JP5605259B2 - 多層プリント配線板の層間絶縁用樹脂組成物、接着フィルム及びプリプレグ - Google Patents
多層プリント配線板の層間絶縁用樹脂組成物、接着フィルム及びプリプレグ Download PDFInfo
- Publication number
- JP5605259B2 JP5605259B2 JP2011031858A JP2011031858A JP5605259B2 JP 5605259 B2 JP5605259 B2 JP 5605259B2 JP 2011031858 A JP2011031858 A JP 2011031858A JP 2011031858 A JP2011031858 A JP 2011031858A JP 5605259 B2 JP5605259 B2 JP 5605259B2
- Authority
- JP
- Japan
- Prior art keywords
- resin composition
- resin
- component
- insulating layer
- printed wiring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011342 resin composition Substances 0.000 title claims description 122
- 239000002313 adhesive film Substances 0.000 title claims description 45
- 239000011229 interlayer Substances 0.000 title description 7
- 238000009413 insulation Methods 0.000 title description 3
- 229920005989 resin Polymers 0.000 claims description 68
- 239000011347 resin Substances 0.000 claims description 68
- 229920000647 polyepoxide Polymers 0.000 claims description 64
- 239000003822 epoxy resin Substances 0.000 claims description 59
- 239000004020 conductor Substances 0.000 claims description 39
- 238000000034 method Methods 0.000 claims description 38
- 239000011256 inorganic filler Substances 0.000 claims description 34
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 34
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 29
- 239000004593 Epoxy Substances 0.000 claims description 21
- 238000007788 roughening Methods 0.000 claims description 20
- 125000003118 aryl group Chemical group 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 238000010030 laminating Methods 0.000 claims description 19
- 125000003700 epoxy group Chemical group 0.000 claims description 18
- 238000007747 plating Methods 0.000 claims description 17
- 230000009477 glass transition Effects 0.000 claims description 15
- 238000005259 measurement Methods 0.000 claims description 12
- 239000000758 substrate Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 11
- 239000000155 melt Substances 0.000 claims description 11
- 239000007800 oxidant agent Substances 0.000 claims description 11
- 239000013034 phenoxy resin Substances 0.000 claims description 10
- 229920006287 phenoxy resin Polymers 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 9
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 8
- 239000011354 acetal resin Substances 0.000 claims description 8
- 229920006324 polyoxymethylene Polymers 0.000 claims description 8
- 230000003014 reinforcing effect Effects 0.000 claims description 8
- 229920001187 thermosetting polymer Polymers 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- 239000004962 Polyamide-imide Substances 0.000 claims description 7
- 238000005553 drilling Methods 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 229920002312 polyamide-imide Polymers 0.000 claims description 7
