社 | 扁平ガラス繊維含有ペレットの製造方法 |
| JP5281735B2 (ja) * | 2006-02-28 | 2013-09-04 | ユニチカ株式会社 | 光反射成形品用ポリアミド樹脂組成物 |
| JP2007315483A (ja) * | 2006-05-25 | 2007-12-06 | Nsk Ltd | スライドドア用転がり軸受 |
| US8859665B2 (en) | 2006-12-05 | 2014-10-14 | E I Du Pont De Nemours And Company | Polyamide housings for portable electronic devices |
| ATE427341T1 (de) | 2006-12-28 | 2009-04-15 | Ems Chemie Ag | Mit flachen glasfasern verstarkte polyamidformmassen sowie daraus hergestellte spritzgussteile |
| JP5279415B2 (ja) * | 2007-09-03 | 2013-09-04 | ユニチカ株式会社 | 樹脂組成物およびそれを用いた成形体 |
| JP2008274301A (ja) * | 2008-08-07 | 2008-11-13 | Ube Ind Ltd | エンジン冷却水系部品用ポリアミド樹脂組成物及びそれからなる部品 |
-
2009
- 2009-12-17 US US12/640,086 patent/US8476354B2/en not_active Expired - Fee Related
- 2009-12-22 WO PCT/US2009/069142 patent/WO2010075351A2/en not_active Ceased
- 2009-12-22 EP EP09775076.4A patent/EP2367884B1/en not_active Not-in-force
- 2009-12-22 JP JP2011542561A patent/JP5628829B2/ja not_active Expired - Fee Related
- 2009-12-22 CN CN200980152329.7A patent/CN102264839B/zh not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002031053A2 (en) * | 2000-10-10 | 2002-04-18 | E.I. Du Pont De Nemours And Company | Translucent polyamide blends |
| EP1413604A1 (en) * | 2002-10-24 | 2004-04-28 | Ube Industries, Ltd. | Polyamide resin composition for part of engine cooling water system and part comprising the same |
| JP2008202693A (ja) * | 2007-02-20 | 2008-09-04 | Nsk Ltd | 樹脂製プーリ |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2367884B1 (en) | 2018-09-26 |
| US20100160008A1 (en) | 2010-06-24 |
| WO2010075351A2 (en) | 2010-07-01 |
| JP5628829B2 (ja) | 2014-11-19 |
| CN102264839A (zh) | 2011-11-30 |
| US8476354B2 (en) | 2013-07-02 |
| WO2010075351A3 (en) | 2010-08-19 |
| JP2012513499A (ja) | 2012-06-14 |
| EP2367884A2 (en) | 2011-09-28 |
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