- 229920006122 polyamide resin Polymers 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- 239000012756 surface treatment agent Substances 0.000 claims description 2
- 239000004821 Contact adhesive Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 97
- 239000002966 varnish Substances 0.000 description 28
- 238000001723 curing Methods 0.000 description 24
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- -1 phosphine compound Chemical class 0.000 description 13
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 12
- 229920003986 novolac Polymers 0.000 description 11
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 10
- 238000003475 lamination Methods 0.000 description 10
- 238000001035 drying Methods 0.000 description 9
- 239000003960 organic solvent Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 description 7
- 239000005020 polyethylene terephthalate Substances 0.000 description 7
- 230000001681 protective effect Effects 0.000 description 7
- 239000000377 silicon dioxide Substances 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229920001155 polypropylene Polymers 0.000 description 6
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 5
- 238000007772 electroless plating Methods 0.000 description 5
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 5
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000011049 filling Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000013557 residual solvent Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
- JYLNVJYYQQXNEK-UHFFFAOYSA-N 3-amino-2-(4-chlorophenyl)-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(CN)C1=CC=C(Cl)C=C1 JYLNVJYYQQXNEK-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000011889 copper foil Substances 0.000 description 2
- 229930003836 cresol Natural products 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 238000013007 heat curing Methods 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 239000012286 potassium permanganate Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000000930 thermomechanical effect Effects 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 1
- DJOYTAUERRJRAT-UHFFFAOYSA-N 2-(n-methyl-4-nitroanilino)acetonitrile Chemical compound N#CCN(C)C1=CC=C([N+]([O-])=O)C=C1 DJOYTAUERRJRAT-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 description 1
- ULKLGIFJWFIQFF-UHFFFAOYSA-N 5K8XI641G3 Chemical compound CCC1=NC=C(C)N1 ULKLGIFJWFIQFF-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- 229920001665 Poly-4-vinylphenol Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- OJMOMXZKOWKUTA-UHFFFAOYSA-N aluminum;borate Chemical compound [Al+3].[O-]B([O-])[O-] OJMOMXZKOWKUTA-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 229910021523 barium zirconate Inorganic materials 0.000 description 1
- DQBAOWPVHRWLJC-UHFFFAOYSA-N barium(2+);dioxido(oxo)zirconium Chemical compound [Ba+2].[O-][Zr]([O-])=O DQBAOWPVHRWLJC-UHFFFAOYSA-N 0.000 description 1
- 229910002115 bismuth titanate Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AOWKSNWVBZGMTJ-UHFFFAOYSA-N calcium titanate Chemical compound [Ca+2].[O-][Ti]([O-])=O AOWKSNWVBZGMTJ-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- AFEQENGXSMURHA-UHFFFAOYSA-N oxiran-2-ylmethanamine Chemical compound NCC1CO1 AFEQENGXSMURHA-UHFFFAOYSA-N 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63H—MARINE PROPULSION OR STEERING
- B63H21/00—Use of propulsion power plant or units on vessels
- B63H21/21—Control means for engine or transmission, specially adapted for use on marine vessels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4644—Manufacturing multilayer circuits by building the multilayer layer by layer, i.e. build-up multilayer circuits
- H05K3/4661—Adding a circuit layer by direct wet plating, e.g. electroless plating; insulating materials adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63H—MARINE PROPULSION OR STEERING
- B63H21/00—Use of propulsion power plant or units on vessels
- B63H21/12—Use of propulsion power plant or units on vessels the vessels being motor-driven
- B63H21/14—Use of propulsion power plant or units on vessels the vessels being motor-driven relating to internal-combustion engines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D45/00—Electrical control not provided for in groups F02D41/00 - F02D43/00
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/02—Fillers; Particles; Fibers; Reinforcement materials
- H05K2201/0203—Fillers and particles
- H05K2201/0206—Materials
- H05K2201/0209—Inorganic, non-metallic particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/901—Printed circuit
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31515—As intermediate layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31515—As intermediate layer
- Y10T428/31518—Next to glass or quartz
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31515—As intermediate layer
- Y10T428/31522—Next to metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31525—Next to glass or quartz
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31529—Next to metal
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- Ocean & Marine Engineering (AREA)
- Production Of Multi-Layered Print Wiring Board (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Epoxy Resins (AREA)
- Reinforced Plastic Materials (AREA)
- Adhesive Tapes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
(A)1分子中に2以上のエポキシ基を有し、温度20℃で液状であるエポキシ樹脂、
(B)1分子中に3以上のエポキシ基を有し、エポキシ当量が200以下である芳香族系エポキシ樹脂、
(C)フェノール系硬化剤、
(D)ガラス転移温度が100℃以上である、フェノキシ樹脂、ポリビニルアセタール樹脂、ポリアミド樹脂およびポリアミドイミド樹脂からなる群より選ばれる一種以上の樹脂、及び
(E)無機充填材
を含み、無機充填材(E)の含有割合が樹脂組成物の35重量%以上であり、成分(A)と成分(B)のエポキシ樹脂の割合が重量比で1:0.3乃至1:2であり、樹脂組成物中のエポキシ基と成分(C)のフェノール系硬化剤のフェノール性水酸基の割合が1:0.5乃至1:1.5であり、成分(D)の樹脂の含有割合が樹脂組成物の2乃至20重量%である多層プリント配線板の層間絶縁用樹脂組成物。
[2] 下記成分(A)〜(E):
(A)1分子中に2以上のエポキシ基を有し、温度20℃で液状であるエポキシ樹脂、
(B)1分子中に3以上のエポキシ基を有し、エポキシ当量が200以下である芳香族系エポキシ樹脂、
(C)フェノール系硬化剤、
(D)ガラス転移温度が100℃以上である、フェノキシ樹脂、ポリビニルアセタール樹脂、ポリアミド樹脂およびポリアミドイミド樹脂からなる群より選ばれる一種以上の樹脂、及び
(E)無機充填材
を含み、無機充填材(E)の含有割合が樹脂組成物の40重量%以上であり、成分(A)と成分(B)のエポキシ樹脂の割合が重量比で1:0.3乃至1:2であり、樹脂組成物中のエポキシ基と成分(C)のフェノール系硬化剤のフェノール性水酸基の割合が1:0.5乃至1:1.5であり、成分(D)の樹脂の含有割合が樹脂組成物の2乃至20重量%である多層プリント配線板の層間絶縁用樹脂組成物。
[3] 成分(A)のエポキシ樹脂が芳香族系エポキシ樹脂である[1]又は[2]記載の樹脂組成物。
[4] 成分(B)の芳香族系エポキシ樹脂のエポキシ当量が150〜200である[1]又は[2]記載の樹脂組成物。
[5] 成分(B)の芳香族系エポキシ樹脂が20℃で固体である芳香族系エポキシ樹脂である[1]又は[2]記載の樹脂組成物。
[6] 成分(E)の無機充填材の含有割合が樹脂組成物の35乃至70重量%である[1]記載の樹脂組成物。
[7] 成分(E)の無機充填材の含有割合が樹脂組成物の40乃至70重量%である[2]記載の樹脂組成物。
[8] 樹脂組成物中の成分(A)と成分(B)の合計量が10〜50重量%である[1]又は[2]記載の樹脂組成物。
[9] [1]乃至[8]記載の樹脂組成物からなる樹脂組成物層が支持フィルム上に形成されている多層プリント配線板用の接着フィルム。
[10] 樹脂組成物が、これを測定開始温度60℃、昇温速度5℃/分及び振動数1Hz/degで動的粘弾性を測定した場合の溶融粘度が、90℃で4,000乃至50,000ポイズ、100℃で2,000乃至21,000ポイズ、110℃で900乃至12,000ポイズ、120℃で500乃至9,000ポイズ、130℃で300乃至15,000である[9]記載の接着フィルム。
[11] [1]乃至[8]記載の樹脂組成物が繊維からなるシート状補強基材中に含浸されていることを特徴とする多層プリント配線板用のプリプレグ。
[12] [1]乃至[8]記載の樹脂組成物の硬化物により絶縁層が形成されている多層プリント配線板。
[13] [11]記載のプリプレグの硬化物により絶縁層が形成されている多層プリント配線板。
[14] 下記の工程(a)乃至(g)を含むことを特徴とする多層プリント配線板の製造方法:
(a)[9]記載の接着フィルムを回路基板の片面又は両面にラミネートし、支持フィルムを剥離するか又は剥離しない工程、
(b)ラミネートされた樹脂組成物を熱硬化し絶縁層を形成する工程、
(c)支持フィルムが存在する場合に該支持フィルムを剥離する行程、
(d)絶縁層が形成された回路基板に穴あけする行程、
(e)絶縁層の表面を酸化剤により粗化処理する工程、
(f)粗化された絶縁層の表面にめっきにより導体層を形成させる工程、および
(g)導体層に回路形成する工程。
[15] 下記の工程(h)乃至(m)を含むことを特徴とする多層プリント配線板の製造方法。
(h)[11]記載のプリプレグを回路基板の片面又は両面にラミネートする工程、
(i)ラミネートされたプリプレグを熱硬化し絶縁層を形成する工程、
(j)絶縁層が形成された回路基板に穴あけする行程、
(k)絶縁層の表面を酸化剤により粗化処理する工程、
(l)粗化された絶縁層の表面にめっきにより導体層を形成させる工程、および
(m)導体層に回路形成する工程。
次に、樹脂ワニスをポリエチレンテレフタレート(厚さ38μm、以下PETと略す)上に、乾燥後の樹脂厚みが70μmとなるようにダイコーターにて塗布し、80〜120℃(平均100℃)で6分間乾燥した(残留溶媒量約1重量%)。次いで樹脂組成物の表面に厚さ15μmのポリプロピレンフィルムを貼り合わせながらロール状に巻き取った。ロール状の接着フィルムを幅507mmにスリット(slit)し、これより507×336mmサイズのシート状の接着フィルムを得た。
次に、樹脂ワニスを実施例1と同様にPET上に、乾燥後の樹脂厚みが70μmとなるようにダイコーターにて塗布し、80〜120℃(平均100℃)で6分間乾燥した(残留溶媒量約2重量%)。次いで樹脂組成物の表面に厚さ15μmのポリプロピレンフィルムを貼り合わせながらロール状に巻き取った。ロール状の接着フィルムを幅507mmにスリットし、これより507×336mmサイズのシート状の接着フィルムを得た。
次に、樹脂ワニスをPET(厚さ38μm)上に、乾燥後の樹脂厚みが70μmとなるようにダイコーターにて塗布し、80〜120℃(平均100℃)で6分間乾燥した(残留溶媒量約1重量%)。次いで樹脂組成物の表面に厚さ15μmのポリプロピレンフィルムを貼り合わせながらロール状に巻き取った。ロール状の接着フィルムを幅507mmにスリット(slit)し、これより507×336mmサイズのシート状の接着フィルムを得た。
液状ビスフエノールF型エポキシ樹脂(エポキシ当量170、ジャパンエポキシレジン(株)製 「エピコート807」)20部、クレゾールノボラック型エポキシ樹脂(エポキシ当量210、大日本インキ化学工業(株)製「N673」)12部をMEK10部、シクロヘキサノン10部に撹拝しながら加熱溶解させた。そこへトリアジン構造含有フェノールノボラック樹脂のMEKワニス(大日本インキ化学工業(株)製「フェノライトLA−7052」)25重量、フェノキシ樹脂ワニス(不揮発分35重量%、東都化成(株)製「YB−50−EK35」、ガラス転位温度84℃)23部、さらに球型シリカ60部(平均粒径1μm、アミノシラン処理)を添加し樹脂ワニスを作製した(樹脂ワニスの不揮発分に対する無機充填材含有量52重量%)。
次に樹脂ワニスを実施例1と同様にPET上に、乾燥後の樹脂厚みが70μmとなるようにダイコーターにて塗布し、80〜120℃(平均100℃)で6分間乾燥した。(残留溶媒量約1重量%)次いで樹脂組成物の表面に厚さ15μmのポリプロピレンフィルムを貼り合わせながらロール状に巻き取った。ロール状の接着フィルムを幅507mmにスリットし、これより507×336mmサイズのシート状の接着フィルムを得た。
比較例1で得られた接着フィルムを用いて実施例5と同様にして4層プリント配線板を得た。得られた導体層の導体めっき厚は約30μmであり、スルーホールは完全に樹脂充填されており、導体層のピール強度は0.4kgf/cmであった。
実施例5、6及び比較例2における粗化処理後の樹脂表面をSEM観察した。結果を図1〜3に示す。図1〜3より、実施例5及び6においては粗化処理後、表面に樹脂層が残っているが、比較例2においては粗化処理後、樹脂組成物の硬化物(絶縁層)表面の多くの部分で無機充填剤の球形シリカが剥き出しとなっていることが分かる。
実施例1、2及び比較例1で得られた接着フィルムの樹脂組成物面を180℃で90分熱硬化させた。本サンプルをJIS K7127に準拠し、引張破断強度測定を行った。
実施例1、2及び比較例1で得られた接着フィルムの樹脂組成物面を180℃で90分熱硬化させた。本サンプルを幅約5mm長さ約15mmの試験片とし、理学電機株式会社製熱機械分析装置(TMA)を使用して、引張モードで熱機械分析を行った。荷重1g、昇温速度5℃/分で2回測定した。表2に、2回目の測定における室温(23℃)から150℃までの平均線膨張率を記した。
実施例1で得られた接着フィルムのエポキシ樹脂組成物を(株)ユー・ビー・エム社製型式Rheosol-G3000を用いて、動的粘弾性を測定した。測定結果を図4に示す。測定は初期温度約60℃から昇温速度5℃/分で、測定間隔温度2.5℃、振動数1Hz/degで測定した。表3に各温度における溶融粘度値を以下に示す。
Claims (15)
- 下記成分(A)〜(E):
(A)1分子中に2以上のエポキシ基を有し、温度20℃で液状であるエポキシ樹脂、
(B)1分子中に3以上のエポキシ基を有し、エポキシ当量が200以下である芳香族系エポキシ樹脂、
(C)フェノール系硬化剤、
(D)ガラス転移温度が100℃以上である、フェノキシ樹脂、ポリビニルアセタール樹脂、ポリアミド樹脂およびポリアミドイミド樹脂からなる群より選ばれる一種以上の樹脂、及び
(E)無機充填材
を含み、無機充填材(E)の含有割合が樹脂組成物の35重量%以上であり、成分(A)
と成分(B)のエポキシ樹脂の割合が重量比で1:0.3乃至1:2であり、樹脂組成物中のエポキシ基と成分(C)のフェノール系硬化剤のフェノール性水酸基の割合が1:0.5乃至1:1.5であり、成分(D)の樹脂の含有割合が樹脂組成物の2乃至20重量%である、めっきで導体層を形成する多層プリント配線板の絶縁層形成用樹脂組成物。 - 成分(E)の無機充填材が表面処理剤で表面処理してある請求項1記載の樹脂組成物。
- 成分(E)の無機充填材がシランカップリング剤で表面処理してある請求項1記載の樹脂組成物。
- 成分(A)のエポキシ樹脂が芳香族系エポキシ樹脂である請求項1記載の樹脂組成物。
- 成分(B)の芳香族系エポキシ樹脂のエポキシ当量が150〜200である請求項1記載の樹脂組成物。
- 成分(B)の芳香族系エポキシ樹脂が20℃で固体である芳香族系エポキシ樹脂である請求項1記載の樹脂組成物。
- 成分(E)の無機充填材の含有割合が樹脂組成物の35乃至75重量%である請求項1記載の樹脂組成物。
- 成分(E)の無機充填材の含有割合が樹脂組成物の40乃至75重量%である請求項1記載の樹脂組成物。
- 樹脂組成物中の成分(A)と成分(B)の合計量が10〜50重量%である請求項1記載の樹脂組成物。
- 請求項1乃至9のいずれか1項記載の樹脂組成物からなる樹脂組成物層が支持フィルム上に形成されている多層プリント配線板用の接着フィルムであって、
樹脂組成物が、これを測定開始温度60℃、昇温速度5℃/分及び振動数1Hz/degで動的粘弾性を測定した場合の溶融粘度が、90℃で4,000乃至50,000ポイズ、100℃で2,000乃至21,000ポイズ、110℃で900乃至12,000ポイズ、120℃で500乃至9,000ポイズ、130℃で300乃至15,000である接着フィルム。 - 請求項1乃至9のいずれか1項記載の樹脂組成物が繊維からなるシート状補強基材中に含浸されていることを特徴とする多層プリント配線板用のプリプレグ。
- 請求項1乃至9のいずれか1項記載の樹脂組成物の硬化物により絶縁層が形成されている多層プリント配線板。
- 請求項11記載のプリプレグの硬化物により絶縁層が形成されている多層プリント配線板。
- 下記の工程(a)乃至(g)を含むことを特徴とする多層プリント配線板の製造方法:
(a)請求項10記載の接着フィルムを回路基板の片面又は両面にラミネートし、支持フィルムを剥離するか又は剥離しない工程、
(b)ラミネートされた樹脂組成物を熱硬化し絶縁層を形成する工程、
(c)支持フィルムが存在する場合に該支持フィルムを剥離する行程、
(d)絶縁層が形成された回路基板に穴あけする行程、
(e)絶縁層の表面を酸化剤により粗化処理する工程、
(f)粗化された絶縁層の表面にめっきにより導体層を形成させる工程、および
(g)導体層に回路形成する工程。 - 下記の工程(h)乃至(m)を含むことを特徴とする多層プリント配線板の製造方法。
(h)請求項11記載のプリプレグを回路基板の片面又は両面にラミネートする工程、
(i)ラミネートされたプリプレグを熱硬化し絶縁層を形成する工程、
(j)絶縁層が形成された回路基板に穴あけする行程、
(k)絶縁層の表面を酸化剤により粗化処理する工程、
(l)粗化された絶縁層の表面にめっきにより導体層を形成させる工程、および
(m)導体層に回路形成する工程。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011031858A JP5605259B2 (ja) | 2003-05-27 | 2011-02-17 | 多層プリント配線板の層間絶縁用樹脂組成物、接着フィルム及びプリプレグ |
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003149583 | 2003-05-27 | ||
JP2003149583 | 2003-05-27 | ||
JP2003377301 | 2003-11-06 | ||
JP2003377301 | 2003-11-06 | ||
JP2011031858A JP5605259B2 (ja) | 2003-05-27 | 2011-02-17 | 多層プリント配線板の層間絶縁用樹脂組成物、接着フィルム及びプリプレグ |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004158247A Division JP4725704B2 (ja) | 2003-05-27 | 2004-05-27 | 多層プリント配線板の層間絶縁用樹脂組成物、接着フィルム及びプリプレグ |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2011140652A JP2011140652A (ja) | 2011-07-21 |
JP5605259B2 true JP5605259B2 (ja) | 2014-10-15 |
Family
ID=33566712
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2011031858A Expired - Lifetime JP5605259B2 (ja) | 2003-05-27 | 2011-02-17 | 多層プリント配線板の層間絶縁用樹脂組成物、接着フィルム及びプリプレグ |
Country Status (4)
Country | Link |
---|---|
US (1) | US7179552B2 (ja) |
JP (1) | JP5605259B2 (ja) |
KR (1) | KR101001529B1 (ja) |
TW (1) | TWI335347B (ja) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100688864B1 (ko) * | 2005-02-25 | 2007-03-02 | 삼성전기주식회사 | 인쇄회로기판, 플립칩 볼 그리드 어레이 기판 및 그 제조방법 |
EP1863038B1 (en) * | 2005-03-23 | 2010-09-08 | Murata Manufacturing Co., Ltd. | Composite dielectric sheet, method for manufacturing same and multilayer electronic component |
US7883766B2 (en) | 2005-07-13 | 2011-02-08 | Mitsubishi Rayon Co., Ltd. | Prepreg |
US20070295607A1 (en) * | 2005-11-29 | 2007-12-27 | Ajinomoto Co. Inc | Resin composition for interlayer insulating layer of multi-layer printed wiring board |
TWI410442B (zh) * | 2005-11-29 | 2013-10-01 | Ajinomoto Kk | A resin composition for an insulating layer of a multilayer printed circuit board |
JP2007273583A (ja) * | 2006-03-30 | 2007-10-18 | Toshiba Corp | 部品内蔵プリント配線板、部品内蔵プリント配線板の製造方法および電子機器 |
US20070231581A1 (en) * | 2006-04-03 | 2007-10-04 | Pui-Yan Lin | Epoxy with low coefficient of thermal expansion |
US20090323300A1 (en) * | 2006-04-25 | 2009-12-31 | Daisuke Fujimoto | Conductor Foil with Adhesive Layer, Conductor-Clad Laminate, Printed Wiring Board and Multilayer Wiring Board |
EP2070963B1 (en) * | 2006-09-14 | 2013-04-03 | Panasonic Corporation | Epoxy resin composition for printed wiring board, resin composition varnish, prepreg, metal clad laminate, printed wiring board and multilayer printed wiring board |
US8216668B2 (en) * | 2006-10-06 | 2012-07-10 | Sumitomo Bakelite Company, Ltd. | Resin composition, insulating sheet with base, prepreg, multilayer printed wiring board and semiconductor device |
KR101077435B1 (ko) * | 2007-01-25 | 2011-10-26 | 파나소닉 전공 주식회사 | 프리프레그, 프린트 배선판, 다층 회로 기판, 프린트 배선판의 제조 방법 |
KR101002500B1 (ko) * | 2007-02-06 | 2010-12-17 | 이비덴 가부시키가이샤 | 프린트 배선판 및 그 프린트 배선판의 제조 방법 |
TWI548320B (zh) | 2007-09-11 | 2016-09-01 | Ajinomoto Kk | Manufacturing method of multilayer printed circuit board |
US8163381B2 (en) * | 2007-10-26 | 2012-04-24 | E. I. Du Pont De Nemours And Company | Multi-layer chip carrier and process for making |
CN101836511B (zh) * | 2007-10-26 | 2013-04-03 | 纳幕尔杜邦公司 | 非对称的介电薄膜 |
KR100899720B1 (ko) * | 2008-01-10 | 2009-05-27 | 엘에스엠트론 주식회사 | 다이 접착 필름과 이를 위한 수지 조성물 |
JP5150381B2 (ja) * | 2008-06-20 | 2013-02-20 | 太陽ホールディングス株式会社 | 熱硬化性樹脂組成物 |
JP5344394B2 (ja) * | 2008-07-10 | 2013-11-20 | 山栄化学株式会社 | 硬化性樹脂組成物、並びにハロゲンフリー樹脂基板及びハロゲンフリービルドアッププリント配線板 |
US8039109B2 (en) * | 2008-10-07 | 2011-10-18 | Hexcel Corporation | Epoxy resins with improved burn properties |
US8034453B2 (en) | 2008-10-07 | 2011-10-11 | Hexcel Corporation | Composite materials with improved burn properties |
CN102300936B (zh) * | 2009-03-16 | 2014-03-12 | 东丽株式会社 | 纤维增强树脂组合物、成型材料及纤维增强树脂组合物的制造方法 |
JP5683093B2 (ja) * | 2009-11-13 | 2015-03-11 | 株式会社Adeka | ポリアミド化合物及びそれを含有してなるエポキシ樹脂組成物 |
TW201204548A (en) * | 2010-02-05 | 2012-02-01 | Sumitomo Bakelite Co | Prepreg, laminate, printed wiring board, and semiconductor device |
JP2011249745A (ja) * | 2010-04-28 | 2011-12-08 | Denso Corp | 多層基板 |
US20140370265A1 (en) * | 2011-09-20 | 2014-12-18 | 3M Innovative Properties Company | Composition for preparing a bonding material and uses thereof |
US20130180760A1 (en) * | 2011-09-22 | 2013-07-18 | Hitachi Chemical Company, Ltd. | Laminate body, laminate plate, multilayer laminate plate, printed wiring board, and method for manufacture of laminate plate |
CN103188886B (zh) | 2011-12-31 | 2016-02-03 | 北大方正集团有限公司 | 一种印制电路板及其制作方法 |
JP6353184B2 (ja) * | 2012-07-26 | 2018-07-04 | 味の素株式会社 | 保護フィルム付き接着シート、積層体の製造方法、及びプリント配線板の製造方法 |
JP6291714B2 (ja) * | 2013-03-22 | 2018-03-14 | 味の素株式会社 | 絶縁樹脂シート |
JP2014237811A (ja) * | 2013-05-09 | 2014-12-18 | 住友ベークライト株式会社 | 接着フィルム、接着シート、ダイシングシート一体型接着フィルム、バックグラインドテープ一体型接着フィルム、ダイシングシート兼バックグラインドテープ一体型接着フィルム及び半導体装置 |
KR101513350B1 (ko) | 2013-06-18 | 2015-04-17 | 삼성전기주식회사 | 인쇄회로기판용 절연필름 및 이를 이용한 제품 |
JP2015137299A (ja) * | 2014-01-21 | 2015-07-30 | 住友ベークライト株式会社 | 樹脂組成物、接着シート、ダイシングテープ一体型接着シート、バックグラインドテープ一体型接着シート、バックグラインドテープ兼ダイシングテープ一体型接着シート、および電子装置 |
JP6467774B2 (ja) * | 2014-02-28 | 2019-02-13 | 味の素株式会社 | プリント配線板の製造方法 |
CN103834337B (zh) * | 2014-03-21 | 2015-07-22 | 南京林业大学 | 将普通酚醛树脂转变为快速固化木结构胶粘剂的方法 |
US20170002242A1 (en) * | 2014-05-28 | 2017-01-05 | Toyobo Co., Ltd. | Adhesive composition using polyamide-imide resin |
KR102476862B1 (ko) * | 2014-10-16 | 2022-12-14 | 아지노모토 가부시키가이샤 | 지지체, 접착 시트, 적층 구조체, 반도체 장치 및 프린트 배선판의 제조 방법 |
JP6156479B2 (ja) * | 2015-12-21 | 2017-07-05 | 日立化成株式会社 | 接着フィルム、該接着フィルムを用いた多層プリント配線板、及び該多層プリント配線板の製造方法 |
JP6874350B2 (ja) * | 2016-12-06 | 2021-05-19 | 住友ベークライト株式会社 | 樹脂シート |
JP6801608B2 (ja) * | 2017-08-21 | 2020-12-16 | 味の素株式会社 | 樹脂組成物 |
JP2018027703A (ja) * | 2017-11-13 | 2018-02-22 | 味の素株式会社 | 絶縁樹脂シート |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61197624A (ja) * | 1985-02-27 | 1986-09-01 | Toshiba Corp | 半導体装置封止用エポキシ樹脂組成物 |
EP0379468B1 (de) * | 1989-01-20 | 1995-03-01 | Ciba-Geigy Ag | Härtbare Epoxidharz-Stoffgemische enthaltend einen Thermoplast mit phenolischen Endgruppen |
GB9421405D0 (en) | 1994-10-21 | 1994-12-07 | Dow Chemical Co | Low voc laminating formulations |
JPH0959346A (ja) * | 1995-08-28 | 1997-03-04 | Matsushita Electric Works Ltd | 積層板用エポキシ樹脂組成物 |
ID19337A (id) * | 1996-12-26 | 1998-07-02 | Ajinomoto Kk | Film perekat antar-pelapis untuk papan pembuat kabel cetakan berlapis-banyak dan papan kabel cetakan berlapis-banyak memakai film ini |
JP4117690B2 (ja) | 1996-12-26 | 2008-07-16 | 味の素株式会社 | 多層プリント配線板用接着フィルムを用いた多層プリント配線板の製造方法 |
JP3580352B2 (ja) | 1998-01-22 | 2004-10-20 | 信越化学工業株式会社 | ボール・グリッド・アレイ用液状エポキシ樹脂組成物 |
US7247381B1 (en) * | 1998-08-13 | 2007-07-24 | Hitachi Chemical Company, Ltd. | Adhesive for bonding circuit members, circuit board, and method of producing the same |
JP4423779B2 (ja) * | 1999-10-13 | 2010-03-03 | 味の素株式会社 | エポキシ樹脂組成物並びに該組成物を用いた接着フィルム及びプリプレグ、及びこれらを用いた多層プリント配線板及びその製造法 |
JP2001354936A (ja) * | 2000-06-14 | 2001-12-25 | Sumitomo Bakelite Co Ltd | フレキシブル配線板用接着剤組成物 |
US20040099367A1 (en) * | 2000-06-15 | 2004-05-27 | Shigeo Nakamura | Adhesive film and method for manufacturing multilayer printed wiring board comprising the same |
JP2002023302A (ja) * | 2000-07-12 | 2002-01-23 | Konica Corp | 熱現像記録材料とその処理方法 |
JP2002241590A (ja) * | 2001-02-20 | 2002-08-28 | Ajinomoto Co Inc | 難燃性エポキシ樹脂組成物 |
JP2002309200A (ja) | 2001-04-17 | 2002-10-23 | Ajinomoto Co Inc | 接着フィルム |
JP4725704B2 (ja) * | 2003-05-27 | 2011-07-13 | 味の素株式会社 | 多層プリント配線板の層間絶縁用樹脂組成物、接着フィルム及びプリプレグ |
-
2004
- 2004-05-03 TW TW93112412A patent/TWI335347B/zh not_active IP Right Cessation
- 2004-05-20 US US10/849,171 patent/US7179552B2/en active Active
- 2004-05-21 KR KR1020040036292A patent/KR101001529B1/ko active IP Right Grant
-
2011
- 2011-02-17 JP JP2011031858A patent/JP5605259B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
KR20040101912A (ko) | 2004-12-03 |
US20050008868A1 (en) | 2005-01-13 |
US7179552B2 (en) | 2007-02-20 |
KR101001529B1 (ko) | 2010-12-16 |
JP2011140652A (ja) | 2011-07-21 |
TWI335347B (en) | 2011-01-01 |
TW200504146A (en) | 2005-02-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5605259B2 (ja) | 多層プリント配線板の層間絶縁用樹脂組成物、接着フィルム及びプリプレグ | |
JP4725704B2 (ja) | 多層プリント配線板の層間絶縁用樹脂組成物、接着フィルム及びプリプレグ | |
JP6572983B2 (ja) | エポキシ樹脂組成物 | |
JP4983228B2 (ja) | 多層プリント配線板の絶縁層用樹脂組成物 | |
JP5505435B2 (ja) | 多層プリント配線板の絶縁層用樹脂組成物 | |
JP4992396B2 (ja) | 多層プリント配線板の層間絶縁層用樹脂組成物 | |
JP5573869B2 (ja) | 多層プリント配線板の層間絶縁層用樹脂組成物 | |
JP5381764B2 (ja) | 樹脂組成物 | |
JP5396805B2 (ja) | エポキシ樹脂組成物 | |
JP5733679B2 (ja) | 樹脂組成物 | |
JP5651941B2 (ja) | エポキシ樹脂組成物 | |
JP5298852B2 (ja) | 樹脂組成物 | |
JP5029093B2 (ja) | 樹脂組成物 | |
JP5446866B2 (ja) | エポキシ樹脂組成物 | |
JP5011641B2 (ja) | 熱硬化性樹脂組成物、それを用いた接着フィルム及び多層プリント配線板 | |
JP4400337B2 (ja) | 多層プリント配線板用樹脂組成物および接着フィルム | |
JP2010090237A (ja) | エポキシ樹脂組成物 | |
JPWO2007097209A1 (ja) | エポキシ樹脂組成物 | |
JP2013234328A (ja) | エポキシ樹脂組成物 | |
KR20050001473A (ko) | 다층 인쇄 배선판용 수지 조성물 및 접착 필름 | |
JP5293065B2 (ja) | 樹脂組成物 | |
JPWO2003099952A1 (ja) | 接着フィルム及びプリプレグ | |
JP2002241590A (ja) | 難燃性エポキシ樹脂組成物 | |
JP6269401B2 (ja) | 表面処理無機充填材、該無機充填材の製造方法、および該無機充填材を含有する樹脂組成物 | |
JP5664693B2 (ja) | 樹脂組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130625 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130823 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A132 Effective date: 20131203 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140120 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140729 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140811 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5605259 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |